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By I. Perus, M. Fazarinc, G. Kugler, M. Tercelj

"Ledeburitic tool steels are highly alloyed steels used for specific highly loaded applications but are characterized by low and variable hot workability. In this contribution the importance of selecting the right choice of some essential process parameters, i.e. casting temperature, solidification rate and soaking temperature, needed for improving the intrinsic hot deformability of ledeburitic tool steels, is studied. An inappropriate selection of casting temperature and cooling rate results in precipitation of unusual eutectic carbides that decreases the hot workability, whereas with the selection of appropriate soaking temperature the temperature range of safe hot working can be broadened. For each initial as-cast microstructure individually determined soaking temperature should be selected.IntroductionThe surface cracking during hot deformation of ledeburitic tool steels reduces mechanical properties and their industrial yield. These tool steels have high hardness, wear resistance and high tempering resistance on one hand, and high flow stresses and low hot deformability on the other. Decreased hot deformability of the tool steels is attributed to the type, size, shape, distribution, fraction of eutectic carbides and/or other phases, grain growth, etc. at upper limit while precipitation of secondary carbides and decreased recrystallization rate at lower limit of the safe hot deformation temperature range, [1-6].The occurrence of cracks on most exposed areas of workpiece are related to the areas where similar conditions related to upper and/or lower limit of temperature working range prevail, i.e. areas with accelerated cooling, areas with higher value of accumulated strains where also decreased recrystallization rate with simultaneously presence of higher tensile stresses takes place, furthermore areas of workpiece which are due to combustion conditions in furnace heated to higher temperatures, etc. Thus the areas, where combination of previously mentioned conditions prevails, are more exposed to cracking. This additionally requires that hot deformability of ledeburitic tool steel should be considered as a complex problem. Publications in the literature with regards to hot deformability of tool steels are predominately of a partial nature thus all reasons for unexpected occurrence of cracks are not sufficiently explained in available literature so far. Furthermore modern practice proves that previous processing parameters significantly influence the hot deformability and thus this cannot be considered as a constant value. During heating, soaking and hot deformation various processes take place: decay (decomposition) of carbides, formation of new carbides, dissolution of carbides and of alloying elements, etc. Thus depending on variation of process parameters and chemical composition, that consequently influences the processes related to carbides, shifting of decreased deformability at both limits of temperature working range to higher and/or to lower temperatures can occur, [1-14]."

Jan 1, 2012

By Chuanfu Zhang, Liwei Liang, Yanxin Wu, Jinliang Wang

"According to the reaction shaft operation characteristics during the flash smelting process, 15 groups of slag samples containing high Fe3O4 were prepared by some chemical reagents, and then the slag viscosities were measured using a RTW-10 type synthetic test instrument for melt physical property by the rotating cylinder method. The effects of Fe/SiO2 ratio (mFe/mSiO2), Fe3O4 content (wFe3O4), Cu2o), MgO content (WMgO) and Cao content (wCaO) on the slag viscosity were also studied. Results show that slag viscosity is decreased with the increase of temperature, mFe/mSiO2, wCu2o, wMgO and wCao, and with the decrease of wFe3O4, under the range of slag contents: mFe/mSiO2 1.36~1.78, wFe3O4 17.83%~21.18%, wCu2o 3.51%~8.34%m wNgI 2.21%~6.57%m w/caI 6.22%~9.387% and temperature range if 1250 o/c~1450 oC. Only wFe3O4m and w/caO have great influence on the slag viscosity when temperatures as high as 1400 oC. Only wFe3O4 and wCaO have great influence on the slag viscosity when temperatures as high as 1400 oC or so. To form a freeze slag with higher viscosity inside the reaction shaft, wFe3O4 should be more than 20% and wCaO should be less then 6%.IntroductionSince its appearance in 1949, Outokumpu flash smelting technology has making continuous innovation and has become the most competitive intensified smelting technology [1], widely considered to be the standard clean smelting process [2]. At present, flash smelting technology is adopted to newly build or reconstruct most of the world's copper or nickel smelting enterprise [3]. Reaction shaft is the most important part of the flash smelting furnace. During the flash smelting process, reaction shaft must be able to withstand the following harsh conditions at the same time: 1) high temperature varying from 1400 °C to 1500 °C. 2) strong oxidative atmosphere containing 50% - 80% oxygen. 3) solid particles and melt with speed up to l00 m/s. 4) high acidic or basic slag with strong chemical corrosiveness. 5) smelting gas containing 50% - 80% SO2. 6) matte with strong dissolution."

