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In analyzing cost performance, managers must initially consider the issue of scope. Is the analysis for a single responsibility center or multiple centers? For a single period or a number of periods? If multiple responsibility centers are being examined, how can managers compensate for differences in their sizes? Several techniques have been developed to analyze the relationships in a set of financial statements at a single point in time and the trends in these relationships over multiple periods. Cross-sectional techniques focus on the first of these, and time-series techniques look at the latter. Although this text focuses on cost performance, these methods also can be used for revenue-related analyses.

Jan 1, 1999

By K. V. S. Sastry, M. Cross

A summary of recent progress in understanding the main factors affecting the pelletization of fine particles is presented. A scheme for categorizing the mechanisms responsible for pellet growth is out- lined and laboratory methods to both identify the important growth mechanisms and quantify the effects of the major factors influencing the rate of pelletization are described. Next laboratory and mathematical simulations of the commercial process involved in pelletizing iron ore concentrates, are presented. The operational instabilities associated with this pelletization process are described and subjected to a control theory analysis. This analysis, in conjunction with the mathematical models, is used to both explain existing control problems and assess the effectiveness of possible circuit redesigns at producing a more stable and controllable operation. Although much of the discussion is in the context of iron ore pelletizing the approach developed to analyze the agglomeration behavior of these concentrates should apply to most other fine particle systems.

Jan 1, 1980

By Petr Sulovsky, Jaroslava Ledererova, Miroslav Svoboda, Michaela Suchardova

"The thinning resources of natural raw materials necessitate an increased degree of waste material recycling. The building industry offers a range of technologies enabling incorporation of industrial wastes into building materials for construction purposes in an economically acceptable way. Our research is focused on finding the appropriate technologies for specific groups of industrial waste materials (IWM). The studied IWM involve coal combustion residues (CCR), desulphurization products, sludges, metallurgical slags, and various other wastes. Many of them contain increased amounts of toxic elements that can under certain conditions get released. In order to prevent this, each specific IWM requires finding the technology that best ensures the binding of toxic elements in the building matter are fixed for the long term.Introduction The sustainable development of mankind is more than ever viewed as a matter of resources. Many aspects of the switch from a throw-away to a recycling society concern one of the largest consumers of natural resources and producer of greenhouse gases, the building industry. One of the biggest tasks lying before the researchers in the field of building materials is to find substitute or alternative raw materials that would save the thinning reserves of natural resources. The most promising and natural way is to replace the traditional raw materials with rejected and unwanted products of industrial processes, classified as wastes. These of course are not produced with the primary intention of achieving some desired properties. The usage of industrial wastes therefore involves finding the optimal way of usage their existing positive (from the point of view of utilizations) properties and minimizing the impact of their undesired properties, i.e. from the perspective of the considered application."

Jan 1, 2008

By B. R. Reddy, Y. V. Swamy, B. V. R. Murthy, H. S. Ray

The Ni oxide was reduced with a CO-CO2-N2 gas mixture and the effects were observed of process variables such as roasting temperature, time and CO partial pressure. Extraction of over 90% of Ni was achieved by ammoniacal leaching of ore that had been reduced for 1 h at 760 degrees C under a gas mixture with a volumetric CO/(CO+CO2) ratio of 0.57. The kinetic data were found to conform to the Ginstling-Brounstein equation. The applicability of this model was confirmed by evaluating the apparent activation energy with the use of independently constructed differential and integral plots, which showed an excellent match

Dec 1, 1995

By M Ljunggren, M Lundh

Dissolved air flotation (DAF) in wastewater treatment as a separation process of submillimetre biological flocs is based on the generation of bubble/floc aggregates. DAF is a complex process but has got advantages, such as allowing a high hydraulic load, compared to sedimentation. A thorough knowledge of the physics of the DAF process is, however, still lacking. This paper will present results of experimental studies on three aspects of significance to the separation process û the flow structure in the flotation tank, rise velocities of aggregates, influence of floc size on the separation efficiency. Flow structure. Measurements were performed in a pilot plant mapping and visualising the velocity field. The dispersion water (bubbles) had a decisive influence on the flow structure due to the effect of the bubbles on the bulk water density. Stratified conditions with a less dense, bubble-containing upper layer and a clear water, denser bottom layer were important for a good separation. A simple model of the stratified flow structure was elaborated making it possible to interpret the function of the aggregate rise velocities. Bubble/floc aggregates. The dynamics of single flocs, bubbles, aggregates were visualised using a borescope + CCD video camera + digital recorder + image analysis. Sequences of video frames made it possible to determine the rise velocities of the single aggregates. These velocities were found to be in the range 1 - 9 mm/s with a tendency for large flocs to have higher rise velocities. Separation versus floc size. The floc size distribution was measured in the DAF process. Data from three different DAF cases showed, that large flocs (> about 100 ¦m) were entirely separated, whereas small flocs experienced a less good separation. It was, moreover, found, that a very significant separation of flocs took place in the very upstream end of the separation zone in a pilot plant case.

