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By G. Zárate, G. Tapia

Anglo American Chile has been doing copper concentrate leaching studies at the laboratory and small pilot plant scale since 1992. Among the processes evaluated are bacterial leaching and pressure leaching using Mantos Blancos, Salobo Project and Quellaveco Project concentrates. Late in the nineties, it was decided to focus the research on pressure leaching, either medium or total pressure oxidation. Preliminary scouting tests were run with Mantos Blancos concentrate samples during 2000, which were repeated during 2003 together with samples of Los Bronces and El Soldado concentrates, in order to define the most suitable concentrate for running a pilot plant campaign at AARL, which was carried out in two campaigns, a first one from November 2003 through January 2004 and a second one during April 2004. Mantos Blancos was the selected concentrate and the laboratory and pilot plant results are discussed in this paper together with some preliminary economic estimates.

Jan 1, 2004

By G. Dörsam, M. Spreij, S. J. Van der Wal, A. P. Schmidt

The transfer of hot metal desulphurising from the torpedo cars to the hot metal ladles at the IJmuiden BOS plant no.2 caused a decrease in ladle lining life from 680 to 470 heats. Changing the desulphurising agent CaC2 for CaO during a trial period, for environmental reasons, led to a further decrease in refractory life. Availability of the ladles became critical and the major reasons for the low life were identified. Solving one of them, temperature, quickly resulted in restoration of the original lives. However, re- introduction of the new desulphurising agent on 50% of the heats again resulted in a decrease, this time from 700 to 550 heats. In order to be prepared for the full introduction of the new agent, thorough investigation of worn linings was conducted, revealing the major (chemical) wear mechanisms. With these findings, a new design for the hot metal ladle is proposed.

Jan 1, 2004

By M. X. Yao, Y. Ning, P. C. Patnaik, R. Liu, X. J. Wu

Stellite 712 composites were developed with the reinforcement of bare TiC or Ni-coated TiC particles using HIPing powder consolidation technique. The emphasis of this research was on the effect of the Ni coating on the TiC particles and the HIPing conditions on the microstructure and performance of the composites. Calorimetric effects of the mixed composite powders were investigated using the differential scanning calorimetry (DSC) technique before the HIPing process, which provided the basis of the HIPing cycles designed. The microstructures of the composites were examined using SEM with EDX. The hardness and wear resistance of the materials were evaluated respectively. It was found that the HIPing temperature influenced the microstructure and the performance of the materials. The Ni coating on the TiC particle has improved the fracture toughness of the composites, but detracted the wear resistance. The experimental results and relevant mechanisms were discussed.

Jan 1, 2004

By S. Hoskins, S. Chiovelli

"The annual budget for the repair and maintenance of equipment at Syncrude Canada Ltd. is in excess of $450 million. Of this amount, a significant portion can be attributed to the loss of material on various pieces of equipment throughout the operation. In order to effectively battle the different wear and corrosion mechanisms that lead to material loss, it is important to understand how materials behave in the environments in which they are used. Through the work carried out at Syncrude, and work conducted with various external collaborators, significant improvements in both equipment reliability and productivity have been achieved. This paper will review some recent field trials where materials research has demonstrated the potential for significant improvements in equipment run life and reduced maintenance costs. These field trials will demonstrate the need for understanding the interaction between various damage mechanisms and the materials used in different services. The paper will also discuss current areas of focus along with future directions for further work. IntroductionSyncrude Canada Ltd, located in northern Alberta, Canada, operates a mining, extraction, and upgrading facility that removes bitumen from oil sand to produce synthetic crude oil. Oil sand is mined from the orebody using conventional open pit mining techniques. Recently, the mining scheme has changed from a dragline/bucketwheel/conveyor system to a shovel/truck/crusher/hydrotransport operation as depicted in Figure 1. Since the start of production in 1978, the identification, development and application of wear protection has been an ongoing challenge due to the abrasive nature of the oil sands and the massive volumes of materials that are moved. The use of various materials and application processes along with component design modifications has resulted in significant improvements in both productivity and reliability (Adamic et al., 1995; Llewellyn, 1996, 1997; Anderson et al., 1998; Chiovelli et al., 1998).In an effort to continuously improve the operation, Syncrude has been quick to adopt new wear technologies. As seen in Figure 2, since the start of operation, a variety of materials have been used to increase wear performance and ultimately equipment reliability and availability. Although Figure 2 does not show a time axis, the bottom axis may also be used to represent a time progression for the predominate use of these materials at Syncrude. Tungsten carbide metal matrix composite (WC-MMC) overlays are currently the materials of choice for most of Syncrude’s critical production applications. Metal matrix composite overlay technology has potential for significant improvements and Syncrude is actively working with powder consumable manufacturers to advance this technology."