Jan 1, 2012

By Q. G. Reynolds

The dual-electrode DC arc furnace, an alternative design using an anode and cathode electrode instead of a hearth anode, was studied at small scale using computational modelling methods. Particular attention was paid to the effect of two key design variables, the arc length and the electrode separation, on the furnace behaviour. It was found that reducing the arc length to brush arc conditions was a valid means of overcoming several of the limitations of the dual-electrode design, namely high voltages and arc deflection.

Jan 1, 2012

By David R. Shields, Michael T. Bracher

"The $330 million (U.S.) Dana-Farber Cancer Institute’s Yawkey Center for Cancer Care (Yawkey Center) sits in the heart of Boston’s Longwood Medical Area. The Yawkey Center is a cutting-edge cancer care facility that houses Dana-Farber’s adult clinical care and clinical research programs. Standing 14 stories above grade, it includes 7 stories of underground parking extending 75 ft (23 m) below ground. The structure is on a 198 by 186 ft (60 by 57 m) site sandwiched between Dana-Farber’s 13-story Richard A. and Susan F. Smith Research Laboratories Building, the Medical Area Total Energy Plant (MATEP), Jimmy Fund Way, and Brookline Avenue, a busy four lane artery through the heart of the Longwood Medical Area. Together with Simon Design Engineering, the project structural engineer, GEI Consultants designed an innovative foundation and excavation support system to isolate the building from ground vibrations generated by the adjacent MATEP power plant. In effect, the Yawkey Center is a 21-story free-standing structure that starts 7 stories below grade.The MATEP facility provides power for 9 million sq ft (840,000 sq m) of occupied space in the medical area. There are six 32-cylinder diesel engine generators in the facility that produce low-frequency ground vibrations in the 10 Hz range, similar to the natural frequency of typical building elements. The resonant response of the Yawkey Center building structure to these ground vibrations would affect the performance of sensitive medical research equipment and cause an unacceptable environment for clinical care.The soil profile at the site consists of stiff clay, fine sand, glacial till, and bedrock consisting of hard metamorphosed conglomerate. In-situ measurements of ground vibrations performed in boreholes showed that there was little attenuation of the vibrations with depth in the soil layers overlying the bedrock, but the vibration amplitude in the bedrock was markedly lower than in the overlying soil. Based on this data, an innovative foundation system was designed to support the building on bedrock located up to 110 ft (34 m) below ground surface, while isolating it from the surrounding soil. This was done by physically separating the below-grade parking garage floors from the perimeter foundation walls to create a free-standing structure supported on the bedrock"

Jan 1, 2012

By David F. Gearhart

The Burrell Can1 is a thin, steel, tubular shell filled with aerated concrete that is used as a roof support in coal mines. The Can height is always shorter than the mining entry, so it is capped with wooden timbers and wedges when it is installed. This combination of the Can and the wooden header is a standing support system that is designed to yield in a controlled manner and exhibit a constant yield, or elastic-plastic behavior. The Burrell Can is capable of withstanding 20 in or more of vertical convergence and 15 in or more of horizontal displacement. Because of this exceptional ability to sustain load through extended convergence and displacement, it is one of the most robust standing supports in use today. The National Institute for Occupational Safety and Health (NIOSH) conducted testing on seventeen Burrell Cans in 1995, during development of the support where the ratio of the height to the diameter, or the aspect ratio, was between 2:1 and 4:1. Based on the results of that testing, it was suggested that the standard aspect ratio of the Can be less than 5:1. This suggestion is intended to preserve the overall stability of the Can, which will help to maintain the initial stiffness and prevent load shedding. Recently, the necessity of the aspect ratio has been questioned, and this issue will be addressed in this paper. Since the initial development and introduction, more than 130 tests of the Can have been conducted at the NIOSH Mine Roof Simulator (MRS), and 25 of those specimens had aspect ratios greater than 5:1. The 18-in-diameter by 10-ft-tall specimens had the largest aspect ratio, 6.67:1.However, the aspect ratio is not the only parameter that affects the performance characteristics of the Can. Multiple factors, such as the use of different wood species, the use of different header or footer configurations, and the use of pedestals, as well as biaxial loading conditions can also decrease the stiffness and capacity of the Can. Data from full-scale tests that include these other factors are analyzed to show that the initial stiffness is primarily affected by the roof and floor contact configurations. Furthermore, load shedding is more likely to occur or begin earlier when the aspect ratio is greater than 5:1 and one or more of the other factors are present.

