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By Cam Thomas, Steve Bernard

Various types of blasting instrumentation can be used in the field to analyze conditions before, during and after a blast, and to indicate what changes need to be made. When different types of measurements are combined together, the blaster can end up with useful data that can pinpoint the source or sources of problems and what changes have to be made. This paper outlines two case examples where blasting instrumentation was used to overcome problems in separate quarry operations. Extensive measurements with different systems led to significantly improved blasting results.

Jan 1, 2012

By Shadia J. Ikhmayies

"Nanocrystalline CdS thin films were prepared by vacuum evaporation on glass substrates at ambient temperature. The films were characterized by recording and analyzing their transmittance, X-ray diffraction (XRD) patterns, scanning electron microscope (SEM) images and Energy dispersive X-ray (EDAX) spectra. X-ray diffractograms revealed that the material is nanocrystalline with predominant cubic crystal structure and preferential orientation along (1 1 1) plane. SEM micrographs confirmed the nanostructure of the material and showed uniform and well covered surfaces. EDAX reports revealed that the films are cadmium rich and contain oxygen. The first derivative of the absorbance was used to estimate the effective bandgap energies of the nanocrystallites and the hyperbolic band model was used to estimate their radii. The results were compared with those obtained by XRD and SEM measurements.IntroductionCdS thin films are of considerable interest as they can be used in fabrication of solar cells and other opto-electronic devices. In particular, heterojunction solar cells with a narrow band gap base and wide band gap window have been investigated in an attempt to develop efficient, stable and low-cost solar cells [1]. The CdS quantum dot embedded in a glass matrix is one of the well-known quantum dot systems and its electronic and luminescent properties have been studied extensively [2].Three-dimensional confinement of carriers within the quantum dots leads to the blue shift of the optical band-gap and to modification of many properties of semiconductor material [3]. It has been argued that in these semiconductor nanoparticles the hyperbolic band model gives a better fit to the observed quantum size effect as compared to the effective mass approximation [4]."

Jan 1, 2012

By Jason Ganley, Yingjia Liu, Adam Dekich, William Tilson, Jeffrey Fergus, Dileep Kumar CJ

"Manganese cobalt spinel oxide coatings have been shown to be effective for preventing chromium volatilization from interconnect alloys, and the associated cathode poisoning, in solid oxide fuel cells. During high temperature exposure a reaction layer consisting of chromium containing spine! forms due to reaction with the chromia scale formed on the alloy. The electrical conductivity of this reaction layer is much lower than that of the coating material and thus can increase the overall area specific resistance (ASR) of the system. The approaches to reducing the ASR are to reduce the thickness and/or increase the electrical conductivity of the reaction layer, which includes both the high-chromium spinel phase and the chromia scale. In this paper the effects of transition metal dopants on the amount and properties of reaction products formed during the reaction of spine! oxide coating materials with chromia are presented.IntroductionThe high cost and difficulties involved with the processing of chromia based ceramic interconnect materials for SOFCs are driving the search for metallic interconnects [1, 2]. The reduction in the operating temperature of SOFC has allowed for the use of high chromium alloy steels for this application [3]. However, the volatilization of chromium from the chromia scale, and the associated poisoning of the cathode, remains a problem which needs to be addressed [ 4]. Though the application of manganese cobalt oxide spine! coatings on the alloy surface substantially reduces chromium poisoning of the cathode [5], the low electrical conductivity of the reaction layer formed between the chromia scale and coating affects the performance of interconnect. Incorporating transition metal ions in the reaction layer could alter the electrical characteristics and improve the performance. Copper and nickel doped manganese oxide spinels are widely used as thermistors due to their high electrical conductivity and negative temperature co-efficient of resistance characteristics [ 6, 7]. Hence doping of copper and nickel in manganese-cobalt spine! oxide composition may improve the electrical characteristics of interaction layer as well and is attempted here."

