Search Documents

By Andrew L. Mular, Robert P. Edwards

"The operation of flotation circuits is often regarded as a combination of art and science. Expert systems offer a method by which the art may be captured and supervisory control of flotation circuits fully realized. Operating knowledge, the art, can be consistently employed to enhance regulatory control through the judicious application of an expert system. Using an expert system, a supervisory control routine was developed, and success- fully implemented, in the copper flotation circuit at Brenda Mines Ltd.The expert system ran in conjunction with regulatory PI controllers on a personal computer. The expert system received assays via an on-stream analyzer and adjusted regulatory loop set points as required in real-time. From its commissioning in November, 1989, to the end of the mine 's operation in June, 1990, it was enthusiastically embraced by the operators and attained operating levels superior to those achievable manually.IntroductionExpert system (ES) software springs from research into artificial intelligence and is currently making significant inroads into business and industry. ES proponents make many attractive claims; they are a means of capturing the knowledge of experts and they can be programmed by non-programmers. To date, most uses of this software in the process industry are in off-line applications, meaning that the applications are not tied directly to operating (on-line) environments. Moreover, in on-line environments, they are typically employed as advisors and only suggest changes. Human operators are required to close-the-loop to the process. Yet, an ES should be applicable to operating environments and, if the claims of the proponents are valid, should also be better than existing tools. As an intelligent controller an ES must use the knowledge of experienced operators, apply it directly to a process and do this without the intervention of human operators. On-line applications have been successfully employed in the closed loop control of SAG circuits (Herbst et al., 1989) and flotation circuits (Hales, 1989). Harris and Kosick (1988)detail an implementation for flotation control at the Polaris Mine."

Jan 1, 1992

By D. G. Macintyre

Thick westward prograding clastic wedges were deposited along the margin of ancestral North America from Mid-Proterozoic to Mid-Paleozoic time. Periodic rifting and tectonic subsidence resulted in the formation of starved sub-basins along this otherwise passive continental margin. These sub-basins host important sedimentary exhalative barite-zinc-lead-silver deposits. In northeastern British Columbia, a thick succession of Paleozoic basinal facies clastic rocks is preserved within the northwest-trending Kechika Trough. Within the trough, sedimentary exhalative barite and barite-sulfide deposits occur in starved basin sediments of Middle Ordovician, Early Silurian, and Late Devonian age. The last are the most economically sigrrificant and are hosted by carbonaceous cherty argillites and siliceous shales of the Middle to Late Devonian Gunsteel Formation of the Lower Earn Group. The largest deposit, Cirque, has reserves in excess of 35 million tonnes averaging 100J0 (Pb +Zn) and 47 g/t Ag. Other potentially significant deposits include Driftpile Creek, Bear, Mt. Alcock, Fluke, Pie and Elf. Stratiform barite deposits are also common, particularly near the basin-to-shelf transition zone. The Late Devonian barite-sulfide deposits typically are zoned: interlarninated barite-sphalerite-galena-pyrite occurring near suspected vent areas grades outward into bedded barite. Laminated beds of pyrite typically occur in hangingwall siliceous shales, particularly above the inferred vent zone. The apparent absence of epigenetic stringer sulfide zones and footwall alteration implies that the deposits were formed from ponded brines at relatively low temperature. Away from the main deposits, the favourable stratigraphic interval is marked by the presence of thin beds of nodular and laminated barite and thin laminae of pyrite. Thin tuff beds also occur locally in this stratigraphic interval and are evidence for a Late Devonian volcanic event. A paleogeographic reconstruction of the Kechika Trough in Late Devonian to Mississippian time suggests that the barite-sulfide deposits formed in third-order starved basins between uplifted, northwest-trending horst blocks that were capped by shallow-water carbonate banks. The presence of intraformational breccias suggests that fault movement accompanied barite-sulfide precipitation. This tectonic activity may have allowed the escape of heated, overpressured metalliferous brines from permeable reservoirs within the sedimentary pile. Sedimentary exhalative deposits formed where these brines were exhaled as buoyant plumes onto the seafloor, cooled, and ponded in anoxic seafloor depressions.

