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By A. W. F. Smith, P. B. Prangnell, D. N. Crowther, P. J. Apps

It is well known that the refinement of grain size in metals leads to a significant improvement in important mechanical properties. As part of a European collaborative project, processing schedules have been investigated aimed at producing a homogeneous ultra-fine ferrite and spheroidised carbide aggregate microstructure structure in high carbon (CMn) steels (0.6-1.2wt%C), via conventional 'warm' rolling and innovative Equal Channel Angular Extrusion (ECAE). Suitable deformation schedules were determined from dilatometry and thermo-mechanical Gleeble simulations. Evidence of an ultra-fine ferrite and carbide aggregate microstructure following 'warm' rolling is given. A significant improvement in tensile strength, particularly proof stress (0.2%) was also noted in comparison to material deformed at higher temperatures. Concurrent Equal Channel Angular Extrusion (ECAE) experiments investigated microstructural evolution with incremental strain. Extensive analysis was carried out using various techniques, including high resolution Electron Back Scattered Diffraction (EBSD). Evidence of ferrite grain refinement was noted in a eutectoid composition steel. A sub-micron ferrite structure was observed following high strains (E-3.33) and the mechanical properties exhibit a marked increase in tensile strength.

Jan 1, 2004

By K. Johanson, M. Hubert, C. Eckert, D. Ghose

The mining industry routinely processes material with different particle sizes. Coal, nickel ore, copper ore, lignite, shale, and phosphate ore are all examples of materials with wide particle size distributions. It is often assumed that these materials are homogenous and that any particle size distribution has the same chemical activity and composition. It is entirely possible, and quite likely, that chemical composition is a function of particle size distribution. In addition, particle size distributions in ore materials are often responsible for the difference in flow behavior in process equipment. This is evident in coal electrical production facilities. Fine coal may have the same ash content, sulfur content, and BTU value as coarse coal. However, all electrical production facilities know the extreme flow problems that result when attempting to handle wet fine coal. Segregation of these bulk materials is an important issue that must be understood to prevent these cohesive flow problems. Additionally, fertilizers are mixtures of particles with different shape and sizes. These mixtures must remain homogenous to optimize fertilizer performance. Segregation leads to poor product quality. This paper presents a method of measuring the magnitude of sifting segregation occurring in bulk material and the relationship between the strength of the bulk material and the separation tendency. It shows an inverse relationship between the yield strength of the material and the bulk segregation.

Jan 1, 2004

By A. Zarei-Hanzaki, O. Golmahalleh, S. M. H. Hosseini, H. Azizi-Alizamini

The main importance of acicular ferrite microstructures arises from their desired combination of mechanical properties in comparison with the bainite and ferrite-pearlite microstructures. Several factors affect the microstructural transition from bainite microstructure into the acicular ferrite one. As is well established any factor corrupting the prior austenitc grain boundaries nucleation potential, such as the thin layer of allotriomorph ferrite and the austenitc deformation inhomogenities may promote the acicular ferrite formation instead of bainite. Accordingly, this study deals with the effects of the aforementioned features on the acicular ferrite formation in low carbon microalloyed steel. The results indicate that the formation of strain-induced ferrite at the prior austenite grain boundaries accompanied by deformation inhomogenities in the austenite grains change the effectiveness of allotriomorph ferrite on acicular ferrite formation from active to inert one.

Jan 1, 2004

By K. Galovich, P. Krivokuca

"Quinsam coal mine is located about 25 km west of Campbell River on the east coast of Vancouver Island, British Columbia. Using continuous miners in a fully mechanized retreat room-and-pillar operation, it produces low sulphur, “super compliance” thermal coal for domestic and international markets at a rate of about 2600 t/d. Currently, 65 people work at the site, including some corporate employees.Opened in 1993, the Quinsam mine had a dismal safety record until 1997. Lost time injuries and medical aids were unacceptably high. In 1998, a change in corporate structure brought a change in safety attitudes; a total and unequivocal commitment to safety as job No.1 by corporate and site management. This commitment was clearly spelled out in a new mission statement, circulated to all employees by the new President and CEO, David Slater: “Safety is job No. 1; Production flows from safety; and Think safety at all times.” As well as re-defining workplace safety practices, QCC tightened engineering controls and enforced strict adherence to mine plans.This paper provides a general background to the mining operation, and describes the safety practices that have resulted in an enviable safety record in recent years, reflected by provincial and national recognition."