Jan 1, 2012

By Suleyman Tekeli, Serdar Salman, Bulent Aktas

"The effect of La2O3 content up to 15 wt% on phase stability, sintering and microstructure of cubic zirconia (8YSZ) was investigated. XRD results showed that the specimens containing up to 15 wt% La2O3 were composed of only cubic structure. Also, the specimens doped up to 5 wt% La2O3 revealed no La2O3 peaks, indicating that La2O3 was completely solubilized in the cubic structure. However, when> 5 wt% La2O3 was added, the peak of La2Zr2O7 compound emerged, showing that the overdoped La2O3 was not solubilized in the 8YSZ matrix. The lattice parameter of the 8YSZ slightly decreased with the increasing La2O3 content up to 1 wt% but further increase in the La203 amount resulted in an increased lattice parameter. The comparison of grain size of the 8YSZ specimens with various La2O3 content showed that grain size slightly increased with the increasing La2O3 content up to 1 wt% but further increase in the La2O3 amount resulted in a decreased grain size.IntroductionAt atmospheric pressures, three polymorphic forms of Zr02 are stable at different temperatures i.e. monoclinic, tetragonal and cubic. A high-pressure orthorhombic form of Zr02 has also been reported[l]. The successful production of pure Zr02 bodies is not possible all the time due to the large volume expansion associated with the martensitic tetragonal-monoclinic transformation. This fact restricts the applications of zirconia, in spite of its excellent mechanical and thermal properties. However, the stabilization of the high temperature polymorphs at room temperature as stable phases is made possible by addition of suitable dopants. Fully stabilized cubic Zr02 and partially stabilized tetragonal Zr02 show interesting properties and are widely used as ionic conductors, coatings and gas sensors in solid oxide fuel cells and structural applications[2]. Most frequently used dopants include Y203, CaO, MgO and Ce02, although other oxides, such as those of rare earth elements, can also act as stabilizers of the high temperature structures. The incorporation of aliovalent cations to the lattice, forming substitutional solid solutions, allows to control the concentration of anionic vacancies in the structure. This aspect is particularly important in designing ionic conductors[3], and is also determinant in the stabilization process[ 4]. The process of stabilization with larger ionic radii dopants is rationalized by the crystal chemistry model[ 5], that describes the dopant cations as typical stabilizer when they have larger ionic size, lower charged state and higher ionicity than Zr4+ The ionic radius of Zr4+ is 0.84 Å and that for La3+ is 1.016 Å [6]."

Jan 1, 2012

By J. E. Danoczi

Shore Gold Inc. (Shore) is presently designing a diamond processing plant for the Star and the Orion South kimberlite deposits in the Fort à la Corne (FalC) area in central Saskatchewan. The first step in the plant is diamond liberation and occurs in the comminution section. Diamond liberation is the process of breaking up the kimberlite rock, as gently as possible so as not to damage the diamonds. Autogenous grinding mills (AG mills) use a combination of impact crushing, abrasion and attrition to break up the kimberlite. The forces that occur during the actions of abrasion and attrition cause the kimberlites to break up preferentially along lines of weaknesses which offers a ?diamond friendly? method of comminution. Hard competent kimberlite is commonly found in the diatreme zone as well as the root zone of the volcanic pipe and is the source of kimberlite for most of the Southern African diamond mines. Softer kimberlite is typically found in and around the crater area of a volcanic pipe and it is this kimberlite that makes up the majority of kimberlite for both the Star and Orion South deposits. These softer kimberlites can be readily broken up using abrasion and attrition imparted by AG mills. In order for Shore to benefit from the softer kimberlite found in the Star - Orion South diamond project, two large (10.97 m diameter x 7.10 m long) AG mills were designed for the comminution section based on extensive test work and simulations by Metso Minerals (Metso).

Jan 1, 2012

By I. Govender

Positron-Emission-Particle-Tracking (PEPT) has enabled the non-invasive observation of charge and slurry transport in model mills under operational conditions. We use high quality PEPT data to infer that the charge motion can be effectively described by a non-Newtonian granular fluid. An improved theory for slurry transport, including inertial effects, is presented.

