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By Donald Markle

ANTHRACOAL is a mixture of small particles of anthracite coal and a matrix of practically pure carbon, formed from the distillation of coal-tar pitch or other suitable bitumen. It is a hard, dense, homogeneous mass, with a silvery luster and in color varies from silvery to grayish black. When pushed from the oven, it develops only partly the fingerlike structure of coke; but, unlike coke, it has a tendency to remain in blocky masses. When struck with a hammer or passed through crushing rolls, it breaks with an irregular fracture, similar to anthracite, but with very little fines. Due to its density, anthracoal is harder, tougher, and stronger than coke. The results of a test made by the blast-furnace department, of the Bethlehem Steel Co., on two barrels of anthracoal are given in Table 1. TABLE I.-Results of Shatter Tests on Anthracoal and Coke Anthracoal Test Good Blast-furnace Coke First Second Barrel Barrel Moisture, per cent 0.77 0.76 Under 5, variation not over 3 points Sieve test Through 2-in. screen, per cent 7.71 7.29 Under 40 Through 1-in. screen, per cent 1.37 1.56 Through ½ -in. screen, percent 0.93 1.08 Under 8 Over 2-in. screen, per cent 92.29 92.71 Over 60 Shatter test Through 2-in. screen, per cent 10.06 ' 12.40 1 Under 16 Through 1-in. screen, per cent 2.66 2.06 Through ½ -in. screen, per cent 1.80 1.26 Over 2-in. screen, per cent Hardness number 86.40 86.10 Over 81 Analysis Ash, percent 16.64 16.48 Under 11 Sulfur, per cent 1.17 1.10 Under 0.95 Volatile matter, per cent 0.77 0.27 Fixed carbon, percent 82.59 83.25 Over 87

Jan 8, 1921

By G. Geremia, M. I. Serrano, L. Costa, Strohaecker

The advances in electronics and the development of more efficient algorithms, allow for the designing of more complex and sophisticated automated systems. The new devices include lighter, faster, reliable, and stronger robot manipulators. One available technology, with relatively low cost, is a simple robot manipulator controlled by remote control. The device has been designed to be used in both mining and law enforcement, where it can be useful for inspection, rescue, gas analysis, and even to manipulate dangerous objects, such as explosives. The applications may even include the rescue of trapped miners in risky environments. The major advantage is the fact that the robot can be controlled with a remote and monitored through a video camera, minimizing human exposure to hazardous areas, where robots can perform tasks in an aggressive atmosphere and confined spaces. This article presents a mining robot manipulator controlled by remote control, using video cameras for positioning and sensors for movements, which are located on the operator's arm. With this system, it is possible to create a sensation of virtual reality, allowing easy operation for anyone trained in dealing with explosives, rescues, or other dangerous tasks. Blasting and mining are becoming perfect applications for robots, and its use should increase very soon. The results are discussed and presented for the brand new Xiru 01 robot manipulator.

Jan 1, 2010

By S. A. Sanderson

The last two decades have witnessed the resurgence in popularity of a century old tool for shaping laws and public policy – the ballot initiative. In recent years, anti-mining special interests have used the initiative process to secure voter approval of measures to ban modern surface mining for gold and silver. In November 1998, voters in Montana approved such a measure1 – the effects of which have been devastating to the mining industry in that state. In November 1999, anti-mining groups sought to place a nearly identical provision on the general election ballot in Colorado. They did not succeed, but the battle over mining’s future continues in the most important forum of all – the court of public opinion. The Colorado measure failed, in large part, because its proponents failed to convey a positive environmental theme. The mining industry also exercised early-on the rights available under state law for administrative and judicial review of the initiative, instead of relying upon the limited relief that would have been available had it waited until after the secretary of state approved the measure for the November election ballot. This article will summarize the ballot initiative process in Colorado and the proceedings that took place over Initiative No. 215.

Jan 1, 2001

By Osamu Yamamoto

In antibacterial evaluation of carbon-ceramic composites, we prepared two type composites with emphasis on carbon-ZnO system; one was porous carbon materials containing ZnO nano-particles and another was porous ZnO coated with carbon thin film. Porous carbon samples containing ZnO at highly dispersed state were prepared by carbonizing the resin exchanged by Zn2+ ion. Porous ZnO coated with carbon thin film was obtained by the pyrolysis of poly (vinyl alcohol). Antibacterial activity of these composites obtained was evaluated by measuring the changes in electrical conductivity with bacteria growth. The antibacterial activity on the composites increased with the increase of t he amount of ZnO in composite and decreased with the increase of carbonization temperature. The antibacterial activity for Staphylococcus aureuswas found to be stronger than that for Escherichia coli. No activity of the carbon samples without ZnO was observed. The occurrence of antibacterial activity was supposed to be due to the generation of hydrogen peroxide from ZnO in composite. In the present work, antibacterial activity of carbon-ZnO composites was studied in the details.

Jan 1, 2006

By Cz. Mazanek

Specific biostimulating and anticancerous properties have been observed in peat, Ash Vacanta, and in an amorpous silica that is obtained as a by-product of alumina production from Turow clay in Poland. The anmphous silica was characterized and found to have a large specific surface area. This property may account for the beneficial characteristics of the material.