Jan 1, 2004

By J. S. Stachulak, K. A. Mackinnon

This paper deals with specifying and evaluating fans for mine ventilation projects. Topics such as fan and equipment design life, operating points, and operating conditions are discussed. Common operating problems, such as vibration, parallel operation, mechanical failure, erosion, corrosion, and deficient fan performance are covered. Apart from identifying the potential operating problems, likely causes and suggested remedies are given. Fan type, fan accessories, and likely system effects and fan testing are discussed. Suggestions on what should be covered when evaluating different fan options and proposals and suggestions on the verification of supplier claims and guarantees, including cost of operation, the evaluation of initial capital cost, estimate on maintenance costs, and likely replacement expenditure over the life of the fans. In addition, fan reliability, operational flexibility, suggested construction details and fan vendor past history and experience are reviewed.

Jan 1, 2004

By T. Watanabe, M. Nakagawa, K. Kimapong

Lap joint of A5083 aluminum alloy and SS400 steel was produced by Friction Stir Welding (FSW) Process. The effect of welding parameters such as rotational speed, traverse speed and tool dimensions on the mechanical properties and the interface microstructures of the joints were investigated. FSW process could successfully produce the lap joint between A5083 aluminum alloy and SS400 steel. The variations of rotational speed, traverse speed and pin depth of a rotating tool gave rise to various characteristic interfaces of the lap joint and had conspicous influences on the joint properties. The increase in hard and brittle intermetallic phase and defects formed at the interface of the joint decreased the mechanical properties such as the shear load of the joint.

Jan 1, 2004

By R. Pelletier, Herny. E., C. Allaire

Corrosion of refractory linings by molten metals is controlled by interactions between penetration and chemical reaction. Corrosion of aluminosilicates by molten aluminium is no exception. The early stage of corrosion can be described as a particular case of reactive wetting over a porous medium. Although the reactivity between aluminium and silica is great, which should improve wetting and penetration, the presence of air and the formation of a protective oxide layer disfavours initial penetration. This paper presents the results of an exploratory study on the effect of some parameters on the initial stage of aluminium penetration. Penetration kinetics and metal intrusion tests have been performed on alumina and silica powders with pure aluminium and Al¬5%Mg. Capillary models are used as tools of interpretation. Penetration kinetics tests had a poor reproducibility and the kinetics itself can not be explained very well by the capillary-tube-bundle model. On the other hand, a capillary model initially developed for ice intrusion into freezing soils produced predictions in reasonably good agreement with intrusion pressure measurements. The effect of particle size and alloy composition can be predicted using this model. However, the effects of temperature and powder chemistry need additional interpretations to be rationalised. An unusual resistance to penetration of silica powder by molten aluminium have been observed in a series of experiments. This led the authors to the strange conclusion that oxygen should be seen as an excellent non-wetting agent and that there might be ways to use it in industrial applications.

Jan 1, 2004

By G. Forté, R. Girard

The Alcan Bayer Process Experimental Centre (BEC) is an essential development tool for the Bauxite & Alumina researchers at the Alcan Arvida Research and Development Centre in Jonquiere, Quebec. Between the laboratory tests and the industrial prototypes or the industrial applications, the BEC is a key element for technology transfers. The Bayer process is the extraction of aluminium oxide (or alumina) from the bauxite ore. The Bayer Experimental Centre's history and flowsheet are presented. The major pieces of equipment are described. Safety and design considerations are presented. Finally, examples of applications, double digestion and pressure decantation, are briefly described.

Jan 1, 2004

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By R. Guimarães, L. Silva, J. Milboume

The São Bento concentrator was built by Gencor in 1985 to treat refractory gold-bearing flotation concentrate. The plant was the first commercial application of pressure oxidation for refractory gold ore following about a year after the first use of pressure oxidation on a whole ore at Homestake's McLaughlin operation in California. Ore from the Sao Bento mine is remarkably consistent in gold grade and arsenic and sulphide concentration as is typical in banded iron formations (BIF) (l). Gold content is approximately 9 g/t with approximately 30 - 40% free milling. The balance is associated with arsenopyrite and pyrrhotite. An expansion of both process facility and mine was undertaken between 1996 and 1998, raising the treatment capacity from 32,000 t/mo to 45,000 t/mo.

Jan 1, 2004

By Yoshimasa Funakawa, Kazuhiro Seto, Akio Kobayashi

A new hot rolled high strength steel consisting of ferrite matrix and nanometer¬sized precipitates was developed. The ultra fine precipitates were identified as TiMoC2, and the strengthening by the precipitates was evaluated more than 300MPa in case of TS/800MPa grade steel. Due to the strengthening effect of the ultra fine precipitates, alloy elements for solid solution hardening can be reduced. It is notable that the steel shows very high yield strength (730MPa in case of TS/800MPa) and very high local elongation leading to excellent stretch flange formability at the same time. The mechanical properties of the steel are attractive for chassis parts and structural parts of auto body. The steel has been produced commercially, and applied to the parts successfully.