Jan 1, 1992

By A. A. Levinson, M. B. Kirkley, J. J. Gurney

"Scientific advances in the past decade have greatly clarified our understanding of certain concepts relating to the age and origin of diamonds. These advances are largely the result of geochemical studies of mineral inclusions in diamonds, made possible by modem analytical techniques which enable the accurate chemical analysis of micro-sized particles of the order of 200 microns in maximum dimension. As a generalization, the inclusions indicate that most diamonds formed from either of two rock types, peridotite and eclogite. Peridotitic diamonds have yielded ages of 3300 million years, whereas eclogitic diamonds areyounger and rangein agefrom approximately 1000to 1600million years. Kimberlite and lamproite, the two rock types usually associated with diamonds, typically are much younger than the diamonds they contain. Thus, it is now dear that kimberlites and lamproites are only the transporting mechanisms which brought diamonds to the surface and are in no way related to the formation of most diamonds. The latest concepts which developed during the past decade regarding the sources of carbon for the crystallization of diamonds from peridotite and eclogite, and the mechanisms of kimberlite and lamproite emplacement, IntroductionThe decade of the 1980s has seen major advances in our understanding of the age, origin and emplacement of diamonds. The information presented herein is applicable to virtually all natural diamonds, excluding diamonds related to meteorite impacts. There is still some question, however, as to the applicability of the new information to industrial grade ""fibrous"" or ""coated"" diamonds, and to microdiamonds (< 1 mm). In addition to drawing upon our own experiences, this review is summarized from a voluminous literature and for those interested in the original sources we recommend the books by Mitchell and Bergman (1991), Ross (1989), Nixon (1987), Mitchell (1986), Glover and Harris (1984) and Dawson (1980), and the review articles by Mitchell (1991), Gurney (1989) and Meyer (1985).are also discussed."

Jan 1, 1992

By H. K. Fredrickson

"Midwest Joint Venture (MJV) owns a high-grade uranium deposit in northern Saskatchewan. The deposit is located too deep below surface to be mined economically by open pit methods, and as a consequence, present plans are that it will be mined by underground methods. High-grade uranium ore of the type at MJV, encased in weak, highly altered ground and with radon-rich water inflows, has not before been mined by underground methods.The test mining phase of the project, completed in 1989, had three objectives: 1. to evaluate radiation protection requirements associated with the handling of large quantities of radon-rich water and mining highgrade uranium ore in an underground environment; 2. to investigate the quantity and quality of water inflows into the mine; and 3. to investigate ground conditions in and around the ore zone as an aid in determining the production mining method to be used.With information gained from the test mining project, a mining method for the production mine has been devised. Level plans have been drawn up, ventilation system designed, pumping arrangements made and methods of ore handling considered. All this is to be done in a manner that will be safe for those doing the work underground. Some of the mining methods planned are felt to be unique in that they are designed to cope with mining problems not known to have been encountered before. New problems underground have required new methods to handle them. Remote drilling, blasting, mucking and backfilling form the basis of the planned mining method."

Jan 1, 1992

By Robert B. Parsons

"The Department of Finance introduced draft amendments to the resource allowance regulations on July 23, 1992 that effectively nullify the decision in the Gulf Canada Limited case. Prior to the amendments it appeared that only ""directly"" related general and administrative, capital cost allowance and scientific research expenditures had to be deducted from resource profits. Now ancillary expenditures are required to be deducted. Consequently, the ability of taxpayers to claim the resource allowance is curtailed.IntroductionOn October 25, 1990 it was almost certain that taxable mines were going to get a break. The Federal Court-Trial Division had just decided in Gulf Canada Limited&apos;s favour to allow it to claim resource related tax benefits larger than what Revenue Canada evidently wished. Revenue Canada appealed first to the Federal Court of Appeal and then to the Supreme Court of Canada. On January 10, 1992 the Federal Court of Appeal agreed with the Federal Court decision and on July 2, 1992the Supreme Court declined to hear any further appeal. A mere three weeks later, on July 23, 1992, the Department of Finance issued draft ""clarifying"" measures to amend the calculation of the resource allowance. These measures effectively nullify the benefits that arose under the decisions of the Federal Court."

