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By S. S. Hsieh

As part of a program to address the long-term need to ensure adequate supplies of domestic phosphate raw materials, the Tennessee Valley Authority (TVA) has conducted considerable research on dolomitic phosphate rock beneficiation. The discovery that alkyl diphosphonic acids act as phosphate mineral depressants led to the development of several processes involving a carbonate flotation step for the effective beneficiation of these problem ores. Most recently, a partial deoiling process in which the reagent consumption is greatly reduced has been developed. The reduction is achieved because part of the initial feed is beneficiated without passing through the separate carbonate flotation step. Using this method, a phosphate product containing 30.6-30.9% P2O5 and 0.7-0.8% MgO was obtained from a Florida dolomitic phosphate pebble that contained about 23% P2O5 and 2.0% MgO. The P205 recovery was 80.8-86.5%.

Jan 1, 1991

By W. L. O?Connell

[Patent Issue No. Date Issued To Subject 386,504 July 24, G. Sweanor The separation of quartz from a 1588 metal with a liquid such as CS2 or CHC13 under water by introducing mixture into water layer. Quartz will stay in water layer while metal sinks through organic.]

Jan 1, 1963

By J. A. M. Cano

Pot Grate tests were carried out in the pilot plant at Samarco producing pellets containing SiO2 between 2.0% and 2.2% in a wide range of basicity to be used in blast furnace. These pellets were submitted to tests in Samarco's laboratory and another laboratory in Germany to evaluate the metallurgical properties. The pellets in the binary basicity range (CaO/SiO2) from 0,87 to 0,95 were those that presented the best results in the Pot Grate tests. Based on the results, these pellets are being routinely produced?on industrial-scale confirming the results observed in laboratory tests.?

Jan 1, 1994

By J. A. M. Cano

Since the beginning of operations at the pellet plant at Ponta Ubu ES, Samarco Mineração SA has produced pellets for direct reduction and blast furnace processes. Of the total amount of pellets produced from 1977 through 1993, 55% are used in the blast furnace, about 45 Mt (49.6 million st). The principal components of pellet gangue are calcium oxide, magnesium oxide, silica and alumina. They should be added in adequate quantities to guarantee the mechanical resistance of the fired pellets under blast furnace conditions. Over the years, the pellets produced by Samarco had a silica content between 2.5% and 2.8% and varying binary basicity preferably between 0.8 and 0.85. On the other hand, the increasing amount of industrial waste in siderurgical plants caused by the increase of steel production has caused some countries to put into practice methods to reduce the volume of slag produced in the blast furnace. This paper’s goal is to find an alternative for decreasing the amount of slag produced in the blast furnace. It is possible to decrease pellet gangue by decreasing the silica content to about 2%, leaving the metallurgical properties and quality of pellets unaltered. For this work, Samarco pellets were used with SiO2between 2.5% and 2.8%, pellets with high silica and pellets with SiO2 between 2.0% and 2.3% low silica. Both were partially fluxed by the range of varying basicity CaO/SiO2from 0.8 to 0.95 during production.

Jan 1, 1995

By W. E. Horst

Historically, research organizations have made significant contributions to the development and commercialization of new chemical products for the mining industry and examples of commercial results are cited With the recent demise of research organizations within the mining industry and dynamic changes in the industry, the supporting role of R&D groups has become limited or non-existent. Cat- reduction requirements and new raw-material sources offer future opportunities for R&D organizations to continue their effective participation in the commerical development of new chemical products. Potential areas of interest for future process applications are reviewed.

Jan 1, 1986

By Adam Feiler, John Ralston

Optical reflectometry was used to study the attachment and subsequent detachment of silica particles (diameter 25 nm) from the surface of titanium dioxide wafers under well-defined hydro- dynamic conditions. Atomic force microscopy was used to measure the interaction between silica spheres (diameter 7 pm) and titanium dioxide wafers under the same solution conditions. In addition to repulsive electrical double layer forces, adsorbed polyphosphates provide a short-ranged steric layer that reduces the lateral interaction between the surfaces. The use of these two complementary techniques has given valuable insight into the process responsible for fine particle detachment and has particular application to surface cleaning.

Jan 1, 2003

By M. D. Flavel

Research programs conducted by Allis-Chalmers Corporation are showing that the most efficient energy use in crushers is achieved when the forces applied to particles undergoing breakage are increased. Laboratory bench scale tests have been developed to confirm this phenomena, which was first observed in the field using HYDROCOME crushers with automatic setting controls. A new testing machine is described and methods of maximizing such benefits are postulated. FOREWORD Allis-Chalmers Corporation was founded in Milwaukee, Wisconsin, in 1847 as the E. P. Allis Company, which had an initial interest in manufacturing components in the grinding of flour. As such, its roots were started in reducing material size, which is covered by the generic term, comminution.