Jan 1, 2004

By A. Innus, R. Pelletier, C. Allaire

Refractory used for molten aluminium confinement is typically assessed separately for thermo-physical properties and molten aluminium resistance. This present work provides a case study comparison of four commercial refractory products that were subjected to a test procedure that combines mechanical impact, thermal shock with molten aluminium contact. The main conclusion of this work is that physical and mechanical property values by themselves do not, and cannot, predict the response of refractory to potential interactions between molten aluminium contact and thermal shock and mechanical impact. Adequate physical simulation is imperative to quantify the effect of such interactions.

Jan 1, 2004

By V. G. c Papangelakis, M. Huang

A conductivity cell, developed previously, was employed in an effort to investigate the inter-relation between electrical conductivity and acidity of sulphuric acid - metal sulphate solutions at high temperatures. The measured solutions include the H2SO4-H2O, MgSO4-H2O, H2SO4-MgSO4-H2O, H2SO4-MgSO4-Al2(SO4)3-H2O solutions. All solutions reported in this paper were measured from 15 to 250 °C at equilibrium vapour pressure. The maximum measured concentrations of H2SO4, MgSO4 and Al2(SO4)3 were 0.45 m, 0.30 m and 0.10 m, respectively. It was found that, from 15 to 250°C, there is a linear relationship between H2SO4 concentration and electrical conductivities for acid concentration up to 0.45 m. At 250 °C and constant H2SO4 concentration, the solution conductivity drops with the increase of MgSO4 concentration. Lt is suggested that this drop is caused by a decrease in the concentration of H. Finally, an empirical model was developed based on the available measurements. This model has been tested against real laterite leach solutions where sulphuric acid and metal sulphates are dominant electrolytes. The average difference between the estimate acid concentration from this model and the one from titration was less than 5%.

Jan 1, 2004

By E. V. Konopleva, H. J. McQueen, V. M. Khlestov

In addition to increasing grain boundary area during hot working of austenite, the dislocation substructures create potential sites for nucleation of ferrite both at original grain boundaries and at transition boundaries between deformation bands. This development gives rise to a marked increase in the rates of nucleation, of growth and of transformation to ferrite. The combined net effect is product grain refinement that requires less stringent cooling between finish rolling and coiling; hence determination of the above rates would advance process optimization. The important control parameters are the preheat temperature (degree of homogenization), finishing temperature, strain (accumulation near finishing) and the extent of recrystallization after finishing. These effects vary greatly with steel composition; nevertheless, some general rules have been formulated. Moreover, there is also potential for deformation of the refined ferrite. There are other thermo-mechanical processes such as warm forming of metastable alloy austenite to provide a dense substructure that is carried into the martensite on quenching. In other processes, the austenite may be deformed during cooling through the transformation to develop a dense substructure in the ferrite that is stabilized by fine carbides.

Jan 1, 2004

By B. T. Lu, J. L. Luo, T. Yu, C. W. Chen

In this paper, the synergism in erosion-corrosion process occurring in oil sand wastewater transportation caused by the interaction of mechanical and electrochemical factors was experimentally investigated. The erosion-corrosion tests were conducted with A1045 steel in synthetic slurries comprising tap water and silica sand. The material loss due to corrosion-enhanced erosion was assessed with the chemo-mechanical model developed by the authors recently. The results indicate that the material loss produced by corrosion-enhanced erosion at the open circuit potential can be formulated as a linear function of logarithm of corrosion current density. The wastage caused by the erosion-enhanced corrosion was analyzed based on the concept of non-equilibrium thermodynamics. The material loss induced by the erosion-enhanced corrosion is approximately a linear function of overall erosion rate measured in synthetic slurries, indicating that erosion-enhanced corrosion could be reduced by adopting surface strengthening techniques to improve the resistance to the plastic deformation in surface layer.

Jan 1, 2004

By B. Simser, V. Falmagne

"Noranda’s Brunswick mine is a 10 000 t/d producer of lead-zinc-copper-silver ore that has been in operation since 1964. Mining of this multiple lens deposit is primarily by blasthole stoping techniques between 400 m and 1200 m below surface. The combination of a high overall extraction ratio, an overall steeply dipping tabular shape, and high horizontal stresses (twice the vertical) have elevated the induced stress regime to levels comparable to much deeper operations. Improved mine design, and a better understanding of how the rock mass responds to mining in high-stress environments is essential to improve overall recoveries and maintain safety. Seismic monitoring has proven to be an essential tool at Brunswick, for both short-term safety of workers, and long-term strategic planning.Practical case studies illustrate how seismic data, particularly source parameter information, can be used to measure the rockmass response to mining and improve mining layouts in difficult regions. As the global trend continues toward mining in deeper, higher stress environments (e.g., South African Witswatersrand Basin, Sudbury Basin) and as local extraction and thus ground stresses continue to increase in existing deposits, seismic monitoring will play a critical role in mining safely and economically."

