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By R. L. Hopkins

Some typical thiacyclopentanes and thiacyclohexanes were synthesized to provide reference compounds needed for the identification of sulfur compounds in crude oils. Two general methods of synthesis were employed: (1) cleavage of 2-alkyltetrahydropyrans with hydrogen bromide followed by the reaction of the resulting dibromoalkanes with sodium sulfide and (2) the catlyzed reaction of cyclic ethers or 1)4-or 1)5-alkanediols with hydrogen sulfide. Both methods produced mixtures of 2-alkylthiacyclopentanes and 2-alkylthiacyclohexanes with 2-alkyltetrahydropyran as the starting material. The structures of the reaction products were established by analysis for sulfur; desulfurization; gas-liquid chromatography (GLC); mass, infrared, and nuclear magnetic resonance (NMR) spectra; and an alternate synthesis. The synthesis of the cyclic sulfides contributed substantially to the identification of 10 members of this class of sulfur compounds in crude oil.

Jan 1, 1967

By Peter Swanson, Collin Stewart, Wendell Koontz

A seismic monitoring network has recently been installed in the North Fork Valley coal mining region of western Colorado as part of a NIOSH mine safety technology transfer project with two longwall coal mine operators. Data recorded with this network will be used to characterize mining related and natural seismic activity in the vicinity of the mines and examine potential hazards due to ground shaking near critical structures such as impoundment dams, reservoirs, and steep slopes. Ten triaxial strong-motion accelerometers have been installed on the surface to form the core of a network that covers approximately 250 square kilometers (100 sq. miles) of rugged canyon-mesa terrain. Spread-spectrum radio networks are used to telemeter continuous streams of seismic waveform data to a central location where they are converted to IP data streams and ported to the Internet for processing, archiving, and analysis.

This report includes a short history of uranium and its uses, mineralogy of common uranium minerals, and information on the use of electronic prospecting equipment and tests for detecting the presence of uranium. Details are given on geologically favorable areas and formations and practical methods of prospecting. Some information is given on the staking of claims, what lands are open to prospecting, and methods of securing mining rights. A forecast of the economic outlook for uranium is included. Appendixes give sources of additional information and a list of libraries where unclassified Atomic Energy Commission reports may be consulted. Because the increasing use of uranium by industry has revived interest in prospecting and exploration for this element, the Bureau of Mines has issued this report, which brings up to date and expands the subject matter of a hand- book on uranium exploration and production published in 1956.l

Jan 1, 1968

By David J. Kusler

This Bureau of Mines study is an appraisal of the demand for platinum, should this strategic metal be used as a. catalyst in the National abatement of automobile exhaust pollution. The Clean Air Act 0f 1970, as amended, requires that automobiles produced in 1975 and thereafter be provided with antipollutive measures to control automotive exhaust emissions. The study considers the need for automobile pollution control, the methodology for such control, the annual primary (new) platinum demand for automobiles produced from 1975 to 1990, primary platinum availability, and supply-demand forecasts and outlook. The correlative demand for platinum for the production of the required unleaded gasoline is also considered. Methodology for the study included a forecast of new automobile production from 1975 to 1990, development of automobile survival and retirement data, estimates of new platinum demand under various conditions of salvage, and data on recycling the precious metal from the catalytic converters of scrapped vehicles and existing vehicles when their spent converters are exchanged for replacement units. The new platinum demand for automobile exhaust converters, based on a converter service life of 50,000 miles, is estimated to be 1.41 million troy ounces initially in 1975, rising to 1.68 million in 1980, and declining curvi-linearly to 0.94 million in 1990. The platinum demand for converter longevities other than 50,000 miles can be derived from the tabular data presented. An appendix to the report presents a comparison between longevities of 50,000 miles and 25,000 miles. The petroleum industry's demand for new platinum for the production of lead-free gasolines could total as high as 1 million troy ounces between 1972 and 1981, just for expansion of isomerization and reforming capacity, and is in addition to normal operating demand for this metal.

