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By J. E. Dutrizac

A pyritic Zn-Pb-Cu ore waspercolation leached with acidified ferric sulphate solutions; zinc and copper were leached, lead was oxidized, but not dissolved, and pyrtte was essentially unattacked. High zinc extractions were achieved after a few months leaching, and substantial zinc solution concentrations could be produced by recycle of the oxidized solution. The leaching rate was generally controlled by the transport of the ferric sulphate oxidant. Zinc extractions increased with increasingferric ion concentration or flow rate, but were essentially independent of the concentrations of sulphuric acid, ferrous sulphate, cupric sulphate or chloride ion. The leaching rates were insensitive to the height of the ore column once a minimum height had been exceeded (0.8-1.0 m). Elemental sulphur was the principal sulphidic reaction product, but variations in the ratio of sulphur to sulphate produced anomalous temperature effects.

Jan 1, 1979

By A. S. Romaniuk

More than a decade ago, CANMET management recognized the need to make better use of existing technological information in mining and extractive metallurgy-two fields basic to the economic well-being of Canada. There were at that time no indexes or files dedicated to disseminating technical information for the many minerals mined and processed in Canada, including coal. CANMET, with the nation's largest research and library resources in the minerals field, was in a unique position to fill this need. Initial efforts were concentrated on building a mining file, beginning with identification of world sources of published information, development of a special thesaurus of terms for language control and adoption of a manual indexing/retrieval system. By early 1973, this file held 8,300 references, with source, abstract and keywords given for each reference. In mid-1973, operations were computerized. Software for indexing and retrieval by batch mode was written by CANMET staff to utilize the hardware facilities of EMR's Computer Science Centre. The resulting MINTEC file-one of the few files of technological information produced in Canada-is the basis for the national literature search service in mining offered by CANMET. Attention is now focussed on building a sister-file in extractive metallurgy using the system already developed. Published information sources have been identified and a thesaurus of terms is being compiled and tested. The software developed for CANMET's file-building operations has several features, including the selective dissemination of information and production from magnetic tape of photo ready copy for publication, as in a bi-monthly abstracts journal.

Jan 1, 1979

By V. K. Karra

A mathematical model for the performance of a vibrating screen is developed in terms of an oversize partition curve. This is a normalized curve for any assemblage of particles presented for screening when their size is normalized with respect to the 50 per cent passing size (d50 ) under the prevailing screening conditions. Based on the throughfall aperture (hT) of the wire mesh on the deck, the effects of oversize (% >hT), half-size under (% <0.5 hT), deck location and feed rate were evaluated using the existing screen sizing information. All these variables and also the near-mesh (1.25 hTx 0.75 hT) content (%) of the feed affect the d50. Performance data from different decks of a double-deck screen with various feed rates, size distributions and screen apertures were used to evaluate the near-mesh factor. Effects of wet screening and material bulk density are also incorporated in the model. This generalized model is useful for the simulation of a multiple-deck screen. It furnishes the sieve analysis information of all the deck output streams and therefore has a potential use in the over-all circuit evaluation when used in conjunction with relevant crushing and grinding performance models. An example illustrating the prediction capabilities of the model is given.

Jan 1, 1979

By J. S. Fox

Major-element data for unaltered, unmineralized felsic host rocks from a number of stratigraphically simple, massive volcanogenic Zn-Cu(-Pb) sulphide deposits of low metamorphic grade have been compiled. The petrochemical affinities of these host rocks have been determined (by standard means and by discriminant analysis) and compared. This comparison indicates that volcanogenic deposits in felsic terrains are not restricted to the classical calc-alkaline rock association as previously thought, but can actually be hosted by rocks showing a range of iron content. There is a positive correlation between differentiation trend and are tenor. Zn-Cu ores usually have iron-rich felsic hosts (most Canadian Shield deposits); Pb-Zn -Cu ores have iron-poor felsic hosts (Japanese, Iberian and Tasmanian deposits). This parallels the antipathetic relationship between iron content and background lead levels evident in young, unmineralized, island arcs as well as in many older belts. Correlations between differentiation trend on one hand and massive ore mineralogy and the relative proportions of various rock type (including rhyolite, quartz-porphyry and coarse pyroclastic rocks) on the other are also evident. It is concluded that the recognition of a calc-alkaline differentiation trend cannot be used as a prospecting guide, as has previously been proposed. However, in view of the above correlations, the recognition of a given trend may aid in the formulation of an effective exploration philosophy.