Jan 1, 2004

By Eric Konigsmann, Doug Spence, Scott Jones

"The Williams Gold Mine is located in the Hemlo camp of Northwestern Ontario and is one of Canada’s largest gold producers with annual gold production of 400,000 ounces. The operation is owned and operated as a 50:50 joint venture between Teck Cominco Limited and Barrick Gold Corporation.In July 2002, the decision was made to introduce paste backfill produced from mill tailings as the primary backfilling method in the mine and to decommission the existing cemented rock fill system. This required a fast track design to be completed for both a surface paste backfill plant and an underground paste distribution system followed by an intensive construction phase through the fall and winter of 2002/2003. The paste system was commissioned on schedule in late April 2003 and was in full production within 4 weeks of the initial start up. Overall, the project duration was only 42 weeks from initial project release to commissioning and it was completed $2 million under the budget of $14 million.This paper presents an overview of the lab testwork and process flowsheet design, process control methodology and describes the construction and commissioning phases of the project. Preliminary paste plant performance and operating cost data is also presented.IntroductionThe Williams Gold Mine is located in Northwestern Ontario adjacent to the Trans Canada Highway in the Hemlo Gold Camp as shown in figure 1. The mine currently produces approximately 400,000 ounces of gold annually and is owned and operated as a 50:50 joint venture between Teck Cominco and Barrick.The deposit was discovered as part of the Hemlo gold discovery in 1981 which led to the development of three mining operations within a 2 kilometre radius. The neighboring operations are the Golden Giant Mine, currently owned and operated by Newmont Gold, and the David Bell Mine, currently owned and operated by the same joint venture which is running Williams. David Bell ore is blended and milled in the Williams concentrator."

Jan 1, 2004

By L. Bloomquist, C. Arnoldi

"This paper describes how Automated Mining Systems (AMS) is evolving the state-of the- art in guidance systems for autonomous underground vehicles. The techniques, tradeoffs, and lessons learned from these systems are described, including the safety regime that has been implemented.First generation autonomous guidance systems for underground vehicles relied on infrastructure for the vehicle to follow. However, there are additional costs associated with that approach.The current generation uses a pair of laser range finders as its only guidance sensors. This system uses a minimum of infrastructure, in the form of a redundant system of location referencing. Advanced steering and drive control algorithms are incorporated into this generation of system.The next generation of infrastructureless guidance systems will be based on a 3D vision sensor, which was originally developed for autonomous Mars rovers and is being adapted for underground mining use. Results of early underground field trials are presented, along with a description of this emerging technology."

Jan 1, 2004

By N. Mejia, Z. Xiao, D. Fragomini, A. R. Laplante

"The adaptation to platinum-group minerals (PGMs) of a protocol developed to predict gold recovery by gravity is presented. The protocol is based on three different data sets: ore characterization of gravity-recoverable minerals, description of their behaviour in cyclones and ball mills, and performance of recovery units. Examples of these are given. It is shown that the gravity-recoverable PGM (GRPGM) content can be very high. A case study at the Clarabelle mill is presented. Sperrylite is the dominant platinum mineral, and its partition curve is very similar to that of gold, despite its lower density. Its grinding kinetics is significantly higher than for gold. As a result, sperrylite accumulates in finer sizes than native gold, but can still be recovered by gravity or flash flotation. Recovery projections based on gravity recoverable data are presented.BACKGROUNDReliable modeling of gold recovery by gravity or flash flotation from a grinding circuit is based on the ability to describe the properties of gold-bearing particles in the ore, their behaviour in grinding and classification units and the performance of the equipment used for recovery, be it gravity or flotation. This is shown in Figure 1."