Jan 1, 2012

By K. Koruyan

Although remote sensing technology has been available for many years, it has rarely been used for monitoring mining activity. Recent studies indicate that remote sensing is also a valuable tool for managing and planning certain aspects of the mining operation. In this paper, we examine areal expansion of marble quarries and the affected vegetation over a period of 10 years in the Mugla region in Turkey, using geographic information system (GIS) and remote sensing (RS) techniques. Images captured by ASTER Level 3A01 (3D Ortho Data Set), Landsat 5, and Landsat 7 satellites between 2001 and 2009 were used for the analysis. Changes in the natural vegetation as a function of the production level in the marble quarry were calculated using the normalized difference vegetation index. According to the study results, land cover and natural vegetation decreased by less than 3 per cent and 1 per cent respectively between 2001 and 2009, following an upsurge in mining activity in the region.

Jan 1, 2012

By R. Boom, Y. V. Meteleva-Fischer, B. Kraaijveld, H. Kuntzel

"Segregation of impurities during refining of metallurgical grade silicon (MG-Si) is an option to produce solar grade silicon (SG-Si). Directional solidification is a last step in production of SG-Si effective for removal of metallic impurities. The possibility is investigated to use metallic impurities originally present in MG-Si for removing boron and phosphorus. MG-Si has been treated using two methods: 1) alloying with calcium and 2) refining with Na2O-CaO-SiO2 slag, both by controlled cooling. The microstructure of silicon and the impurities distribution have been studied before and after the treatments. Using EPMA phosphorus and boron have been detected in 1-2 wt% concentration range in several intermetallic compounds in grain boundaries after both treatments. This observation points to a different possible mechanism of silicon refining from boron and phosphorus. Controlled cooling improves migration of phosphorus and boron to the silicide phases in grain boundaries, which can be removed by acid leaching treatment.2. IntroductionStandards for silicon solar cells and growing demand on “green” energy require economical and efficient route to the production of solar grade silicon. Refining of cheap metallurgical grade silicon is one of the promising options, where application of existing metallurgical approaches can result in cost-efficient production on industrial scale. Focus in refining is on impurities, which are most difficult to remove: B, P, Al, Ti, due to their large segregation coefficient in silicon and low vapour pressure [1]. Moreover, more environmentally friendly technology in comparison to the traditional Siemens process [2] will be in accordance with societal needs. Based on properties of common impurities in metallurgical grade silicon, alloying refining and slag refining are suggested as competitive techniques having potential effect on removal of impurities harmful for conversion of solar energy [3, 4]. Alloying with Ca followed by acid leaching was found to be effective for removal of Fe and Ti from silicon [5] and to enhance also removal of boron [6] and phosphorus [7, 8]. In the work of Inoue et al. [8] drastically increasing removal of phosphorus from silicon has been observed with an increase of Ca content and a thermodynamics-based explanation was provided. Since phosphorus has been found to condense in the secondary precipitate mainly composed of CaSi2, it can be removed together with iron and titanium by consecutive acid leaching treatment. Slag refining is one of the metallurgical methods proposed to be effective for refining of metallurgical grade silicon from boron [9, 10]. Slags with additions of the following oxides to silica have shown positive effect on removal of boron: CaO [11-13], Na2O [11,14]. Mechanism of slag refining from boron is based on oxidation of boron followed by its incorporation in the slag network [9,11]; the same mechanism is suggested for refining from phosphorus taking into account that oxides of boron and phosphorus are known as network-formers [15]."

