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By E. Scheepers

Within a phosphorus producing submerged arc furnace it was found that the continuous fluctuation of the furnace between a flowrate-driven state (high throughput) and a thermodynamic-driven state (low throughput) caused both techniques to have similar overall, predictive abilities and resulted in a linear, ARX-type, adaptive prediction model as the model of choice. Secondly, this pre-diction model was developed, tested and then shown to have a reasonable, 8-hour-ahead predictive accuracy (R2, coefficient of determination) of 30% (±6%) on future Pslag values. This inherent relationship exists because, at the precise moment of a Pslag prediction, the furnace already contains the metallurgical memory (input variables to the linear model) needed to ensure that some predictive possibilities will always exists - all as a result of the long residence times in the furnace. Residence time, however, is not a directly adjustable variable but rather a fully dependent variable and a function of an array of interconnected and interactive variables. In fact, this applies to virtually all input variables, reemphasising the importance of innate metallurgical memory. Thirdly, predictive control possibilities were explored by simulating the set-points of two fully independent variables used by operators to control the process: the ratio of fixed carbon-to-P2O5 and the ratio of silica gravel-to-pellets. This linear, predictive control model showed only a slight improvement with an 8-hour-ahead predictive accuracy of 35% (±7%). This highlights how ineffective current adjustments are in optimally steering the process and how difficult even incremental improvements in feed-forward and predictive control can be. Finally, it is shown that fundamental design-, sampling- and process restrictions currently associated with the process will always limit the predictive and especially control accuracy or meaningfulness of any dynamic model. These restrictions include the size of the furnace resulting in long residence times, 8-hours sampling intervals, an extremely complex and interactive process and a 16% spatial analyses variation on the Pslag values ? the very value that the model is to predict. The point is made that, given the current status quo, even the perfect dynamic prediction model can not improve on an 8-hour-ahead prediction of 30% (±6%). This barrier can only be pierced with e.g. tidier and more frequent sampling regimes and other upfront capital investments, a decision that becomes a cost accounting exercise and that can only be taken by the management structure. An investment demanding ever-increasing attention is CFD software and it?s potential to shed more light on the complex interactions within the furnace.

Jan 1, 2014

By Arkady Senchenko, Yury Kulikov

"Basic theoretical grounds of the methods applied for crushing and grinding parameters determination according to international standards are given in this paper. Statistical data about crushability and grindability research are shown. The potential relationship between the values of Fred Bond Work indices and John Starkey indices (Crushing index, Ball mill index, Rod mill index and AG/SAG index) are discussed in this paper. In order to establish correlation between the crushability and grindability indices the analysis of over 2 500 tests for 165 deposits located in different parts of the world was performed. The relationships among different types of energy consumed for crushing and grinding were determined. A method for preliminary estimation of energy consumption in semiautogenous + ball mill grinding circuit is suggested for its application in preliminary technological solutions development and technical-and-economic assessment."

Jan 1, 2014

By T. L. Lee, D. Y. Tan, J. Mi

Considerable progress has been made in studying the mechanism and effectiveness of using ultrasound waves to manipulate alloy solidification microstructure, However, uncertainties remain in both the underlying physics of how microstructure evolve under ultrasonic waves, and the best technological approach to control the final microstructure and properties. We used the ultrafast synchrotron X-ray phase contrast imaging facility housed at the Advanced Photon Source, Argonne National Laboratory, USA to study in-situ the highly transient and dynamic interactions between the liquid metal and ultrasonic waves/bubbles. The dynamics of ultrasonic bubbles in liquid metal and their interactions with the solidifying phases were captured in-situ for the first time. The experiments were complemented by the simulations of the acoustic pressure field, the pulsing of the bubbles and the associated forces acting onto the solidifying phases, providing more quantitative understanding for using ultrasound to control the growth of dendritic grains and to enhance grain multiplication effects for grain refinement.