Jan 1, 2004

By M. Venkatraman

The limit of Hall - Petch relationship in ultra fine grained steels has been examined based on dislocation pile-up mechanism. When the grain size becomes small the dislocation multiplicity ceases resulting in very low work hardening rate in these materials. An approximate analysis of the theories of hardening indicates that H-P relation is obeyed up to 100nm. It appears that grain refinement is not the suggested approach to improve toughness as well as strength below a critical size.

Jan 1, 2004

By R. A. L. Drew, C. A. Rodríguez González, Caleym W. F.

This work addresses the need of new refractories for copper converters. Technological improvements and environmental regulations for chromium containing refractories have generated this need. Chemical interactions, mechanism of penetration and the effect of oxygen potential and temperature in the system Cu2S-FeS-SiO2-O2 are presented for two refractories: a burned magnesite chrome brick (typically used by the copper industry) and a chrome-free spinel direct bonded brick. The main difference determined in the refractory performance was the blister copper penetration resistance; burned magnesite chrome brick is penetrated while direct bonded brick is not. These results are very promising since blister copper penetration has been reported as the major cause of refractory wear. The results are explained in terms of refractory porosity and wetting characteristics.

Jan 1, 2004

By Shoma Sinha, Nirmal K. Sinha

Deformation in a material at any temperature is known to consist of two major components - a reversible (elastic) part and an irreversible part (often called plastic). What is not universally known is the fact that at high temperatures greater than about 0.4Tm, where Tm, is the melting point in Kelvin, the reversible part includes not only elastic but also a delayed elastic (recoverable but time dependent) component. A very simple computational model is presented here for a constant-strain stress relaxation test (SRT) on the basis of a three-component constant-stress rheological equation derived from strain relaxation and recovery test (SRRT) data. It is shown that the rapid stress reduction during the early periods of relaxation when the stresses are high is governed primarily by delayed elasticity irrespective of the imposed strain level. This is in contradiction to the popular concept prevailing today. The asymptotic approach to a quasi-stable stress rate at longer times and lower stresses is, however, controlled by viscous flow (power-law creep). The validity of the theory is examined by comparing the predictions with experimental results obtained for a titanium-base alloy Ti-6246 at 0.45Tm.

Jan 1, 2004

By R. Boom

Corus Umuiden, formerly Hoogovens, was the first steel plant in Europe after Voest to introduce oxygen steelmaking. In the decision-making process contacts with Dofasco in Canada about the production of formability steel grades were crucial. In developing oxygen (LD-) steelmaking high liquid steel output rates had to be combined with accurate process control. For ingot casting static models with input control and sampling during interrupted blowing were sufficient to deliver liquid steel within the required carbon, phosphorus, sulphur and temperature windows. Computers were introduced to perform the complicated charge calculations. Continuous casting called for strict control of composition and temperature at process end point and made predictable timing crucial. Dynamic control was introduced based upon sub lance measurements and waste gas analysis. Reliable disposable measurement sensors were developed in a concerted international action. Dissolved oxygen at blow end deteriorated the quality of low carbon aluminium killed steel grades. Blowing gases through the converter bottom improved process kinetics, resulting in lower carbon-oxygen products, yield increase and better phosphorus removal and generated new families of hybrid blowing processes. Introduction of secondary metallurgy facilities such as argon stirring stations, vacuum degassers and ladle furnaces relieved the demands for strict BOF end point control. Desulphurisation of hot metal became standard practice. In regions with scrap shortage hot metal desiliconisation followed by dephosphorisation, was introduced in the blast furnace cast house and hot metal transfer ladles. Later redundant converter vessels were used for pre-treatment, resulting in a two-stage process. The fundamentals of oxygen steelmaking are described and a vision on the future is presented.

