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By A. D. Davis, D. J. Dixon, J. L. Sorenson, C. J. Webb, S. Dawadi

Limestone-based material appears to be an effective arsenic removal process that has great potential for source reduction in drinking water. Limestone-based material offers several benefits to the drinking water community: 1) reasonable removal efficiency as compared to material cost, 2) broad geographic and water system applicability, 3) compatibility with other water treatment processes, 4) ease of technical use, and 5) low-cost disposal in ordinary landfills. Batch and column experiments have evaluated the removal efficiency of several limestone types. Additives and material alteration have increased the removal efficiency. Granulation of powdered limestone as a filter media currently is being investigated.

Jan 1, 2006

By T. Fujita

A high-grade fluorite ore is converted into hydrogen fluoride to produce many kinds of materials containing fluorine. Recently, it is becoming necessary to use low-grade fluorite ore due to the depletion of high grade ore. The low-grade fluorites usually have impurities such as SiO2, P, CaCO3 and arsenic. The most impurities such as SiO2, CaCO3 and P can be removed by using flotation method. However, the removal of arsenic is difficult, and the arsenic contamination decreases the hydrogen fluoride production percentage. The novel technologies for processing low-grade fluorite ore are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, the removal of arsenic from low-grade fluorite ore has been investigated by means of an autogenous grinding using tower mill in sulfuric acid aqueous solution and 0.3 mm zirconia balls in water. The nano grinding in water can prevent the dissolution of 0.3 mm size zirconia balls as grinding media by sulfuric acid solution. Experimental results showed that the arsenic concentration was reduced from 260 mg/kg to 90 mg/kg and CaF2 recovery reached 90% by this process.

Sep 1, 2012

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By D. Laguitton

The basic chemistry of a1•senic related to its dissolution and subsequent precipitation in gold-mine waste waters is discussed. The lime addition methods provides the most economic treatment of arsenical slurries, but requires a careful control of the oxidation of Asm into Asv, of the pH (>12) and the filtration of the precipitate. If arsenic levels below 0.5 mg/ l are required, a modification of the method by phosphate addition must be considered.

Jan 1, 1976

Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014

By Larry G. Twidwell

The removal of dissolved arsenic from mine waste waters utilizing a lime/phosphate precipitation technique has been studied on a laboratory scale at Montana Tech of The University of Montana and on a pilot scale at MSE Technology Applications as a wastewater treatment process potentially capable of removing dissolved arsenic to <50 µg/L. Arsenic bearing lime and lime/phosphate slurries were subjected to laboratory extended-time air-sparged aging for over four years. The lime slurries released their arsenic back into solution in a relatively short period of time, whereas the lime/phosphate slurries showed limited release of arsenic. The developed process has been pilot scale tested by MSE-TA for the EPA Mine Waste Technology Program on three waters, ASARCO smelter blowdown water, ASARCO thickener overflow water, and Mineral Hill Mine groundwater. The laboratory study results will be presented and discussed in this presentation. The pilot scale results will be presented and discussed in a companion presentation. Stability, Aging, Apatite, Johnbaumite

Jan 1, 2005

By C. M. Acuña

At the Chuquicamata Division of Codelco-Chile high arsenic concentrates are produced, which at the smelter are processed via the Outokumpu Flash Furnace and Teniente Converters to obtain copper mattes. In the case of the Teniente Converters the production of matte grade near white metal composition is a common practice since the eighties and provided in the pyrometallurgical route no appropiate measures are taken, penalties have to be paid because of arsenic content in the anodes. During smelting huge volume of slag is produced and elimination of arsenic by slagging at this step is not economically attractive. Although during fire refining is possible to eliminate arsenic by use of mixtures of calcium and sodium carbonates this alternative is expensive, takes long process time and decreases the lifetime of the refractory lining. In spite of these facts a reasonably way to control arsenic in metal, and therefore in the anode, is taking, action in the converting step. The effects of oxygen and arsenic content in metal, arsenic in white metal and basicity index of the slag upon the distribution coefficient of arsenic between metal and slag were investigated at pilot and industrial levels. The best results are obtained for metals around 7,000 ppm oxygen and 0.3 basicity index slag, which results in a 5.7 distribution coefficient for a 5,800 - 7,100 ppm arsenic content in white metal, 18%-24% CaO slag at 1473 - 1523K. Furthermore, no significant/visible refractory wear has been realized.