Jan 1, 2012

By Xuewei Lv, Maojun Zhou, Xiaobo Huang, Rende Zhang

"The characterization of the surface roughness of the mineral particles is of vital importance for the studies of the mineral processing. In this study, an evaluation of the roughness of the iron ore particles, with the measurements of size distribution and the measurements of specific surface area with the liquid nitrogen absorption, was developed. The main theory of this method is the fact that the roughness of the particle influences the specific surface area apparently. The specific surface area of the particles can be measured with the laser diffraction method and the liquid nitrogen absorption method. The influence of the surface roughness of the particle can be measured with the nitrogen absorption and cannot be measured with the laser diffraction. Therefore, the roughness can be got by comparing the specific surface area with two measurement methods.IntroductionThe characterization of the surface roughness of the mineral particles is of vital importance for the studies of the mineral processing. There are three main methods for measuring the size distribution of mineral particles: sieving, laser diffraction, and sedimentationl). Many techniques involve sedimentation such as the Horiba2, 3) and the Cyclo-sizer1). In the mineral industry, size distribution is usually determined by sieving because it can be carried out accurately for all particle sizes larger than 45 . The preferred method to obtain the size distribution of finer particles is laser diffractometry. The technique has several advantages: it produces measurements in a few minutes with considerably less labor compared with the cyclo-sizer and for a range of sizes considerably wider in comparison with the sedigraph4). The equivalent-sphere size distribution reported by laser diffractometry is valid for metallurgical calculations and can be routinely used in mineral processing plants. The surface area of the particles can be measured by the BET method of nitrogen adsorption, or it can be calculated from the size distribution. However, the latter calculation requires the size distribution to be accurately known across the whole size range, and assumptions have to be made about the shapes and surface roughness of the particles and presence or absence of pores (see below). The BET method is based on the physical adsorption of gas over the whole exposed surface area and measures the surface area stemming from the roughness and open pores on the surface of the particle5). The calculation of the surface area from the size distribution is usually based on the assumption that all the particles are smooth spheres, without considering the shape and/or roughness of the particles. Determining the surface roughness of the particle with these methods, is the objective of this study."

Jan 1, 2012

By Erik Westman

Few studies have been conducted regarding the location, movement, and relative magnitude of the rear abutment of a longwall coal mine. The rear abutment, or the abutment pressure arch in the gob area, is controlled primarily by the quality of pack of the gob; the more compacted the gob is, the larger the stress would be theoretically. While there is no definitive location for the rear abutment, early studies showed that it could be located as far back in the gob as 300 m (1,000 ft). Like the location of the rear abutment, there has been little research conducted and very few answers as to the exact magnitude of the rear abutment load. Due to the fact that the rear abutment has been studied considerably less than the front or side abutment, the need for further studies is evident. From a ground control standpoint, the location and magnitude of a rear abutment could reveal information on the caving process associated with longwall mining, such as when the initial cave could be expected to occur in future panels. Besides the possible importance of the rear abutment from a ground control perspective, evidence related to the longwall rear abutment could be vital from a ventilation standpoint. The peak rear abutment location could serve as an area for harmful gases, such as methane, to accumulate because forcing air through repacked rock is more difficult than through loose rock. The objective of this study is to determine whether passive seismic tomography could image the location, movement, and relative magnitude of the rear abutment as the longwall face retreated, in addition to the forward abutment and gob. The results of a passive seismic imaging study at a western US longwall show evidence for the location, movement, and relative magnitude of a rear abutment. A clear zone of highlystressed strata is shown where the forward abutment is expected and a low-velocity, damaged zone is shown behind the face where the gob is located. These two zones retreat with the face over a three-week period. In addition, the images show a return to stress levels behind the gob that are slightly higher than overburden stress levels, which is presumably the rear abutment. This occurs at a distance behind the face that is approximately the same as the face width for this mine. We can conclude that passive seismic imaging can be used to identify the location, movement, and relative magnitude of the rear abutment of a longwall mine. This conclusion is dependent on the use of appropriate data collection and processing methods. The information provided can benefit the both ground control and ventilation engineers as they strive to improve the safety and efficiency of longwall mines. The knowledge associated with the rear abutment of a longwall could not only help increase production through proper initial planning and reduce down time, but it could also make positive strides in improving the overall safety surrounding a longwall mining operation.