Jan 1, 2014

By Joseph Kelly, Christopher Kelsey

This revolutionary super-fine crusher has the unique capacity to generate fine and ultra-fine products from single stage reductions of coarse or fine mineral feeds. The crusher consists of a rotating compression chamber and an internal gyrating mandrel. The axis of rotation of the shell is displaced relative to the axis of the vertically mounted mandrel. The inner surface of the compression chamber is machined as double cone frustums at an angle equal to the displacement angle. Crusher feed is accelerated into a compacted particle bed, which lines the inside of the compression chamber. The depth of the compacted bed progressively increases until the mandrel is engaged. The mandrel is then free to rotate with the compression chamber. Continued feeding increases power draw and triggers the counter rotating mandrel gyration drive. The gyrating mandrel delivers multiple compressions at high pressure to the rotating particle bed. High concentrations of energy are harnessed within a small active volume over short retention times. The combination of extraordinarily high power intensity and extreme compressive force results in primary compressive fracture and induced secondary tensile failure. The axially displaced rotation of the compression chamber effectively distributes the breakage forces throughout the particle bed. This paper covers open circuit, pilot trials on magnetite, perlite, garnet, marble and a copper/pyrite concentrate. Particular emphasis is placed on the extraordinary results achieved with trials on zircon and highly refractory fly ash. The extreme duties were deliberately chosen to demonstrate the crusher’s application scope and potential to impact capital operating and maintenance costs as the technology matures. Super-fine crushing, once considered impracticable has the potential to offer compelling options for the generation of ultra-fine products.

Jan 1, 2014

By W. J. Whiten

"Models of cone crushers and vibrating screens are described. These models have been constructed from actual plant data using a systematic model-building technique. Included in this technique is regression analysis using multi-dimensional spline functions.The models have been used to simulate complete crushing plants and hence to design and evaluate a control system for crushing plants."

Jan 1, 2014

"Chairman: Mr R. A. PLUMBRIDGE Rapporteur: Dr D. M. HAWKINSPapers:The relevance of computer methods to the economics of the mineral industry by R: A. PerlmanDynamic control of a mining enterprise by R. G. CoyleAn economic model of the mineral sands industry by G. P. A. HoweMr M. Splaine, in opening the discussion on Mr Perlman's paper, asked whether the model, as fitted by data up to 1963, predicted the rise in the price of copper in 1967, and whether the model could be used to capitalize on short-term price fluctuations.Answering the second question first, Mr Perlman said that the horizon used is six months to one year. In the very short term the activities of speculators obscured the effect of the fundamental econometric variables. This effect, however, was removed if one moved to a longer term, say, quarterly. In 1963 the model had predicted a price rise in 1964 and 1965 and a drop in price in 1966. The rise in 1967 had been caused by a strike, and imponderables such as large strikes were difficult to include in the model since they were unpredictable. Model simulation can be used to show the effect of strikes on price and the effect of small strikes is small.Mr B. R. van Rooyen said that because models are both calibrated and tested on historical data a bias was introduced which gave rise to an overoptimistic estimate of the accuracy of the forecasts. To this Mr Perlman replied that there seemed to be no alternative to the use of historical data for calibrating and testing models, and thus little hope of avoiding the bias. A second point made by Mr. van Rooyen was that manage¬ment tended to be suspicious of complex models and that frequently more heuristic models were sufficiently accurate and preferable for investment decisions. He added that if management were not involved in the model building the econometrician might easily go astray, Mr Perlman replied that symbiosis between data analysts and users of the model was essential and that the experience of the practitioner must be reflected in the model.Mr M. R. Fuller-Good remarked that a clear understanding of future price trends was essential for effective capital planning, and asked, first, how one went from the compiled data on supply and demand to the determination of their effect on price, record, whether necessary data, for example, capacities, could be obtained timeously, and, third, when strikes restricted supply, whether stockpiling by consumers induced large price fluctuations."

