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By A. V. Abshilawa, D. G. Talakhadze, R. I. Sturua

"Processing of the tailings accumulated over the lifetime of Madneuli Copper Concentrator is an opportunity to extract additional salable copper and gold products. This paper presents a pre-concentration process for the valuable components (copper and gold) of the accumulated tailings. The developed process makes it possible to obtain a copper pyrite concentrate with a yield of 14.05%, copper grade of 1.36%, and recovery of 83.22% containing 3.78 g/ton of gold at a recovery of 84.31%. The bulk concentrate is produced by a combined process bringing together selective flotation to produce salable copper concentrate and hydrometallurgical processing of the selective flotation tailings to recover gold. KEYWORDS: FLOTATION, ALBION PROCESS, LEACHING, COPPER CONCENTRATE, SELECTION Madneuli Copper Concentrator, Georgia, was put into operation in 1975. Over its lifetime, 40 mn tons of tailings have been accumulated at the tailings storage facility (TSF). Sampling of the TSF has indicated that the average copper and gold grade is 0.23% and 0.56-0.65 g/ton, respectively. Accordingly, the TSF can be classified as a technogenic reserve. This paper discusses pre-concentration of valuable components using flotation, followed by processing of the bulk concentrate in the Albion process. Mineralogical analysis of the accumulated tailings showed that the main ore mineral is pyrite (11.71%). Copper minerals are mainly represented by chalcopyrite (0.7%). The main nonmetallic mineral is quartz (67.3%); sericite, chlorites, etc. also occur. Pyrite is present both as liberated grains and intergrowth. The absolute majority of copper minerals are found as intergrowth with pyrite, less often with quartz. Ore minerals are slightly oxidized. Chemical analysis results are shown in Table 1. Particle size distribution shows that the size class -0.2 mm - 0.045 mm has the highest grade of 0.85 to 0.97 g/ton of gold. Size class +1.25 mm has the lowest grade. Based on the chemical and mineralogical studies and particle size distribution, an optimized process was developed for pre-concentration of the valuable components prior to hydrometallurgical processing. Several gravitation, direct selective, bulk, and bulk selective flotation processes were trialed. (1,2)"

Jan 1, 2018

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By M. Stogran-Baker, E. Legault-Seguin

"Fluorspar mining in the St. Lawrence area of Newfoundland and Labrador began in the 1930s and ended in the mid-1980s. In 2013, Canada Fluorspar (NL) Inc (CFI) discovered a new ore body, the AGS vein, which proved amenable to more economic open pit mining methods and began developing this resource. This paper discusses the flowsheet development of the AGS vein deposit. Testing at SGS began in 2009 with samples from other deposits in the area. The testwork included pilot-scale dense medium separation (DMS), laboratory-scale flotation tests to develop the flowsheet and a flotation pilot plant. The more recent work that is presented here has been devoted to the AGS vein, and included a variability testing program that gave tremendous insight into the metallurgical drivers of processing the deposit. The ore was found to be fairly variable in terms of fluorite grade, but also gangue mineralogy, which had greater implications on the DMS performance. The gangue mineralogy was also found to significantly impact the grindability characteristics of the DMS product. This paper will detail the testing conducted and the mitigating steps which were identified for the operation.INTRODUCTION Fluorspar is the industrial trade name for the mineral fluorite (CaF2), which is the primary industrial source of fluoride. There are a number of categories of fluorspar, most notably acid-grade fluorspar and metallurgical fluorspar (metspar). Acid-grade fluorspar has stringent specifications and is suitable for the production of hydrofluoric acid that is used for many applications. The typical specifications of acid-grade fluorspar are >97% CaF2 and less than 1% each of SiO2 and CaCO3, with a particle size distribution in the order of 80% passing 100 µm. Metspar is typically used for metallurgical purposes, typically as a flux in smelting, and has significantly more relaxed specifications (< 15% SiO2). The principle source of fluorspar in Canada has been from the Burin Peninsula in Newfoundland and Labrador. More than 3 million tonnes of fluorspar were produced there between 1940 and 1978 and from 1987 to 1990, when production ceased (Fulton & Montgomery, 1994)."