Jan 1, 1992

By W. Cholewa, T. S. Golosinski, J. Wedzicha

"Power requirements of belt conveyor drives are usually estimated based on the calculated belt tension which equals the sum of unit resistances to motion which the belt has to overcome. In most situations, the value of various unit resistances can be accurately predicted using published information (5,6,8,12). A simpler approach calls for use of standard formula and tabulated values of related factors which reflect various features of both the conveyor and the transported material (2,3,7) . None of these approaches is reliable when materials with unique properties are conveyed, nor if applied to conveyors working in extreme climatic conditions. Such is the case of oil sand mines in northern Alberta.There the bitumen content of oil sand causes it to behave in a unique manner. Furthermore the conveyors operate year around, with winter temperatures often lower than - 40°C. It was the objective of presented investigations to quantify the power requirements of conveyors, and related resistance to motion for the conveyors used in oil sand mines during winter operations.The other objective was to quantify the drive power requirements of oil sand conveyors during start-up. These requirements are usually much higher than those during norm al operation, and their quantification is of paramount importance for operation of large conveyors."

Jan 1, 1992

By E. M. De Souza

"A scientific testing program, sponsored by the Mining Industry Research Organization of Canada (MIROC), was undertaken on the surface and underground facilities of Inca&apos;s Crean Hill Mine to investigate the effectiveness of using dry drilling with a dust control system.The surface test work consisted of the monitoring of advance rates and bit life white a series of 165 mm holes, wet and dry, were drilled at both mine air (0.69MPa) and high pressure air (1.72MPa). The results, based on statistical evaluations of field data, indicated that penetration rates can be increased by an average of 24% when drilling dry with high air pressure and by approximately 27.5% when drilling dry with mine air as compared with wet drilling under the same conditions. Dry drilling also has the effect of reducing button wear by approximately 69% using high pressure air. The underground test work employed a dust collection system developed for use with large diameter holes (165 mm) and high pressure drilling. The testing program has indicated that an average increase in penetration rate of 35% can be achieved when dry drilling in rock (waste) and of 49% when dry drilling in ore with high air pressure. Although preliminary dust monitoring did not indicate any appreciable increase in dust concentration during dry drilling, further dust monitoring is still required.A comparative cost analysis has indicated the potential for reduction in drilling costs when dry drilling is utilized. Further testwork is to be conducted to develop a reliable dust collection system for underground production."

Jan 1, 1992

By Steve R. McCutcheon, Cees R. Van Staal, John P. Langton, Leslie R. Fyffe

The volcanic-dominated Tetagouche Group in northern New Brunswick contains numerous massive-sulfide deposits and intimately associated metalliferous sediments. The massive sulfides are generally hosted by Llanvirnian-Llandeilian volcaniclastic sedimentary rocks of the Nepisiguit Falls, Patrick Brook, and Boucher Brook formations. These formations are intercalated or closely associated with rhyolitic-dacitic flows and/or domes, and minor continental tholeiites of the Flat Landing Brook Formation. Pyroclastic rocks are relatively scarce in the silicic volcanic complex. Tuffites and epiclastic sandstones, of the Nepisiguit Falls and Patrick Brook formations, respectively, generally occur along the fringes of the silicic volcanic complex. The flows and tuffites are intruded by quartz- and feldspar-phyric rhyolite (porphyry) dykes, sills, and domes. Although the volume of the silicic volcanic complex is large, evidence for a previously proposed collapsed-caldera model is lacking. On the basis of host-rock type and stratigraphic position, the sediment-hosted massive sulfides have been divided into three groups: the Brunswick-, Caribou- and Halfmile Lake-type deposits. Syngenetic feeder pipes and asociated alteration zones are generally not present beneath the Caribou- and the Halfmile Lake-type deposits and, if present at all, are poorly developed underneath the Brunswick-type.