Jan 1, 2012

By Sudhir Kumar Kashyap

In underground activities ground control is a challenging problem. It affects safety, production, and efficiency. As per statistics of accident data, ?fall of roof/sides? is one of the major causes of mine accidents. In many cases, our experiences and understanding of soil and rock behavior still fall short of being able to predict how the ground will behave. Presently, empirical approaches to design are widely used in estimating mine support parameters. Under these circumstances, expert judgment plays an important role, and such accidents can be obviated with accurate measurement and optimization of data and analysis using the neuro-fuzzy technique of artificial intelligence. Recently, a neuro-fuzzy hybrid approach has become one of the major areas of interest in engineering fields because it gets the benefits of neural networks as well as those of fuzzy logic systems, and it removes the individual disadvantages by combining them on the common features. Neural network and fuzzy logic technologies have common features, such as a distributed representation of knowledge, the ability to handle data with uncertainty and imprecision, etc., like in ground control. Fuzzy logic technique has tolerance for imprecision of data, while neural networks have tolerance for noisy data. In this paper we have focused an intelligent technique, i.e., neuro-fuzzy technique, to approximate the setting load given to the standing support (props) erected for the purpose of supporting freshly exposed roof during underground mining. We have used twelve input variables of rock parameters, and after having trained using a neural network with a sigmoidal function as an activation function, simulation was done to find the output parameter, i.e., the pre-load (setting load)to be applied on props. Outputs of the neural network were again fed to the fuzzy system together with the twelve parameters, incorporating five triangular membership functions for each parameter. Final optimum output was approximated using the MATLAB program, which was found to be satisfactory. Neuro-fuzzy technique has better performance over individual neural networks or fuzzy logic technique.

Jan 1, 2012

By Sundarrajm Suresh, Hrushikesh G. Pimpalgaonkar, Thiyagarajan Paramadayalan

In this paper, a model of a fuel cell system has been proposed to account for the membrane physics at the micro level which is coupled with the macroscopic flow and mass transport phenomena occurring in a single channel of a Polymer Electrode Membrane Fuel Cell (PEMFC) system. We have developed a novel approach to model the catalyst layer electrochemical processes in a Membrane Electrode Assembly (MEA) and coupled it with mass transport and fluid flow calculations at the channel level using STAR-CD commercial software. The predicted values of the cell voltage from this micro-macro model are validated with experimental data available in the literature. A sensitivity analysis has been carried out to study the effect of the design and operating parameters such as catalyst loading and initial temperature on the overall performance of the PEMFC. The results indicate that the cell voltage increases at higher platinum catalyst loading and is also independent of the choice of initial cell temperature.

Jan 1, 2012

By D. Royston

Reducing SAG Mill feed size has been a major trend in recent years. ?Mine to mill? strategies have reduced blasted-rock size, and in a growing number of operations reducing the primary crusher CSS and/or adding additional crushing upstream of the SAG mill have reduced rock feed size. While reducing feed size will increase SAG mill throughput, issues arise in terms of retaining charge in the mill, exposing the shell lining to impact damage, and maintaining milling performance should the pre-crush system shut down. This paper reviews the past experience on pre-crushing for SAG mills and provides an analysis of liner design (in particular grates and shell liners) for pre-crushed feed.

Jan 1, 2012

By S. P. Pereira

The mechanized mining cycle using loaders and shuttle cars had its peak in terms of usage in the mining industry during 1950 through 1960. In Brazil, this system is still used at underground coal mines in southern Santa Catarina coal basin. With the aim of investigating the benefits of a new mining scheme using the room and pillar method for these local mines, a computational simulator model was developed in order to investigate the mining cycle. This paper presents the methodology used to develop the simulator and the results that the simulation shows regarding impact of the proposed new scheme on mining productivity.

