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By R. H. Schonewille

One of the many challenges in developing new metallurgical processes is choosing the best option for validating process design parameters and establishing the process operating window. Historically this has been achieved by constructing pilot or demonstration plants of considerable size and complexity, to enable integrated operation of all key process units for a significant duration. While this would appear to be the best option for minimizing technical risk, it is often impractical from a perspective of cost, schedule, resources or bulk sample acquisition. Such an undertaking can even provide a false sense of security, as the optics of running a complete scaled-down version of a commercial plant suggest a high level of process understanding, regardless of the challenges encountered during operation. Xstrata Nickel has undertaken numerous process development and improvement projects over the past 15 years to support green field project development and continuous improvement in existing operations. The approaches used have included; computer simulation, cold flow modeling, construction of pilot test units in third party facilities, commercial plant referencing and the more conventional construction of integrated test plants. Regardless of the strategy employed, the keys to success have included; managing stakeholder expectations, involving the commercial plant design engineers in the planning stage, anticipating subsequent data and sample requirements and most importantly, constructing and operating complex demonstration plants only as a last resort. This paper provides examples of various process development approaches used by Xstrata Nickel and discusses the rationale specific to each project.

Jan 1, 2011

By J. Güntner

A significant portion of Outotec's business relates to the application of fluidized bed for processing a wide range of industrial materials, including gold ore and gold concentrate. As part of the former Lurgi and Boliden organization, our division constructed the first industrial reactor for roasting sulphur-bearing materials in 1950, based on the principles of fluidized bed technology. This process, when combined with efficient heat recovery and off-gas treatment and its conversion to sulphuric acid, became the standard for processing sulphur-bearing ores. In the last 60 years we have delivered more than 265 plants and developed (in addition to the standard fluidized bed solution) variants of the fluidization technology, such as the circulating fluidized bed and the bubbling fluidized bed. This paper describes the different options of the fluidized bed technology for gold roasting reflecting on main process design criteria.

Jan 1, 2011

By Kevin Jinrong Ma

Underground mines often experience roof falls in entries, crosscuts, and intersections of active mining sections, main travel ways, and belt entries. Roof fall heights greater than 20 ft (6 m) make re-bolting of the newly exposed roof dangerous and impractical. To protect mine personnel, belts, moving vehicles, and other facilities, mine operators typically install steel structures such as square or arch sets in the roof fall areas. Wood lagging is usually installed between the steel-sets to enclose the area and protect the entry from recurring falls. Usually the void space above the steel-sets and laggings is backfilled. However, backfilling high roof fall voids is costly, which causes some operators to leave the voids open. In this case, durability of wood over time and the capability of the steel-set and wood lagging to resist falling rocks are unknown. During the last few years, Keystone Mining Services, LLC (Jennmar Corporation affiliate engineering company) designed, tested, and developed an impact-resistant lagging system to protect steel-sets1. Various steel-sets protected with the impact-resistant lagging were approved by MSHA and installed in different underground roof fall rehabilitation projects. This paper presents (1) design, development, and laboratory testing of the patent-pending impact-resistant lagging panel, (2) steel-set design methodology according to the American Institute of Steel Construction (AISC) national standard, and (3) impact-resistant steel-set design method based on Law of Conservation of Energy. Two underground cases are reviewed to demonstrate the successful application of the impact-resistant lagging system.

Jan 1, 2011

By Muhannad T. Suleiman

The design of deep foundations supporting heavy buildings, bridges, transmission lines, and highway structures, is governed by lateral loads in many cases. However, due to the use of empirical or semiempirical approaches to develop the soil force-displacement relationships (i.e., p-y curves), a wide range of recommendations are presented in the literature. Recent efforts by the author and co-workers enabled simultaneous direct measurements of soil-pile interaction pressure and lateral movement along the pile length, resulting in p-y curves based on direct measurement. Advanced sensors including sheet pressure sensors and shape acceleration arrays were used in these experiments. The experiments were conducted at the Soil-Structure Interaction (SSI) facility funded by the Major Research Instrumentation Program at the National Science Foundation. This paper focuses on the SSI of single laterally loaded piles. The test pile was 101.6 mm in diameter and 1.42 m long, which were installed in well-graded loose sand. This paper provides a summary of the installation and testing procedures, soil properties, pile instrumentation, measured lateral load-displacement response, strain profile along the pile length, lateral movement along the pile length and the pressures measured at the soil-pile interface. Furthermore, the paper presents measured p-y curves compared to estimated p-y curves using empirical methods available in the literature.

