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By G. Chisakuta, P. Bwando, G. Mitshabu

By the end of 2022, the south-eastern Copper Belt region of the Democratic Republic of Congo was host to more than 40 small, medium, and relatively large sized copper solvent extraction sites. To date, solvent extraction reagents supplied in this region have never exceeded 50% of ketoxime content. We generated laboratory extraction and strip isotherms and used these with the BASF IsocalcTM modelling software to assess the benefit of using higher ketoxime blends on the main metallurgical performance indicators such as copper recovery and net transfer. Pure ketoxime extractants combine a relatively low strip point and a decent loading capacity, which are most effective as the pH of the pregnant leach solution gets closer to 2.

Jan 1, 2023

By J. P. Garnier, T. Bhambhani, J. A. Garcia, N. Renaud

Most flotation plants use a static reagent scheme, i.e., a set combination of collectors, frothers, and modifiers. This scheme is usually developed and refined over time to deliver optimal (not necessarily the highest) performance when the major ore types are fed to the plant. However, when ore types or mineralogy coming to the plant change substantially (and this often happens as different areas of the pit(s) are mined and crushed at the same time), there are upsets in the process, typically leading to lower recoveries. Adapting to this variability is usually done only when performance drastically suffers, and the changes made may be too late and bring additional variability in performance. The premise for SmartFloat™ is that the reagent suite needs to be dynamic, adapting continuously to changes in the ore and operating conditions. Solvay has combined advanced analytics and data science techniques with its expertise in flotation reagent chemistry to systematically and automatically achieve the above, and in real time. Thus, SmartFloat™ is optimizing the reagent suite continuously, removing the additional variability created by belated human interactions resulting in a better and more stable process. In addition, this advanced approach allows for continuous improvement by identifying poor performing ore domains and improving the reagent suite using Solvay’s FM-100 approach to design appropriate solutions.

Jan 1, 2023

By N. du Preez, J. Christie, F. Crundwell

Precipitation is a key process in the recovery of copper and cobalt. While there is a wealth of experience in operating precipitation steps, improving their performance remains challenging. Chemically, the reaction might be controlled by reaction kinetics, be limited by oxygen mass transfer, or be at equilibrium. In this paper, we examine these different operating regimes and demonstrate how they can be identified from plant operating data, process modelling, and pilot plant test work

Jan 1, 2023

By T. Bhambhani, E. Arinaitwe

Solvay has developed several novel reagent innovations to improve separations in sulfide ore flotation and address major industry challenges. These innovations include: a) carbon management strategies to reduce the deleterious impact of organic carbon on flotation circuits; b) new collectors for heavily tarnished or oxidized Cu-Au ores; and c) a functionalized depressant for minimizing penalty elements in metal concentrates. Owing to their unique chemistries, these innovations exhibit a wide spectrum of rather unique properties that are quite in contrast to the traditionally used reagents. The chemistry, attributes, application, and advantages of these innovations are discussed in this paper based on laboratory, pilot, and plant results and observations for various ores

Jan 1, 2023

By K. C. Sole, M. E. Mitshiabo

Although surfactants have proven to increase metal extraction by improving solution flow in porous media, these reagents have not been widely adopted in heap leaching operations because of potential incompatibilities with downstream processes that are subject to surface properties. The BASF leaching aid, LixTRA 118, was previously found to have no significant effect on post-leach operations. This study evaluated its performance in ores of different particle size distributions and the impact on acid consumption and metal recovery. Column leach studies, carried out on a copper oxide ore and mixed oxide–sulfide ore, showed that the effect of LixTRA 118 was more pronounced in ores with wider particle size distributions than in those with more uniformly sized particles. Solution percolation rates increased by up to 18% in the presence of leaching aid, and increased copper recovery and acid consumption. Improved wetting facilitated the kinetics of acid diffusion at macroand micropore level. There was no significant effect on iron recovery

Jan 1, 2023

By G. P. O’Malley, A. N. Nikoloski

One of the most promising options for extraction of copper from low-grade chalcopyrite ores by heap leaching, however, chalcopyrite is refractory and suffers slow leaching kinetics and poor overall extraction due to formation of a passivation layer on the particles. The solution composition is believed to strongly affect the formation of this layer. This paper examines the effects of the major cationic species of Fe3+/2+, Mg2+, Cu2+, and Al3+ and the anionic SO42− species in acidic ferric sulfate media with a composition simulating recycle heap leach conditions. It was found that altering the sulfate, iron or aluminium concentration had significant effect on the copper extraction, the concentration of copper slightly influenced the extraction, and the amount of magnesium had no appreciable effect. Also, iron and aluminium caused a change in the sulfate concentration, and the sulfate ions had the greatest influence on the extraction of copper under recycle leach conditions