Jan 1, 1992

By T. Schmidt, J. Merza

"This study considers two lead/zinc/silver orebodies which have historically had a problem with pyrite, pyrrhotite and sphalerite contamination in the lead circuit. The problem was previously addressed with high dosages of sodium cyanide as the primary depressant. However, large amounts of cyanide led to environmental problems in the effluent, especially during winter months. The objective was to reduce cyanide consumption while maintaining or improving overall lead grade and recovery via the reduction of the undesirable sulphides.Extensive laboratory and mill testing was necessary to determine the optimal operating parameters for continuous plant application. Evaluation of data received from this testing has shown that selective addition and optimization of the dosage of Unimax SD100 to specific areas of the flotation and grinding circuits has resulted in improved Pb grade and recovery. Parameters such as pH control, regrind operation, the cyanide/Unimax ratio and sulphide mineral content may also affect the performance of the depressant. Each factor is discussed and optimal operating conditions were determined based on the testing.Results are presented for two case studies. Both indicate that Unimax SD100 improves the lead grade/recovery curve by increasing iron and zinc rejection while reducing cyanide consumption and the resulting environmental concerns. 1. Hart"

Jan 1, 1992

By M. B. McClenaghan, O. P. Lavin, Ian Nichol

"Exploration in most areas of Canada has to contend with problems posed by glacial overburden. In many areas exploration for gold has been based on the sampling of tills, frequently by deep overburden drilling, and analyses of heavy mineral concentrates. Notwithstanding the significant role that till geochemistry has played in the discovery of some important gold deposits over the last few years, increased appreciation of the nature of the glacial history and stratigraphy and the character of gold within till has led to the recognition of a number of ways whereby the effectiveness of exploration can be improved upon.In order for till geochemistry to be useful in exploration, a number of conditions must be fulfilled, including:1. mineralization, or alteration halo related to mineralization, subcropping at the bedrock/overburden interface;2. glacial erosion and dispersal of a recognizable signature of mineralization into the glacial sediments;3. preservation of glacial sediments containing this geochemical component (trace metal or mineral) at positions subsequently selected for sampling (normally drill sites);4. correct identification of specific till units and associated ice movement history;5. collection of adequately large and representative samples;6. appropriate sample preparation and processing;7. appropriate geochemical analyses; and8. correct data processing and interpretation.While we have no control over the first two geological conditions, and only limited control over till availability, we can control the quality and thoroughness of sampling, sample identification, sample preparation, analysis and interpretation. In particular attention needs to be focussed on obtaining a large enough sample to be adequately representative, an unbiased sample must be collected, together with appropriate sample processing, analysis, data processing and interpretation. It is considered that by modifying or extending existing approaches to gold exploration the chances of exploration success can be increased. In particular, analyses of both the heavy mineral and minus 63 µ m fractions of till is recommended because gold in till may occur in different size fractions."

Jan 1, 1992

By G. Pouskouleli, T. A. Wheat

"The role and benefits of using statistical methodology in the development and optimization of materials and processes is examined. It is shown that considerable benefits accrue from the use of an appropriate design in which a number of factors (process parameters) are varied simultaneously while the system response such as percent recovery, degree of separation, purity, etc. is monitored and ultimately optimized.Compared with the commonly encountered one-factor-at-a time approach, this schema exploits reduced experimentation (thereby requiring reduced resources [staff, time, dollars, etc.]) yet yields quantitative information on the significance of each factor and their combinations on the measured response."