Jan 1, 2004

By Y. Masuda, Y. Nakamura, K. Haraguchi, A. Taniguchi, K. Arita

Availability of the elements originating from steelmaking slag for various marine phytoplankters including purely cultured strains and natural populations was tested in land and shipboard laboratories. The results obtained demonstrate that, although their solubility was not uniform among different slags, dissolved iron, silicate and phosphate from the slag stimulate phytoplankton growth. No negative effect of the slag addition on their growth was observed at lower dose, e.g. less than 200 mg/l. Since most coastal waters are the hypernitrogenous environment due to anthropogenic load of ammonium, the slag can be an ideal source of silicate and phosphate, which restore the hyper-nitrogenous condition into truly eutrophic condition with balanced Redfield ratio. In so-called HNLC (high-nitrate low-chlorophyll) oceanic areas such as the Southern Ocean and the subarctic North Pacific, where iron is almost only limiting factor of the phytoplankton growth, the slag could also be a source of iron and enhance CO2 fixation by phytoplankton photosynthesis. (Key words: carbon deposition in deep-sea, marine environmental remediation, phytoplankton, slag as a source of iron, phosphate and silicate.)

Jan 1, 2004

By Fengxiang He, T. Meadowcroft, Yanjun Zhang

Slag from the zinc fuming furnaces contains about 3 percent zinc and 0.1 percent lead. The paper outlines several experimental techniques for recovering these components from liquid fumer slag. The simplest method, remelting followed by a hold period, indicated that a substantial fraction of the metal values was recoverable as a result of fuming into the gas phase, presumable by reduction of the metal ions by divalent iron ions. Following on from this, slag samples were equilibrated with copper, chosen because the activity coefficients of zinc and lead in copper are very low. This improved metal recovery, with substantial amounts of lead and zinc reporting to the liquid copper as well as to the fume. Application of an electrical emf across the slag-metal interface, using a graphite anode and a liquid copper cathode, resulted in further gains in metal recovery.

Jan 1, 2004

By M. Azzaz

In this paper, we report on new mechanical tests, at high temperatures, performed with a supposed better aluminium nitride (A1N) material, containing fewer oxygen. Our purpose was twofold: (i) check whether creep resistance is modified and hopefully enhanced and (ii) determine the elementary mechanisms controlling plastic deformation through transmission electron microscopy (TEM) observations of deformed samples up 10% strain in compression at elevated temperatures (1823-1923 K) under constant stress in the range 150¬250 MPa. Stationary rates are lower by an order magnitude than those previously measured in MN with higher oxygen content. All dislocations imaged by TEM look undissociated, which clearly relates the formerly observed wide dissociation to oxygen in excess.

Jan 1, 2004

By Jean M. Richardson, Steven R. Williams

"Geometallurgical mapping is a new team-based approach that documents variability within an orebody and quantifies the impact of geology (host rocks, alteration and structure) and mineralogy on grinding, metallurgical response and metal recovery processes. The quantitative, spatially constrained database that results can be readily integrated into 3-D block models and mine planning activities. Thus it is an important tool to reduce the technical risk associated with new mine developments or expansions.Normally undertaken during pre-feasibility or feasibility planning stages, the first step of geometallurgical mapping is to review the geology, mineralogy and other critical parameters and construct a geometallurgical matrix. This matrix provides an objective base to then guide sampling and/or compositing activity for physical property and metallurgical testing. Depending on the project, an array of testing techniques can be used to characterize the ore and feed data into the geometallurgical model.While the range and number of tests needed is project-dependant, the geometallurgical mapping approach allows the development of empirical models or interdependent relationships, grounded by spatially-constrained real data. Extensive data sets collected using less expensive testing methods can be meaningfully correlated with results from complex specialty tests to yield realistic metallurgical recovery data.With geometallurgical mapping completed, the resulting database can be integrated into an overall 3-D block mine model. This means that metallurgical response can be used to realistically forecast the recoveries of specific blocks, perhaps sampled only by drilling. Mine planning can then incorporate the forecasted metallurgical response and generate future project cash-flows; opening the door to economic optimization of the mine exploitation."