Jan 1, 1979

By R. D. Brown

This article summarizes some of the principal features of the taxation of industrial mineral mining in Canada. Where the rules applicable to such operations differ from those pertaining to the production and processing of precious and base meta s (non-industrial minerals), the two sets of rules are compared. If a conclusion could be drawn from such an over-all comparison, it may be that the total tax burden on an industrial mineral mine can be considerably more onerous than on both base meta mining operations and manufacturing profits.

Jan 1, 1979

By J. A. Finch

Samples of feed and product from a closed grinding circuit treating a heterogeneous lead-zinc ore were taken. The feed was subjected to laboratory batch grinding in a rod and ball mill with the objective of simulating the closed-circuit size distribution. It was concluded that the batch rod mill can closely simulate this product if only the over-all size is considered, but mineral-by-mineral large differences occur. If, as is suspected, the mineral sizes are the important factor in flotation, the differences could lead to problems in interpreting flotation results. An example of mineral recovery as a function of size is described to illustrate the potential problems.

Jan 1, 1979

"7.1. Glossary of the Platinum-Group Minerals7.1.1. IntroductionA glossary of the platinum-group minerals (POM) serves as a useful introduction to a chapter on their mineralogy. Earlier glossaries (Cabri, 1972, 1976) were prepared for different purposes and composed in a different manner. As for most mineralogical textbooks, from Dana's System of Mineralogy, 3rd Edition (1850) , to Fleischer's Glossary of Mineral Species (1980), this glossary is primarily a chemical classification, arranged here in two tables. Table 7.1 groups the mineralforming compounds of the six platinum-group elements (POE) according to their essential anion(s) or according to the nonPOE element in intermetallic compounds. Table 7.2 is a similar listing for the native metals and alloys of the POE. Both tables include unidentified POM considered to be bona fide new minerals requiring additional study for complete characterization and recognition (see Chapter 9*). Some information on the chemistry of the POM is given in the sections on X-ray data (7 .2) and ore microscopy (7 .3). Because the overwhelming majority of POM have been characterized by the electron microprobe, a more detailed account of representative analyses is given in Chapter 8**. The total POM listed in Tables 7.1 and 7.2 is about 100, after deleting some which would not qualify as discrete species if found today, but which are still recognized on historical grounds; e.g. iridosmine, osmiridium, platiniridium. Tables 7.1 and 7.2 also include 28 unnamed POM; included because they are considered to be probably new species (Cabri 1981 b). The referral scheme for unnamed minerals is the same as in Chapter 9. There are considerably more palladium minerals known than other POM; the proportion of total species (listed in Tables 7.1 and 7 .2) for the POE is: Pd 48%, Pt 21 o/o , Ru and Ir 9% each, Rh 8% and Os 5%. These proportions are in marked contrast to the estimated cosmic abundance, as compiled for average type C1 chondrite by Naldrett and Duke (1980): Pt 29%, Ru 20%, Pd, Ir and Os 15% each, and Rh 6%."

Jan 1, 1979

By E. W. Johnson

"The current increase in gold price may presage a resurgence of gold milling plants in Canada similar to that of the thirties. Because the industry has been at a low ebb for almost two decades, future operating responsibilities will likely devolve upon personnel with limited cyanidation experience. My comments, which may seem elementary to experienced operators, are directed towards these industry newcomers to highlight operational features in cyanidation which forty years' experience has shown me to 0e of importance. A brief review of what actually takes place in a cyanide circuit may help give a better understanding of the topics to be discussed.These will include: (1) expose the gold (2) dissolve the gold(3) make solid/liquid separation(4) recover the gold from solution.1. Expose the GoldThe chemical key to gold recovery by cyanidation lies in the ready solubility of the metal in a relatively weak solution (0.04%-0.075% NaCN equivalent by weight) of calcium or sodium cyanide. Obviously, dissolution cannot start unless the cya1ide is in contact with the gold. As an analogy, the yolk of a hard-boiled egg can oe taken to represent the gold particle and the egg white and shell, the surrounding gangue or sulphide host. As the sl1ell and white must be fractured to expose the yolk, similarly the surrounding gorngue or sulphide host must be broken or fractured to enable the cyanide solution to contact the gold."

Jan 1, 1979

By G. Stenning

The paper outlines the need for high-volume ventilation in a uranium mining operation based on the design to meet environmental requirements for dust, radiation and diesel equipment. Mining methods in a highly mechanized operation, a key factor in design, are discussed. The construction and installation of major intake and exhaust fans are described briefly, together with the development of the mine airways and distribution system. Controls in the form of doors and bulkheads are important considerations in planning. Finally, the need to lower ventilation requirements in response to increasing power costs will result in future improvements.