Jan 1, 2023

By J. van Deventer

Ion exchange is widely used in hydrometallurgical operations for the recovery and purification of valuable metals. Special chelating resins have a high affinity for specific elements, allowing the selective removal of low levels of impurities from a background of highly concentrated valuable metal. Solvent-impregnated resins have been added to this group more recently, expanding the treatment options. These products find application in the purification of cobalt-rich liquor prior to the production of high-purity metal or metal salts. Impurities in copper-cobalt circuits that are typically targeted by ion exchange include iron, uranium, copper, zinc, nickel, bismuth, and antimony. Ion-exchange resins can also be used to treat tailings, thereby recovering additional valuable metal and improving the Environmental and Social Governance credentials of the operation. This article takes a look at various applications of ion exchange in copper-cobalt operations

Jan 1, 2023

By J. Cilliers, R. Seitz, D. Drinkwater

Mineral processing produces a saleable product from high-cost ore. The Mineral Processing Engineer must constantly improve the separation to create the most value from the ore and reduce the associated costs. Graduate Metallurgists (or Chemical Engineers) have had the university theoretical training required, but often are illprepared to perform their plant roles. The in-work Metcelerate programme was designed specifically to develop the practical skills that Mineral Process Engineers require, by combining three key elements: 1. Knowledge transfer through self-paced, on-line training; 2. Practical skills acquisition through assessed, practical plant exercises; 3. Skills development through online tutorials. A final process improvement project adds significant value to the operation that far exceeds the training cost. Experience from Metcelerate clients has indicated improved staff retention, greater confidence, and pro-active process intervention.

Jan 1, 2023

By I. Druce, C. Li, T. Qu, J. Dong, W. Y. Xinchao, V. Nkuna

CITIC Heavy Industries has a large installed base of grinding equipment throughout Africa in different configurations, including high-pressure grinding rollers with ball mill and semi-autogenous ball crusher. The total installed power of CITIC’s mills exceeds 430 MW. In this paper, we compare several typical grinding circuits of copper in Africa with about 15 kt/d throughput based on ore properties, process selection, equipment sizing, and key equipment capital and operating costs. Actual operating performance is also introduced. The comparison for the following mine sites provides a general reference for the selection of copper grinding circuits with this approximate throughput: Kamoa-Kakula Copper Mine with high-pressure grinding rollers with ball mill circuit, and Deziwa and Sicomine Copper-Cobalt Mines with semi-autogenous ball crusher circuits

Jan 1, 2023

By L. Thomas, A. Argyn, B. Mbao, G. Longo Banza

Since the first application of solvent extraction as part of the hydrometallurgical processing of copper, several studies have been carried out to optimize extractant formulations. In 2006, Solvay developed the ACORGA® OPT series of solvent-extraction reagents to optimize copper transfer by use of a blended formulation containing both aldoxime and ketoxime as well as selected modifiers. The incorporation of selected modifiers in these blended reagents resulted in increased copper transfer, due to the interaction between the modifier and oximes within the blend. By changing the ketoxime concentration and ratio of modifier to aldoxime, the strength of the formulation was optimized to enhance copper transfer and improve Cu:Fe selectivity. This formulation is well known in the African region under the ACORGA® OPT5540 name and provides the best performance at the conditions of agitated leach plants with pregnant leach solutions that fluctuate in Cu grade and pH. This paper discusses advantages of using ACORGA® OPT5540 in the Copperbelt

Jan 1, 2023

By R. Pretorius, N. Mautsa

In a cobalt precipitation plant, phosphoric acid is used to eliminate excess uranium from the pregnant leach solution, resulting in a cobalt hydroxide product that has little uranium contamination. However, the amount of phosphoric acid added must be monitored and controlled to avoid financial and sustainability impacts and to prevent negative impacts on the final product quality. One possible solution to this problem is the use of online residual phosphorus measurement techniques to regulate the addition. By continuously monitoring the residual phosphorus levels in the solution, the plant can adjust dosing in real time to maintain the target residual phosphorus level. As a result, the cobalt precipitation plant can improve phosphorus level control, lowering the risk of overdosing, and ensuring consistent product quality. This approach can also improve process efficiency, reduce operational costs, and have a positive environmental impact