Jan 1, 2005

By J. W. Craig

THERE are, broadly speaking, three classes of refractories: acid, basic, and neutral. Fireclay, diaspore, silica, and the sillimanite group of minerals are included in the acid class, which for the most part are not very resistant to basic slags. The neutra! class includes chrome, graphite, and silicon carbide, while most important in the basic class are magnesite and dolomite. Although chrome is a neutral refractory, it has no sharp distinction from magnesitic refractoriness. The two are mineralogically (1) and chemically related, and there is available on the market a complete range of brick from straight chrome to straight magnesite. In many indus trial applications, one. type may be replaced by another. The present paper is confined entirely to such refractories. The following types of basic and neutra! brick, each sold under sorne special trade name, are available for use in Canada: (1) Burned chrome from crude ores (2) Burned chrome from treated ores (3) Chemically bonded (unburned) chrome-magnesite ( 4) Burned chrome-magnesite (5) Chemically bonded ( unburned) magnesite-chrome (6) Chemically bonded (unburned) high-iron magnesite (7) Burned high-iron magnesite (Regular) (8) Burned low-iron magnesite (9) Burned olivine-magnesite (10) Burned magnesitic dolomite-chrome (Magnecon) (11) Chemically bonded magnesitic dolomite-chrome (Magmecom) (12) Dolomitic brick

Jan 1, 1936

By D. A. Dahlstrom

Since the initiation of continuous vacuum filtration over a half a century ago, control of the performance of these units has been largely in the hands of the plant operators, Obviously there has been the introduction of variable speed drives, adjustable speed feed slurry agitation, vacuum control, etc. However, control of , filtration rate, cake moisture content, dissolved solids recovery by cake washing and dryness of solids where thermal drying is practiced is primarily up to the operators judgment and the settings he imposes on the controls he regulates, - filter cycle time, submergence, vacuum level, filter medium condition, wash water- rate, and other such factors. While this may seem to indicate that good operators are a paramount necessity, and certainly always desirable, a considerably more vital factor is a properly designed filter and filter station for the particular application. With improper design, highly skilled operator control will still leave much to be desired in the way of process performance. On the other hand, with correct design and application, the operator can easily and quickly control normal plant surges and quality variations within the flow sheet. Due to the growing complexity and inter dependency between the various processing steps in the modern flow sheet as well as the rising costs of capital investment, labor, maintenance, and losses involved with off quality product or insufficient recovery, automatic or inherent performance control of many of the unit operations within the metallurgical mill must be achieved. Continuous filtration should and can be susceptible to such control. However, as every instrument engineer knows, before control and automation can be achieved, a basic understanding of the operation is mandatory. This is primarily due to three factors. First, as in so many control applications, it may not be possible or feasible to measure the factor that it is desired to control. Thus, secondary variables that influence the major factor are substituted for control purposes. Secondly, it is always desirable to take advantage of any ?self-regulation? within the operation being performed on the equipment. In so doing, not only will automatic control be facilitated, but instrumentation is minimized while experiencing most efficient operation. Finally, automatic control is not a cure-all for improper process and equipment design and application. Hanging instruments on such an operation can be compared to constructing a sizable building on sand, Results will be disappointing.

Jan 1, 1960

By E. Daniel Baker

"The term ""oxide disseminated gold deposits"" refers to near surface, gold-bearing veins, faults, and shear zones that typically contain appreciable amounts of oxidized ore or gossanous material, resulting from oxidation of sulphides.The concept of oxide gold deposits underwent a dramatic change after the discovery of the Carlin gold mine in north-central Nevada in the early 1960's. Now the term implies large tonnage, low-grade bulk minable deposits that are processed by milling and/or heap leach methods.Oxide gold deposits may now be classified into two types: (1) primacy ores derived directly from the effects of hydrothermal alteration on host rocks, and (2) secondary oxide ores derived from the supergene oxidizing effects of circulating post-mineral meteoric waters on gold-bearing sulphides. Each type of deposit has unique diagnostic mineralogic and metallurgical characteristics that must be addressed to achieve successful exploration strategies and viable metallurgical exploitation.The author would like to thank the management of Newmont Metallurgical Services and Newmont Mining Company for allowing presentation of this paper. Thanks are due Sevkett Acar, Donald M. Hausen, Jerry R. Odekirk, and D. Erik Spiller for their critical review of the manuscript. Also, thanks are extended to all those cited and uncited whose hard work and dedication have led to the discovery and exploitation of near-surface oxide gold deposits. Our knowledge would be greatly limited without the dedication and research of many others."