Jan 1, 1972

By Robert T. Mann

This paper is one of a series being prepared for and published by the United States Bureau of Mines on the quarrying, crushing, and grinding of limestone for cement manufacture. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total coats. It is recognized that publication of total costs might in many instances cause embarrassment to individual producers, as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance of J. B. Thoenen, mining engineer of the Bureau of Mines, in the preparation of this paper.

Jan 1, 1933

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution3 by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1930, however, was unusually dry and represents what may be termed "extreme" low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscahonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.4

Jan 1, 1931

By Liane L. M. Kacinuck

This U.S. Bureau of Mines publication is intended to provide mining industry representatives and regulatory authorities with a reference package dealing with studies on hydrology and underground mine subsidence. An annotated bibliography and a list of additional sources are given and represent references published prior to June 1993. Ninety-two references ware identified and 72 obtained for assessment. Annotating the references included evaluating the study methodology and summarizing the basic results. The references are also compiled based on geographic location to aid the user in identifying articles of particular interest.

Jan 1, 1994

By A. F. Baker

Laboratory flotation of synthetic coal-pyrite mixtures and high-pyritic-sulfur coal indicated that ferric chloride (FeCl3), aluminum chloride (AIC13), chromium chloride (CrCl3), and cupric sulfate (CuSO4) are potential pyrite depressants. For each metal salt there appeared to be a range of pH values and optimum concentration for selectively depressing pyrite in coal flotation. Pyrite was depressed in the pH range from 4.5 to 7.0 with ferric chloride, from 5.8 to 7.0 with aluminum chloride, from 6.4 to 7.1 with chromium chloride, and from 6.4 to 7.4 with cupric sulfate. Best separation of pyrite from coal was achieved in flotation solutions containing from 2 X 10-5 to 5 x 10-5 mole/ liter of each salt. In solutions containing excess salt concentrations, coal was also depressed. These Bureau of Mines tests demonstrated on a laboratory scale that, in solutions containing 4 X 10-5 mole/liter ferric chloride and from 1 x 10-4 to 2 x 10-4 mole/liter sodium hydroxide, the pyritic sulfur content of a Lower Freeport bed coal sample could be reduced from about 2.51 percent to less than 0.60 percent with recoveries of over 83 percent. The depression of pyrite appears to be due to the adsorption of positively charged colloidal metal hydroxide at the pyrite-solution interface. This hypothesis is supported by zeta potential determinations which showed that suspended coal and pyrite particles in solutions containing metal salts are positively charged in the pH range where depression occurs.

Jan 1, 1971

By C. A. Geffen-Fowler

This report, sponsored by the Bureau of Mines, presents the results of an examination of the safety of the Blind Shaft Borer (BSB) shaft sinking system and an alternative modified BSB design concept in comparison to conventional shaft sinking technology. Detailed study of the two systems was also performed to identify and recommend design changes for optimum safety conditions. A comparison of the BSB systems with conventional shaft sinking was made an the basis of relative risk levels. Risk incorporates both the frequency and the potential consequence of accidents. A safety evaluation of the component operations of the two BSB systems was performed using a Failure Modes and Effects Analysis (FMEA) methodology. The results of this analysis show generally that both BSB systems are safer than conventional shaft sinking. The potential risk of conventional shaft sinking operations could be reduced by over 30%, on the average, with the use of the original BSB system, and by an average of about 10% with the modified BSB. Design change recommendations to further improve the safety of these systems include a better fire suppression system, improved man haulage systems and more compact hydraulics. An operational safety manual was also developed for the modified BSB system.