Jan 1, 2011

By D. D. Southworth

In 1981, 1982, and 1983, the Bureau of Mines examined the potential for lode deposits of platinum-group metals (PGM) in the Goodnews Bay ultramafic complex, Alaska. The complex consists of the Red Mountain, Suzie Mountain, and Smalls River ultramafic bodies and displays concentric zoning of rock types similar to complexes in southeast Alaska, British Columbia, and the Ural Mountains in the U.S.S.R. Results of the study indicate that platinum is preferentially associated with chromite and magnetite in the dunite core of the complex, and palladium is preferentidlly associated with sulfide minerals in the outer clinopyroxene-rich zones. the most promising targets for PGM lode deposits are the chromite-rich dunite at the heads of Fox Gulch and Squirrel Creek and iron-nickel and iron copper sulfide-bearing magnetite clinopyroxenite and hornblende-rich rocks outward of the dunite core, also in the Fox Gulch-Squirrel Creek area. Significant placer reserves are present in the unmined, deeply buried placer ground in the lower Salmon River Valley, and also in tailings from previous dredging.

Jan 1, 2011

By I. A. Mwamba

Titanium sponge, which is almost pure titanium, is extremely ductile and not easily processed into titanium powder. One method of producing powder is the hydride-dehydride (HDH) process, where titanium sponge is hydrided to form brittle titanium hydride (TiH2). Titanium hydride is easily milled to produce powder and is then dehydrided to form Ti powder. In this work, titanium hydride powder obtained from titanium sponge was used as a starting material for blending and mechanical alloying with elemental powders. Firstly, titanium hydride powder was blended with aluminium elemental powder to produce a homogenized powder, which was then compacted and sintered to produce powder metallurgy compacts. Secondly, titanium hydride powder was mechanically alloyed with aluminium elemental powder and then compacted. The mechanically alloyed powder was characterized in terms of particle size distribution, morphology and microstructure. In both blending and mechanical alloying, the green compacts were characterized by assessing the green density, while the sintered compacts were characterized by their sintered density, microstructure, and hardness. The two processes have resulted in the formation of TiA13 intermetallic compound. It was established that by simple mixing and homogenizing, titanium hydride can be used as a starting material to produce powder metallurgy components in which porosity is a benefit rather than a problem, much akin to metallic foams. From the products obtained in the TiHz-Al system, it appears that titanium hydride can be used as a precursor in mechanical alloying. However, the possible formation of complex hydrides may introduce detrimental properties, and needs to be further investigated. For the production of non-porous components, it would be advisable to dehydrogenate the TiH2 powder before milling i.e. producing titanium powder by the hydride-dehydride (HDH) method. Keywords Mechanical alloying, titanium hydride, titanium aluminide and blending

Jan 1, 2011

By Hongxu Li, Pu Liu, Hao Bai, Daqiang Cang, Lihua Zhao

"Coal, as the main energy in ferrous metallurgy, is consumed on a large scale and great amount of CO2 is emitted likewise. In this paper, a model, based on carbon balance, was developed for CO2 emission analysis, with data obtained from a typical integrated steelworks in China. The result shows that, CO2 emissions increase almost constantly with the growth of steel production. However, coals of different classes and product variety in the steelworks exerted an influence on CO2 emissions. Furthermore, three scenarios, including natural gas instead of coal for power generation, EAF process partly replacing integrated steelmaking, and feasible techniques applied to achieve lowest process energy consumption (FLPEC), were assumed to seek possible ways of carbon emission reduction. The result proves that the second scenario is most effective. If 40% of the steel product could be from EAF process, CO2 emissions would be reduced by 45.07%.IntroductionGlobal warming has become a global environmental problem, which is generally caused by excessive emission of greenhouse gases, such as CO2, generated from human activities and industrial processes. It is estimated that about 7% of global CO2 emissions was from iron and steel industry. Further, if the ore and coal’s mining and transportation are included, the CO2 emissions would reach 10%[1]. In general, the relationship between energy saving and CO2 emission reduction is positive correlation. However, in iron and steel enterprises, due to different types of energy resources like coal, heavy oil, natural gas, the consumption of which will generate different amount of CO2, are used, different energy consumption structure in iron and steel enterprises will lead to difference of CO2 emissions.In order to assess the CO2 emission reduction potential of China’s steel industry, Ke Wang etc.[2] developed a model using LEAP software to generate 3 different CO2 emission scenarios for the industry from 2000 to 2030. LEAP is a scenario-based software tool for integrated energy-environment and greenhouse gas mitigation analysis. The amount of CO2 emissions was obtained by the following equation:"

