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By Kyle Ott, Bernard Daly, Syed Haq, Douglas Anderson, Parsons Brinckerhoff

Drill and blast was determined to be the most cost-effective means of excavating the Raw Water Tunnel (RWT) for the Croton Water Treatment Plant in the Bronx, New York City. One of the major issues confronting project designers was the potential impact of blast vibrations on a major City Distribution Tunnel (CDT). The proposed path of the RWT would cross less than 30 meters (100 feet) above the CDT, which was built in 1917. Discussions with New York City Department of Environmental Protection led to vibration criteria on the CDT of 51 mm/sec (2 in/sec) peak particle velocity as an alert level, and 38 mm/sec (1.5 in/sec) as a review level.

Jan 1, 2012

By Bird. M.

As the Cadia mill was the first 40ft diameter SAG mill, commissioned in 1998, its performance, liner and discharge design attracted considerable international attention. Twelve years on, the liner design and the control philosophy are being readdressed to further improve the mill?s performance. A comprehensive series of 3D liner scans, over life of the liner, have been used to calibrate liner mass loss and progressive changes in the liner profile. This data is being used to provide true charge mass and mill filling, plus progressive trajectory profiles over life of liner. This information, along with measures of mill performance over liner life, is being used to select the optimal operating conditions as the liner wears, and hopes to inform future liner design.

Jan 1, 2012

By A. J. Thompson

The Metropolitan Transportation Authority (MTA) East Side Access project (ESA) will, when it is complete, provide a new link to the east side of Manhattan from Long Island, NY that, linked with the Second Ave. Subway currently under construction, will assist in relieving overcrowding at Penn Station as well as the Lexington Ave. subway. ESA will bring Long Island Railroad (LIRR) directly from Long Island into a new station located 37 m (120 ft) beneath the existing Grand Central Terminal (GCT) located in the heart of Manhattan. It will connect the LIRR?s mainline tracks in Queens, via the existing 63rd Street Tunnel under the East River, to a new terminal constructed within, and beneath, the historic Grand Central Terminal.

Jan 1, 2012

By Erik Olsson, Gunilla Hyllander, Stefan Schuster, Lena Sundqvist Ökvist, Maria Lundgren, Michael Hensmann, Olavi Antila

"Residual materials from the integrated steel plant itself or other sources often contain valuable compounds of e.g. C and Fe. Dust and sludge have to be agglomerated to be able to recycle to the blast furnace (BF) via top-charging. By injection of the materials, preparation methods in terms of e.g. drying and/or screening only, can be used. Alternative carbon materials (ACM) in terms of BF dust and sludge have been successfully injected up to levels of 60 kg/tHM in the LK.AB Experimental Blast Furnace (LKAB EBF®). Efficiency in recovery of valuable compounds as well as the behavior of undesired elements have been evaluated and are discussed.IntroductionTraditionally, recycling of steel in-plant fines is made via the sinter plant and blast furnace route. Steel plants operating with 100% pellet as ferrous burden and have no sinter plant. There are limited areas for land fill and costs are caused for preparation of landfills and deposit fees. Very fine paniculate dusts or sludges cause decreased productivity and increased coke rate in the sinter plant, and therefore other ways for recycling must be considered. Injecting them into the BF could be an economically and technically feasible alternative. Additionally, as the materials contain valuable compounds of e.g. C and Fe."

Jan 1, 2012

By Dao Su, Ganghua Fu, Xuling Chen, Yufeng Guo, Min Gan, Tao Jiang, Xiaohui Fan

"The sinter quantity and quality of limonite in the magnetite and hematite sintering models were studied and compared. For the sintering of magnetite, the results showed that the increase of limonite improved the permeability of sinter mixture, increased the sinter quantity and quality. The sinter strength and productivity were decreased when the proportion of limonite exceeded 50%. The appropriate proportion of limonite was 40%-50%. For the sintering of hematite, the sinter quantity and quality were first maintained at the same level thereafter declined, more obviously when the proportion of limonite exceeded 40%. The amount of calcium ferrite increased whose shape changed from acicular to leaflike and block gradually with the proportion of limonite increased from 0% to 80%.IntroductionWith the fierce competition of domestic and overseas iron markets in the twenty-first century, cheap ores such as limonite are used to be sintering raw materials to cut the costs of sinter and pig iron for steel making, and boosts the competitiveness of steel companies [1, 2]. In addition, as the reserve volume of hematite of high grade is reducing year by year, the usage amount of limonite in sintering are expanding in major domestic and international sintering plant [3, 4]. Sintering can be divided into two types, majoring in concentrates and fine ores, according to the different types of raw materials. The sintering characteristics of limonite in the two types above have been studied and compared in this paper, which makes a significant sense for the research of limonite sintering properties and guidance of ore proportioning in sintering plants."