Jan 1, 1999

By D. C. Foguel, J. L. R. Bravo

For several years, Caraiba Metais S.A. (CMSA) had to stock the arsenic sludge generated from the electrolyte purification process of its tankhouse. The amount stocked · reached approximately 3,500 tonnes, as the effects of its recycling during the smelting process and consequently in the sulfuric acid plant were unknown. Besides, it had as limiting factors the high content of arsenic in the copper concentrates supplied by foreign countries as well as the reduced capacity of the tankhouse's purification plant. The choice for selling the mentioned residue, which generally contains more than 50% of Cu, was attractive, but the environmental policies and regulations had not allowed this option. Other alternatives, such as the production of bicupric arsenic by means of a solvent extraction process or arsenic trioxide, were considered but the economic feasibility was not attractive due to the absence of a domestic market and a poor international market. After a study of the arsenic partition in the metallurgical process, it was verified that the residue could be recycled without causing any operational problems or damage to the environment. To make this possible, the capacity of the purification plant was increased and the way of removing the arsenic sludge from the cells was modified from manual to mechanical, therefore avoiding the direct contact of the workers with this poisonous substance. Moreover, procedures for recycling in the smelter were established and tolerance limits were set for both the smelter and the sulfuric acid plant. The main amount of arsenic to be recycled is released with the smelting furnace off-gas, which is washed during the purification stage of the sulfuric acid plant. The acid water, rich in arsenic, is then treated in the waste plant and the arsenic, in its stabilized condition, is confined in an appropriate area.

Jan 1, 2000

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By R. N. Tempel, M. Lengke

Arsenic sulfide (orpiment, realgar, amorphous AsS and As2S3) oxidation rates were measured in mixed flow reactors at pH-2 and at temperatures of 25 ° to 30 °C. The measured oxidation rates for arsenic sulfide solids by dissolved oxygen are in the range of 10-11 to 10-10 mole m-2s-1 after being normalized to final surface area. The order of arsenic sulfide oxidation rates decreases at pH-2 from amorphous AsS > realgar > orpiment > amorphous As2S3. Compared to pyrite, arsenic sulfide oxidation rates are approximately 1.5 to 15 times slower than pyrite oxidation rates at pH-2.

Jan 1, 2003

By R. N. Tempel, M. Lengke

Arsenic sulfide [orpiment, realgar, amorphous AsS and As2S3] oxidation rates were measured in mixed flow reactors at pH~2 and temperature of 25-30oC. The measured oxidation rates for arsenic sulfide solids by dissolved oxygen are in the range of 10-11 to 10-10 mole m-2 s-1 after being normalized to final surface area. The order of arsenic sulfide oxidation rates decreases at pH~2 from amorphous AsS > realgar > orpiment > amorphous As2S3. In comparison to pyrite, arsenic sulfide oxidation rates are approximately 1.5 to 15 times slower than pyrite oxidation rates at pH~2.

Jan 1, 2002

By James Elton

THIS paper covers, besides laboratory work, a study of actual operation at the Washoe Smelter over a considerable period of time, together with the results of a visit to the Midvale plant of the United States Smelting- & Refining Co., near Salt Lake. For the latter privilege, as well as permission to publish the resulting data herein given, I am indebted to George W. Heintz, General Manager of the Midvale plant, and here take pleasure in. expressing my appreciation for the many courtesies extended to me by Mr. Heintz and members of the technical staff at the smelter. Almost all of the world&apos;s supply of arsenic is recovered as a by-product in the smelting of other metals. It is seen on the market in various forms, the most common being arsenic trioxide, the ? white arsenic " of commerce, which is sold as a heavy white powder, or in white, glassy, translucent masses. The trioxide is used in the manufacture of pigment, glass, and insecticides. About 50 per cent. of the domestic consumption is supplied by imports.