Jan 1, 2018

By M. Gonzalez Fernandez

"If the final goal of metallurgy is the extraction of metals from a given ore, everyone knows that this achievement relies on many separation steps involving much more than a biphasic material made of metal and gangue. Nevertheless, still today, most of the design and follow-up of industrial processes only consider metal grades; in best case metal grades per size class. Working with such heterogeneous material, made of several minerals, with different grain size and texture, implies to consider finer ore models to be able to predict the behavior of material and the subsequent operation performances. Analytical tools are now available to provide such relevant and accurate data which are applied in geometallurgy. To achieve a true geometallurgical approach for process design, but also for optimization, accurate process simulation absolutely needs to combine these fine ore models with the corresponding unit operation models. Based on generic, but configurable, criteria of description and a hierarchical approach, the material modelling tool embedded in the USIM PAC process simulator provides the necessary flexibility to describe any type of ore with almost no limit in the level of details and associated physical properties that can be met in the mining industry. The simulation engine and the mathematical models of unit operations are designed to manage such a diversity of material modelling. The paper present various ore models and some of their applications in flowsheet simulation. It proves the interest of this detailed and advanced approach to accurately predict plant performances. INTRODUCTION Process simulation used for process design and optimization requires accurate unit operation modeling. During the last decades, main efforts of the different teams developing software simulators have been dedicated to those models for comminution and physical separations such as flotation or gravity concentration (Kojovic et al., 2012, Soni and Yoon, 2014). In most case, the ore is modelled with a size distribution and metal or mineral grades. A water phase is considered for wet processes. The association of unit operations and such material models generally allows, after some parameters adjustment, to achieve good agreement between experimental and simulated data. The use of the obtained simulator to test alternative configuration of circuits or settings of equipment devices can be accurate enough as far as the ore processed is close to the ore used for simulator adjustment. However, when the ore gets very different grades, coming from different mineral proportions or grain sizes, the simulation results can be of poor accuracy. Because any physical separations such as gravity, magnetic or flotation, do not sort metal and gangue but particles, made of minerals, containing metals, the only way to be accurate enough for allowing extrapolations, is to model particles. The phase model tools embedded in the USIM PAC process simulator gives this possibility. However, as such level of details are not always available for analyses, the tool has been designed with a high level of flexibility, to adapt the model to the available data. In this paper, the principles of this conceptual modelling tool are presented, and some application cases illustrate the material model flexibility and its interest."

Jan 1, 2018

By T. K. Akopyan, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"A qualitative and quantitative analysis of the new Al-Ca-Mn-Fe phase diagram in the region of the aluminium corner is carried out using both thermodynamic calculations and experimental methods. Using the obtained data, the principal possibility of creating both cast and wrought sparingly alloyed aluminium alloys with calcium, manganese, scandium and zirconium at allowable iron contents of up to 0.4% that do not require solution treatment and quenching is justified. At the selected concentrations, the entire amount of manganese (1%) is practically included in the aluminium matrix, while calcium (~2%) and iron are in the multiphase eutectic, which has a fine structure. The joint introduction of 0.25% Zr and 0.1% Sc into the alloy leads to precipitation hardening due to the formation of the L12-Al3(Zr,Sc) phase during annealing. Based on the experimental data for the model multicomponent Al2CaMnFeZrSc alloy, it is shown that such alloys can combine high mechanical properties and good manufacturability during both casting and metal forming. This is due to the combination of a narrow temperature range of solidification with a fine eutectic structure.INTRODUCTION Hardening in branded aluminium alloys (both cast and wrought) is generally achieved by heat treatment of the T6 type, including quenching and artificial aging (Zolotorevskiy, 2007; Kaufman, 2004; Mondolfo, 1976). Heat treatment significantly increases the cost of the final products. Therefore, industrial companies are interested in developing alloys that can be hardened to the desired level without quenching. To solve this problem, alloys with scandium are the most suitable (Toropova, 1998; RØyset, 2005). This element (usually in an amount of ~0.3%) is one of the most effective hardeners in aluminium alloys, due to the formation of Al3Sc (L12) phase secondary precipitates, the size of which is less than 10 nm (Knipling, 2010; Fuller, 2005). These nanoparticles are formed during the annealing via decomposition of the supersaturated aluminium solid solution (hereinafter referred to as (Al)). This feature allows us to significantly increase the strength of aluminium alloys by simple annealing (at ~300°C), i.e., without heat treatment, including quenching. However, scandium is a very expensive metal, so its use as an additive is severely limited. The most effective method is the introduction of scandium together with zirconium (Lefebvre, 2009; Booth-Morrison, 2012). The optimal combination is the introduction of ~0.1% Sc together with 0.20–0.25% Zr, which, according to (Belov, 2006), gives approximately the same strengthening effect as the introduction of 0.3% Sc."