Jan 1, 2012

By J. Utt

Recent developments in circulating fluidized bed (CFB) once-through supercritical technology (OTSC) have enabled this technology to be offered as a utility-scale alternative competing head-to-head with pulverized fuel (PF) OTSC offerings. One clear example is the CFB supercritical unit at the Lagisza Power Plant in Poland, owned by PoludniowyKoncernEnergetyczny SA (PKE). This unit has now been in commercial operation for three full years, exhibiting very good performance, and has validated Foster Wheeler's performance model at this utility scale as well as for units in the 600 MWe and 800 MWe size ranges offering net efficiency of -43 per cent (LHV basis). This operating unit has also proven the use of the world's first FW/BENSONTM vertical-tube OTSC low mass flux technology. Since the Lagisza original international tender specified OTSC PF technology, it is important to note that the alternative selection of CFB OTSC technology over conventional PF technology is of historic significance, not only for the validation of the CFB supercritical platform as a viable alternative to conventional PF technology, but it also positions the CFB OTSC with fuel flexibility for offering of sizes up to and including 800 MWe units. This paper explores the differences between CFB OTSC technology and standard PF OTSC in utility power generation. Selection criteria, fuel burning range in both technologies, and other selection drivers are discussed. Economic analysis of both technologies, based on existing cases, is also provided. Also discussed are the technical advantages and uses of each technology. Foster Wheeler has recently been awarded a contract for four units of CFB OTSC technology, which utilizes a 2 on 1 configuration of two 550 MWe CFB OTSC boilers on two single 1000 MWe turbines. Essentially this provides a fuel-flexible low-emissions alternative to a 2 x 1000 MWe solid fuel power block.

Jan 1, 2012

By Lucas Nana Wiredu Damoah, Lifeng Zhang

"The use of electromagnetic field to remove suspended particles from metals such as aluminum by pushing to the boundary has been well studied. However, the potential of this method is yet to be exploited for the removal of inclusions from silicon. Considering the increasing amount of Top-cut SoG-Si scraps year upon year, there is the need to harness all the potentials of technologies to recycle this materials to ensure sustainability. This study investigates, and discusses new results on the effect of processing parameters such as composition, coil current, and frequency on the removal of inclusions from silicon under high frequency AC electromagnetic field.IntroductionThe solar cell silicon making industry requires pure and clean silicon in order to maximize the conversion potential of the solar cell material. The conversion efficiency of solar cells is limited by minority carrier recombination at dislocations and those intra-granular defects such as impurities, small clusters of atoms, or precipitates [1]. Recent global developments in the energy sector with a drive for the production of clean, reliable, and affordable energy have stirred a rapid growth in the production of photovoltaic (PV) cells.[2] Thus over the years, silicon based PV cells has seen a lot of growth as it has a PV market share of over 90 % [3] either as single-crystalline silicon, or multi-crystalline Si (MC-Si), or amorphous Si [4]. MC-Si produced by directional solidification of solar grade silicon melt dominates the silicon PV market. During the directional solidification process, SiC and Si3N4 particles within the melt are pushed by the solidification front to the top of the ingot which is the last to solidify. Therefore the top of the ingot is cut generating what is known as top-cut solar silicon scraps. The Si3N4 particles are mainly from the coating material at the inside surface of the silica crucible and from the air absorption during solidification process. The SiC particles mainly stem from the carbon reduction process of the primary production of silicon [5]. For sustainability the silicon in the top-cut silicon scraps must be recovered. Therefore methods for removing non-metallic particles, such as SiC and Si3N4, from the silicon are important in order to recycle the top-cut scraps to a useful feedstock for the silicon solar cells manufacturing."

Jan 1, 2012

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Jan 1, 2012

By H. C. Liang

Reverse osmosis (RO) and nanofiltration (NF) are widely regarded as being best available technologies (BATs) for removing contaminants of concern from water. In recent years, NF or RO treatment has increasingly gained more acceptance in the mining industry for treating mine water to remove a wide assortment of contaminants, either for meeting discharge standards or for internal re-use in mining processes. Consequently, the number of NF or RO membrane mine water treatment facilities has steadily increased. Although NF or RO membrane filtration can be a powerful tool in mine water treatment, especially when multiple contaminant removal is required, it also has many potential disadvantages. Besides the generally higher capital and operational costs for the high pressure membrane processes, organic constituents in mine water may foul the membranes, while inorganic compounds such as gypsum, calcite, or silica are liable to scale the expensive membranes if proper pre-treatment processes are not implemented. Additionally, because these membrane treatment processes generate a substantial reject or brine waste stream in addition to the clean treated water or permeate stream, brine management also needs to be considered carefully when deciding upon the viability of an NF or RO mine water treatment process. Because of these issues, it is important to conduct detailed analyses of the trade-off between selecting NF or RO vs. using chemical treatment processes when designing a mine water treatment facility.