Jan 1, 2023

By L. Tartibu, S. Assuli, P. Nkul, A. Kabimba, W. Elongo, N. Makhotla, D. F. Verwey, F. G. Ndiitwani, J. Bilali, T. Mukongo

The presence of colloidal silica negatively impacts various hydrometallurgy processes. This paper details the nature of colloidal silica, operational issues caused by colloidal silica, as well as various mitigation measures. MMG Kinsevere observed severe phase-continuity instability, increased crud formation, and reagent consumption, and reduced current efficiency in electrowinning with a deterioration in copper quality. Historical mitigation measures were initially implemented but failed to solve the problem. MMG Kinsevere successfully achieved efficient silica removal without adverse effect on the solvent extraction with the use of DEHSCOFIX® SC12 coagulant. A week into the coagulant trial, silica concentration had dropped from > 1500 mg/L to within 500 mg/L. The solventextraction plant recovered its stability and again operated at maximum capacity. Additionally, improvement was observed on current efficiency and copper cathodes quality with use of the coagulant.

Jan 1, 2023

By N. Hadebe, A. Mampuru, F. Jantjies

Mintek conducted test work to study the effect of media wear when using Mintek’s Milling-in-raffinate technology. The grinding media consisted of high-chrome and ceramic balls. The tests were conducted using a laboratory 5L 316 stainless-steel rubber-lined mill. Magotteaux supplied the high-chrome and ceramic balls. The raffinate was synthetically prepared using a typical Cu/Co (2.2 g/L Cu, 3 g/L Co) composition. The milling rate, media wear, mill, leach extraction efficiencies, gangue acid consumption, and residence time were studied. The tests indicated that the high-chrome balls had a higher corrosion rate than the ceramic balls. The ceramic corrosion rate was lower than 0.1 mm/y. The highchrome balls performed better during the leach stages with faster milling time, higher leaching efficiencies for both Cu and Co, lower gangue-acid consumption, and lower residence time

Jan 1, 2023

By Y. Zhou, G. Chisakuta, P. Bwando, G. Mitshabu

A newly started copper hydrometallurgical plant was confronted with a manganese oxidation issue in electrowinning. This oxidation, in the absence of the amount of iron required to stabilise the electrolyte oxidation-reduction potential, is known to produce oxidants (MnO2, MnO4) that can cause accelerated degradation of the organic phase components in solvent extraction and corrosion of lead anodes in electrowinning. The overpotential required to build up the protection layer on new anodes causes an increased electrolyte potential that creates oxidized species in the electrowinning tankhouse, and these species come back to solventextraction plant with the recycled spent electrolyte. This paper discusses the impacts of manganese oxidants on the health of a plant organic phase. It also outlines the actions taken using iron scraps and sulfur dioxide to mitigate the problem that happened due to the lack of ferrous iron sulfate available on site, as recommended for better control.

Jan 1, 2023

By P. Kitobo, T. Nduba, D. Mbay, J. B. Vangu, R. Ciband

The flotation plant tailings at Kamoa Copper Mine concentrator were found to contain a high proportion of extremely fine particles. The potential issues with settling these fine solids were resolved by the use of a poly-di-allyl-di-methyl ammonium chloride (DADMAC) coagulant, Flobead DB 45 VHM, in conjunction with a standard anionic polyacrylamide flocculant. This paper outlines some of the issues encountered and how they were resolved at the Kamoa concentrator. The potential to use this process and technology at other sites is also considered

Jan 1, 2023

By W. E. Oching, M. M. Ghomshei

Attracting and retaining workers in mining industry has become an uphill battle to many mining companies. As workers with significant experience retire, it is getting more difficult to attract not only new workers but also top talent to the mining industry to replace professionals exiting the workforce. To make matters worse, students’ enrolment in the post-secondary mining programs in Canada and USA is continuously declining year after year for reasons not directly linked to job market. This raises a question of how can the future needs of mining be met? This paper focuses on avenues for collaboration of industry and educational institutions to meet the current and future needs of mining. It provides effective approaches that mining institutes can engage with program advisory committees, role of the mining industry in supporting both faculty and students, how to harness the benefits of diverse workforce in the country and use of innovative technologies to attract young workers in mining. This work presents Human Resources (HR) professionals with tools that they can use to hire and retain skilled workers with strong interest to work in the mining industry. It also provides HR professionals with an opportunity to re-evaluate their restructuring practices during economic downturns as they reduce number of employees on temporary or permanent basis. The paper stresses the need of working together of the mining stakeholders including mining industry, academic institutions, First Nations’ communities and provincial(state) and federal governments to meet the current and future demands of mining as the industry experiences shortage of labour and low students’ enrolment in post-secondary mining programs. It is shown that mining educational institutes can enhance their programs and recruitments through establishing a better communication with all stakeholders. This communication can be facilitated by creating a national advisory board, to work with all mining programs at the national level for sustainable mining.