Jan 8, 1913

By R. Padilla

A thermogravimetric study has been conducted to follow the decomposition and volatilization of arsenic from enargite concentrate in nitrogen and slightly oxidizing atmospheres. Temperature has a large effect on the rate of volatilization of arsenic. Fractional volatilization of arsenic as high as 98% were obtained in less than 60 min at 650°C in nitrogen atmosphere, while in slightly oxidizing atmosphere the same volatilization could be achieved in 30 min. It was found that arsenic volatilizes as sulfide in nitrogen atmosphere and as 4xture of sulfide and oxide in atmospheres containing 1% oxygen. By using the pore blocking and the first order kinetic models, apparent activation energies of 213 and 200 kJ/mol for the temperature range of 780 - 900 K and 205 and 184 kJ/mol for the temperature range of 900 - 985 K were determined for enargite and copper concentrate, respectively.

Jan 1, 1997

By Harold Roast

THE object of this investigation was to compare the arsenical antimony-lead alloy with some of the regular bearing-metal alloys. With this end in view, the following tests were made: 1. Chemical analyses to show the composition. 2. Thermal analyses. 3. Macroscopic examination of fractures. 4. Microscopic examination. 5. Tensile tests. 6. Crushing tests. 7. Scleroscope tests. 8. Brinell tests, at temperatures from 80° to 400° F. Tests 3 to 8 were conducted on both sand-cast and chill-cast specimens. For the purposes of this paper the alloys have been numbered from 1 to 6; their composition is as follows: LEAD, ANTIMONY, TIN, COPPER, ARSENIC, NUMBER PER CENT. PER CENT. PER CENT. PER CENT. PER CENT. 1 82.64 12.95 4.40 0.01 none 2 27.54 9.94 59.87 2.65 none 3 77.65 20.75 none 0.13 1.47 4 82.95 16.85 none 0.20 none 5 83.78 15.35 none 0.05 0.82 6 0.15 7.87 84.13 7.85 none The analysis, in the case of the antimony, was made by solution in sulfuric acid and titrated with permanganate. For tin, the ferric-chloride method was used; for copper, the alkaline separations, and the thiocyanate methods; for arsenic, volatilization of arsenic and titration with iodine. The lead, with the exception of alloy 6, was taken by difference.

Jan 2, 1922

By W. Hopkin

INTRODUCTION Necessary science and technology are not well established for the design of responsible treatment and disposal of arsenical residues from refractory gold ores. Specifically, there is uncertainty about the precise composition and behaviour of oxidised arsenic species in these wastes, and an analysis of possible chemical behaviour suggests that potentially difficult control and disposal problems remain to be so 1 ved. In tackling these the undoubted toxicity of arsenic in excess and its bad press should not blind one to the realities of actual behaviour in the environment, and that some adverse behaviour inevitably has to be to 1 erated as a cost in return for the recovery of an operation's gold for society. The problem is to minimise any such cost. Each refractory ore will be different. Many will contain so little arsenic that it will cause only trivial problems in disposal, but there remain others with significant arsenic content, say in the order of 1% or more, to cause concern. As already implied, concern can be over emphasised but equally underestimated. The balance which must be struck in the design of responsible disposal in the widest sense requires objective and practical assessment of a complex range of chemical, biochemical, engineering and economic design factors, all of which should involve the process design team in constructive dialogue with the 1 oca l regulatory authorities. In British terms, the general objective should be the Best Practicable Environmental Option. Arsenic is ubiquitous in waters, rocks and soils and all living things. Its compounds undergo natural geochemical and bi ochemi cal cycles including powerful adsorption and precipitation processes which return to nature all leakage from the inevitable disturbance of mining and extraction operations. Within limits, all life is tolerant to its presence, and adaptation and detoxication processes occur to deal with local excesses.