Jan 1, 1997

In attempting to vegetate pnob!em sites some basic pn.i,ne%ptes, namely the phys.ica.e and chemi.ca2 pnope/ti;es og the problem mateni.al and the selection oU hu.itab.2e p!antts {cor pnopagati.on, have to be considered. Pnobtem sites such as tai ing dams, mined-out atteas, and areas which have been genehaUy advehse2y a46eeted by mining activities, are not only o~ten located in a divehs.ity o4 climatic regions, but they also usuaUy dL64en substantially in theAjt .int' Lns c phys.ica2 and chem.i cat pnopen t i.es . To estabP.ish vegetation on such sites 6requent2y requites: .%) The ame Lonaton oU adverse {yaetors in onde t to exeate a hoot env.utonment suitable Uon "satis1actony" plant growth. .%i) These.2eationo4 plant species suited to the improved Hoot env.utonment, and eompat%b&e with the e2imate o{y the site, and the ultimate Land use o4 the site. iii) The estabL shment o{y a Laboratory and p-LLot scale testing programme to aeeomptizh the above.

Jan 1, 1976

By R. E. J. Putman

The, principle purpose of applying control to any process is to improve -its profitability. Even when considering the impact of a plant on its surrounding ecology this is still, true, since the sanctions felt most immediately from violations of the regulations are the economic penalties or fines which result. 'Economic performance can be improved within a plant in several ways. Steps can be taken to cut the cost or quantity of resources (power, water, steam, reagents) consumed per ton of throughput. Alternatively the operation of the plant can be changed so as to increase product yield per ton of throughput. Or the cost of labor and plant overhead per ton of product can be reduced by raising the total 'throughput, assuming-that the increased amount of product can be sold for the same unit price. In designing a program to improve plant performance, all three routes should be borne in mind. To maximize the return on investment over a longer period, it is also desirable to set up a comprehensive plan of improvement, equipment being specified at each step in the implementation so as to ensure that it fits in with later requirements later implementation being either by means of modular additions or by having the necessary interfaces built into the original equipment. It is much cheaper in the long run to buy features which have been factory-installed, than to have to make provision for their later addition in the field. This paper examines some ways of improving plant performance by the application of various process control techniques using both analog and digital con¬trol equipment. A general philosophy of application is suggested and specific examples described.

Jan 1, 1972

By Wayne D. Gould

Planning for a project does not start with the announcement of the approval for a project. Planning actually begins when the project is only a prospect and it involves the years of experience of many people because their expertise influences the final decisions. In partial anticipation of the Pinto Valley project, as well as a search for improvement in the Copper Cities operation, two projects were undertaken. The first project was to substitute one 26" cyclone for three 20? cyclones in the single stage grinding circuit. The second project was to replace the Hunt air flotation cells with 300 cubic foot mechanical cells. The 300 cubic foot cells were just being introduced, consequently two types of cells were selected for testing. The results from both projects influenced the decisions on equipment for the Pinto Valley project.

Jan 1, 1975

The paper will review the fundamental policy issues and options that have been considered in the determination of the proposed allocation and pricing (ie royalty) regime for minerals under the Crown Minerals Act 1991. It will consider such influences on the new disposal, allocation, pricing and management arrangements for the Crown's mineral estate as the existence of prior ownership claims, exclusivity in access, the requirement for cost recovery and the treatment of contingent liabilities.

Jan 1, 1993

By Guillermo V. Borquez

The economics of open pit mine design are dictated by three basic elements: cut-off grade, stripping ratio and slope angle. Although these elements are functions of a number of independent parameters, they are interrelated through their influence on the overall economics. The optimum slope angle is the most uncertain element to determine, because rock mass properties are difficult to obtain. However, for preliminary estimation, the slope angle can be determined from the relationship between the probability of failure and the safety factor. The economics of the slope selected will depend on a profit versus risk judgment. In this paper, the author will present an actual case of application of this postulate.