Jan 1, 1981

By Robert P. Vinson

The U.S. Bureau of Mines evaluated a light-scattering technique for discriminating between spherical and nonspherical particles. This evaluation was a three-step procedure. The first step required collecting light-scattering data for a variety of particles. This was accomplished with a particle analyzer called the DAWN-A. The DAWN-A measured the scattered light intensities of individual particles at a forward scattering angle of 40°. These DAWN-A measurements of individual particles are called scattering signatures by the Bureau researchers. The second step in this evaluation was to calculate a sphericity index number using the scattering signatures produced by the DAWN-A. The sphericity index number can range from 0 to 1. A calculated sphericity index of 1 would show that based on the intensity of scattered light, the particle was a perfect sphere. The third and final step of this evaluation was the comparison of the calculated sphericity indices of the various particles. Comparing these indices made it possible to discriminate between the nearly spherical waterdrops and the nonspherical coal and rock dust particles.

Jan 1, 1993

By R. V. Ramani, R. Bhaskar

"The results .of an experimental and theoretical research study into the spatial and .temporal behavior of dust in mine airways is summarized in the paper. Experiments were performed in mine airways under both controlled and .normal operating conditions. The controlled experiments included the documentation of the concentration and deposition patterns for two types of dust under three different velocities. Real-time dust concentration data were obtained using Real-time Aerosol Monitors (RAM-1) to determine the dispersion coefficient in a mine airway. On the theoretical front, a convection diffusion model of the dust flow phenomenon in mine airways was developed considering dominant mechanisms affecting dust transport and deposition in mine airways. Mechanisms modeled include turbulent and gravitational deposition, coagulation, and dispersion.In this paper, comparative analyses of results of the controlled experiments with the predictions of the mathematical model are presented. In addition to the overall validity, the adequacy of the individual components of the model, such as deposition in the total and respirable range, and dispersion are examined in light of the experimental observations.The experimental data from controlled experiments compared more favorably with model predicted results for similar conditions as opposed to the ·comparative analysis results for in-mine experiments. Specifically, the model· predictions for an 800-meter stretch of a mine airway reveal some significant differences from the behavior noticed in the mine. The deposition was lower than that predicted by the model. Consequently, concentrations were higher than those predicted by the model. The implications of these and other findings for further investigations are discussed in the paper."

Aug 31, 1989

By James J. Scott

Eleven workshops were held in various locations throughout the country in an attempt to reach the many diverse groups working in various mineral commodity areas and special ties. These meetings were held between March 1, 1974 and June 25, 1975. They were held under the auspices of the Bureau of Mines Contract to the University of Missouri-Rolla which was designed to help define Bureau research and development priorities. At each workshop a summary of current Bureau research and development was presented and the attendees were asked to present their ideas on what Research and Development programs should be undertaken to meet their needs locally. Participants included representatives of federal and state agencies, educational institutions, mining companies, equipment companies and other interested parties. The workshops covered under this report include lead mining in Missouri, limestone mining, coal mining both surface and underground in the midwest and in the Rocky Mountain area, iron mining in Minnesota, two top management meetings on institutional problems and, finally, a special two-day meeting on roof control.

Jan 1, 1977

By John H. Soulé

"INTRODUCTION The Peerless mine was examined by W. R. Storms, an engineer of the Bureau of Mines, on June 2, 1944, in conjunction with a mineral survey of the adjoining For Bayard Military Reservation. Storms again studied the mine on January 13; 15 and 16, 1945, to determine the possibilities of finding new ore reserves to replace these depleted by mining. A project to explore the Peer-less vein at depths below and to the south of the principal mine workings was proposed. Special attention was given to the possibility of exploring favorable beds in the Magdalena and Lake Valley limestones at points near the Peerless fault.The proposed project was approve and exploratory work started on January 2, 1946, and was completed on June 5, 1946. The mine was not in operation during the project, and all equipment had been removed."