Jan 1, 2018

By I. V. Makarskii, D. N. Nikitin, L. G. Tarasova

"The extent and nature of the damage to diamonds at processing plant is largely determined by the design features of the equipment, the characteristics of the feed ore and the parameters of the ore disintegration process (change in the rotational speed of the autogenous mills, variations of the water supply to comminution process, choice of the optimum charge, etc.). To monitor the intactness of diamonds, an instrumental method using the X-ray tomography system and colored synthetic indicator diamonds was developed for identifying the process-related damage. The X-ray tomography system consists of a CT-Portable X-ray tomographic scanner, a crystal positioning device and customized software (developed by the Fraunhofer Institute and Aliud GmbH, Germany). The developed method enables improvement of the accuracy of the results, exclusion of the subjectivity of the mineralogical assessment, acceleration of data processing and promptly planning of the activities aimed at reducing the process-related damage to diamonds. KEYWORDS Diamonds, colored indicator diamonds, process-related damage, loss of mass, instrumental method, X-ray tomography system. INTRODUCTION Industrial tests of ore processing technology at the enterprises of ALROSA PJSC are accompanied by assessment of the process-related damage to diamonds. The assessment of the process-related damage to crystals is carried out for prompt elimination of factors contributing to the increase of impact forces in the process flow sheet of ore treatment plant. For this purpose a specially selected parcel of -4.0 + 2.0 mm sized natural indicator diamonds is used. The diamonds are exposed to ionizing radiation in order to turn them green and thus to create a distinctive feature. Colored natural indicator diamonds are described, photographed in several views and introduced into the process flow sheet of the processing plant, then extracted from the process flow, described and photographed again. The comparison of diamonds before and after their passing through the process flow sheet of the plant allows to find evidence of process-related impact on the crystal and to calculate the factor of process-related damage (the number of crystals damaged during liberation and recovery), the loss of crystal weight and the degree of damage to the crystals. The method of colored indicator diamonds is used to select processing methods, equipment or regime which would be the safest for diamonds based on the analysis of the factors of process-related damage. There are limitations of the method, such as:"

Jan 1, 2018

By N. Jovanovic, A. Vazirizadeh

"The main objective of this study is to find a solution to design a mass flow observer system with the minimum required sensors and maximum observability for a mineral processing plant. The second objective is designing a mass flow observer configuration with high reliability to manage sensor failures. This configuration will provide a robust monitoring system that increases plant availability and process measurement fault detection. Furthermore, the monitoring system is expected to improve process efficiency. In this investigation, the procedure of designing an observer system is presented along with three models to design the sensor network. The advantages and disadvantages of each models are discussed and finally the models result for an industrial case are presented and analyzed. INTRODUCTION The concepts of observability and redundancy of mass flow are directly linked with the ability to solve and estimate the mass flow. There are hundreds of streams in a process plant flowsheet, and for technical and economic reasons it is not possible to measure all mass flows. It is thus important to know for a set of measured streams, which of the unmeasured streams can be estimated. The concept of observability deals with this issue. It is also valuable to know whether a measured mass flow of streams can be estimated even if a sensor fails for some reason. Redundancy deals with this failure question. A stream is said to be observable if it can be estimated by using the measurements and/ or mass conservation equations. Also, a stream is redundant if it is observable even when its measurement is removed. Observability and redundancy analysis can be exploited for adding new measuring instruments. It can also play a useful role in efficient decomposition and data reconciliation problem (Narasimhan and Jordache 1999). The value of an observer system cannot be justified without considering its benefits. This justification is done through evaluation of data reconciliation, gross error detection and improving process performance such as outlined below:"