Jan 1, 2014

By V. A. Feofanov

Technogenic water of ore mining enterprises, nonferrous metals operations, the enterprises of electroplating and instrument making, containing copper in the form of those or other connections can serve as perspective sources on receiving the copper-bearing raw material. Extraction of copper from the given water also solves a problem of water treating from a toxic component that reduces environmental load at evacuation of water in an open basin. The method of case hardening allows extracting copper selectively with reception of a deposit with the content of copper up to 70%. Weakness of the method is its efficiency basically in acid reduction, and also its low degree of copper extraction. On the basis of case hardening the method of galvanic coagulation is devised. It is based on the work of a short-circuited galvanic cell of iron-coke at variable contact of coupled metals components among themselves, cleared by the oxygen of air. The following processes of galvanic coagulation are considered: ? Extraction of copper; ? Formation ferrites of copper; ? Copper sorption on just-aggregated oxide forms of iron. Establishing conditions for passing the given stages provides an opportunity of copper extraction from technogenic water at any value of ??, content of salt and concentration of copper with reception of a compact deposit from which it is possible to extract copper by the known ways of enrichment and metallurgy. Investigations on optimization and intensification of galvanic coagulation with the purpose of reception the maximum rich deposit on copper have shown that the average contents of copper in a solution of 100~200 mg/dm3 the contents of copper in a deposit is 6%~10% at extraction 85%~90%, depending on characteristics of treated technogenic water. Using methods of scanning microscopy it is determined structures, composition and mechanism of phase formation in investigated electro-chemical process. The second stage of galvanic coagulation increases a degree of copper extraction up to 98%~99% that allows returning the cleared waters in circulation for waste recycling or evacuation in an open basin. Nowadays the method of galvanic coagulation is the most acceptable for copper extraction from technogenic water both from the point of view of efficiency and instrument setting that allows applying the method in conditions of the working enterprises.

Jan 1, 2014

By P. Banerjee, P. Dash, S. Sriramoju, A. Suresh, R. Lingam, T. Ray

"One single property that influences the quality and market value of coal to the maximum extent is the ash content. The lower the coal ash higher is the energy utilization and potential for different applications. Even though Indian coal washeries aspire to produce coal with low ash, the intimate distribution pattern of ash bearing minerals in the coal matrix becomes the real bottleneck, as it brings down the clean coal yield to the impractical value. Because of this fact, most of the Indian washeries are operated to produce coal with 14-15% ash content at the yield of around 40%. In this context, with an objective to produce low ash coal at higher yield, a novel chemical beneficiation route has been explored to demineralize the high ash containing Indian coals. In this present work, the production of low ash clean coal from high ash Indian coals using chemical leaching process has been studied at pilot plant level. The leaching process parameters such as reaction temperature, reagent concentration, reaction time, coal-liquid ratio and agitator speed have been optimized for the flotation tailings sample from a captive washery of Tata Steel. The results obtained show that 67% demineralization could be achieved in a single stage of leaching process with a product yield of more than 65%. For further demineralization, multistage leaching was carried out and the results showed that 75-85% demineralization could be achieved with significant reduction in alumina to silica ratio. Additionally, the phosphorus content is also significantly reduced from 0.20 % to 0.022 %. Further, it is interesting to note that there is no increment of sodium content in the product coal after chemical treatment."

Jan 1, 2014

By A. Bois-Brochu, G. Morin, G. Marin, M. C. Parr, J. Carignan

The presence of an alpha case on titanium parts produced by investment casting is problematic and has to be eliminated. The traditional techniques for the evaluation of its thickness are metallographic measurements and micro-hardness profiles. To obtain a better understanding of how the alpha case is formed with the underlying objective of limiting its depth, the present study proposes to characterize the microstructure and the chemical composition of the alpha case. Electron microprobe analyzer (EMPA) linescans were used to quantify the oxygen and substitutional elements that come from the mould and promote the alpha case formation. The chemical profiles were correlated with metallographic and microhardness measurements. For microstructure, optical microscopy (etched and polarized light analysis) was used. For phase analysis, samples were mechanically polished step by step and analysed using X-ray diffraction and optical microscopy. Furthermore, surface analysis techniques such as XPS and Auger Microscopy were evaluated but results were found to be inconclusive because the formation of the oxide layer was faster than its ablation and the matrix could thus not be analysed. The alpha case was observed on a Ti-6Al-4V step block casting.