Jan 1, 2011

By Atsuhiro Nabei, Ken-ichi Yamaguchi

"Wet chlorination process of de-copperized anode slime is followed by de-chlorination stage in which lead-sulfate and metallic silver form silver residue. The silver residue is subsequently reduced to Ag2Se matte and PbO-SiO2 slag to remove lead to the slag in a short rotary furnace. Although this smelting process is proven well in actual operations, few papers have investigated its metallurgical aspects. This paper will describe the effectiveness of controlling parameters adopted at the Naoshima Smelter & Refinery and discuss the decisive factors influencing silver loss to PbO-SiO2 slag.IntroductionThe precious metals plant at Naoshima smelter & refinery was established in 1989, and has produced electrolytic silver, refined gold and platinum-group metals (PGM) from de-copperized anode slime as by-products of electrolytic copper. The process for gold production has been innovated from conventional smelting process to hydrometallurgical process since 2004 [1], while the process for silver production has still remained the same.The process for silver production at the Naoshima smelter & refinery is illustrated schematically in Figure 1. De-copperized anode slime is, at first, concentrated in the froth flotation process, then leached in the wet-chlorination process, and converted to silver residue in the de-chlorination process. The silver residue, which is a mixture of lead-sulfate and metallic silver, is charged to a short rotary furnace for the oxidation roasting to volatilize selenium dioxide and subsequent reduction smelting. In the smelting stage, silver residue and reverts containing selenium are smelted with flux and carbonaceous materials to form PbO-SiO2 slag and Ag2Se matte. Furthermore, Ag2Se matte is transferred to a rotary cupell and oxidized by air with the addition of sodium carbonate and sodium nitrate to produce silver anodes while removing impurities into litharge. Silver anodes are electrolytically refined by the Moebius process. Electrolytic silver is washed, dried and, finally, cast into 30kg-bars."

Jan 1, 2011

By D. Limpitlaw

Industrial mining in Zambia started in the 1930s when the world class copper deposits near the border with Katanga were developed. The discovery of these deposits began at the turn of the century when the first claims in the Copperbelt were pegged at Chambishi, north of what became the town of Kitwe1. World War I and the difficulties of raising sufficient capital for such large scale undertakings delayed the exploitation of these deposits. Following this hesitant start, a large copper mining complex was built, resulting in the development of five major towns, all highly dependent on the mining and beneficiation of copper and cobalt. Copper became so important to the country that, on independence, the only non-mining town to make it onto a list of the top six was the capital, Lusaka. From commissioning of the mines to the end of the colonial period in 1964, copper production increased to just over 640 000 t annually2 (see Figure 1). After the establishment of the new Zambian state, production continued to increase, supported by a benign legislative environment and strong international copper prices. The government of Kenneth Kaunda was intent on improving the conditions of the rural poor and reducing unemployment in urban areas. To this end, the government embarked on an ambitious project of refocusing Zambia's economy away from the colonial role of commodity supply to one of decentralized mass employment. The Copperbelt industrial complex was key to the success of this approach, and in 1969 the Zambian State acquired a 51 per cent stake in Zambia's two main copper producing companies: Roan Selection Trust and Rhodesian Anglo American Corporation. The former became Roan Consolidated Mines Ltd (RCM) and the latter became Nchanga Consolidated Copper Mines Ltd (NCCM). In the year they were nationalized, the mines produced at least 720 000 t of copper? and employed approximately 48,000 workers (see Figure 2)2-4. The subsequent economic policies of the Zambian Government depended heavily on the state's ability to monopolize the proceeds of copper mining.