Jan 1, 1992

By A. J. Keen

"Cominco&apos;s Polaris Mine is an underground lead/zinc operation located on Little Cornwallis Island in the Canadian High Arctic. Polaris is the world&apos;s most northerly base metal mine, situated at about latitude 75°N and longitude 97°W (Fig. 1). The closest community is Resolute Bay about 100 km to the southeast.During the construction and development phase Cominco adopted a unique scheme to save time and money. Many facilities including concentrator, powerhouse, shops and warehouse were built on a barge in southern Canada. The barge was towed 4800 km to the site in August 1981. Production at Polaris began in November 1981. The current mining rate is 1 million tonnes per year. The mine employs 250 people with about 190 on site at any time.GeologyThe deposit is a Mississippi Valley type orebody and lies near the top of the Ordovician Thumb Mountain Formation. Ore minerals consist of sphalerite and galena with the gangue being predominantly dolomite with calcite and marcasite. The orebody is situated completely within permafrost, consequently the voids frequently found in the ore are filled with ice. The orebody strikes north-south, dips approximately twenty degrees to the east and takes up an area about 400 m wide by 700 m long. The upper portion of the orebody (60 m to 150 m below surface) lies in an area called the Panhandle Zone. The deeper portion of the orebody known as the Keel Zone extends to 300 m below surface (Fig. 2). The deposit is strongly zoned with a high grade zinc/lead and iron-rich tabular core overlain and underlain by vein, stringer and breccia mineralization. The ore reserves at January 1991 were 14.6 million tonnes at 3.6% Pb, 13.7% Zn, 3.2% Fe, after producing 8 million tonnes at 3.9% Pb and 14.2% Zn since November 1981"

Jan 1, 1992

By C. Veloo

"Westmin Resources operates a mine/mill complex at Myra Falls and produces copper and zinc concentrates with minor associations of gold, silver, and lead from a polymetallic, massive sulphide orebody. Mill flotation performance has historically been plagued by periods of uncontrollably high circulating loads leading to low concentrate grades and below optimal tails. This led to a detailed examination of the flotation process. Locked cycle, and pilot plant data are presented. In addition, plant design and commissioning as well as column cell details are discussed. A comparison between actual and predicted performance is also presented. Benefits realized are higher copper and zinc concentrate grades and improved zinc recovery.PrologueMyra Falls Operations is located at the south end of Suttle Lake in Strathcona Provincial Park. Access to the mine site is provided by a 90km paved highway from Campbell River, British Columbia.The mine and facilities are nestled in the narrow Myra Valley between Mount Phillips and Mount Myra. These steep, rugged mountains rise from the valley floor at an elevation of 900 feet to summits of almost 6000 feet. The steep slopes are heavily wooded with fir, hemlock, and cedar up to an elevation of 4000 feet where a transition to alpine meadows occurs. The summits are craggy rock faces, some capped with glacial ice. Myra Creek winds its way through the valley dropping several hundred feet into Suttle Lake. Precipitation is high at over 100 inches per year, which may include up to 10 feet of snow in winter. The temperature may range from 32° C in summer to -18° C in winter.Myra Falls began production in 1965 with the Lynx Mine, supplemented by the Myra and Price Mines in subsequent years, feeding a 950 stpd mill up until the middle of 1985 when the H-W mine was brought into production. The original mill was replaced with a modern 2700 mtpd facility and in 1988 production was increased to 4000 mtpd.Both Lynx and H-W mines are currently in production producing an average of 3650 mtpd. The ore minerals are primarily sphalerite and chalcopyrite, with subordinate galena, bornite, tetrahedrite, and electrum."