Jan 1, 2018

By Teja Reddy, Narasimha Mangadoddy, Mandakini Padhi

"In mineral comminution circuits, the feed to hydrocyclone consists of a heterogeneous mixture having varied degrees of liberation and sizes leading to the multi-component particle system. The presence of multicomponent particles exhibits a significant change in the classification performance parameters. In this work, a numerical study is conducted with an artificial mixture of magnetite and silica of different proportions having similar particle size distribution to understand the multicomponent interaction in a laboratory scale hydrocyclone. The heterogeneous feed is injected tangentially would attain different settling rates under the influence of centrifugal, drag and turbulent dispersion forces. In this work, Large Eddy Simulation (LES) is used to resolve the continuous phase turbulence. Modified Algebraic Slip Mixture (ASM) model using the corrected Newtonian rheology of fines to simulate multi-density and multi-size particles of the mixture in a hydrocyclone. The influence of the multi-component particles on classification performance is extracted from the simulation in terms of the performance curve, i.e. recovery to underflow, volume fraction distribution and the key forces acting on each particle in the mixture. An interaction was observed between different components during the classification process, featuring accumulation of heavier particle at wall-side pushing the lighter particles into the inner locus of zero vertical velocity (LZVV) zone. The comparison of separation factors of different size particles presented the higher probability of the magnetite of same size reporting to wall region and hence to underflow. Hence, an increased component cut-size with the increased magnetite proportion, particularly a profound effect on lighter density component’s cut-size was observed. INTRODUCTION The multicomponent existence is found in naturally occurring ores, affecting the pure metal extraction, nonetheless also affects the comminution and classification processes. Among many another classifier, hydrocyclone is a vital equipment used vastly in many industries. The main advantages over other classifiers are a static body, low operating cost and maintenance, high throughput, low floor space requirement etc. A typical hydrocyclone consists of a cylindrical section with a central tube connected to a conical section with a discharge tube. The fluid is injected tangentially into hydrocyclone causes swirling and thus generates centrifugal force within the device. The multiphase interaction inside the hydrocyclone is extremely complex and mostly explained by theories based on hypothesis. In past years, many theoretical models were proposed like a balanced orbital model (Criner, 1950), the residence time model (Reitema, 1961) etc. Though these models give an estimation of the cut-size and other performance parameters, it cannot predict the accurate performance of the actual state of operation. Among these models, the balanced orbital theory is the most adapted concept, based on the force balances of the particle in the dual vortex flow of hydrocyclone. The finer particle is subjected to the inward drag force, generated from the outer vortex flow to the air core, and drags the particle towards the overflow. The larger particle with the higher mass have enhanced centrifugal force and falls into primary vortex near wall reporting to the underflow. Generally, the forces acting on the particle include the drag force, centrifugal force, pressure gradient force, added mass force, Saffman lift force, Magnus force and basset force (Kraipech, 2005). The major forces like a drag, centrifugal, pressure gradient are the function of the particle properties like the size and the density. Hence, the existence of the multi-size and the multi-density particle will affect the separation phenomenon, with the varied forces acting on it. The understanding of the multicomponent classification effect using ores has been only explored in few studi"

Jan 1, 2018

"The most common agglomeration technique in iron and steelmaking is sintering, which requires the use of iron ore/concentrate mixtures, limestone and dolomite as fluxes and coke as fuel in order to produce the required melt at high temperature to cause agglomeration of the particles. Sinter feed blends containing high proportions of magnetite concentrate are difficult to granulate and to produce granules of high permeability, and sufficiently robust quasi-particles for successful sintering operations. Since the granulation of iron ore sinter feed requires no use of a binder, the added fluxes play a vital role in holding the granule particles together until they sinter. The fluxes also help to improve the granule quality and control slag composition in the blast furnace. It is well-known that the particle size distribution of the fluxes affects the granulation effectiveness and green bed permeability which determine the productivity, physical and metallurgical properties of the granules and sinter. Hence it is necessary to understand the role of flux particle size on granule properties so as to improve the granulation of iron ore sinter feed blends containing high magnetite concentrate. In this study, laboratory granulation experiments have been carried out on iron ore sinter feed blends containing high proportions of magnetite concentrate at different addition levels of limestone and dolomite mean particle sizes, to understand the influence of limestone and dolomite particle sizes on granulation rate processes and granule properties.INTRODUCTION Increases in iron ore production to meet the global demand for iron and steel products has led to the depletion of high grade iron ores and thus the current utilisation of low grade iron ore fines and concentrates. However, sinter, pellets and the lump are the required feed types used in the blast furnace. The high basicity sinter is the main iron bearing feed accounting for 70-85% in the blast furnace due to its good metallurgical and mechanical properties that allow high productivity, efficient processes and low production cost (Adam et al., 2017)."

Jan 1, 2018

By F. O. Milovich, V. A. Ignatkina, L. A. Samatova, E. D. Shepeta

"The aim of the research was to increase technological parameters of the flotation of finely disseminated scheelitecarbonate ore using selective reagent regime.In the studies the monomineral fractions of scheelite and calcite; samples of the scheelite-carbonate ore of the Primorsky deposit with the range of the carbonate module 3-65 were used. A carbonate module of ore is the ratio an initial assay of calcite to an initial assay of scheelite. Sodium oleate, iso-decyl alcohol, water glass, calcium chloride, soda or sodium hydroxide as flotation reagents were used. The flotation method in the Hallimond tube and in a mechanical cell, an adsorption method for study the kinetics of adsorption of oleate and isodecyl alcohol and its combinations on scheelite and calcite, IR spectroscopy including ATR to study the composition of surfacecompounds were applied. Selective reagent regime may include two ways - a combination of collectors or a modification of depressants of calcite and other gangue minerals. On one hand the combination of sodium oleate and higher fatty iso-alcohols of fractions C12-C16 in the rough scheelite flotation to reduce the flotation activity of calcite has been studied. On the other hand depression of calcite flotation by calcium chloride with water glass into rough flotation was used; modified the steaming cycle by Petrov's method applying change the concentration of water glass and other. Fatty iso-alcohols can adsorb on the surface of the calcite that reducing the adsorption of sodium oleate and floatability of calcite has been fallen. Their co-adsorbing with oleat on the scheelite surface were support the hydrophobization and flocculation of slime particles of scheelite. Flocculation of the particles of scheelite leads to increased up 3 times of the recovery of scheelite from the slime class, and calcite change up only 1.4-1.1 times it’s recovery.The growth of the carbonate module more than 11 is decreased the assay of WO3 in the scheelite concentrate of selection cycle."