Jan 1, 1991

By Michael S. Moats, Addin Pranowo, Gerardo R. F. Alvear F., Nigel Aslin

The toxicity of arsenic is well known and documented. However, the presence of arsenic in copper electrorefining anodes and electrolyte is critically necessary to produce high quality cathode. Arsenic as well as antimony and bismuth concentrations vary depending on their relative concentration in the anode copper received from the smelter. This paper will discuss the behaviour and benefits of arsenic in copper electrorefining and the detrimental effects of antimony and bismuth on cathode quality and tankhouse performance. This will include the minimization and mitigation of problems associated with arsenic, antimony and bismuth including cathode contamination, floating slimes, scaling and anode passivation.

Jan 1, 2014

By Morris Beattie

Arseno Processing Ltd. has developed process technology for the extraction of gold from refractory ores and concentrates. These ores, which do not respond to conventional extraction processes, are rapidly becoming the primary targets for mining companies wishing to become significant gold producers. It has recently been estimated that by the mid 1990's, the annual gold production from the Pacific Basin Epithermal Arc in southeast Asia could be as high as 550 tonnes. Within this area the Porgera deposit under development by Placer, Renison and MIM, and the Lihir Island deposit under development by Kennecott have been shown to be refractory and require pretreatment before the gold can be extracted. The additional deposits which are now starting to be developed in this area are also expected to require such pretreatment. The Arseno process promises to be an economical pretreatment for these ores and to result in the maximum achievable gold recovery. Numerous refractory deposits are also known in Australia, North America, China and other parts of the world. Samples from many deposits throughout the world have been tested using the Arseno process conditions and the consistently successful results have demonstrated its widespread application. The samples which have been tested include ores in which the gold is locked in pyrite, marcasite or arsenopyrite. The process is insensitive to the sulphur content of the feed. Feed materials containing from 1 % to 50% sulphur have been tested successfully with the process. In the Arseno refractory gold process, sulphide minerals are dissolved so that the contained gold becomes accessible for subs7qu7nt gold recovery. This gold recovery is achieved by cyamdat1on of the process residue. For many of the materials which have been tested, gold extractions in excess of 95% have been achieved.

Jan 1, 1998

By E. H. Hall

"Perhaps .I should start this talk on Arsine poisoning, by giving a brief background and history of the Bralorne Mill.The present Bralorne company started milling operations in 1932, with amalgamation and flotation, and operated continuously until 19 61 . In 19 59, it was decided to change over to cyanidation, and to use double filtration rather than counter current. The cyanide portion of this new plant was completed and went on stream in August 1961 utilizing the grinding circuit of the old flotation plant. The new grinding circuit was completed and started operating December 15, 1961.The grinding circuit consists of a 7 1 x 101 Hardinge Rod Mill, and a 7 1 x 101 Hardinge Ball Mill. In series with the rod mill is a 16"" x 24"" Denver Duplex Jig, and two of these jigs are also in parallel with the ball mill. The rod mill product is classified by a Kreb cyclone, the oversize going to the ball mill. The ball mill is in closed circuit with this same cyclone. The jig products are amalgamated daily, and the amalgam barrel tails are returned to the ball mill for regrind. Arsenious oxide (As203) is one of the reagents used in amalgamation. Approximately 39 ozs. per day is used.The cyanide circuit consists of a 481 x 121 thickener, three 24' x 24' agitators, two 141 x 161 drum filters and a Merrill Crowe precipitation unit.The Krebcone overflow is thickened to 60 - 62% solids. Hydrated lime, along with a settling agent is added to the thickener. Some of the overflow water from the thickener is returned for use in the jigs. The balance of this overflow water goes to waste. To the thickened pulp entering No. 1 agitator, barren solution is added, along with sodium cyanide and hydrated lime. Cyanide strength is held at 0. 9 - 1. 0 lbs/ ton solution and lime at 0. 8 lbs/ ton solution. The lime content usually drops to 0. 5 lbs/ ton in No. 3 agitator. The two drum filters are in series and are washed with barren solution. The discharge of No. 3 agitator is fed to No. 1 filter and the discharge of No. 1 filter is repulped in barren solution and feeds No. 2 filter. No. 2 filter discharges to tails, The filtrate is clarified, deaerated and the gold precipitated. One hundred to two hundred tons of barren solution are bled to waste each day. The ore contains 1 % Arsenopyrite and 1. 5% Pyrite."