Jan 1, 2012

By A. Iván, Patiño C. Francisco, Flores B. Javier, Peréz L. Miguel, Hernandez A. Juan, Trapála P. Norma, Salinas R. Eleazar, Rivera L. Isauro, G. Flores, U. Mizraim

"Tills work is related with the production of tiles using wastes from mining and metallurgical industry of Hidalgo State, as raw material. These wastes present a majority particle size (60 %), minor than 53 m (mesh 270, in Tyler Series) with the following composition; 70.01 % wt. of Si02, 12.82 % wt. of Ah03, 3.80 % wt. of Fe, 0.70 % wt. of Mn, 3.98 % wt. ofK20, 3.34 % wt. of CaO, 2.50 % wt. ofNa20, 0.04 % wt. of Zn, 0.026 % wt. of Pb, 56 grams per ton of Ag and 0.6 grams per ton of Au. In this work, the partial results and experimental conditions for the preparation of some composites to produce tiles are shown. The composite that offers the best results in productions of tiles was that with 66.67 % wt. of mining waste, 26.67 % wt. of red mud and 6.67 % wt. of black mud.IntroductionTo now, mining activities carried out during more than 457 years in Hidalgo State, Mexico; has lead a great volume of wastes; which can be classified into different types, having among the more common; Acid mining water, solid transport water, elements in radical form, abandoned minerals without processing and processing minerals wastes known as burrows, being these the most abundant in the region counting with an approximated volume of 110 million of tons, presenting a fine particle size that can affect population health during windy epochs [1 -4].Form metallurgical point of view, is well known that a fundamental characterization study it is necessary to know the viability of reusing or recycling of these wastes. According this, these residues can also be considered as raw materials in other economical activities, due its Si, Fe, AI, Ca, Na and P oxides contents, its mineralogy and the distribution of chemical elements in the primary and secondary phases [1,2,5,6]."

Jan 1, 2012

By S. P. Pereira

The mechanized mining cycle using loaders and shuttle cars had it speak in terms of usage in the mining industry during 1950 through 1960. In Brazil, this system is still used at underground coal mines in southern Santa Catarina coal basin. With the aim of investigating the benefits of a new mining scheme using the room and pillar method for these local mines, a computational simulator model was developed in order to investigate the mining cycle. This paper presents the methodology used to develop the simulator and the results that the simulation shows regarding impact of the proposed new scheme on mining productivity.

Jan 1, 2012

By D. P. Roberts

This investigation aimed to simulate the experiments performed by Nic Gay (Gay, N.C.1976. Fracture growth around openings in large blocks of rock subjected to uniaxial and biaxial compression. International journal of Rock Mechanics and Minining Sciences and Geomechical Abstracts, vol. 13. pp. 231-243) on fracture growth around openings in blocks of rock subjected to uniaxial and biaxial compression, using the Elfen discrete element code. The results of the physical experiments indicated a number of trends that were successfully replicated in the numerical simulations, including crushing ahead of the face, the formation of a sub-vertical tensile fracture at centre-span, the formation of groups of fractures originating from the crushed face zone, the formation of large corner-to-corner fractures which precede sample failure, and linking of slot corner and sample corner fractures leading to sample failure. In addition, other features were apparent that were not reported by Gay. It is believed that these took the form of conjugate shear fractures (as reported by Gay in a previous paper) and other features that may have been altered or inhibited by the presence of pre-existing structure in the physical samples. It was found that the samples, though nominally made up of the same rock type, must have had significantly differing properties. The presence of pre-existing structures may have contributed to this discrepancy. Strain measurements from the physical experiments were reasonably well matched, except where the gauge lay directly in the path of advancing fractures.