Jan 1, 1992

By G. H. Blackwell, A. J. Sinclair

"The main components of a ""PC” -based mineral inventory system are described in a sequence common to many real reserve/ resource estimation projects and in the practical context of problems and decision-making typically encountered in such studies. Some components are designed particuarly to improve the geostatistical instructional capability of the package. An important part of this approach involves the use of widely available software for data manipulation and evaluation in the design of a mineral inventory study progressing to mine design and feasibility. A variety of more or- less fixed routines written in high level languages provide acceptable computational speeds on a personal computer. These critical segments are linked by simple, short, compiled Basic programs easily adjustable to various data configurations and needs. IntroductionGeostatistical mineral inventory estimation has progressed greatly since its slow dissemination during the 1960s. The mining industry generally has accepted the benefits of the technique, notably the quantification of grade and geology, an indication of error in grade estimation, and of the mined volume / grade variance relationship (Clark, 1979, Isaacs and Srivastava, 1989).Acceptance has been slowed, first by complexities of geostatistical theory and second by a bewildering variety of computer systems and applications programs. Continuing improvements in education will facilitate a better understanding of the underlying theory.The purpose of this paper is to describe, in a practical context, the development of a geostatistical-based approach to reserve/resource estimation. The approach integrates various existing commercial software packages with a wide selection of programs developed by the authors for personal computers which estimate mineral inventories and educate users in the techniques applied; that is, the QMIN system.It is hoped that the approach presented here will convince mining and geological engineers concerned with resource estimation, of the soundness of geostatistical methods and its broad potential to their problems."

Jan 1, 1992

By Yve Potvin, Fabien Miller, Deni Jacob

"The potential benefits of measuring the volume of excavated open stope are enormous. By comparing the actual excavation of the orebody contour, it is possible to determine the “real"" amount of mining dilution, as well as the ore left in place. Noranda Technology Centre (NTC) has developed a stope survey system that allows for rapid and efficency measurement of underground excavation volumes. The system comprises a commercial laser (EDM), a set of lightweight rigid rods, an automated scanning device, a hand-held data logger and Autocad-based software for volume calculation and drawing manipulations. This system is an invaluable tool for the optimization of mining practices and could also be used for the delineation of caving areas. IntroductionDilution is the most common and devastating mine disease. In some instance s it could systematically cripple the profitability of an operation, and in more extreme cases, it could become a terminal disease. The Northern Miner Journal (1988) reported that many operations have closed because of uncontrolled dilution, before they even completed their first year of production. Other studies (Pakalnis, 1986) have shown that approximately 40% of all underground operations have more than 20% dilution. Considering that every ton of dilution costs in the neighbourhood of $25, the total direct cost of dilution to the Canadian mining industry may easily exceed one hundred million dollars per year.The dilution problem has been a major concern to Noranda Minerals for some time and in 1984 a comprehensive geomechanics research program was created at the Noranda Technology Centre (NTC) in Pointe-Claire, Quebec. New empirical stope dimensioning techniques, improved cable bolting techniques and sophisticated ground control instrumentation projects (among others) contributed to improve the situation at Noranda.A new tool which can have a very significant impact on the ""war"" against dilution is being developed by the Noranda Technology Centre. The laser stope survey system allows for a rapid, precise and efficient measurement of underground excavation volumes. By comparing the excavation planned with the volume excavated, it becomes possible to determine the ""real"" amount of mining dilution as well as the amount of ore left in place. This system may also allow for early detection of a dilution problem. As with other diseases, early detection provides the best chance for a fast and total recovery."

Jan 1, 1992

By R. I. Grauch, Michael D. Glascock, Chen Nansheng, Jr Coveney, James B. Murowchick