Jan 1, 1964

By A. Majumdar, B. Servière, H. Persson

The CCR refinery, which was built in 1931, treats both internal and third party copper anodes to produce 325,000 mt of copper as cathodes. These anodes contain high levels of impurities, such as Ni, As, Sb and Bi, that reports to the electrolyte during the refining step and need to be removed in order to maintain cathode quality and operating efficiencies. In the purification plant, the electrolyte is de-copperized via electrowinning in three stages. In the last stage, the copper content of the electrolyte is reduced to below 1 gpl in order to maximize the co-deposition of As, Sb and Bi with the Cu. This is accomplished with minimum arsine gas generation by using periodic reversal of the current and by controlling the final copper content of the electrolyte. Nevertheless, the possibility of exposure to arsine is treated as a major risk and controls have been implemented to reduce this risk. This paper describes the controls in place at the purification plant, which are being continuously improved through periodic risk assessments and audits. INTRODUCTION The CCR Refinery, which is a part of Glencore Canada Corporation and located in Montreal-East, Quebec, is a custom copper and precious metal refinery, with a capacity to refine 325,000 tonnes of copper anodes per year. Copper anodes are received from the Horne smelter in Rouyn-Noranda, Quebec, Altonorte smelter in Chile and other 3rd party smelters. CCR anodes are produced using the spent anodes from the tankhouse along with purchased spent anodes and copper scrap. The precious metal plant treats the tankhouse anode slime, purchased anode slime, precious metal ingots and Doré anodes from Glencore’s Brunswick lead smelter in Belledune, New Brunswick. CCR products include copper cathodes, silver and gold bullion, a platinum-palladium concentrate, selenium, tellurium dioxide and nickel sulfate. In 1975 an accident occurred at CCR where two employees were exposed to fatal levels of arsine emitted from the then existing purification cells. This process was therefore shut down immediately. Research and development work was then initiated to determine the optimum electrowinning conditions whereby arsine gas generation would be minimized while maintaining high copper and impurity removal efficiencies. It was found that the application of periodic reversal of current (PRC) during the last stage of electrowinning retarded the onset of arsine formation while at the same time allowing the copper concentration to be reduced to less than 1 gpl (Houlachi & Claessens, 1978). A new purification plant was designed based on the PRC technology and was started up in 1976. In addition to the use of PRC electrowinning, the new plant is located in a fully enclosed section of the tankhouse. A special effort was made to design a ventilation system to evacuate the acid mist in addition to any arsine gas. Arsine monitors were installed to measure the emissions from the stack along with arsine levels in the workroom. The arsine monitors and the ventilation system were interlocked with the rectifiers (Thiriar et al., 1983).

Jan 1, 2019

Let’s start off with your assessment of the mining industry. Today, the status of the mining industry is stronger than it has been over the previous few years. While mining continues to be a major part of the world’s economic foundation, the industry is gaining strength due to rebounding metals and minerals prices. And now, with these rising prices and the changes the industry instituted during the years when mining-related commodities were selling at low prices, our stronger, more productive and internationally competitive industry should flourish. Mining remains an essential business and the industry is far ahead of the game when it comes to the trend of globalization as a key to sustained growth. Also, the industry continues to realize increased productivity through technological innovations. And an increasing number of countries are moving towards capitalism, which opens doors for exploration and mining within their borders. After looking at all of these factors, I believe that the mining industry will only continue to gain momentum in the future.

Jan 1, 2004