Jan 1, 2012

By R. Asmatulu

According to Darcy's law, the rate of filtration should increase with increasing pressure drop across a filter cake. In centrifugal filtration, the driving pressure is created by the centrifugal forces applied in the free water on the surface of a filter cake. However, the pressure drop can become negative when the free water surface disappears, which makes it difficult to achieve low cake moistures. In hyperbaric centrifugal filtration, this problem is overcome using air pressure to restore the pressure differential. In the present work, various mineral and coal fines have been subjected to hyperbaric centrifugal filtration tests. The laboratory tests show that the moistures of various mineral fines, such as copper and zinc concentrates, phosphate, talc, kaolin clay, and precipitated calcium carbonate, can be reduced substantially below that achieved by conventional centrifuges. Similar promising results have also been obtained with various coal fines in laboratory and pilot-scale test programs and in full-scale plant demonstrations.

Jan 1, 2012

By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By R. Rumpold

The platinum group metals (PGMs) palladium, platinum, and rhodium represent the key materials for automotive exhaust gas treatment. Since there are currently no adequate alternatives, the importance of these metals for the automotive industry is steadily rising. The high value of PGMs in spent catalysts justifies their recycling. The state-of the-art technology is to melt the ceramic carrier and collect the precious fraction in a liquid metal bath. As the feed material has quite high melting points, huge amounts of energy are required for this process. Hydrometallurgical treatments of the spent catalysts offer the possibility to recycle the PGMs with less energy and time demands. Moreover, automotive catalysts contain further valuable materials to improve the exhaust gas treatment. These compounds, like cerium oxide, cannot be recovered in pyrometallurgical processes. This paper deals with a special process that uses hydrometallurgical principles to recycle the valuable metal fraction from spent automotive catalytic converters. Hydrochloric acid in combination with hydrogen peroxide is used as leaching agent. This combination selectively dissolves the PGMs and the cerium, which can be recovered in separate steps. As the leaching solution is regenerated and reused, wastewater generation is minimized. Furthermore, the process residues constitute potential byproducts.

Jan 1, 2012

By Guolin Zheng, Tiejun Chun, Jian Pan, Deqing Zhu, Xianlin Zhou, Dong Chen

"The high temperature oxidizing-chloridizing roasting is one of useful methods to separate nonferrous metals from pyrite cinder and metallurgy slag. However, as one kind of main nonferrous metals in pyrite cinder and metallurgy slag, copper’s chlorination behavior is not demonstrated. In the present study, chlorination behaviors of CuO, Cu2O and CuS at the temperature range of 1025-1175 ? in air by simulating the chloridizing roasting process of pyrite cinder and metallurgy slag have been investigated. It is shown that Cu2O and CuS is much easier to remove, CuO is refractory to remove. In addition, the presence of SiO2 and CaO increases the Cu removal rate from CuO while the presence of SiO2, Al2O3, CaO and MgO decreases the Cu removal rate from Cu2O. Fe3O4 influences the Cu removal rate from CuO and Cu2O positively.IntroductionAs two kinds of significant secondary resources, pyrite cinder and metallurgy slag contain not only abundant iron but also considerable copper, lead, zinc etc. Millions of tons of pyrite cinder and metallurgy slag were discharged from nonferrous metal and chemical industries annually [1, 2] in China. The pyrite cinder and metallurgy slag are formed by roasting of minerals at a high temperature, so the properties of them are distinctly different from the natural iron ores, and the iron in them is closely associated with copper, lead, zinc and other nonferrous metals. High-quality pyrite cinder and metallurgy slag containing high iron and low impurities can hardly be obtained, leading to their low utilization degree [3]. Chlorination is characterized by the high reactivity of chloridion, the high volatility and low melting point of metal chlorides, and the big differences in the formation of metal chloride. Therefore, chlorination is widely applied in extraction metallurgy."