Jan 1, 2018

By A. Saramak

"The paper focuses on problems of atmospheric pollution by the dusts, produced during the course of crushing and grinding processes, and the main objective of investigative programme is an assessment of emission of particulate pollutants for following crushing devices operated in plant scale: impactors, cone and jaw crushers. All crushers operate in aggregate production plants in Poland. In the first stage of investigations there were determined dust emission levels and supporting characteristics for all crushers under investigation. Then there were introduced indices that allow for comparative analysis in terms of dust emission, for devices with different energy consumptions and comminution ratio. It appeared that crushers with high the overall dust emission do not always achieved unfavorable dust emission per comminution ratio or energy consumption. The introduced indices proved their usefulness, because they helped to carry out a comparative analysis among crushers, operating under different technological conditions. It is also easier to assess environmental impact of individual crushing devices, under analysis. Results of investigations also show that environmental impact of different types of crushers is diverse and it is difficult to compare dust emissions of various types of crushers without taking into account technological aspects (like throughput, comminution ratio, energy consumption, and others) of their operations.INTRODUCTION Mineral processing of raw material is a complex process, involving in general operations of size reductions and separation. Depending on the type of specific raw material, the technological circuit may include operations of comminution and size classification. This is a typical circuit for aggregate production. In ore treatment industry the process in much more complicated and include also a metallurgical treatment of ore concentrate – the final product from processing plant stage.In general, regardless the type of raw material, operations of size reduction are present in each technological circuit of mineral processing. Operations of crushing and grinding are an integral part of processing technology, because they play a crucial role in effective treatment of mineral raw materials (Gawenda 2013). Their duty is to liberate the useful minerals from the gangue in ore treatment industry, or to produce the material with the required particle size in case of aggregate processing. Crushing and grinding operations are of a high negative impact on environment and humans. They consume great amounts of energy, what indirectly contributes to higher emission of carbon dioxide CO2. Apart from energy, crushing and grinding device consume significant amount of steel and other metals and alloys due to high wear of working parts and grinding media. This is also of negative environmental impact due to emissions of additional amounts of CO2 in production of steel and other metals required as spare parts for comminution devices."

Jan 1, 2018

By Hui Zhang, Fei Yang, Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"For a copper-sulfur polymetallic mine in south China, the main valuable minerals were chalcopyrite, pyrite and pyrrhotite. The flotability of pyrrhotite was similar with chalcopyrite and pyrite and it was easy to be oxidized. As a result, the indexes of copper concentrate and sulfur concentrate were unsatisfactory. Furthermore, the recycling of tailings water ulteriorly deteriorated the technical indexes of copper-sulfur ore beneficiation. After a large amount of experimental studies, under the condition that the tailings water recycling rate was 100%, the copper concentrate with a grade of 22.25%Cu and a recovery of 82.46% on average was obtained for the raw ore containing 0.517%Cu, 15.94%S, 25.46%Fe on average, through using new technology “magnetic separation-flotation” and effective adjustment of parameters in the industrial test which was continuously conducted for 14 shifts in 5 days with a scale of about 75t/d. Comparing with the production indexes (the copper concentrate with a grade of 17.49%Cu, the recovery was 62.27%) during the corresponding period, the grade of copper concentrate increased 4.76%Cu, and the recovery increased 20 percentage points. Besides, the indexes of sulfur concentrate gained a considerable improvement. Currently, the new technology was adopted in the design of the new-built plant with a scale of 7000t/d of this mine. The new technology provided powerful support for the tailings water recycling and indexes improvement of copper-sulfur ore beneficiation.INTRODUCTION Chalcopyrite was usually associated with pyrite and pyrrhotite in copper-sulfur ore. Due to the similar flotability, it was difficult to obtain copper concentrate and sulfur concentrate with high grade. Furthermore, sulfide ore was easy to be oxidized and a large amount of ions formed in the pulp by the dissolution of minerals, which made the pulp become acidic. As a result, pyrite and pyrrhotite were easy to be activated in acidic solution and their flotabilities became stronger. Meanwhile, hydrophilic film formed on the surface of chalcopyrite in raw ore. The flotability of chalcopyrite became weaker and it made the separation of chalcopyrite from pyrite and pyrrhotite more difficult. So it was more difficult for copper and sulfur recovering with the recycling of tailings water containing high content of heavy metal ions and reagents."