Jan 1, 2004

By O. -J. Siljan

"Refractory materials are an integral part of aluminium production. One special feature of aluminium making is the prominent role of sodium in all parts of the production process. This presence of sodium inflicts stresses on the refractory materials through reactions and may cause severe damages to the refractory linings. The present paper address possible reactions between sodium and refractories in anode bake furnaces, electrolytic pots and casting furnaces. The discussions presented in the paper points to the importance of selecting materials with excellent alkali resistance in all parts of the aluminium making process, although alkali resistance is not the sole parameter to determine refractory life-time. ""Acid"", i.e. silica-rich alumino-silicate refractories are shown to be the best materials for aluminium electrolysis cell potlinings, whereas high- alumina refractories based on minerals like andalusite seems to be the preferred choice for anode bake furnaces as well as cast house furnaces."

Jan 1, 2004

By H. A. Bilgin, G. G. U. Aldas

"Ground vibration is the natural result of the blasting process. Many empirical formulae and methodologies including analysis of travel path effects have been developed. The scaled distance, which is the most popular approach for the calculation of the attenuation of particle velocity in the ground, has led to significant advances in the prediction of particle velocity when both explosive charge and distance vary. However, this approach does not consider the effect of ground anisotropy and existence of structural geological features on ground vibration. Therefore, in this study, the effects of these rock mass properties on types, amplitudes, and frequencies of ground vibration waves at four surface mines are examined. The results, which were implemented at Kangal coal mine, Bastas quarry and Kíbrís quarry, provided guidance for the extensive study at Orhaneli surface coal mine.As a result of the study, the authors came to the conclusion that vibration amplitudes change depending on the ground on which sensors were deployed and the conditions depending on whether measurements were done near major structural geological features. It was determined that the vibration amplitudes, measured at equal distances from the source but in different directions, change because of the propagation velocity anisotropy. Besides the change of wave type due to the kind of ground at the measurement location, it was determined that vibration anomolies were due to structural features."

Jan 1, 2004

By Y. Kocaefe, D. Kocaefe, G. Ergin

Filtration efficiency depends strongly on the wetting of the bed media by aluminum. This project was undertaken to study the wettability of different types of bed media (tabular alumina) using sessile-drop and infiltration techniques. The samples were analyzed using optical microscopy, SEM, and TEM to study the chemical interactions. The results indicate the spinel formation at the interface. This paper presents some of the findings which compares the two methods and gives the results of the analyses on the wetting of alumina by aluminum.

Jan 1, 2004

By J. Paraszczak

For mining companies facing strong international competition and unfavourable commodities’ prices, automation of underground operations has the potential to increase productivity and help cut costs. However, despite considerable technological progress in this field, there still remain many problems to overcome. Furthermore, successful implementation of automation depends also on numerous operational, organizational, and even human factors. In this context, this paper briefly reviews technological progress with regard to different underground operations. Following that, several issues related to implementation of automated equipment and systems are presented and discussed. Particular emphasis is put on the factors whose importance is often underestimated. Some recommendations in this respect are also given. It is stated that the success of an automation project is a function of many “winning conditions,” which may be created through very thorough planning and preparation. It is also underlined that despite achievements made, a vision of a man-less underground mine is not yet as much a matter of near future as it may seem.

Jan 1, 2004

By C. J. Brown

Since its commercialization thirty years ago, the Recoflo® short bed ion exchange process has been extensively utilized for the recovery of a wide variety of acids and metal salts. In addition to a reduction in resin bed height from 200 cm to 300 cm to 15 cm to 60 cm, the process has a number of features such as utilization of fine mesh resins in a compressed bed which together make it ideal for a number of applications. The process has been extensively exploited, for example, in the metal finishing industry for recovery of valuable chemicals from electroplating, anodizing, etching and pickling wastes. More recently, it has also been applied in the primary metals industry for purification of copper electrolytes and metals recovery from leachates. The paper discusses several of these applications and some of the issues that were found to be key to their success.

Jan 1, 2004