Jan 1, 2012

By Dachun Liu, Wenlong Jiang, Baoqiang Xu, Yongnian Dai, Bin Yang

"In the traditional method for refining of indium, glycerin-KI and glycerin-NH4Cl are used as electrolytes to remove Cd and Tl by electrolytic refining, which produces In with a purity of 99.995%. Large quantities of polluted industrial waste water are the result. It is calculated that the saturated vapor pressure of Cd and Tl are between 1-200 Pa, which is much larger than the vapor pressure of In. Thus, the study of removing Cd and Tl was carried out over the temperature range between 700-950 °C and pressures between 1-15 Pa. After vacuum distillation the contents of Cd and Tl in crude indium could sharply fall below 1 ppm..IntroductionIndium is a is a pale blue and silver white metal, and has high ductility [1-2]. Pure indium is generally used as a raw material to produce semiconductor compounds, fluorescent material and ITO targets [3]. Sublimation, zone melting and electrolytic refining are major methods to produce pure indium from crude indium. Electrolytic refining is the main method to product pure indium at present. High productive efficiency, simplicity of operation and short cycle of production are major advantages. However, glycerin-KI and glycerin-NH4Cl are used to remove Cd and Tl in electrolysis method. Large quantities of polluted industrial waste water are the result[4]."

Jan 1, 2012

By Y. Huang, P. B. Prangnell

"An Al-0.1Mg alloy was firstly deformed at room temperature by ECAE to a true strain of 10, where a steady state deformation was established and further processing had little effect on grain refinement. The ECAE samples, with an average grain size of ~0.55µm, were then compressed in a channel die at 77K- 473K to various reductions. Microstructures were characterized by electron backscatter imaging and EBSD in a FEGSEM. Grain refinement to the ECAE submicron structure occurred during deformation at cryogenic temperatures of 77 – 213K, whereas coarsening took place during deformation at elevated temperatures. A steady state deformation was observed at all temperatures where a constant grain structure was developed and maintained upon further straining due to dynamic recovery. The mechanisms of dynamic recovery during steady state deformation at cryogenic temperatures are discussed.IntroductionSevere deformation processing (SDP) has been successfully used to produce submicron grain structures, and in some cases nano-scale crystallite sizes, in a wide range of alloys. However, the rate of grain refinement becomes increasingly inefficient at high strains as a steady state grain structure is approached [1-3]. Steady-state grain sizes have also been reported in other ultra-high strain deformation processes, like cryogenic ball-milling [4]. There is thus a minimum grain size achievable in a material by a given SPD process under constant deformation conditions.It is well documented that a steady state subgrain size is observed in warm deformation of metals due to dynamic recovery (e.g. [5]). In severely deformed alloys a constant grain size at ultra-high strains has similarly been attributed to dynamic recovery [1-3]. Mechanisms have been proposed, for rapid deformation induced grain growth including stress driven boundary migration and breakaway from solute pinning [2]. However, as pointed out by Humphreys et al. [2] the restoration processes are currently poorly understood, particularly at low temperatures, where the boundary migration rates required to maintain a constant grain size are orders of magnitude higher than can be satisfactory explained from diffusion controlled migration. Similar to the subgrain size, the steady state grain size obtained during SDP is generally related to the temperature compensated strain rate [2, 6]. Thermally activated restoration processes are thus expected to be suppressed by lowering the deformation temperature and a smaller steady state grain size can be achieved."

Jan 1, 2012

By D. Van Orden, Y. Kamiya, R. Lee, E. Ilgren

Crocidolite is a well-known causative agent for mesothelioma. However, studies have shown that the pathogenicity of the fiber from different mines varies considerably and it has been postulated the parameter that appears most likely to account for this variation is fiber width although this has never been formally confirmed. To date, crocidolite appears to be the only asbestos mineral for which an epidemiological study comparing the risk of mesothelioma in a population exposed to ‘thin’ fibers with another exposed to ‘thick’ fibers of the same species may be carried out. Finnish anthophyllite, South African amosite, and African Transvaal crocidolite can also be classified as thick fibers, and there is a paucity of mesotheliomas in populations exposed to them compared to those exposed to thin Cape crocidolite. No thin occurrences of these minerals are known. Our previous study looked at crocidolite from several sources. The present study considers the amphibole anthophyllite found in many places in the world. This mineral, regardless of source, does not show the same variation in fiber width found with crocidolite from different areas. All anthophyllite fibers that have been mined may be classified as thick and populations exposed show very low levels of mesothelioma. We suggest the most likely explanation is related to the fiber width distribution and a concomitant reduction in the ‘Stanton fiber size’ fraction.