Jan 1, 1981

By P. R. Khangoankar, S. Devasahayam

An experimental study of the particle charac¬teristics of the magnesium carbonate crystals formed by the reaction between magnesium chloride and sodium bicarbon¬ate at different temperatures is described. The rate of growth of magnesium carbonate crystals for any constant tempera¬ture is established, and this rate of growth is related to the degree of supersaturation at the given temperature. The activation energy calculated using empirical constants de¬rived from the relationship between the crystal growth rate and supersaturation, is indicative of a surface-reaction mechanism.

Jan 1, 1996

By D. Lelinski, X. Nie, J. D. Miller, J. Hupka, K. Bukka

A preliminary characterization of soil components contaminated at a low level (7 nanocuries per gram) with toxic/radioactive metals has been carried out. Most radioactivity and metals content were present in the minus 100 mesh (<150 µm) size fractions. None of the size fractions examined qualified for uncontrolled disposal at dump sites, thus all material would have to be moved to discharge-controlled landfills. The metal content of the sample was below the limits for economical recovery, therefore eventual processing would be dictated by environmental concerns.

Jan 1, 1992

By J. D. Miller

The recent non-equilibrium electro-phoretic mobility measurements by laser-Doppler electrophoresis coupled with the stability and prevalence of collector colloids in soluble salt flotation systems suggest that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by hetero-coagulation. Previously reported flotation results confirm this surface charge/collector colloid adsorption model. However, the nature of the inter-particle forces responsible for hetero-coagulation of such oppositely charged particles at high ionic strengths remains to be determined. In this regard, atomic force microscopy was used for inter-particle force measurements at high ionic strengths. Model systems such as polystyrene/quartz and silica/sapphire were studied to measure the particle interaction forces prevalent at high ionic strengths. Results from this study indicate that while repulsive hydration forces exist between similarly charged hydrophilic particles, attractive forces exist between oppositely charged hydrophilic particles in high ionic strength solutions. The repulsive forces between similarly charged hydrophilic surfaces at high ionic strengths (2-4 M) are described by a double exponential function with decay lengths of 0.17 and 1.4 nm depending upon the surfaces involved. On the other hand, attractive forces were observed between oppositely charged hydrophilic surfaces at high ionic strengths (2-4M) and were described by a single exponential function with decay lengths of up to 9 nm depending upon the surfaces involved.

Jan 1, 1996

By P. Bevilacqua, G. Ferrara

Hydrocyclones and other dynamic separators are normally fed with pulps consisting of water and solid particles. The solids usually consist of particles of different sizes, shapes and densities. Except in the special case of monocharacteristic particles, the particles are segregated by these differences in size, shape and density. Segregation is magnified by the high values of centrifugal acceleration in the hydrocyclones. This paper develops a segregation theory that indicates the major variables involved. Experimental data on segregation under different operating conditions for mixtures of magnetite and/or ferrosilicon and nonmagnetic minerals are reported.

Jan 1, 1997

By G. Ferrara

Hydrocyclones and other dynamic separators are normally fed with pulps of water and solid particles. The particles have different sizes, shapes and densities and, except in the special case of mono-characteristic particles, are segregated into size, shape and density. Segregation is magnified by the high values of centrifugal acceleration in the hydrocyclones. This paper develops the theory of the segregation, indicates the major variables involved and reports experimental data of segregation under different operating conditions for mixtures of magnetite and/or ferrosilicon and non-magnetic minerals.

Jan 1, 1995

By S. Brummelkamp, G. Van Weert

Separation of minerals by shape has received little attention, since minerals normally do not break into different shapes during crushing and grinding. However, comminution of consumer wastes generates opportunities for novel separations based on particle shape. For instance, ductile plastics are broken into longer curved shapes, whereas brittle plastics yield angular particles. Using spouting beds for particle separation in water requires controlling the spout&apos;s instability. The preferred geometry for such redesigned spouting beds is reported. Plastic cylinders, discs and spheres were separated as a function of rising water velocity and amount of particles in the system. By using 5 mm particles, differences in settling behavior could be video recorded.

Jan 1, 1999

By G. Van Weert

Separation of minerals by shape has received little attention, since minerals normally do not break into different shapes during crushing and grinding. However, comminution of consumer wastes generates opportunities for novel separations based on particle shape. For instance, ductile plastics are broken into longer curved shapes, whereas brittle plastics yield angular particles. Using spouting beds for particle separation in water requires controlling the spout&apos;s instability. The preferred geometry for such redesigned spouting beds is reported. Plastic cylinders, discs and spheres were separated as a function of rising water velocity and amount of particles in the system. By using 5 mm particles, differences in settling behavior could be video recorded.