Jan 1, 2012

By A. Choudhury

Deep open-pit mines are becoming increasingly common in the highly mineralized arctic and sub-arctic regions. Air inversion is a frequent occurrence in these regions, and is exacerbated by the natural topography of an open-pit mine. Due to such inversions, the air quality in open-pit mines deteriorates very rapidly. Transport of gaseous pollutants under arctic air inversion is complex and involves an interaction between flow, thermal and convective transport systems. This paper discusses the construction and validation of a three-dimensional model that simulate the flow of air and the transport of gaseous contaminants in an arctic open-pit mine and the effect of low influent velocity and large gust velocities on the contaminants profiles in the mine. It was found that while higher velocities may remove contaminants from the pit bottom, they may not remove the contaminants from the pit entirely, necessitating artificial mitigation measures.

Jan 1, 2012

By Bo Yan, Jiaquan Zhang, Haibo Sun

"Based on the validation of steady-state isothermal mathematical model by a 0.4-scale water model for the single-strand slab casting tundish, the effect of varying pouring temperature on the flow, temperature field, and residence time distribution(RTD) of the liquid steel was studied by a transient hydrodynamic model. Due to the decreasing temperature of ladle stream over a casting period of 50 min, the direction of vortex flow at the downstream side of dam changes to clockwise from the anticlockwise at 4 min after the new teeming, and reverts to anticlockwise direction again at 43 min. Meanwhile, the melt flow state in the dam hole is also varying with time. For conventional isothermal water modeling, the RTD parameters obtained are much different as compared with the non-isothermal ones. For the flow control devices(FCD) design, however, the identical optimal scheme can be concluded from the point of view of isothermal modeling.IntroductionOriginally, tundish was adopted as a buffer and distributor to hold and allocate molten steel for sequence casting upon ladle exchange and to provide a desired steel flow rate to the mould below. With the increasing demand to strand quality, the tundish has become a critical metallurgical reactor to enhance inclusions removal, avoid reoxidation of molten steel, and prevent slag entrapment. The general trends to obtain these metallurgical effects are to optimize steel flow pattern and to extend the residence time of molten steel in the tundish through increasing the volume of tundish and/or using FCDs in the interior of the tundish."

Jan 1, 2012

By A. Allaire

The Goldex operation of Agnico-Eagle Mines (AEM) commenced operations in the spring of 2008. Following some months of initial operation, the grinding circuit capacity was under-performing according to the original design throughput. BBA Inc. (BBA) was commissioned, in February 2009, to study the different options and recommend the quickest and most cost-effective solution to increase the grinding circuit throughput rate. The mandate was to increase the throughput of the grinding circuit to beyond the original design of 7,000 tpd to 8,000 tpd or greater, while retaining the existing SAG and ball mills. The circuit was modelled using JKSimMet software to evaluate the different options, each with a number of different operating parameters. The option of secondary crushing of the SAG mill feed was retained. Comparison of the different options and simulation outcomes, design of the secondary crushing circuit, operating conditions, and initial adjustments in the design and operating results of the new grinding circuit are discussed in this paper.