Jan 1, 2012

By T. A. George, David J. Sellmyer

"The concept of achieving a useful high-energy-product magnet through appropriate nanostructuring of known hard and soft phases has been tantalizing researchers since the idea was first proposed. The fabrication of exchange-coupled nanocomposite magnets faces several challenges including aligning the easy anisotropy axes of the hard-phase grains. Here we investigate experimentally two-phase nanostructures of hard Lio-ordered FePt and soft iron-rich/cc Fe(Pt). The Fe-Pt thin films were produced by epitaxial cosputtering onto MgO (001) single-crystal substrates which lead to strong (001) texturing. The measured hysteresis loops indicate nearly ideal exchange coupling. Excellent magnetic properties are obtained, with largest values of coercivity (51 kOe), saturation magnetization (1287 emu/ cm3, J, = 16.2 kG), and nominal maximum energy product (58 MGOe).1. IntroductionA key figure of merit for permanent magnets is the maximum energy product (BH)rrw.x. The achievable maximum energy product is determined by a magnet's saturation magnetization M, and its magnetic anisotropy. For example, it is well known that (BH)rrw.x :S 4n2M,2• In the past, record energy products have been the result of discovering new compounds with high values of magnetization and anisotropy. However, finding new compounds with better magnetic properties than the current record-holding magnet Nd2Fe14B has proven to be difficult. A different approach is to exploit the exchange coupling mechanism between known hard and soft magnetic phases to enhance the maximum energy product [1-5]. In such a composite system, high coercivity is achieved due to the anisotropy of the hard phase as well as a nanostructure which prohibits large-scale domain wall reversal mechanisms. Magnetization is enhanced by the soft phase and loop squareness results from texturing of the hard phase easy-axis as well as complete exchange coupling between the coexisting hard and soft grains."

Jan 1, 2012

By T. Bhambhani, D. R. Nagaraj

"Ultramafic Ni ores present significant challenges in processing in that both recoveries and grades are not satisfactory, due to the presence of Mg silicates in large amounts. Significant quantities of xanthates and CMCs are generally used for their recovery by flotation. Additionally, given that some of these ores are processed under acidic conditions, CS2 generation due to xanthate decomposition presents some safety hazards. Technology to replace xanthate has been developed for which the safety and health issues are absent. Collector S-10294 shows significant improvements in Ni and overall S recovery at a dosing rate of one half that of xanthate. New polymeric modifiers have also been developed that help reduce the Mg content of the concentrates at very low dosages. The reagents are custom designed for use in normal or hypersaline water, and acid or alkaline conditions.INTRODUCTION The use of xanthates in sulfide mineral flotation is reported to have started as early as 1925 (Nagaraj 2005). The reagent is now ubiquitous in the mining industry, accounting for 40-50% of total collector consumption. In recent years, the development of more selective reagents has rendered xanthates largely obsolete in Cu flotation. However, xanthates continue to be sold in large amounts in the Au, PGM and Ni flotation industry, where bulk sulfide flotation is required. The low cost and easy availability is the largest driver for the use of xanthates in the minerals industry. Of particular interest to this study is the use of xanthates in the flotation of Ni sulfide ores. About 60% of the world’s annual nickel output is obtained from sulfide Ni ores (Hoatson, 2006). A strategically important category of these ores is the ultramafic hosted sulfides, such as those of Western Australia and Canada. These ores are characterized by low Ni grades (<1%), with the Ni minerals being pentlandite, violarite, millerite and mackinawite, and gangue minerals comprising an array of altered Mg silicates, mostly serpentines. The challenges associated with treating these ores are well documented (Eltham et al. 1973; Claridge et al. 1975). One challenge is that Ni recoveries from these ores are lower. This has been attributed to the increased pulp viscosity, as discussed in detail by Vasudevan et al., 2010. Additionally, Mg silicates tend to report to the concentrate in large quantities, which is problematic for two reasons: a) concentrate dilution, and b) the high melting point of Mg silicates tends accelerate wear on the refractory lining of smelters. This has been attributed to network transport to the froth phase via bubble flux and entrainment (Patra et al, 2010)."