Jan 1, 2012

By Tiejun Chun, Jian Pan, Deqing Zhu, Zhiyong Ruan

"In this paper, the desulfuration of pyrite cinder pellets was carried out. Phase analysis shows that most sulfur of pyrite cinder exists in the form of elementary sulfur. Most sulfur was removed in preheating stage. 81.25% sulfur was removed and the average SO2 concentration of exhaust gas was 1365ppm when the pellets were preheated at 950oC for 9 min. The final product, assaying 62.42wt%Fe and 0.02wt%S content at 96.88% desulfuration was achieved under the conditions of preheating at 950? for 9 min and roasting at 1200? for 15 min, which can be used as the burden for blast furnace.IntroductionPyrite cinder, as a subsidiary product of sulfuric acid production by roasting of pyrite ores, was solid waste in sulfuric acid enterprises. According to the statistics, the annual production of pyrite cinder is about 15 million tons in China. Besides, there is lots of pyrite cinder deposited for many years [1-3]. The pyrite cinder consumed in the cement and other industries as auxiliary additives only accounts for less 30% of its total discharge and the left is stored in waste pond, occupying much land and polluting environment in China [4-5]. Moreover, pyrite cinder contains iron between 30-63% which can be utilized as a cheap raw material for ironmaking by sintering or pelletizing processes, which can not only prevent pollution but also provide cheap raw materials for ironmaking [6-7]. However, compared to traditional iron ore concentrate, pyrite cinder possesses higher sulfur content."

Jan 1, 2012

By George W. MacDonald

ALFRED NOBEL was born at Stockholm on October 21st. 1833, and died on December 10th, 1896. Although Sobrero’s discovery of nitroglycerin dated back to 1847, this explosive was manufactured on a commercial scale for the first time in 1862, by Nobel at a factory which he erected at Heleneborg, near Stockholm. These works were entirely wrecked by an explosion in 1864. In 1865, he erected works, which are still in existence, at Winterviken, near Stockholm. In 1864 Nobel introduced modifications in the manufacture of nitroglycerin which were the subject of a patent (see footnote No. 1), and at the same time, claimed a process for the detonation of nitroglycerin. Nobel states that, up to that time, the method used for the manufacture of nitroglycerin consisted in pouring glycerin, drop by drop, into a mixture of sulphuric acid and nitric acid contained in a refrigerating mixture. In order that the nitroglycerin should not be decomposed, the temperature was not allowed to rise above 0° C.

Jan 1, 2012

By Keith Henderson

An open pit quarry operation in West Central Illinois provided a challenging proposition regarding the removal of a rock wall that once separated two pits, but was now in the middle of the north wall of the combined pit. Their mining plan included the development of a new ramp into the quarry pit in order to lessen the slope and to shorten haul truck cycle time. The task would be to remove a section of rock left behind from mining operations more than 20 years ago that was at or near the bottom of the designed ramp.

Jan 1, 2012

By E. Peek, L. Becze, K. Reading

"Gallium oxide is an important semiconductor material used in optoelectronic devices (flat panel and solar cell) catalysts and sensors. One of the methods to produce ?-Ga2O3 is the so-called hydrothermal route. It is practiced by Neo Gallium Compounds and comprises of two steps: (1) the production of mainly gallium-oxy-hydroxide in a pressure vessel by reacting metallic gallium with water at 200-220 ºC and (2) the calcination of gallium-oxy-hydroxide at 700-750 ºC to convert it into ?-Ga2O3. This paper describes this pressure hydrometallurgy process supported with relevant thermodynamic data and presents the characteristics of the ?-Ga2O3 powder produced for commercial purposes. INTRODUCTIONGallium is a relatively new metal, having been predicted by D. Mendeleev in 1871, discovered by P.E. Lecoq de Boisbaudran in 1875, and first commercially produced in the USA in 1943. Gallium is not rare, being more abundant in the earth crust than antimony, bismuth, molybdenum, silver and tungsten. However, few gallium minerals exist in nature, and the dispersion of gallium within other minerals add to the complexity of its recovery. In practice, gallium is found in dispersed state primarily in bauxites and in some sphalerites, and, to a much smaller extent, in some coals. At present, a very large proportion of the primary gallium in the world is recovered as a by-product of aluminum plants, mostly Bayer plants, where gallium is extracted from a bleed of the Bayer liquor (Roskill, 2011). In 2011, world production of primary gallium was estimated at 200 metric tonnes. In addition, there is a significant contribution of recycling to the overall yearly availability of the metal.Gallium exhibits fairly remarkable properties: it is liquid above 29.76 ºC, can be supercooled, and with its high boiling point (2204 ºC), is the metal with the widest liquid range. Gallium is magnetic, and is an excellent conductor of both heat and electricity. Gallium also displays a marked anisotropic electrical conductivity (Roskill, 2011). All these properties render gallium almost irreplaceable in the semiconductors (GaAs, GaN, GaSb, GaP wafers) and the optoelectronics industry (flat panel, solar cell)."