Jan 1, 2018

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto

"The theoretical technique of computational modeling and the experimental determination of the enthalpy of adsorption of a ligand molecule onto a mineral surface deliver the same output parameters and, therefore, complement each other in investigating the affinity of different ligand types for mineral surfaces.This study ran parallel experimental tests and computational calculations to determine the enthalpy of adsorption of a series of increasing chain length xanthates onto a pyrite surface. The outcomes showed that, while the absolute energy values were different, the trends were similar. Both computational and experimental approaches showed that the extent of the interaction of the xanthate molecule increases with increasing carbon chain length. The computational values were larger than the experimental values, which could be explained, in part, by the addition of water to the computational system, which resulted in a decrease in the heat of adsorption on the (100) surface, compared to the adsorption of the collector in a vacuum. The computational method showed that, in the case of the pyrite (100) surface, the most exothermic reaction was obtained when the two xanthate sulfur atoms bridged two pyrite 5-coordinated iron atoms. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted for each of the C2, C3, C4 and C5 chain length xanthates.The experimentally determined exothermic increase in heat of adsorption for the addition of each CH2 group was found to be -8.17 kJ/mol. The contribution of the thiol head group was -34.9 kJ/mol. Previous studies on self-assembled monolayers have shown that these values are compatible with lateral interactions between CH2 groups and the exclusion of water. This study provides a rigorous experimental and computational approach which is intended to afford confidence in modelled data for the screening of new ligands for flotation processes.INTRODUCTIONComputational modelling is a fast and cost-effective method of screening collector molecules for the efficacy of their adsorption onto mineral surfaces. However, it is desirable to measure the computational outputs against experimental outputs to check for congruency. Computational modelling and experimental microcalorimetry both deliver the same output parameter: the energy of adsorption of the molecule onto the solid surface. These techniques are therefore ideally suited to complement one another in investigating the affinity of the interaction between collector molecules and mineral surfaces."

Jan 1, 2018

By Larry Stearns, Lori Tiefenthaler

Remediation of contaminated soil represents a significant market for application of Deep Soil Mixing (DSM). Eighty-one percent of U.S. Environmental Protection Agency (EPA) Superfund Program’s site remedies have involved contaminated soil. Contaminated soil is frequently treated by In-situ Solidification/Stabilization (ISS). ISS treatment of contaminated soil involves mixing binding agents into soil using DSM techniques. DSM is a core business for many DFI members. Members may improve and broaden their services to clients by learning about the recent ISS treatment of contaminated soil at a Superfund site. ISS treatment is part of the EPA-selected remedy for a Superfund Site in the metro New York City area. The property has seen heavy industrial use for more than a century. Soil at the site is contaminated with a variety of volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAHs) including coal tars and heavy metals, principally arsenic and lead. Beginning in 2017 and continuing through 2018, approximately 150,000 cubic yards (115,000 cubic meters) of soil will be treated by ISS at the case study site. Portland cement and slag cement are mixed into the soil by DSM techniques using GPS guided excavators to immobilize the hazardous constituents within the treated soil. ISS treatment by DSM will contribute to redevelopment of this valuable property. This paper will describe ISS constructability and performance, case study grout mix design with geotechnical results for strength and permeability, and deep soil mixing techniques. INTRODUCTION In-situ solidification and stabilization (ISS) is a deep soil mixing (DSM) technique applied in the environmental remediation field to physically encapsulate, or chemically bind, contaminates of concern such that the impacts to human health and the environment are mitigated. Common remediation applications of ISS include mixing cementitious reagents into contaminated soils to form a monolithic mass with desired performance characteristics, and the installation of vertical subsurface walls designed to control groundwater movement. A key characteristic of ISS is that the contaminated soils are treated in their existing location at the project site and then are left in place after treatment. Typical performance characteristics of the ISS treated soils include improved unconfined compressive strength (UCS), reduced hydraulic conductivity (HC), and reduced leaching potential of soil contaminants. Increased shear resistance of the treated soil may also be a performance requirement where seismic loading is a concern.