Jan 1, 2011

By Kanaan Hanna

Abandoned mines pose a serious threat to public health and safety, as well as the environment. When active workings approach old mine workings, miners could encounter significant hazards. Additionally, the presence of mined-out areas or voids underlying residential/commercial properties, transportation, and infrastructure systems can cause subsidence issues ranging from differential settlements and sinkholes to catastrophic collapse. All these features can result in adverse impacts in terms of cost and public safety. Traditionally, mine void detection and related engineering investigations for mine subsidence risk assessment and mitigation have been greatly dependent on systematic drilling and grouting backfill programs. The unknown location and condition of abandoned underground mines represent significant challenges to geologists and engineers in accurately evaluating subsidence hazards and developing appropriate mitigation measures. A comprehensive, multi-phase mine subsidence investigation was conducted at an abandoned western U.S. mine site. The mine operated in an approximately 8-ft (2.4-m) -thick coal seam using room-and-pillar extraction from 1919 to 1922. The mine lies at depths ranging from 50 to 100 ft (15 to 30 m), and it is overlain by critical pipeline and utility corridors. Any future subsidence/ sinkhole that occurs beneath or adjacent to the corridors could pose a significant threat, specifically to the structural integrity of the pipeline corridor. Therefore, the engineering geophysical investigation was initiated to determine the potential subsidence risk. This paper describes a recent success achieved by using integrated engineering geophysics in subsidence risk evaluation. A summary of significant results with emphasis on subsurface characterization, mine workings and voids delineation, modeling analysis, and high risk zones identification and mitigation strategy is presented.

Jan 1, 2011

By M. A. Rodrigues da Silva Enríquez

One of the rare consensual points among different resource-based economic analytical approaches refers to the strategic role of rent from mineral extraction, as a decisive tool to ensure that the temporary wealth generated in the present can turn into permanent income in the future. For this reason, evaluation, distribution and use of mining rent plays a central role in the sustainable development of mining cities. Brazilian legislation provides for this at the municipal level by means of participation in the financial results of mineral extraction accomplished in these municipalities, with the Financial Compensation for Mineral Exploration (CFEM). CFEM is a type of ad valorem royalty, which charges taxes of up to 3% of the net revenue of mineral production. However, legislation does not establish how these resources should be used. Therefore, there is wide variation in the use of CFEM income among Brazilian mining cities. A study from a sample of the 15 largest mining cities in eight Brazilian states made possible identification of two main patterns with regards to the use of CFEM which were labeled "sustained use" and " the pitfall of the single treasury." In that regard, this article discusses the pressuring factors that contribute to these patterns, as well as the institutional arrangements which may be more favorable to inducing more sustained use of CFEM.

Jan 1, 2011

By C. J. Van Niekerk

The study comprised of the investigation into the sensitization characteristics of AISI 409 titanium stabilized ferritic stainless steel during low heat input welding. AISI 409 is a fully ferritic stainless steel used in catalytic converters and tubing for automotive exhaust systems due to the supposition that sensitization does not occur during low heat input welding. Two plates of 2 and 4 mm were tested for sensitization during low heat input welding. The study confirmed that chromium carbide (M23C6) precipitation occurs on the grain boundaries in the heat-affected zone with consequent depletion of Cr adjacent to the grain boundaries during welding. In the 2 mm plate sensitization occurred in the heat input range of 0.1 kJ/mm to above 0.25 kJ/mm and in the 4 mm plate sensitization occurred in the heat input range of 0.2 to 0.9 kJ/mm. Ti stabilization is ineffective at the heat inputs used in this investigation due to the rapid cooling rate through the temperature region where TiC precipitates. The presence of N was found to be detrimental since it consumes Ti on cooling, forming TiN, effectively lowering the amount of Ti available for TiC formation during rapid cooling after welding. Annealing for 5 minutes at 725°C does not improve the sensitization characteristics of the welded plate. There is a linear increase in grain size as heat input increases. The resistance to pitting corrosion decreases in the sensitized, welded plate in theheat-affected zone adjacent to the fusion line of welding. Keywords AISI 409 ferritic stainless steel, sensitization, grain growth, resistance to pitting corrosion, low heat input welding.