Jan 1, 1979

By Gary Raymond

The Similkameen Division of Newmont Mines Limited operates a low-grade open-pit copper mine in southern British Columbia. The copper mineralization is extremely erratic.As a result, over seven years of operation, ore control methods have evolved from standard flagging based on blast-hole assays, through an in-pit grab sampling system, to the present method of mining to computer-determined ore-waste boundaries based on geostatistics. These improved ore control methods have resulted in a gain of at least 25% on ore tonnage miffed, at the same grade as obtained using earlier techniques. At the same time, geostatistical ore reserve estimates are now within 7% of milled ore tonnage and grade on a yearly basis, whereas the original polygon ore reserves under-estimated mineable ore tonnage by 15% to 45% and over-estimated grade by about 20%. The author discusses why traditional ore estimation methods give poor results in erratically mineralized orebodies and describes the geostatistical approach to the problem.

Jan 1, 1979

By T. Richard Davies

This paper primarily deals with the application of wearfacing materials and their role within a well-established preventive maintenance welding program. Some examples are shown, as well as a synopsis of possible benefits and a compendium of methods and materials.

Jan 1, 1979

By M. Beech-Jones

The increased emphasis on the efficient utilization of capital and mineral resources has led to several new advances in the science of mineral separation. One example of a recent development is the application of high-capacity high-intensity wet magnetic separators to fine hematit e recovery by a leading Canadian iron ore producer. The iron ore recovery feasibilit , flow-sheet development, circuit operation and metallurgical performance are reviewed.

Jan 1, 1979

By K. Konigsman

"Representatives of various industries and the Canadian coast Guard formed a Bulk Cargoes Committee three years ago. In 1976 and 1978, I have attended the meeting which take place once per year here in Ottawa as representative of the Canadian Mineral Processors, Dave Hendricks from Granisle accepted the charge in 1977. Our Secretary, Bob Bruce, has suggested repeatedly that I report to the Membership on the deliberations to this group. Twice I found good excuses; this year I did not. I was reluctant to address you since the Committee's deliberation proceeded at a pace which might be identified as Government squared. The Committee advises a Government agency which in turn negotiates with foreign Government agencies.At the outset, I will describe the developments which led to the formation of the Committee and its purpose.The Canadian Mining Industry ships annually millions of tons of products to overseas customers; be it iron ore, coal, fertilizer, or base metal concentrates. Most loadings are in vessels of foreign registry and all will be directly affected by Canadian or International regulations of the transport of such bulk commodities. The major shipping nations are members of an Intergovernmental Maritime Consultative Organization (IMCO). This organization elaborates regulations which govern shipment of all cargo, bulk materials and concentrates included. At IMCO'S deliberations, Canada has one vote, one voice on the Consultative Committee and is represented by our Coast Guard. The Coast Guard has over the years been in contact with industries when discussions concerned shipment of bulk cargoes. In the early sixties, a ""Concentrate Committee"" did exist. It consisted of metallurgists from a number of mining companies and Government representatives. This committee was instrumental in the development of what became known as the ""Concentrate Code"", legislation which has evolved into the Canadian Bulk Cargoes Code as it is known today. The concepts of the flow moisture point and transportable moisture limit originated from its work. Incidentally, both criteria are widely accepted and utilized world-wide. The Concentrate Committee faded away once the Concentrate Code has been adopted."

Jan 1, 1979

"4.1. IntroductionThis chapter reviews the geochemistry of the platinum-group elements (POE) in sulphur-poor silicate rocks, and the limited data on POE in silicate, oxide, sulphide, arsenide and sulpharsenide minerals. The earliest geochemical studies of POE in silicate rocks, minerals and meteorites were carried out mainly by Goldschmidt, the Noddacks and their co-workers, and are reviewed in Crocket (1969). These researchers established the siderophile character of the POE, emphasized the common association of the group with sulphides in ultramafic-mafic rocks and suggested that very low concentrations of POE are typical of sulphur-poor silicate rocks and minerals. Much of these data were for Pt and Pd only and are more than 50 years old. Because of the poor sensitivity typical of the available analytical methods, few reliable data were obtained on silicate rocks in these early studies. Surveys of POE geochemistry demonstrate that the data base for sulphur-poor silicate rocks is very restricted, although considerable highquality data for Pd and Ir have been accumulated (Wright and Fleischer 1965, Yushko-Zakharova eta/., 1967, Mertie 1969, Crocket 1969, 1979, Keays 1981).Two recent publications, Vol. 71, No. 7 (1976), of Economic Geology (An Issue Devoted to Platinum-Group Elements) and Vol. 17, Part 2 (1979), of The Canadian Mineralogist (Nickel-Sulphide and Platinum-Group-Element Deposits), are of special interest. These volumes are clear testimony to the impressive progress made in the last decade toward describing the mineralogical and geochemical aspects of POE ore deposits, but at the same time demonstrate the constraints in modelling POE ore genesis due to our meager knowledge of the. POE content and distribution among minerals in the source rocks of ultramafic and mafic magmas. It is clear that the phases hosting POE in mantle source rocks are poorly understood. Nevertheless, Naldrett and Duke (1980) have shown that the absolute and relative concentrations of POE in magmatic sulphide ores are related to the degree of partial melting of mantle peridotites, and subsequent processes of batch equilibration and fractional segregation of sulphides."