"Unusually rich molybdenum ores (cutoff grade = 4.10/0 Mo) hosted by Lower Cambrian black shales have been mined since 1985 near Zunyi in the province of Guizhou in China. Similar ores were once worked for Mo and Ni near Dayong in the province of Hunan. In both mining areas, mineralization occurs in Lower Cambrian black shale (Niutitang Formation and stratigraphic equivalents) as a single sulfide bed or lens with exposed thicknesses up to 15 cm and reported thicknesses up to 35 cm. In addition to high Mo values (4% to 7%), ore samples contain up to 7% Ni, 2% Zn, 2.5% As, and several hundred ppb Au and Pt-group elements, but the precious metals have never been recovered from the ores. Sporadic occurrences of Mo-Ni sulfide ore beds are found in at least five provinces stretching approximately 1600 Ian from Yunnan to Zhejiang. None of the Mo-Ni ore-bed occurrences has any obvious connection with mafic or ultramafic source rocks. Similar occurrences containing elevated values for Ni, Mo, and PGE exist in Devonian black shale in the Yukon. Future exploration for Pt, Au, Mo, and Ni deposits should consider this previously unknown type of sediment-hosted mineral deposit.Sommaire - Des minerais anormalement riches en molybdène (teneur-limite = 4.1% Mo) provenant de schistes argileux noirs du Cambrien Inferieur ont été exploites depuis 1985 près de Zunyi dans la province de Guizhou en Chine. Des minerais semblables ont déjà été traire pour Mo et Ni près de Dayong dans la province de Hunan. Dans ces deux régions minières, la minéralisation se présente dans le schiste argileux noir du Cambrien Inferieur (Formation Niutitang et équivalents stratigraphiques) sous forme de couche ou lentille unique de sulfures avec des épaisseurs exposées de plus de 15 cm et des épaisseurs rapport6es de plus de 35 cm. En plus des fortes teneurs en Mo (4%-7%), des échantillons du minerai contiennent jusqu’ à 7% de Ni, 2% de Zn, 2.5% d&apos;As, et plusieurs centaines de ppb d&apos;or et d&apos;éléments du groupe du platine; toutefois, les métaux précieux n&apos;ont jamais été récupérés des minerais. Des présences sporadiques sous forme de couches de minerai sulfure de Mo-Ni se retrouvent dans pas moins de cinq provinces s&apos;etendant sur 1600 km de Yunnan a Zhijiang. Aucune de ces présences de minerais, sous forme de couches, ne semble associée a des roches du type mafique ou ultramafique. Des présences similaires contenant des teneurs élevées en Ni, Mo et EOP se retrouvent dans le schiste argileux noir Devonien du Yukon. L&apos;exploration future pour des gisements de Pt, Au, Mo et Ni doit prendre en considération ce type de gisement encore inconnu précédemment."

Jan 1, 1992

By A. T. Robles, L. Buckingham

"When certain gold ores containing pyrite, graphite, humates and fumates or other organic compounds which are possibly adsorbed on clay minerals are treated with aqueous solution of alkali metal cyanide, the aurocyanide complex which forms is adsorbed by these ""pregrobbing"" species in the ore. Dissolution of gold proceeds until chemical equilibrium is attained between the cyanide complex adsorbed by the ore and in solution.Sodium lauryl sulfate (SLS) may be used to decrease the adsorptive activity of the prerobbing species in the ore. It has successfully improved recovery at Holt-McDermott Mine and is highly biodegradable.INTRODUCTION Precious metal-bearing ores containing preg-robbing species are poorly amenable to standard cyanidation techniques. The ""preg-robbing"" impurities with which they are associated tend to adsorb the gold cyanide complexes and carry them through the circuit to the tailings. Also, gold may be associated with these impurities in the ore and not be leached by the cyanide complexing agents used in conventional cyanidation techniques.Methods for dealing with the problem of preg-robbinq impurities in gold ores are:Carbon-in-Leach (CIL), in which granular activated carbon is added to compete with preg-robbing species for the gold cyanide complexes. This process can improve gold recovery in mildly preg-robbing ores especially when fine carbons with very high activities are used. However, with severely graphitic ore, the carbon associated with the rock may outperform the granular activated charcoal.Chemical Oxidation, in which the ore is subjected to preliminary chemical oxidation techniques to oxidize carbonaceous materials using such diverse reagents including ozone, sodium hypochlorite, calcium hypochlorite, chlorine gas, permanganates, perchlorates, chlorates and oxygen prior to subjecting the oxidized ore to standard cyanidation treatment to extract gold. This is generally a costly method and will not prove economical on a low-grade ore."