Jan 1, 2012

By Simon Pelletier, Jose Delgadillo, Dave Page, Pramod Kumar, Raj Rajamani, Dilek Alkac, Martin Fillion

"In general, many past works examine mill load, mill power, shell lifter design etc with a view to improving the mill capacity. On the contrary, only a handful of papers have addressed the transport of fine slurry through the pulp lifters. We present the flow dynamics of pulp lifters via laboratory scale experiments, high speed photography and modeling with computational fluid dynamics. Next, the flow behaviour in ArcelorMittal’s Mont-Wright autogenous mill discharge flow is examined. In an effort to improve mill throughput, a comprehensive simulation and plant scale study of the mill was taken up with a focus on the shell and pulp lifter design. The shell lifter was found to be at its optimum limit for breakage of ore particles given the constraints of wear life and occupied volume. Next, the pulp lifter study was taken up with computational fluid flow code and discrete element code. The simulations directly showed that there was considerable carry-over of slurry. This effect was traced to the area restriction in the pulp lifter channels. Further, crash-stop studies confirmed slurry pooling within the mill. Thus it was readily apparent that mill throughput can be increased if the pulp-lifter could be redesigned. Consequently, the discharger section of the pulp-lifter was redesigned.First, this paper outlines the modeling in laboratory scale studies and plant scale studies leading up to the discharger design. Next, the discharge flow in seven different published mill surveys is predicted with computational fluid dynamics (CFD) methodology shown here. Finally, Mont-Wright mill circuit performance before and after the discharger redesign is described. The usefulness of fluid flow simulations in the design of pulp-lifters is emphasized."

Jan 1, 2012

The accompanying supply/demand flow diagrams and 10-year tables for mineral and fuel commodities present essential data required by government, industry, and others to formulate policies and programs that can help assure an adequate and continuing supply of mineral raw materials. The 10-year data base terminates with 1974 figures because adequate world information was not available beyond that date. The selected mineral supply/demand tables and flow diagrams comprise but one "output" from the massive body of information and data collected and com-piled by the Bureau of Mines on a continuing basis covering mineral production, consumption, prices, shipments, imports, exports, and stocks, as well as industry activities in all States and abroad.

Jan 1, 2012

By J. M. Benson

Metal powder compaction offers unique advantages in the manufacture of net-shape components using techniques such as laser sintering, conventional press and sintering, metal injection moulding, direct rolling, direct forging, and hot isostatic pressing. If the output from the primary metal production process is in powder form, then considerable cost and energy savings can be realized by direct conversion to semi-finished or final shapes. This possibility exists for titanium and possibly also for Ta, Zr, Hf, and Nb metals. However, these attractive benefits are associated with some significant risks. The high surface-to-volume ratio of powder particles coupled with the reactive nature of these metals means that special care must be taken when handling them. Powder explosions are unfortunately still a regular occurrence internationally and these often result in serious injury and loss of life. Even seemingly &apos;safe&apos; compounds such as sugar, flour, and grain can be extremely hazardous when handled or milled and dust clouds are produced. In addition, exposure to airborne particles can have adverse effects on the human body, especially when particles are inhaled on a regular basis. Furthermore, the medical consequences of these are not fully understood, especially in the case of nanoparticles. The impact is often not observed immediately and debilitating illnesses may emerge only years or decades later. As far as is known, there are no South African guidelines for handling of metal powders. This paper attempts to provide an awareness of the risks associated with metal powders (including those produced indirectly by other metalworking/finishing operations) as well as some guidelines for their safe handling, based on international best practices.