Jan 1, 2023

By P. G. Smith, A. Axiuk

The objective of this paper is to present, from a practical perspective, a review of the most relevant maintenance procedures that are accepted or prescribed to be the most effective in optimising service life potential and to ensure continued safe use of steel wire ropes for shaft mining applications. The paper will address the most common operational issues encountered in the care and operation of shaft ropes for both conventional drum hoists and multi-rope friction winders. For each distinct maintenance procedure presented, a limited amount of theory is discussed to identify the underlying mechanisms at play that must be addressed and to emphasize the logical basis for the recommended course of action. It is recognised that each installation is unique and that the recommended maintenance procedures may not always be practical or cost effective from an operations standpoint under select circumstances, however the intent remains to promote industry best practices for the knowledge and benefit of the mine hoisting community, from experienced maintenance personnel to new entrants to the industry alike.

Jan 1, 2023

By Paul B. Batten

Shutdown is a generic term for what may be called an Outage, Turn Around (TAR) or Overhaul etc. Running a plant shutdown well has always been key to the financial contribution of a mine. However, something important has changed. The post pandemic reality is that it is harder to retain workers and many of those near retirement just didn’t come back to work. This is creating a shortage of experienced people and a workforce that changes employers easily. We are seeing the impact of this manifested in the erosion of established maintenance and supply chain processes that now struggle to yield the plant runtime that could once be taken for granted. The scope, cost and duration of a shutdown varies widely depending on the nature of the work and the equipment being renewed. The PM of an electric shovel might require a week of downtime and cost $100,000. A gold plant may need to go down for 3 days when its time to change mill liners and cost $500,000. A turnaround in a refinery can take more than a month and cost multi millions. Despite the huge differences.

Jan 1, 2023

By I. WILKOMIRSKY, J. BECKER, F. Parada

The current processes that aim to purify molybdenite concentrates are not able to dissolve some copper compounds, hence limiting the processes. Typically, the copper content results are from 2 up to 4 weight percent in the last concentrate. Such values are still too high for the molybdenite concentrate to be further processed to molybdenum trioxide by roasting. In order to achieve lower levels of copper — but also avoid excessive molybdenite losses — a continuous sulfation-leaching process is investigated and applied successfully on a pilot scale. Additionally, a reactor prototype and its process parameters are proposed for a commercial plant.

Jan 1, 2023

By LUKAS FAHLE, JURGEN F. BRUNE, ANDREW J. PETRUSKA, ELIZABETH A. HOLLEY, Gabriel Walton

Adverse ground behavior events, such as convergence and ground falls, pose critical risks to underground mine safety and productivity. Today, monitoring of such failures is primarily conducted using legacy techniques with low spatial and temporal resolution while exposing workers to hazardous environments. This study assesses the potential of novel simultaneous localization and mapping (SLAM)-based light detection and ranging (lidar) data quality for rapid, digital and, eventually, autonomous minewide underground geotechnical monitoring. We derive a comprehensive suite of quality metrics based on tests in two underground mines for two state-of-the-art mobile laser scanning (MLS) systems. Our results provide evidence that SLAM-based MLS systems provide data of the quality required to detect geotechnically relevant changes while being significantly more efficient for large mine layouts when compared to traditional static systems. Additionally, we show that SLAM-specific processing can achieve an order of magnitude better relative accuracy relevant for change detection than quality metrics derived from traditionally deployed tests would suggest, while reducing SLAM-drift error by up to 90 percent. In collaboration with an operating block-caving mine, we confirm these capabilities in field tests on a minewide scale and, for the first time, demonstrate methods of rockfall detection using MLS data. While more work is required to investigate optimal collection, processing and utilization of MLS data, we demonstrate its potential to become an effective and widely applicable data source for rapid, accurate and comprehensive geotechnical inspections.

Jan 1, 2023