Jan 1, 1999

By Mark C. Williams, Thomas P. Meloy

Particle shape characterization is a complex task made more difficult because of the human eye&apos;s sophisticated recognition of shapes, giving rise to the assumption that shape analysis is considered a simple problem. Further exacerbating the problem is the question of whether particles have a general shape. Old and new shape measuring techniques are discussed, particularly the new image analysis methods techniques such as Fourier, Haar, Walsh and Delta. Problems with the current image analysis equipment and future research equipment needs are presented.

Jan 1, 1989

By S. K. Kawatra

For efficient control of particle size in a wet grinding circuit, three alternative methods for monitoring pro- duct particle size are available. These methods are based on: 1. Ultrasonic wave absorption. 2. Low-angle forward scattering of a laser beam. 3. Inferential sizing techniques. The relative advantages and disadvantages of each technique are discussed. A particle size monitor can be used on a single grinding line to control the product particle size. To minimize the number of particle size monitors at an operation consisting of many similar grinding lines, a portable multi-stream on-line analyzer can be used. The paper outlines the design and the operational characteristics of the portable multi-stream online analyzer.

Jan 1, 1979

By G. S. Dobby

Particle collection is considered to occur by particle collision with the bubble followed by the particle sliding over the bubble during which attachment may occur. Collision is quantified by a collision efficiency, EC. The existing model for EC is extended by including particle inertia. Attachment is quantified by an attachment efficiency, EA calculated as the fraction of particles which reside on the bubble for a time greater than the induction time. These calculations use recent data on the liquid velocity distribution over the upper half of rigid spheres. Collection efficiency, EK is given by EK = EC ? EA. Detachment is not considered. The mode is examined and shown to agree with much experimental data. For example the maximum observed in recovery vs particle size (d) can be explained as E increases with increasing d , while EA decreases. The decrease in selectivity at fine sizes is in accord with the model result that for dp < 5µm, EA ? 100% (i.e. EK ? EC) almost regardless of induction time. A decrease in bubble size does increase EK but does not improve selectivity. A high particle density (> 5g/cm3) is shown to cause a sharp peak in recovery vs size and a decreased maximum size of floatability. Finally, the possible effects of bubble and particle concentration are explored.

Jan 1, 1985

By I. O. Otunniyi

The natural hydrophobic response flotation method for beneficiation of printed circuit board comminution fines (PCB CF) still requires many studies to further basic understanding of the process and the flotation traits that the PCB CF presents. Varying particle size distribution (PSD) and water recovery under the scheme show that higher mass pull, obtained at the finer PSD, gave lower water recovery but higher value loss. The reverse also holds: the least mass pull at the coarsest PSD used, -106 + 75 µm, gave the highest water recovery per unit mass pull with the highest reverse recovery. This is unlike what obtains in primary resources processing, where higher water recovery is often with increased fines entrainment. The reverse recovery loss here is, therefore, more due to entrapment with the heavy mass pull characteristic of the method than to the entrainment of value with water. Other peculiarities of the system observed are discussed, with the goal of improving the performance of the process, and broadening the general knowledge of flotation systems.

By R. Hogg, T. F. Dumm

Procedures for particle size analysis on respirable dust from coal mines have been evaluated. Using respirable dusts dispersed in a laboratory dust chamber, size distributions measured using cascade impactors have been com- pared with the results of a variety of laboratory sizing methods performed on samples collected on filters placed side-by-side with the impactors. The laboratory techniques included centrifugal sedimentation, laser diffraction/scattering and automatic particle counting. The general agreement among the various methods was very good, with systematic differences which can be attributed to the different definitions of size used. Simple conversion factors have been obtained which can be used to transform the laboratory data to equivalent aerodynamic sizes. Similar comparisons have been made on samples collected in underground coal mines. Again, the results are in quite good agreement although small discrepancies were observed in some cases. These have been attributed to some degree of agglomeration in the airborne dust, leading to slightly coarser apparent distributions in the impactor samples.

Jan 1, 1987

By Hillary W. St. Clair

In a previous report 1/the author showed that the essential information from particle size analyses of grinding mill products can be represented by three or four parameters derived from the first four moments of the particle size data. These parameters may be used in gamma or beta distribution functions to estimate the weight fraction in any given size range. Moment analysis was used to study the progressive changes that take place in particle size distribution when a homogeneous isotropic mineral such as quartz is reduced in size by impact crushing. 2/ This report briefly reviews the essential features of moment analysis and describes extension of this method to size reduction by ball mill grinding.

Jan 1, 1972