Jan 1, 2004

By Seong-Taek Lim

Recently, 7xxx aluminum alloys have been evolved into new variants for thick semiproducts which have low amount of 2nd phases and low quench sensitivity. Commercial 7xxx alloys, especially in the thick forgings made of big ingots, often entail microstructural inhomogeneities and concurrent poor mechanical properties due to limited heating ranges and slower quench cooling. In this study, high strength aluminum alloy 7175 and 7050 are adjusted as an attempt to control the equilibrium phases (M-, T- and S-phase) to have optimum microstructure for the thick forging applications. The effects of the relative content of (Zn, Mg, Cu) on the evolutions of the coarse equilibrium phases, hardening response and resultant mechanical properties are investigated. Equilibrium phases (M,T,S) are evolved depending on the constitutional effect, primarily the change of Zn:Mg ratio, and cooling rate following solutionizing. The formation of the T- and S-phases is effectively controlled, and M-phases are homogeneously precipitated in the adjusted (dilute and high Zn:Mg ratio) alloys. It provides extended heating range and lower quench sensitivity than conventional alloys. The attempts ensure the microstructural homogeneity and improved properties, and is expected to be uniquely applicable in 7xxx thick forgings.

Jan 1, 2004

By W. T. Thompson, S. Durham, K. M. Jaansalu

The role of platinum on the relative stability of gamma - gamma prime equilibrium is only qualitatively known, and may bear upon the stability of a superalloy under a protective coating. The binary phase diagrams Ni-Pt and Al-Pt, and the Ni-rich corner of the Ni-Al-Pt ternary, are reviewed and simple self-consistent thermodynamic models are derived. These thermodynamic models are incorporated into a database used to predict the gamma-gamma prime equilibrium for single crystal superalloys. In small concentrations, platinum is predicted to increase the temperature stability, but not the proportion, of the gamma prime phase over the gamma phase in third generation alloys such as CMSX-10. Another effect of platinum addition is to significantly lower the solidus temperature. These findings are compared to experimental data in the literature.

Jan 1, 2004

By R. Loney, M. Militzer

There is a significant demand for new high strength steels with fine grain sizes for structural applications. One approach in this regard is to develop hot-rolled HSLA steels where refining the microstructure leads to increased strength levels, e.g. 700 MPa yield strength, that can be attained by suitable modifications of chemistry and processing. Here, an HSLA steel is investigated that contains 0.05wt%C-1.65wt%Mn-0.20wt%Mo¬0.07wt%Nb-0.02wt%Ti and approaches the above strength class. The ability to control and predict the mechanical properties of hot rolled steel depends strongly on the thermomechanical processes, which the steel undergoes. The final microstructure and, thus, the properties of the hot-rolled steel are a function of the austenite decomposition obtained during accelerated cooling on the run-out table and precipitation during coiling. The austenite-to-ferrite phase transformation under run-out table conditions has been investigated using a Gleeble 3500 thermomechanical simulator equipped with a dilatometer. The effects of cooling rate and initial austenite microstructure including the degree of work hardening on austenite decomposition kinetics and ferrite grain refinement have been quantified. Results show that grain refinement can be optimized by the presence of work hardened austenite and accelerated cooling. Based on the experimental results, a model is proposed to predict the transformation start temperature and the resulting ferrite grain size for run-out table cooling conditions.

Jan 1, 2004

By Neil R. Burns, Michael Doggett

Abstract - The Nanisivik mine offers a unique opportunity to examine the economics of a mining scenario from its original feasibility study through to closure. In the early 1970s, the Strathcona Sound project (exploration around the Nanisivik mine) had advanced to the point where a significant mineralized body had been defined and a feasibility study was initiated. The study supported development of the Nanisivik mine, with government investment in regional infrastructure, and the mine was constructed and operated for 26 years. Many elements of the feasibility study were difficult to estimate because the project was unique in its high Arctic setting. As a result, many differences were found when comparing the actual mining data to the feasibility study. The majority of these differences were the result of an actual mine life of 26 years instead of the planned 12.5 years. Most of the mining costs were higher than estimated and production occurred at a much higher extraction rate than planned. On a constant dollar basis, the metal prices were, on average, below the feasibility estimates. For the most part, these differences balanced out, with the actual mining being only slightly more profitable than anticipated in the feasibility study.

Jan 1, 2004