Jan 1, 2014

By Ken W. Mills

The ground movements associated with underground coal mining and, in particular, longwall mining, are recognised to include horizontal subsidence movements, but the mechanics of the processes that cause these horizontal movements are not well understood. Over the last two decades, three-dimensional subsidence monitoring has become routine in Australia and has provided a wealth of measurements of horizontal movements caused by mining subsidence. These measurements and other sub-surface observations allow the processes that cause mining-induced horizontal movements to be inferred and, subsequently, verified. In this paper, the mechanics of the processes that cause horizontal movements, particularly those in sloping topography, are described and discussed on the basis of field observations. There are several processes recognised to generate horizontal subsidence movements. In flat terrain, systematic horizontal movements cause the surface to move initially toward the newly created goaf and, subsequently, in the direction of mining. Tectonic energy stored as horizontal stress is released by mining, and, when the horizontal stresses are high, the magnitude of this horizontal stress relief movement is large enough to be perceptible for some kilometres from the panel. In sloping terrain, there is an additional component of horizontal movement that occurs in a down slope direction. This movement, sometimes referred to as valley closure movement, has a magnitude that is typically much greater than systematic or stress relief movements.

Jan 1, 2014

By T. Holmes, D. C. Russell, G. Jolly

"The AMEC Oakville office is involved in the design and construction of an iron ore concentrator located in Liberia. Currently, the site ships Direct Shipped Ore (DSO) to overseas customers. The DSO mine-site and port can experience heavy annual rainfalls. The IMSBC Code requires that cargoes are only accepted for loading when the moisture content of the cargo is less than its Transportable Moisture Limit (TML). The moisture content of the DSO has, on occasions, risen to near or above its TML. AMEC was asked to advise whether the concentrate produced from the new concentrator would or would not have the same problems with moisture content and ship loading as the DSO.INTRODUCTION Liberia was, at one time, the world’s sixth largest exporter of iron ore and used some of the most modern mining operations of their time. However, the country has not produced iron ore over the past seventeen years because of civil unrest. The return of stability to the country has allowed the redevelopment of the iron ore industry. ArcelorMittal Liberia (AML) obtained a concession for mining in the Nimba County area of Liberia (Figure 1) in December, 2004 and has studied the known iron ore deposits and former mining operations in this area. It began phase 1 operations in June 2011 with the direct shipping of high grade ore at a rate of up to 4Mtpa. The processing of the lower grade ore in phase 2 of the project requires additional processing capability to produce at the design rate of 15Mtpa. DSO and Concentrate The DSO in the first phase is selectively mined at an average grade of 60% Fe, and then crushed and screened to -10 mm with no washing or concentration. Testing of samples has indicated a size distribution that is finer than typical sinter feed material, although critical material below 0.10 mm is low in most cases, and overall the ore is coarser than typical concentrates or ultrafine products (Feasibility study report, 2011). The phase 1 DSO facility will cease operation after the phase 2 concentrator comes into operation."

Jan 1, 2014

By Y. P. Huang

Experiment results and operation practice on reutilizing old tailings dumped at SCIM (Shang-chang Iron Mine) of KISCO (Kunming Iron and Steel Corp.) are presented. In a production period over 30 years SCIM dumped about 8 million tons of iron ore tailings. For improving resources utilization instead of wasting, experiments on processing for reutilization of the old tailings are con-ducted. These tailings are fine size fractions of weathered iluvial ores rejected out by classification- des-liming in ore washing and dressing processes, containing TFe 21%~22% in hematite mainly and limonite occasionally. Their particle size distribution, in average, is of 72.26% minus 0.037mm and 30.88% minus 0.005mm. Existence of plenty of micro-fine particles makes the tailings refractory to process, resulting in poor metallurgy. The whole sample of the old tailings without size-classification is fed into experimental process. Slon-100 type high grads WHIMS (wet high intensity magnetic separator) with cyc-pulsing is adopted, which magnetism-focusing rod?s diameter is changed from 3mm into 2mm. Operational conditions of optimizing rougher separation tests are strengthened. An iron concentrate assaying 52.21% Fe at quantity rate of 18.39% and iron recovery of 44.40% is obtained. Operational practice shows that metallurgy and economy of the old tailings treatment are close to what achieved at experiments. It is estimated, therefore, that some 1.4 million tons of this iron concentrate may be recovered from the old tailings. This means that KISCO has moved its key one-step in re-mining and reutilizing the secondary resources, which would be a good demonstration in this industry. This is also of social and economic significance in response to China government?s request on reducing consumption of resources and establishing society with economy for achieving sustainable development.