Jan 1, 2012

By C. Carreno, A. D. Gonzalez Escarcega, M. A. Neri, A. Martinez –Villafane, O. Cobarrubias-Alvarado

"Waspaloy is a superalloy used to manufacture some aeronautical parts subjected to high temperatures and stresses. During thermo-mechanical processing cracks are generated, causing some parts to be rejected. In order to determine the causes of these cracks, this alloy was characterized using techniques such as chemical analysis, optical microscopy, scanning electron microscopy, and EDX analysis. Heterogeneous grain sizes in the microstructure cause a non-uniform strain distribution in these parts, creating cracks in zones with different grain sizes.IntroductionNickel-base superalloys are important materials for high-temperature service applications. The manufacture of components from these materials is typically based on solidification or powder-metallurgy processes [1]. Solidification techniques comprise either the direct casting of parts or the casting of ingots which subsequently undergo a series of thermo-mechanical-processing steps to refine the microstructure. During solidification, microsegregation is usually unavoidable. The primary solidification product is a disordered nickel solid solution with an fee crystal structure (?). In many alloys, the material which solidifies last is a mixture of ã and an ordered fee phase (? '). In prototypical nickel-base superalloys, the ?'-phase is Ni3(Al,Ti) [2-3].Waspaloy is a superalloy that is used in demanding high-temperature environments in which good creep and fatigue resistance are required. One of the most common applications of Waspaloy is for turbine engine rings. To ensure the required mechanical properties, the rings are usually forged and heat treated (Figure 1). Two distinct types of microstructures are usually found to be attractive for such applications: a) A microstructure with a grain size of ASTM 10 to 14 for tensile strength, ductility, and resistance to crack nucleation in low-cycle fatigue; or b) A microstructure with a grain size of ASTM 4 to 8 required for creep strength and resistance to crack propagation [4]. Because it is impossible to refine the grain size through heat treatment, a skillfully designed forging process is crucial for the control of the grain size and, hence the properties of the forged ring [5-6]."

Jan 1, 2012

By H. Kinilakodi

The authors previously had developed a methodology that combines injury and citation measures into an overall mine safety performance evaluation tool, called the Safe Performance Index (SPI). It can be easily adopted by mine operators to monitor trends in their injury and citation experiences as a risk assessment method. In this paper, six normalized safety measures and the SPI are used to evaluate the risk that existed at mines in the two years preceding the occurrence of a fatality. The percentage of mines is given for which the risk was high or where trends of some of the safety measures indicated moderate risk. In 50% of the mines, this mine safety performance tracking method could have been helpful to the companies, state agency, or MSHA in recognizing and addressing emerging problems with actions that may have been able to prevent high-risk conditions, the fatality, and/or other serious injuries. The approach would have given scrutiny to the risk for mines that encompassed 74% of the fatalities during 2007-2010.

Jan 1, 2012

By S. Dixon

The Peñasquito deposit in Mexico is one of the largest grassroots precious metal discoveries developed in recent years. Goldcorp Inc. acquired the gold-silver-lead-zinc property with the acquisition of Glamis in 2006. The Peñasquito property is located in the northeast corner of Zacatecas state, Mexico. The elevation of the property averages 1,900 m (6,200 ft) above sea level. It is situated in a wide east-west valley. Minera Peñasquito, S.A. de C.V., wholly owned subsidiary of Goldcorp Inc. has operated twin SABC-flotation lines since June 2010. Each line is capable of processing 50,000 tonne per day using a SABC grinding circuit followed by flotation to produce lead and zinc concentrates. The addition of a Polysius Polycom HPGR 2417 with dual 3,000 kW drives to reduce the crushed pebbles produced by the SAG mills was planned to increase production to 65,000 tonne per day per line. The production has been limited to 100,000 tpd due to operating issues in the grinding circuit. The operating issue has been the amount of pebbles generated by the SAG mills is significantly less than originally planned. This paper describes the planned installation of a crushed augmented feed to maximize utilization of the HPGR capacity. This coupled with full utilization of the SAG and Ball Mill available energies there is the potential to achieve a 50% total capacity increase from the grinding circuit.

Jan 1, 2012