Jan 1, 2011

By Peter Woodall, Paul Telford, Pengfu Tan

"Arsenic enters the Mount Isa copper circuit in the form of arsenic rich minerals in concentrates from both the Mount Isa and Ernest Henry copper mines. Arsenic is a volatile metal, and will partition in the copper smelter between smelter off gases, slag and anode. Most of the volatile arsenic will report to Isasmelt Electrostatic Precipitator (ESP) or Waste Heat Boiler dusts where it will form a re-circulating load within the smelter. ESP dust is produced at a rate of 15,000 - 20,000 t/y and is currently removed from the precipitator and leached in the new ESP Dust Recovery Plant to separate copper and arsenic from the ESP dust. This paper describes the laboratory test works of ESP dust leaching, neutralisation and cementation processes. The planttrial, commissioning and operation have been presented as well.1. IntroductionThe flue dusts generated in the process of copper smelting contain appreciable amounts of copper and other valuable metals including precious metals. These flue dusts also contain appreciable amounts of arsenic trioxide where arsenic occurs in the ore body. The copper smelters processing concentrates generate residuals, such as ESP dust, containing arsenic trioxide. ESP dust contains impurities such as arsenic and bismuth which are harmful to the copper refining process if they report to anode. These impurities are fumed off in the smelting process and report to the dust as arsenic and bismuth oxides.The content of arsenic in the feed of Mount Isa copper smelter is about 0.1 % to 0.4%. Arsenic is a volatile metal, and will partition in the copper smelter between off gases and anode. Most of the volatile arsenic reports to Electrostatic Precipitator (ESP) and Waste Heat Boiler dusts where it will form a re-circulating load within Mount Isa Copper Smelter. Unless arsenic is bled from the smelter circuit, it will build up to a point where both anode quality and smelter hygiene are adversely impacted."

Jan 1, 2011

By S. Agarwal

The mining industry collects a significant amount of operational data. However, gleaning useful information from the terabytes of data is difficult, and not just because of the sheer volume of the data. Therefore, an automated tool was developed at the University of Alaska Fairbanks to go through data and apply very sophisticated statistical and neural network techniques, to identify the data streams that are important to a process. This paper presents results from the tool as applied to SAG mill data from a gold mine. The results were benched against commercial tool. Results indicate that there was little or no loss in performance by automating the very complicated process of neural network modeling. Therefore, the intent of the exercise, to examine if complicated modeling tasks can be automated, was realized.

Jan 1, 2011

By Samer R. Rabab?ah

As part of the PHX Sky TrainTM project at Phoenix Sky Harbor International Airport in Phoenix, Arizona, the existing traffic lanes at the 44th Street underpass below the Union Pacific Railroad (UPRR) Bridge will be shifted to accommodate the people mover guideway. The proposed reconfiguration and reconstruction of 44th Street required the utilization of micropiles and permeation grouting to resist the lateral forces induced by cutting into the slope below the existing bridge abutment footing. This paper discusses the evaluation of the existing bridge abutment, including analysis of the original foundation system, and design, installation and testing of a new micropile-supported retaining wall to support the cut slope below the existing bridge abutment foundation. A monitoring program was implemented during construction to evaluate the short- and long-term performance of the bridge abutment. Instrumentation included survey monitoring points, inclinometers, tiltmeters and crack gauges. A micropile load testing program was conducted to verify design assumptions concerning micropile axial and lateral loading. Numerical analyses (using PLAXIS software) were performed to predict the short- and long-term behavior of both the abutment wall and the bridge foundations. Movement data collected from the monitoring program indicate that the wall and bridge foundations are performing satisfactorily and within the general bounds of predicted movements. The results from the numerical modeling using PLAXIS software showed that the proposed solution is deemed adequate to provide the needed global stability with an acceptable factor of safety, along with acceptable deformation.