Apr 1, 1947

By S. L. Crouch

An important class of mining problems involves excavations in planar seam or vein-type deposits. In many instances it can be assumed that the seam is at 'infinite' depth in a homogeneous, isotropic or transversely isotropic, linearly elastic rock mss, and that the normal to the plane of the seam is a principal stress direction. Rational planning of excavations in such deposits requires a knowledge; of the stresses and displacements induced by complicated, irregular excavation geometries in the plane of the seam. This problem previously has been solved either numerically or by means of an electrical resistance network analog. Both of these methods effectively simulate the mined portions of the seam as a dislocation in an otherwise continuous mass, and determine the complete solution in terms of the stresses and displacements at the seam. In both cases, the plane of the seam is divided into a number - say, M x N - of squares, and the solution to the problem is determined in terms of the solution to an M x N system of equations. The numerical approach requires that these equations be solved explicitly, while the analog; solves them instantaneously with current analogous to stress and voltage to displacement. A purely numerical solution of practical problems can require a substantial amount of computer time, particularly in situations that demand some sort of sequential analysis, either due to successive mining or to nonlinear behavior of the seam material. This report describes a combined analog-digital computer system for solving problems that are impractical when either device is used separately. The digital computer and the analog are interfaced so that the digital computer can receive information from the analog via a switching matrix and an analog to digital converter, and can activate points of the analog via another switching matrix and a set of digital to analog converters. The resulting hybrid system can be used to simulate arbitrary "stress-strain" characteristics for any portion of the seam by an iterative procedure similar to the initial strain method used in nonlinear finite element analysis. Thus, the hybrid system combines the speed of analog computation with the decision-making capability of the digital computer: the analog instantaneously solves the set of equations, and the digital computer decides how the initial strains must be altered for the solution to be compatible with the prescribed "stress-strain" characteristics for the seam material. The hybrid computer system has many implications for rational planning of underground excavations, since it allows practically any type of inelastic seam behavior or artificial support characteristics to be simulated. Inelastic seam behavior, for example, might be due to either rock failure or to time-dependent deformation.

Jan 1, 1974

By N. Malakondaiah

Several growth chamber and laboratory experiments were conducted to study the germination behavior of plant species on mine spoils and plant growth responses to nutrients on spoils and topsoils. Experiments were conducted to study the germination potential of some native and introduced species under various conditions. The seeds of green needlegrass, side oats grama, thickspike wheatgrass, crested wheatgrass, birdsfoot trefoil and emerald crownvetch were less tolerant, whereas those of alkali sacaton. durar hard fescue, slender wheatgrass, yellow sweetclover and alfalfa were most tolerant to the sodic mine spoil conditions. Addition of leonardite improved the germination potential of some of the poor genninators. Slender wheatgrass and yellow sweetclover were used as test plants to study the fertility status and productivity potential of stockpiled topsoils and spoils collected from Center. Glenharold and South Beulah of North Dakota. The topsoils were neither saline nor sodic but low in N and P. The spoils were neutral to alkaline with SAIL of 12-32, EC of 1.8-5.5 mmhos/cm, Olsen&apos;s P< µ4g/g, and total N <0.07%. Application of N and P together to the topsoils increased the yield of wheatgrass and sweetclover by 88% and 70% of their respective maximum yields, whereas near maximum yields were obtained for both the species by the same treatments to the spoils. The average yields on topsoils were higher than the yields on spoils. The concentrations of major nutrients were higher in plants grown on topsoil, whereas the opposite was true with the concentrations of Mn, Zn, and Cu. Growth chamber experiments were also conducted to study the growth responses of alfalfa, oats and slender wheat grass by the application of Mn and Zn to a sodic coal mine spoil which was previously used for pot culture experiments. Significant growth responses to Mn and Zn were observed in alfalfa but not in oats or slender wheatgrass. Fertilizing the spoil with Mn along with NPK increased the yield of alfalfa to 85% and with Mn + Zn to 99%. Growth responses and plant composition results of this study confirm that the application of major nutrients to spoils can accentuate Zn and Mn deficiencies in some plants.