Jan 1, 2018

By S. Gaillard, E. Cauda

"Diesel particulate matter (DPM) is an occupational health hazard in underground mines. It generally occurs in the submicron range, and is often present in the mine atmosphere with significant concentrations of dust particles that tend to occur in the supramicron range. Since dust can interfere with analytical methods to measure DPM, it is often removed from a sample stream using impactor-type size selector (diesel particulate matter impactor, DPMI). Because the DPMI physically removes oversized particles from the stream, its performance may be gradually reduced with aging. Sharp-cut cyclones (SCCs) represent an alternative size selector for DPM sampling applications, with a major advantage being that, by design, they should not be susceptible to rapid aging. This paper presents results of a field study designed to compare the performance of aged versus new/clean DPMIs and SCCs in an underground mine. DPMI aging resulted in clogging of the device, and eventually a reduction of its effective particle cut size – though, when sample flow rate was maintained, DPM sample mass collection was not affected until significant aging had occurred. Under the conditions present for this study, effects of SCC aging were observed to be minimal by the end of the study period. INTRODUCTION Submicron particles are increasingly recognized as significant respiratory health hazards (Cantrell and Watts, 1997; Kenny, et al., 2000; Ristovski, et al., 2012). Diesel particulate matter (DPM) represents a major source of submicron particles in both public and occupational environments (Kittleson, 1998; Abdul-Khalek et al., 1998). Due to their work around large equipment in confined spaces, underground miners have some of the highest exposures to DPM (EPA, 2002; Grau et al., 2004). DPM largely consists of solid elemental carbon (EC), commonly known as “soot”, and organic carbon (OC) that may be sorbed to EC particles (Kittleson, 1998; Abdul-Khalek et al., 1998). EC and OC can be measured by thermal-optical methods such as the NIOSH 5040 Standard Method (Birch, 2016), and their sum is referred to as total carbon (TC). While the complex nature of DPM does not allow for its direct measurement, both TC and EC have been accepted as suitable surrogates for monitoring occupational exposures to DPM (Noll et al., 2007 and Birch, 2016)."

Jan 1, 2018

By D. Krawczykowski, D. Saramak, T. Gawenda

"Annual world zinc consumption is as high as nearly 14 millions of tonnes. Approximately 50% share of zinc is used for corrosion protection in processes of continuous galvanization and the hot dip processes. In the latter, two zinc containing residues are produced: zinc ash and hard zinc, which constitute around 10% each. Paper concerns the method of possible separation of metallic zinc from the non-metallic zinc compounds from the zinc ashes – the waste product of hot dip galvanization process. The investigative programme covered the comminution tests of the feed (zinc ash) in selected crushers: jaw crusher, roller crusher and impactor. Results of investigations show that application of individual crushing device results in various breakage of the feed sample. Impact force caused the highest increase in finest particles size fractions of the product, while metallic and non-metallic fractions were comminuted differently. The compression force, in turn, caused the selective comminution, i.e. the breakage of metallic zinc was observed in a higher degree. The presented approach appears to be an economical supplementary method of initial recovery of metallic zinc from metallurgical zinc waste. For the high demands for the zinc in the world and the need of corrosion protection, the method presented in the paper helps in more effective zinc recovery and environmental protection.INTRODUCTION AND METHODOLOGY World production of metallic zinc during last decade shows a slight increase and in recent years its consumptions reach 14 millions of tonnes. Figure 1 shows world production of zinc in the time period 2009 – 2016. Main directions of zinc utilization include: - Galvanization - Production of zinc alloys - Brass and bronze production - Semi-manufactures of zinc - Chemicals The major share in global zinc consumption constitute galvanization process (Bright 2007). Two main types of zinc galvanization are: hot-dip galvanizing (HDG) and electro-galvanizing."

Jan 1, 2018

By Ventsislav Stoilov, Angel Angelov, Ivan Korolev, Antti Remes, Todor Pukov, Stoyan Gaydardzhiev

"The process modeling and simulation studies aim for better process operation and favorable environmental impact. The objective of this work is to set up a simulation model of the Assarel copper flotation circuit for planning and optimization of the process with the aim of increased metal recovery. The model is parameterized based on laboratory flotation tests of ore samples from the Assarel mine together with mineralogical studies by X-ray diffraction (XRD) and Mineral Liberation Analysis (MLA). A combination of several techniques allows reliable identification of mineralogical composition of the selected samples. The changes in the proportion between sulfide minerals in various products along the circuit have been also documented. Further, this information is used in the simulation model and in data reconciliation procedures for establishing mass balance. The simulation accuracy is studied by comparing the simulations with the plant survey based mass balance. Constructed simulation model can be used to run alternative process scenarios. As an example, the flotation circuit performance with different reagent regimes is simulated based on data from batch flotation tests. Two reagents were considered for this purpose, dithiocarbamate-based one and xanthogen formate/mercaptan blend. It has been revealed that these reagents do not have the same influence on the selective flotation. The one improves flotation of gold and overall recovery but without notable selective action. In contrast, the other showed better selectivity towards copper, rejecting more gangue and lowering gold recovery. The model is also applicable for process optimization studies with different feed compositions, flowrates and circuit configurations. INTRODUCTION In the pursuit for elevated technological indicators, finding an optimal set of process parameters fully utilizing the potential of the equipment is a key factor to success. Over the past decades, there has been a substantial development in flotation circuit optimization through performance benchmarking using metallurgical modelling and steady-state computer simulation. Practical simulation engineering tools are based on experimental data obtained from laboratory tests and from plant surveys and operation data. With the help of flotation models, it is possible to study grade-recovery response with different feed compositions and throughputs, and with various cell-operating parameters, as well as to evaluate and design different flowsheet configurations. Outotec’s HSC Chemistry® software, which incorporates simulation and mass balancing modules alongside with several other tools, can assist with this optimization (Mattsson et al., 2015)."