Jan 1, 1977

From a consideration of the functional requirements of a stope-support pack, simple design principles were developed. The material and dimensional properties of the different components of the pack were determined from a series of laboratory tests. The most important requirement for an adequate pack is that the cushioning layers of timber between the concrete brick layers should provide sufficient transverse reinforcement. The tendency of the compressed timber to creep is shown to be a serious limitation to pack performance and must therefore be an important consideration in the overall design of supports.

Jan 1, 1978

Discussion of the above paper by G. J. van JAARSVELDt Mr Ortlepp's paper is important, and deals with a subject towards which much controversy and insufficient basic scientific logic, in my opinion, have been directed. He attempts to remedy some of our unscientific popular misconceptions, and for this we thank him. However, I regret to say that experience has shown that some of his statements cannot be allowed to pass unchallenged. Author's reply Mr Van Jaarsveld's contribution is welcome because it provides an opportunity for me to clarify certain points that were perhaps not adequately explained in the paper.

Jan 1, 1979

By J. D. Sullivan, Chester R. Austin, J. L. Nunes

IT is characteristic of most shales and surface clays that a bloated or vesicular structure is produced by burning to a sufficiently high temperature, usually about 150° to 200°F. above the normal maturing temperature used when making common brick of the same material. Early investigators recognized this phenomenon and attributed it to the release or expansion of gases in the vitrified piece. A number of theories have been advanced on the source of the gas and the manner in which it is evolved, but none has been proved conclusively. T. E. Jackson's1 early theory that bloating was due to oxygen evolved by ferric oxide in forming ferrous oxide or ferrous silicate was never substantiated by experimental work. Orton2 thought this explanation unlikely, as all clays should bloat at the same temperature, if this were true. He found that clays bloated in the range from 1100° to 1706°C. Also, many clays containing iron did not bloat at all, but fused. Orton also stated that oxidation of different types of carbon was a source of gas during burning of clay and should be expelled before vitrification was reached. Seger3 said that he had dissolved ferric oxide in glass with no apparent evolution of gas. Matson4 came to the conclusion that ferruginous days burned to vitrification in an oxidizing atmosphere did not have the iron in a ferrous form. According to Wilson,5 the gases responsible for bloating might be entrapped air, water, sulphur dioxide, carbon monoxide, oxygen, and hydrocarbons. He spoke of two causes of bloating: (I) incomplete oxidation below the vitrification temperature, and (2) decomposition of compounds and evolution of gases above the vitrification temperature. Decomposition of calcium sulphate was given as the principal example of the latter. Bleininger and Montgomery6 stated that if any time after vitrification began the evolution of gaseous matter was rapid enough so that pressure was produced within the day, bloating was certain to take place, and a vesicular structure would be formed. They recognized that initial structure, rate of heating, kiln atmosphere, and many other variables affected bloating. Work done by the Emergency Fleet Corporation7 indicated that clays suitable for bloating should be high in compounds of metallic oxides, carbon, sulphur, sodium, potassium, or other equivalent compounds, which either act as a flux or give off gas. Orton2 studied the chemical status of the carbon, iron, and sulphur in clays during various stages of burning, using a Huron shale that bloated under oxidizing or reducing conditions. He found that only a small amount of sulphur remained in the clay and that it could be detected only by dissolving the clay in hydrofluoric acid; i.e., the sulphur was in combination with the silica. Orton said that this sulphur was probably in the form of iron sulphide dissolved in the glass phase. The iron sulphide was not broken down by heating, but was dissolved in the basic slag or glass,