Jan 1, 1982

By R. L. Schmidt

The Methane Control and the Respirable Dust Groups at the Twin Cities Mining Research Center (TCMRC) cooperated recently in obtaining production samples of approximately 1 ton each, from the loading conveyors of a ripper, a borer, and a loading machine in conventional development headings. These samples were sized, in four stages, from plus 4 in to minus 10 µm. The conventional product had the least fines of the three production methods. The borer product had more fines than did the ripper product, but it also had a greater amount of large pieces. All three products, as sampled, had essentially the same amount of minus 10-µm particles. Photomicrographs and surface?-area comparisons were made. Gas -adsorption, surface-area determinations on particles under 37 µm give essentially the same value. Surface-area calculations, assuming spherical particles and no porosity, give a smaller area to the conventional product.

Jan 1, 1972

By M. J. Ferrante

Laboratory-scale tests were undertaken to examine several electrolytes for possible use in separating nickel and cobalt from products being prepared at Nicaro, Cuba. The most extensive work was done with nickel sulfate-ammonium fluoride, ammonium fluoride, ammonium sulfate, and nickel sulfate-boric acid electrolytes. All four electrolytes exhibited some selectivity for dissolving nickel carbonate from Nicaro basic carbonate used for regeneration. The nickel sulfate-ammonium fluoride electrolyte exhibited less selectivity for dissolving nickel carbonate from Nicaro basic carbonate than it did from synthetic mixtures. Ammonium fluoride leaching experiments showed that a low concentration and high temperature gave a good nickel extraction with C. P. reagents; however, this was not confirmed in tests using Nicaro basic carbonate. Electrolytic tests employing ammonium fluoride leach liquors gave no further separation, since approximately 90 percent of the cobalt was deposited at the cathode with the nickel.

Jan 1, 1958

By R. Karl Zipf

A fatal explosion in a sealed area at the Sago Mine in 2006 prompted researchers and regulators in the United States to re-examine the requirements for explosion-resistant mine seals. Seals are used in underground coal mines to isolate abandoned mining areas from active workings. Prior to the Sago disaster, mining regulations required seals to withstand a 140 kPa explosion pressure. Recent research at the National Institute for Occupational Safety and Health (NIOSH)Pittsburgh Research Laboratory showed that pressures from explosions can far exceed this pressure. U.S. mining regulations now require much stronger seals. Current research focuses on understanding the science, engineering and management of sealed areas of coal mines. Scientific efforts seek understanding of how explosive methane-air mixtures accumulate using measurements and models of the sealed area atmosphere. Additional scientific efforts aim to understand the explosion pressures that can develop using a combination of numerical modeling and experiments. Engineering efforts aim to produce design guidelines for seals that can resist the new higher pressure design criteria. NIOSH researchers are also developing guidance for monitoring of sealed area atmospheres and inertization of potentially explosive gas mixtures within sealed areas. This paper seeks to encourage scientific discussion among international peers since preventing explosions within sealed areas is of interest to underground coal operators and regulators.

Jan 1, 2009

By T. L. Johnston

The Dobbins property, about 4-1/2 miles northeast of Cartersville, Ga., was fist operated in 1866, it is the oldest manganese mine in Georgia and one of the oldest minus in the United States still producing manganese ore. Changes in ownership, lessees, and operators and lack of records prevent the compiling of statistics regarding total production of ore from the property.

Jan 1, 1942

By Jonathan S. Kelly

Effective control of respirable dust is one of the most serious problems associated with longwall mining in the United States. This report describes the development and the underground evaluation of ventilated cutting drums, on a double ended ranging drum shearer. The ventilated drum uses high pressure (1,500 psi) water sprays to draw air (3,500 cfm) through 12 airmoving tubes mounted in the drum hub. The sprays draw dusty air from the face side of the drum, scrub the air, and discharge the clean air on the gob side of the drum against a deflector plate. During a three week underground evaluation, the cutting drums reduced shearer generated dust levels at the shearer operators position by 40%, at the shield operators downwind of the shearer by 55%, and at the tailgate by 55%. Cutting and loading performance of the drums were superior to the mine?s conventional drums. After the evaluation, the mine continued to use the ventilated drums to finish mining the panel. During this 3 month period, there were no mechanical or seal failures demonstrating excellent system reliability.

Jan 1, 1987