Jan 1, 2012

By H. Ogasawara

Information on rock stress is important for safe mining in seismically active ground. On a major gold mine, a few tens of crews are continuously conducting geological drilling with small pneumatic machines. However, stress measurements are not often carried out in South African deep-level gold mines. One of the reasons is the drilling diameter that overcoring requires, which is much larger than the diameters used in regular geological drilling, e.g. Boart Longyear Metre Eater, which drills A[O] or B[O] holes. Larger diameter holes result in slower drilling advance, more load in transportation and handling at sites, and higher cost. In order to enable overcoring in BX size (60 mm diameter), we modified the compact conical-ended borehole overcoring (CCBO) technique that has been suggested by International Society for Rock Mechanics (ISRM) and was originally designed for NX drilling (76 mm diameter). With a single overcoring, the 3-D stress tensor can be determined. We tested this modified method at a depth of about 3 km at Moab Khotsong mine in South Africa. We worked with drilling crew who usually work at geological drilling with the Metre Eater. In January 2011, we tried using regular geological drilling tools (a sequence of a normal BX bit, reamer, and rod) without success. In August and September 2011, introducing stabilizers and thin BX bits, we succeeded. We could complete a cycle of procedures necessary for an overcoring, including shaping the borehole-end conically, glueing a 16-element strain cell, and overcoring, within 2.5 hours. Only 10 cm overcoring is needed, which increases the chance of successful overcoring in heavily fractured conditions. This modified method is suitable for up-dip holes to depths of 10-15 m from tunnels, and has the potential to be widely used at the initial stage of geological exploration drilling at many localities.

Jan 1, 2012

"Pilot plants for pressure hydrometallurgy represent special design and project execution challenges. Over the past twenty years, Zeton has designed and fabricated a variety of world-class pressure hydrometallurgical pilot-plant facilities, and this paper discusses design considerations and strategies related to such projects. Project execution methods are also discussed, and guidance is given for the selection of materials of construction and for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical pilot equipment. The paper concludes with a discussion of the need for process similarity with future commercial operations and the realities of pilot-scale equipment.INTRODUCTIONThe process technology developer or owner and the designer/fabricator of a new pilot-plant facility are faced with some difficult technical choices even after the decision to build a dedicated plant has been taken. A pilot-plant project is usually on the critical path of a large commercial project involving investments many multiples greater than the capital cost of the pilot plant. Schedule savings in the design, manufacture, and commissioning of the pilot plant or in a rapid completion of the experimental program can be disproportionately beneficial to the overall development project. However, inappropriate shortcuts resulting in major oversights can be disproportionately problematic.A number of considerations and suggestions for both the project execution approach and the process engineering design of pressure hydrometallurgical pilot-plant facilities are presented as a guide for potential owners and operators of new pilot-plant equipment and facilities."

Jan 1, 2012

By Monika Patrycja Polak - Micewicz

This paper presents an approach for estimating the fatigue life for the base of powered roof supports (shield) manufactured by the FAZOS roof support company. FAZOS?s powered roof supports are designed to operate on an inclined coal seam in full caving with a medium, strong roof strength. This shield support is utilized in conjunction with a shearer and face conveyor for a complete longwall mining system. To design shield support, it is essential for contractor to know the physical (hardness, toughness, etc.) and mechanical properties of material (tensile strength, Young?s modulus, etc.) used for the shield support as well as the geotechnical properties of the mine site. The fatigue strength of the shield support material depends on the mean stress, alternating stress, cycle frequency, transport dimensions, mine environment and other factors. In order to estimate the fatigue life for a powered roof support system, it is assumed in this paper that the support must keep the roof stable in the mine under variable load cycles. The approach selected in this study contains Goodman?s model (Goodman, 1899) for all blocks in the design housing which is subjected to sinusoidal load. On this basis, the degree of fatigue damage was calculated and compared to the results of experimental tests. It will be shown that there is a significant detrimental effect on the fatigue life of the base of the powered roof supports due to geometrical notches. The Ramberg-Osgood model and damage accumulation rule (Palmgren-Miner) (Miner M., 1945) were used and numerical analyses were conducted, utilizing ANSYS finite element software. These analyses play a very important role in longwall casing design. The proposed method allows assessment of the yield state and forecast of the structure cracking, taking plastic strains occurrence into account. The presented method is universal and can be applied for fatigue life estimation of other subassemblies of powered roof supports. The final portion of the paper presents results of variable amplitude loading simulations on the S355N and S690Q steel used to make powered roof supports. The results of the physical tests were compared with the results from finite element methods. The proposed approach to calculate fatigue life gives the best correlation between the experimental results and calculated values of fatigue life for the powered roof support base. Finally, the design process uses a simple approach to predict fatigue life in a short time, reducing design costs and providing longer service life for roof supports.

Jan 1, 2012