Jan 1, 2018

By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

By Sanjay Chaudhuri, V. K. Kalyani, Pradeep Kumar Singh, T. Gouri Charan

"Indian coal industry is the world's third largest in terms of production and fourth largest in terms of proven coal resources. Indian coal deposits are generally of high ash content varying from 24 to 50%. The coking coal reserves of India constitute about 12% of the total coal inventory, and the coals are washed in washeries, before being used for metallurgical purposes. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells. Extensive studies were carried out for understanding the performance of an operating conventional flotation plant. The performance studies revealed that appreciable quantity of clean coal is being lost in the tailings due to varied reasons and the required quantity and quality was not achieved. In this study, laboratory Flotation experiments were carried out to examine the cleaning characteristics of the said tailing and to determine the effective process parameters for recovery of clean coal at desired ash level ( 16-17%). Response Surface Methodology was applied to investigate the operating conditions of the Froth Flotation for modeling and optimization. Primary study reflects that there is a possibility to recover clean coal at 16-17% ash level with a yield of about 60-70% from that Flotation tailing of feed ash about 28%.INTRODUCTIONMost of the Indian coking coals are difficult in cleaning characteristics and high ash content due to its drift origin and its age of formation for more than 225 million years. Indian coking coal reserve is limited about 12% of total coal reserve. The minerals are homogeneously mixed with the coal macerals. The open cast mining practice and mechanized mining methods are being adopted to meet the increasing demands of coals resulting in generation of more coal fines and subsequently the quality is deteriorated. Indian good quality coking coal reserves of higher seams are fast depleting and hence coking coals of difficult cleaning characteristics of lower seams (LVC) are being now explored. Due to increased mechanization of coal mines to cope up the increased demand and followed by size reduction of lower seam coals in search of better liberation , the coal fines are increasing by leaps and bounds. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells."

Jan 1, 2018

By Patrick J. Hannigan, Geir Veslegard, Frank Rausche, Rozbeh B. Moghaddam

A common type of deep foundation used in Norway to support bridge structures is the drilled pipe piles (piles) filled with concrete reinforcement after installation. The standard installation practice is the use of down-hole hammers. Complex geology and difficult subsoil conditions in Norway causes a high variability of soil and rock layers which in turn make for differences between actual subsurface conditions and those expected from geotechnical exploratory borings. This situation is strongly noted when the foundations are not fully socketed, and the rock layer is sloped. In this particular case, special testing procedures are required to assess the drilled pile base material and evaluate the rock-socket to ensure full contact between the foundation base and the rock surface. The local standard practice to verify the latter condition, consists of coring and visually evaluating the material recovered at the bottom of the drilled pile. This paper presents a case where the coring and visual inspection were not possible and alternatively the geological material encountered at the base of the deep foundations was evaluated using force-displacement measurements. Two 1016-mm (40in) diameter open-end drilled piles identified as P02-04 and P02-05 were tested and evaluated using in-situ force-displacement data prior to filling the piles with concrete. Test results showed an average displacement of 7mm (0.28in) corresponding to 35MPa (5.1ksi) stress level for P02-04, and 7.2mm (0.28in) corresponding to a stress level of 38MPa (5.5ksi). Based on testing results, both drilled piles were within the established material assessment criterion presented by the local authorities. INTRODUCTION This paper presents a case study in Norway where the material encountered at the base of an open- end drilled pipe pile (pile) was evaluated using force-displacement data. In the deep foundation industry in Norway, it is a common practice to install piles to support transportation structures. Once the piles reach the embedment elevation, and the pile base is assessed, these are filled with concrete. In projects where sloping rock is the supporting layer, and all nominal loads are supported by the pile base resistance, assessing the material encountered at the pile base to ensure full contact with the rock becomes critical. The local practice to make this assessment consists of the use of weighted tape, coring, or inspection cameras. However, similar to any other testing and evaluation methods, these come with their own limitations. The variability associated with the use of the weighted tape, accessibility for the coring equipment to complete a coring process, or the conditions at the foundation base such as murky water or thick drilling fluids could significantly impact the photo or video quality taken at the pile base. In such conditions, it is important to consider alternate testing methods to evaluate the material at the foundation base.

Jan 1, 2018