Jan 1, 1979

By K. G. Stowe

"1. Introduction Mattagami Lake Mines and Orchan Mines operate zinc copper mines adjacent to one another near Matagami, Quebec, situated approximately 300 kilometres north-east of Rouyn-Noranda. (Note: Mattagami Lake and Orchan are in the process of being absorbed by Noranda Mines and will become Noranda Mines-Matagami Division). Both concentrators began operations in late 1963.The Mattagami Lake concentrator is capable of treating up to 3,500 metric tons per day of massive sulphide ore with a mineral composition shown in TABLE 1. The Orchan concentrator consists of two separate circuits - the Orchan circuit with a capacity of 1,050 metric tons per day and a custom circuit with a capacity of 825 metric tons per day. Throughout its operation, Orchan has custom milled ore from several smaller deposits in the Matagami district."

Jan 1, 1979

By Edward R. Rose

This paper summarizes and emphasizes the potential importance of Canadian rare-earth occurrences, and recommends that efforts to locate and evaluate rare-earth deposits should be increased. Increasing world markets, depending on intensive applied research into the numerous unique and remarkable chemical and physical properties of the rare-earth elements (REE), are developing; their properties and uses are becoming better known; methods of separation are much improved. The REE group comprises a Cerium (Light) subgroup of 7 metals and an Yttrium (Heavy) subgroup of 9 metals. REE are trace elements in many rocks and minerals, and major constituents of more than 50 rare-earth minerals, many of which are difficult to detect and identify. They occur preferentially in acidic and alkaline igneous and metamorphic rocks, including carbonatites, as well as in placer deposits, certain uranium deposits, phosphate rocks and others. The main ores now are bastnaesite (in Precambrian carbonatite), monazite and xenotime (in Recent beach sands) as well as uraninite and brannerite (in Huronian quartz-pebble conglomerate) and loperite (perovskite) and apatite (in alkaline complexes). World resources are summarized. Twenty mines in 1973 produced an estimated world total of about 31,000 tons of contained rare-earth oxides (REO), 19,341 tons of which came from one mine at Mountain Pass, California. A selected fifteen, of 315 or more Canadian occurrences, are briefly described and compared, and their relative merits indicated. Their abundance and variety suggest the possibility of finding high-grade deposits in many geological terranes in Canada.

Jan 1, 1979

"2.1. General Considerations and Properties2.1.1. IntroductionOur present knowledge of the platinum-group elements (POE) is extensive, the reason being two-fold. The elements have many uses and, moreover, they exhibit extremely varied chemical behaviour, depending on their state of oxidation and chemical environment. The present chapter reviews a selected body of material which is of particular relevance to mineralogy and geochemistry.Comprehensive treatises on the POE include those by Mellor (1956-1957), Gmelin (1938-1957) and Pascal (1958). The inorganic chemistry, particularly coordination chemistry, has been dealt with in works by Griffith (1967), Hartley (1973) and Livingstone (1975), and the analytical chemistry by Walsh and Hausman (1963), Beamish (1966) and Beamish and Van Loon (1972, 1977). Darling (1973) and Savitsky (1978) have reviewed the metallurgical properties and applications of the metals. Goldberg and Helper (1968) have reviewed the thermochemistry and oxidation potentials of POE systems, and Wagman et at. (1969) have also provided selected values of their thermodynamic properties. The geochemistry of the POE has been reviewed by Yushko-Zakharova et at. (1967), Cousins (1973), Cabri (1974), and Naldrett and Duke (1980).Platinum was used briefly as a coinage metal in ImperialRussia. Otherwise, the principal early use for platinum and its alloys was in the fabrication of chemically resistant apparatus. Subsequently, a large part of platinum production was utilized for catalysts in the sulphuric acid and ammonia industries. Platinum has been replaced by vanadium pentoxide in the manufacture of sulphuric acid, but, in recent times, catalytic upgrading of petroleum and emission control systems for automobiles have opened further huge markets for the metal. All of the POE find uses either as reagents or catalysts in the synthesis of organic compounds, e.g., in the Wacker process, which uses palladium chloride to catalyze the production of acetaldehyde from ethylene. There are, of course, a large number of specialized uses for the elements, particularly in alloys, temperature measurement devices, cancer therapy and so on."