Jan 1, 2014

By S. J. Liu

The conventional collector for bauxite mineral is oleic acid, which is highly insoluble and must be used in high dosage in bauxite flotation operations, that is the great drawback of oleic acid in use. A series of hydroxamic acid were synthesized, and their collecting ability to certain minerals in bauxite: diaspore, kaolinite were studied. The collecting power of various reagents to diaspore in an incremental sequence were shown as follows: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<oleic acid<octylic hydroxamic acid; while the incremental sequence of the collecting power to kaolinite was like this: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<octylic hydroxamic acid<oleic acid. It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity, and octylic hydroxamic acid was chosen to use in the following experiments. Reduced zeta potential showed the adsorption of the anionic collector on the mineral. By the adsorptive capability and IR tests, the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption, which was greater than that of oleic acid, as it was physical absorption. Results of floatation experiments on manually mixed minerals indicated that the collectivity and selectivity of octylic hydroxamic acid were better than oleic acid.

Jan 1, 2014

By Y. M. Fu

In order to evaluate the flotation process, the process flow sheet was investigated. The process mineralogy of main products was studied. Through chemical mineralogical and screening analysis as well as surveying using a microscope and scanning electro-microscope, the oxidation degree and mineral composition of main-products the liberation of main minerals, the occurrence of elements such as Pb, Zn were revealed. It is pointed that to determine the flotation process, the type of prod-ucts optimum grind of original ore and middling was provided on the basis of liberation of main minerals is reliable. As correct finer ground original ore, first high-grade lead-concentrates and zinc-concentrates fast was floated from a great part of free of the galena and sphalerite of liberated. Then for finely re-ground middling of locked mineral grains of difficult liberation, mixing lead-zinc-concentrates second was floated. The four products was best in contact with characteristic of ore of Fan Kou. Therefore be obtained certain to successful economic effect.

Jan 1, 2014

By Dale Preece, Ayman Tawadrous

This paper presents a number of examples of three-dimensional blast modeling in both surface and underground environments that include time-delay explosive decking. These examples include: 1) quarry blasting, 2) coal seam protection blasting, 3) mineral mine blasting with high energy time delayed decks, and, 4) underground single-level/single-shot drawbell blasting.

Jan 1, 2014

By F. W. Crossland

Losses of metal are often traced to incorrect pH/ORP signals in flotation, leaching, extraction, electrolysis, and precipitation processes, aggravated by pressure changes. IC Controls, a Canadian mining sensor manufacturer, developed a new superior pH/ORP sensor that stops metal losses, reduces environmental footprint and contributes to sustainability. The cause of incorrect pH/ORP signal is rooted in the reference. Reference junctions are designed to allow diffusion of reference chloride ions into the process but also allow process ions to diffuse into the reference. This development is important to mines and hydrometallurgists where sulphide, cyanide, ammonia and other poisoning ions are present in the process. These ions react with reference electrolyte components causing the signal to change, drifting from the correct process value. With fluctuating process pressure, ion in migration dilutes the electrolyte producing similar signal drifts. If process ion in-diffusion could be stopped, the pH/ORP signal would be accurate. IC Controls new pH/ORP sensor stops process ion in-diffusion, and remains accurate over long periods. New processes using higher pressure and fluctuating pressurized reactors will greatly benefit from stable pH readings. Similar to IC Controls&apos; proven model 642 Mining pH sensor, our new model 647 contributes to sustainability through reducing disposal costs from waste reagents, lost metal and fewer used sensors.