Jan 1, 2011

By Alan J. Lutenegger

Some years ago, a method was developed to incorporate a grout column around square-shaft helical screw-piles and anchors to increase shaft buckling resistance under compression loading. An additional benefit of this grouted shaft is to increase the load capacity in both compression and tension, depending on the geometry of the lead helical section and the soil conditions. Because of the unique construction procedure, the contribution of the shaft to the total capacity has largely been unknown. The behavior of grouted shaft helical anchors in clay was investigated by performing full-scale axial uplift (tension) load tests on a series of anchors installed at the University of Massachusetts Geotechnical Test Site. In order to isolate the contribution of the grouted shaft to the total load capacity, anchors were installed with a wooden dowel connection between the lead helical section and extension sections on three of the four anchors so that only the shaft resistance would be measured during the load tests. The grouted shafts ranged in length from 10 to 30 ft (3 to 9 m). Initial tests were performed approximately 5½ months after installation. Nearly four years after the initial tests were performed, the tests were repeated to evaluate any significant change in capacity with time and/or repeat testing (preshearing). The soil conditions at the site are presented along with the load-displacement curves for both the initial and repeat teats and a discussion of the analysis of the results. Repeat load tests showed an increase in capacity from the initial testing, however the percent increase was not the same for all depths. The results demonstrate that considerable shaft resistance can be developed in clays from the grouted shafts as might be expected. Depending on the L/D ratio of the shaft and the contribution of the lead helical section, at working loads the shaft capacity can dominate the behavior.

Jan 1, 2011

By John Arrell, James Stuart

We have developed a tester that is uniquely able to measure the no-fire power level of certain types of electro explosive devices (EEDs). In the past, it has been difficult to establish a no-fire power level for nonlinear conductors, such as semiconductor-bridge (SCB) EEDs, and conductive-mix EEDs.

Jan 1, 2011

By Gary E. Sherman

To aid the U.S. Army Corps of Engineers in their Resource Development Navigation Study, the U.S. Bureau of Mines (Bureau) examined the potential for mineral development near ten Alaska port sites. This report presents the results for the following four sites: Balboa Bay, Beluga, Lost River, and Point MacKenzie. There are 579 known deposits within the area considered for these ports. The majority of the deposits are located within a highway/railroad corridor examined for the Point MacKenzie port site. Based on the current level of knowledge, coal deposits near the Beluga and Point MacKenzie port sites are most likely to be developed in the near future. This conclusion is based on the fact that coal projects in these areas are actively being pursued for development. The mineral wealth surrounding the four port sites is substantial. Mine models were used to examine the potential for mining tin, gold, silver, copper, and molybdenum. The models were based on published reserve and grade data and therefore do not include proprietary company data which, if available, would likely change the analysis results. Of the models examined, the tin placer mine model developed for the Lost River port site proved to be closest to being economic.

Jan 1, 2011

By K. Ghyselbrecht, R. Swennen, Y. W. Chiang, V. Cappuyns, R. M. Santos, T. Van Gerven, B. Meesschaert

Heavy metal contamination from mining and metallurgical activities of aquatic systems poses significant risk to the environment and human populations. The investigation of the distribution and immobilization mechanisms of heavy metals in sediments and soils has recently attained high priority. Different remediation methods can be employed to suppress or eliminate these contaminants. A tailored approach using both commercially available and in-house made adsorbents to rem ediate a heavy metal contamination site due to historical metallurgical activities in north Belgium is studied in this paper.

Jan 1, 2011

By James C. Barker

Yttrium and rare-earth element. pegmatite dikes are associated with a peralkaline granitic and nephelene syenite complex near Dora Bay on southern Prince of Wales Island. Mineralized dikes were mapped and sampled during USBM investigations in 1987 and 1988. Coarse-grained pegmatite dikes, which emanated as late-stage magmatic fluids from the intrusion, further evolved into vein-dikes and ultimately silica-rich veins. The dikes can be traced up to two miles along a north-south zone. Lithophile elements exhibit a pronounced zonation in vein-dikes and veins that are distal to the Dora Bay complex with increasing values correlating with increasing distance from the complex. The pattern of mineralization suggests very late stage magmatic fluids containing the incompatable lithophile elements were injected into a preexisting north-south fracture zone. REE mineralogy exhibit fine-grained intergrowths of principally thalenite and bastnaesite with lessor monazite and eudialyte. Euxenite contains most of the columbium values and zircon is commonly associated with the dikes. Estimates of inferred and hypothetical resource tonnage range from 1.7 X 1C6 to 8.5 X 106 st for two deposits. Contained RED (including yttrium) averages 0.5 pct and ranges up to 2.0 pct. Deposits are of polymineralic composition and about half of this resource comprises the heavy yttrium subgroup.

Jan 1, 2011