Jan 1, 1979

By G. E. Agar, R. Stratton-Crawley

"The applicability of a hydrocyclone model to simulation of the cyclone banks in a multi-stage sandplant circuit producing mine back fill has been demonstrated. The model ha~; been used in conjunction with a modular computer program for circuit simulation in order to study the effect of changes in the operating conditions. It has been shown that weight recovery to sand fill increases as feed percent solids decreases, and, to a lesser extent as pressure drop across the banks increases. An increase in apex diameter also causes an increase in weight recovery. Increased weight recovery must, however, be balanced against sump an1l cyclone capacity and dilution of sand fill by fines. The predicted results from circuit simulation were in good agreement with plant data.The model has been found to be applicable to widely different ores."

Jan 1, 1979

By A. L. Mular

"On behalf of Bob Bruce and myself I would like to begin by stressing some key points.First, most of us know that the Canadian Mineral Processors was formed in 1969 and is an offshoot of the Canadian Gold Metallurgists. I attended that first meeting in 1969, and I haven't missed a meeting since! Pretty obvious that CMP serves the best booze! At any rate, we know that our meetings are supported by CANMET. Camsell Hall is always at our disposal; Bob Bruce acts as permanent secretary pretty much free of charge; we receive a financial grant from CANMET. This brings me to a second point.Second the Canadian Mineral Processors do not enjoy a free ride in this relationship. CMP provides a genuine service to the mining industry, to government, and to universities. For the industry, CMP serves as a forum for the rapid dissemination of new ideas and new technology developed at remote locations throughout Canada. New developments outside Canada are introduced by invited speakers at our meetings. The effect is to help reduce operating costs and increase efficiency.For government, problem areas and research priorities can be isolated through mutual discussions. Direct communication at our meetings can help CANMET to temper its goals and modify its national priorities.For universities, CMP provides a wealth of operating experience and practical know how. The yearly proceedings are a major current reference source fo1· those of us who teach mineral processing. Admittedly, the proceedings are publ-shed from CMP coffers. However, I note that our fees are up this year, which brings me to a third point.Third, we face some potential problems of a financial and political nature. From a financial view, we may lose our CANMET grant and other financial good will simply because of spending constraints. Our fees are expected to climb each year thereafter.From a political view, we know that the metallurgical society of CIM is anxious to incorporate CMP as a section. The pros and cons of such a merger have been described in a recent mailing. In th2 final analysis, the political and financial problems are interrelated. There are several alternative solutions to both problems, which brings me to a fourth point"

Jan 1, 1979

"9.1. IntroductionThe application of the electron microprobe for in-situ analysis of platinum-group minerals (PGM), first reported by Borovskii et at. (1959) and Genkin (1959), has resulted in a large and growing number of analyses of unidentified PGM. Figure 9.1 charts the increase in the number of reported unnamed PGM from 3 in 1959 to a total of 140 by 1979. All these minerals, with the exception of UN1968-5 and UN1976-1, were analyzed with the electron microprobe.There has been no recognised or consistent manner for reporting these unidentified PGM. The term ""unnamed"" has been used for PGM that are considered to be new species without a name as well as for PGM which have not been exhaustively compared to named and unnamed PGM in order to determine whether they are unique. Many of the so-called unnamed PGM are only unnamed because of poor microprobe analyses or because larger than usual elemental substitutions (e.g. Bi for As) made it difficult to calculate the true stoichiometry. Some of these unnamed minerals have been unnecessarily reported with non-stoichiometric formulae, as discussed by Cabri (1980). Better analytical data should reduce the number of such proposals.Another unfortunate practice, possibly used to by-pass the scrutiny of the Commission for New Minerals and Mineral Names, I.M.A., is to report a ""new"" mineral by referring to it by a name made up of its constituent elements. This has been deplored on a number of occasions (cf. discussion in Fleischer et at., 1976, p. 179), but some journals continue to publish such material. The Commission on New Minerals and Mineral Names has not recognised such ""names"" and these PGM are therefore included in this chapter with other unnamed minerals.A further example of inconsistency in reporting unnamed minerals is the report of a specific ideal stoichiometry with no further details (not even an analysis!); sometimes with a note that this will be reported in greater detail in due course. I have also been guilty of similar optimistic statements and, unfortunately, it is not always possible to follow through. Some authors give data on unnamed minerals in such a discrete manner that their reports are sometimes missed in literature searches."

Jan 1, 1979