Jan 1, 2014

By Nick Hazen

Many successful actions are required to bring a profitable extractive metallurgical operation into production. Competent process development performed within the project development schedule increases the chances of obtaining project financing and decreases the risk of engineering design errors being built into the commercial plant. The general sequence of steps in process development is well known: technology review, desktop studies, scoping studies, prefeasibility, and so on, with an increasing requirement for experimental evidence as the studies advance. This paper suggests principles for guiding process development work so that the efforts stay on track toward a smooth startup and a profitable commercial operation. It emphasizes closely aligning the research with the corporate goals of the mining company management, understanding the mineralogy and variability in the deposit, and guiding by flowsheet and material balance. Examples of hydrometallurgical process development leading to the early use of solvent extraction in the mining industry are given.

Jan 1, 2014

By T. Krumins, L. Zunti, R. Frischmuth

Mercury is known to occur in sulphide-bearing refractory gold deposits in the form of sulphide minerals or elemental inclusions. These deposits typically require an oxidative pre-treatment process, such as pressure oxidation or roasting, to achieve economic gold recovery. However, these processes also have the potential to liberate mercury, a portion of which may then be released to the environment through gaseous emissions. Mercury emissions from mine processing operations have been of particular interest in recent years, as governments impose lower emission targets and organizations adopt better industry practices to reduce the environmental and health aspects of releasing mercury into the environment. This paper describes various mercury removal technologies with respect to pressure oxidation gas handling circuits, with a focus on key design variables and technology selection criteria.

Jan 1, 2014

By P. I. James, M. R. Baker

This paper examines new copper production from waste-grade ore using Blue Planet Strategies’ DEMET™ (Dynamic Electrode Mining Effluent Treatment) technology, which aims to bridge the practical weak pregnant leach solution (PLS) processing gap in heap leach-solvent extraction/electrowinning (SX/EW) operations by electrochemically removing metals from weak streams and generating product streams strengthened in target metals in a functional analog to SX. Weak PLS treatment was studied and used to estimate the economic and production impacts for a representative hypothetical brownfield copper heap leaching and DEMET-augmented SX/ EW operation to utilize "waste ore." Copper removal at 86% plating efficiency to below 0.1 g/L copper with power consumption of 0.55 kWh/lb copper and product strengths of over 10 g/L copper are presented. Modeling yielded approximately $2/lb total copper production and = $1/lb treatment costs with an immediate operation gross margin increase of 12% for the augmented brownfield. Potential mine life extension with an average 38% gross margin on "waste ore" augmented production at copper values of $3.25/lb was also indicated.

Jan 1, 2014

By D. W. Feng

Thiosulfate as an alternative lixiviant for gold has received much attention in recent years due to the growing environmental concerns over the use of cyanide. Cu(II) is used to catalyze the oxidation of gold and ammonia is to stabilize Cu(II) in alkaline solution. However, the presence of Cu(II) enhances the oxidative degradation of thiosulfate. The high consumption of reagents has made thiosulfate leaching uneconomical to date, in comparison with cyanide leaching. Therefore, further investigations are required to leaching under low reagent concentrations over extended periods where reagent consumption is low and gold leaching rate is low as well. It is thus necessary to find additives to enhance gold dissolution in the thiosulfate leaching system. Electrochemical studies using rotating gold disc showed that the oxidation of gold in ammoniacal thiosulfate solution increased significantly in the presence of a small amount of thiourea and the beneficial effect increased with an increase in the thiourea concentration up to 7.2 mM. Thiourea improved gold extraction in the thiosulfate leaching of gold from a sulfide ore under low reagent concentrations. Excessive addition of thiourea inhibited the leaching of the gold ore. The decomposition of thiosulfate was reduced with the presence of thiourea. X-ray Photoelectron Spectroscopy (XPS) results indicated that thiou-rea likely decomposed to sulfide and formed gold sulfide species at the gold surface.

Jan 1, 2014