Jan 1, 1942

By J. D. Sullivan, Chester R. Austin, J. L. Nunes

IT is characteristic of most shales and surface clays that a bloated or vesicular structure is produced by burning to a sufficiently high temperature, usually about 150° to 200°F. above the normal maturing temperature used when making common brick of the same material. Early investigators recognized this phenomenon and attributed it to the release or expansion of gases in the vitrified piece. A number of theories have been advanced on the source of the gas and the manner in which it is evolved, but none has been proved conclusively. T. E. Jackson's1 early theory that bloating was due to oxygen evolved by ferric oxide in forming ferrous oxide or ferrous silicate was never substantiated by experimental work. Orton2 thought this explanation unlikely, as all clays should bloat at the same temperature, if this were true. He found that clays bloated in the range from 1100° to I700°C. Also, many clays containing iron did not bloat at all, but fused. Orton also stated that oxidation of different types of carbon was a source of gas during burning of clay and should be expelled before vitrification was reached. Seger3 said that he had dissolved ferric oxide in glass with no apparent evolution of gas. Matson4 came to the conclusion that ferruginous clays burned to vitrification in an oxidizing atmosphere did not have the iron in a ferrous form. According to Wilson,5 the gases responsible for bloating might be entrapped air, water, sulphur dioxide, carbon monoxide, oxygen, and hydrocarbons. He spoke of two causes of bloating: (I) incomplete oxidation below the vitrification temperature, and (2) decomposition of compounds and evolution of gases above the vitrification temperature. Decomposition of calcium sulphate was given as the principal example of the latter. Bleininger and Montgomery6 stated that if any time after vitrification began the evolution of gaseous matter was rapid enough so that pressure was produced within the clay, bloating was certain to take place, and a vesicular structure would be formed. They recognized that initial structure, rate of heating, kiln atmosphere, and many other variables affected bloating. Work done by the Emergency Fleet Corporation7 indicated that clays suitable for bloating should be high in compounds of metallic oxides, carbon, sulphur, sodium, potassium, or other equivalent compounds, which either act as a flux or give off gas. Orton2 studied the chemical status of the carbon, iron, and sulphur in clays during various stages of burning, using a Huron shale that bloated under oxidizing or reducing conditions. He found that only a small amount of sulphur remained in the clay and that it could be detected only by dissolving the clay in hydrofluoric acid,i.e., the sulphur was in combination with the silica. Orton said that this sulphur was probably in the form of iron sulphide dissolved in the glass phase. The iron sulphide was not broken down by heating, but was dissolved in the basic slag or glass,

Jan 1, 1942

By R. G. Robins

The effective removal of arsenic(V) from process streams and waste waters by precipitation with excess iron(II1) is sometimes attributed to the formation of basic ferric arsenates. The authors have investigated this system extensively using a variety of techniques and conclude that the solid phase produced is iron(II1) oxyhydroxide (ferrihydrite) with arsenic(V) adsorptively bound to the 2-3 nm particles.

Jan 1, 1992

By R. P. King

The essential features of an image analysis system for the measurement of mineral liberation are described. Good procedures for image acquisition and image processing prior to image analysis are defined. The basic stereological methods for the measurement of volume fraction, surface area per unit volume, particle size distribution and liberation spectra are given. The appropriate methods for fractal correction when measuring perimeters of irregular features and for frame correction when measuring linear intercepts are developed. Practically useful and accurate procedures for the stereological correction of particle size and liberation distribution methods are given.

Jan 1, 1995

Refractory gold concentrates often contain submicroscopic gold that is encapsulated within the crystal matrix of iron sulfide minerals, such as pyrite, pyrrhotite and arsenopyrite. To recover the gold, the host mineral must generally be broken down chemically by oxidative processes, such as roasting, pressure oxidation or bacterial leaching, which expose the gold for subsequent recovery by leaching in cyanide solution. The focus of attention in these pretreatment processes is usually the oxidation of the sulfides to elemental sulfur, sulfur dioxide gas or sulfate ions. Less attention is paid to the deportment of iron and the changes in its oxidation state, although this can have a profound effect on gold and silver liberation, as well as downstream operating costs. Iron sulfide minerals break down completely during pressure oxidation, and dissolve in the sulfuric acid solution that is gener-ated from oxidation of the sulfides. This dissolution liberates the tiny gold particles that were originally trapped in the sulfide crystals, and gold recovery during subsequent cyanidation is usually very high (>95%). Iron goes into solution in the oxidation process, initially as ferrous sulfate, but this compound is rapidly oxidized to ferric sulfate, which then hydrolyzes and reprecipitates. The form of the precipitate varies depending on the operating conditions in the autoclave and the presence of certain metal cations. When the acidity in the autoclave is quite low (<20 g/L H2SO4) and the temperature is high (>200°C), the formation of hematite is favored. When the acidity is high (>20 g/L H2SO4) and the temperature is relatively low (160 to 200°C), the formation of basic iron sulfate is favored. If the ore or the leach solution contains significant levels of certain cations (such as Na+, K+, NH4+, Ag+ or Pb2+) and the acidity is high (>20 g/L H2SO4), jarosite compounds are favored. Hematite is the desired iron product in the autoclave discharge, for both metallurgical and environmental reasons, but it is difficult to operate an autoclave under the conditions required for effective liberation of gold without converting some of the iron to basic iron sulfate and/or jarosite. These compounds fall into a category of iron compounds known generically as iron hydroxy sulfates, all of which can cause significant processing and environmental problems in the downstream gold process. This paper deals specifically with basic iron sulfate: the conditions under which it is formed in an autoclave, the problems that are caused by its presence in the feed to a cyanidation plant and possible remedial strategies that can be adopted, both in the autoclave and downstream.

Jan 1, 2010