Jan 1, 1992

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been conducted, thereby providing a unique opportunity to examine the geochemical evolution of a sulfide rich mine>tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% alumino silicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, S042-, Cu, Zn and Pb (up to 10 000 mglL, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively). In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tin oxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SOi-, Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents. Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massivesulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By Steven R. McCutcheon

"The Bathurst-Newcastle district, a subcircular area approximately 50 km in diameter, contains 37 massive-sulfide Zn-Pb-Cu deposits that have defined tonnages, and has 58 additional significant occurrences. The largest deposit is Brunswick No. 12, with total reserves (including past production) of 148 million tonnes grading about 12.5% combined Pb-Zn. The deposits/ occurrences are spatially associated with a felsic volcanic pile that contains a significant sedimentary component. In the vicinity of the Brunswick deposits the pile is divisible into lower and upper sequences. The lower is characterized by megacrystic rhyolite (QFAS) and coarse- to fine-grained quartz (± feldspar) wackes and/or tuffites (QAS); the upper sequence is characterized by aphyric to sparsely porphyritic rhyolites (HWR), micro-breccias, and acid hyaloclastites with interbedded dark gray sedimentary rocks. A greenish gray to dark gray siltstone (GGS) separates the two sequences and hosts the sulfide deposits. Lithogeo chemistry of least altered samples shows that the QFAS and HWR have an igneous character, whereas the QAS and GGS have a sedimentary signature. The two types can be distinguished on the basis of total alkalies (Na2 + K2O) versus SiO2/Al2O3 and Ti02 versus Fe/(Fe +Mg). Some trace elements, such as Sr and Y, also help differentiate the two types. The QFAS differs from HWR by having higher La/Yb ratios but lower Zr and Th. The Bathurst deposits do not show a close spatial association with rhyolites but rather are stratiform bodies Oacking clastic textures) within fine-grained sedimentary rocks. The scarcity of barite and other sulfates indicates that there was little mixing between the metal bearing fluids and cold seawater. High Fe/(Fe+Mg) ratios in chlorites also indicate the fluids did not contain a significant seawater component. These features and the large size of many deposits suggest that the deposits formed from metal-rich pore waters that were released catastrophicallyfrom an acquifer in the footwall stratigraphy."

Jan 1, 1992

By Robin N. Adair

The Halfmile Lake stratiform volcanogenic massive-sulfide deposit consists of pyrrhotiterich breccia-matrix sulfides and pyrite-pyrrhotite-rich layered sulfides that form a laterally continuous sheet stratigraphically underlain by an extensive pyrrhotite-chalcopyrite-quartz stringer zone. Mineralization is hosted by a sequence of felsic pyroclastics and volcanic-derived, fine-grained metasediments. The proportion of volcanic to sedimentary rocks indicates increasing vent proximity from southwest to northeast across the deposit area. Fine- to medium-grained felsic pyroclastics and roughly equal amounts of fine-grained metasediments comprise the stratigraphic footwall to the mineralization. Quartz-feldspar porphyritic bodies cut this sequence and may have provided the heat source for exhalite activity. Felsic tuffs, locally crystal-rich, and lesser amounts of metasedimentary rocks make up the immediate stratigraphic hanging wall. This sequence is stratigraphically overlain and locally interfmgered with mafic volcanics that contain substantial proportions of felsic fragments. Deposition of sulfides post-dated the beginning of felsic volcanism, which places the deposit in the middle of the Lower Tetagouche Group. Compositions of the volcanic rocks range from basalt to rhyolite and exhibit sub-alkaline affinities. Strongly overprinted whole-rock, trace-element, and REE geochemical signatures resulting from mineralizing hydrothermal activity confirm the genetic relationship between the stringer zone and the mineralized sheet. Large-scale D1 folding has overturned the entire sequence. D1 thrust faults and related sheath-like folds have profoundly affected sulfide distribution. D2 is manifested by a penetrative S2 foliation, and D3 is represented by large-scale open folds.

Jan 1, 1992