Jan 1, 2012

By Kenji Monden

"The creep properties of tin-based lead-free solders Sn3.0AgO.5Cu and SnO.7CuO.1Ni and lead solders 10Sn90Pb and 50Sn50Pb were investigated at temperatures between 298 K and 398 K. The creep-rupture time decreases with increasing initial stress and temperature. The analysis of the solder creep curves uses the Omega method. The creep rate E is expressed by following formula: 1n ? = 1n ?0 + O?, where ?0 and O are experimentally determined. The parameter Eo increases with increasing initial stress and temperature. The activation energy for ?0 is 108 kJ/mol for Sn3.0Ag0.5Cu and 85 kJ/mol for SnO.7CuO.INi. These energies suggest that the lattice diffusion of tin is dominant. The energy of 1OSn90Pb is 37 kJ/mol and that of 50Sn50Pb is 67 kJ/mol. The creep-rupture time is calculated using the parameters, ?0 and O. The calculated creep-rupture time is in good agreement with the measured creep-rupture time.IntroductionLead-free solders are replacing traditional tin-lead solders as part of a major trend toward protecting the earth's environment. However, tin-lead solders are currently needed for a high temperature range. Since creep is the main deformation mechanism in solder joints, understanding a constitutive model for creep and examining creep data for solders are important for reliability analysis of solder joints. A steady-state creep equation is generally used for solders [1,2], and it supposes that the secondary-, or minimum-, creep rate occupies the entire creep life. However, secondary creep accounts for only about 15 % to 40 % of the entire creep life for solders. Thus, the equation may not represent the entire creep life."

Jan 1, 2012

By M. Cuba

Geostatistical modelling aims at providing unbiased estimates of the grades of elements of economic interest in mining operations, and assessing the associated uncertainty in these resources and reserves. Conventional practice consists of using the data as error-free values and performing the typical steps of data analysis - domaining, semivariogram analysis, and estimation/simulation. However, in many mature deposits, information comes from different drilling campaigns that were sometimes completed decades ago, when little or no quality assurance and quality control (QA/AC) procedures were available. Although this legacy data may have significant sampling errors, it provides valuable information and should be combined with more recent data that has been subject to strict QA/QC procedures. In this paper we show that ignoring the errors associated with sample data considerably underestimates the uncertainty (and consequently the economic risk) associated with a mining project. We also provide a methodology to combine data with different sampling errors, thus preserving the relevant global and local statistics. The method consists of constructing consistent simulated sets of values at the sample locations, in order to reproduce the error of each drilling campaign and the spatial correlation of the grades. It is based on a Gibbs sampler, where at every sample location, the actual sample value (with error) is removed and a conditional distribution is calculated from simulated values at nearby sample locations. A value is drawn from that distribution and kept only if it satisfies some statistical requirements-specifically, the global relative error and local means and variances must be reproduced. All sample locations are visited and simulated sample values are generated iteratively, until the required statistics are satisfactorily attained over all sample locations. This generates one realization of possible sample values, respecting the fact that the actual samples are known to carry an error given by the global relative error. Multiple realizations of simulated sample values can be obtained by repeating the procedure. At the end of this procedure, at every sample location a set of simulated sample values is available that accounts for the imprecision of the information. Furthermore, within each realization, the simulated sample values are consistent with each other, reproducing the spatial continuity and local statistics. These simulated sets of sample values can then be used as input to conventional simulation on a full grid to assess the uncertainty in the final resources over large volumes. The methodology is presented and demonstrated using a synthetic data-set for clarity.

Jan 1, 2012

In China, thin coal seams are rich in resources but are technically challenging. The mineable reserves in these seams account for 20.4% of the total coal resources, while the current production accounts for only 10.4% of the total annual production. Characteristics such as narrow mining space, low level of mechanization, poor working environment, and high cost of mining, restrict the development of mining safety and efficiency. Recently, fully mechanized mining technology has developed rapidly for thin coal seams, the level of yield and efficiency has reached or exceeded the international standard, and some state-owned key coal mines are considering automation of their mining process. In thin coal seams with hard stone bands that contain concentrations of pyrite, a specialized software, LS-DYNA, is used to calculate the rational blasting parameters that are used in the deep-hole pre-splitting blasting. Using this method the hard stone bands are fractured effectively, and hence increasing the coal productivity. In addition, mining advance rate were increased by enhancing the level of fully mechanized equipment and safety improved by increasing gas drainage from the gas outburst prone seam located some 7 m below the coal horizon. At present, thin coal seam mining technology faces many challenges, including the low level of equipment automation, the low advance rate in mixed coal-rock ground, and the large number of the mine personnel underground. By lowering the labour intensity and improving efficiency through automation and other measures, more efficient working faces can be implemented in thin coal seams.

Jan 1, 2012

By T. van Heerden

A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2?5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50?500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complement the typically used electron microscope techniques.

Jan 1, 2012