Jan 1, 1989

By Ronald E. Heuer, Debra L. Virgens

INTRODUCTION Behavior of clay soils in response to tunneling is reasonably well understood by reference to the tunnel stability factor NT = Pz/su (Peck, 1969; Heuer, 1974). With this analysis tool, care must be taken to use a value of clay shear strength which represents the actual mass strength, considering such factors as slickensided fissures often found in stiff and hard clays. Behavior of clean sand and gravel soils is also reasonably well understood. Above the water table these soils must be assumed to act as running ground unless they are known to have significant cementation or have a very dense and angular interlocked grain structure. Below the water table they must be tunneled using some form of groundwater control such as dewatering, grouting, freezing, or internal fluid pressure in the tunnel such as compressed air or a slurry tunneling machine. The internal fluid pressure must approximately balance the external water head. Without such precautions these soils behave as flowing ground and may yield large volumes of water flow into the tunnel. A wide range of very fine sand, silty sand, cohesionless silt, and clayey sand soils exist in nature in a variety of geologic environments. The behavior of these soils in response to tunneling, and guidelines for anticipating their behavior, are not well described in the literature. Because of their content of fine particles, these materials may behave as if they initially have appreciable cohesion and moderate to low permeability. They may exhibit significant standup time, and require tunnel internal fluid pressure (compressed air or slurry pressure) less than the full external water head. It is important to be able to estimate the behavior of these soils when planning construction methods. For example, if the external water pressure is 140 kPa (20 psi), but soil stability at the tunnel face can be achieved as a compressed air pressure of 80 kPa (12 psi), a large cost savings may result.

Jan 1, 1987

By D. B. Desai, J. T. Waggoner, J. S. Hill, R. R. Redd, S. J. Klein

The 13 km (8 mile) long Riverside Badlands Tunnel is planned for construction starting in 1998. Extensive geotechnical investigations indicate that the 3.7 m (12 ft) finished diameter tunnel will be excavated through soft ground, weak sedimentary rocks, and heavily fractured metamorphic rocks. Nearly 80 percent of the tunnel will be excavated beneath the groundwater level. Tunneling conditions are expected to range from raveling and over-stressed in the sedimentary rocks, to blocky and seamy/crushed with some squeezing in the metamorphic rocks. Two alluvium reaches will require dewatering. The variable and interspersed ground conditions are expected to be a key factor in selection of tunneling methods, equipment, and initial support.

Jan 1, 1997

Prevent collisions between large mine-haulage trucks and smaller vehicles parked in areas not visible to the haulage-truck operator, Approach Two electronic systems were developed to detect the presence of vehicles in the blind areas of a parked haulage truck. The systems can warn haulage truck operators of presence of vehicles that are blocked from view. The systems do not apply for trucks in travel. How It Works The systems use electronic transmitting techniques-one system is based on low-frequency radio waves and the other on very-high-frequency radio waves. Each system requires that a signal transmitter be mounted on the smaller vehicle to be detected. Continuous signals from this transmitter are sensed by receiving antennas mounted on the right front and rear of the large haulage truck. Upon receiving a signal, the receiver energizes warning lights and a buzzer in the cab of the haulage truck, alerting the operator to a possible collision hazard. Detection distance is adjustable, depending upon the size of the haulage truck, but a minimum of 30 feet was the design goal.

Jan 1, 1990

By Katerina Kryst

Antimony and bismuth are two of the elements that need to be removed from copper electrolyte to ensure a trouble free operation as well as to maintain copper cathode purity. One method to control these impurities is the use of aminophosphonic ion exchange resins. Antimony is present as both Sb(III) and Sb (V). Sb(V) is very difficult to remove from these resins, requiring excess amounts of highly concentrated hydrochloric acid. In industry this affinity of Sb(V) for the resin causes a buildup of Sb(V) and degrading resin performance due to continual reduction of resin capacity. A new method for regeneration of aminophosphonic resins loaded with Sb(V) has been developed, which utilizes catalytic regeneration of the resin. Ion exchange can then be utilized for continual control of Sb and Bi in copper electrolyte.

Low tonnage quartz vein-hosted stibnite lodes are widely distributed in rocks of the Tasman Fold Belt System in eastern Queensland, with particular concentrations in the Hodgkinson - Broken River Fold Belt and to a lesser extent in the Gympie Province of the New England Fold Belt: Higher grade deposits have been worked intermittently on a small scale since 1873, resulting in the production of about 5500 tonnes of antimony ore/concentrate with an estimated grade of about 55% Sb. Future production of antimony may be as a by-product from deposits, currently being explored/mined for gold in the Hodgkinson/Mitchell River area and the Amanda Bel goldfield. Establishment of an antimony processing plant in Queensland using the Quelar Process would provide a more reliable market for small producers and could stimulate future exploration and production.

Jan 1, 1990

By D. H. C. Griffiths, D. R. Davis, D. B. Paterson

Consolidated Murchison Limited is the only primary producer of antimony in South Africa, producing approximately 18 per cent of the total world production. This paper gives a technical review of the history, occurrence, mining, and metallurgy of antimony at Consolidated Murchison. World antimony markets are also discussed, together with the end-uses.

Jan 1, 1986

By B. St. Pierre

"The alchemists' symbol for antimony is a diamond with a dot in the centre. The latin name ''stibium'' gives this mineral its chemical symbol ""Sb"" and the name to the principal ore containing antimony. This is Stibnite, a sulphide of antimony, and the valuable mineral at the Consolidated Durham operations. Stibnite chemically pure contains 71.69% antimony metal.Antimony is used in many forms, as an alloy in the production of metal products and as chemical compounds of oxides and sulphides. In Biblical times, antimony was used as a medicine and as eyebrow makeup.Today, the largest single use of the metal is as a hardener and strengthener of lead, and corrosion inhibitor in storage batteries. New applications for antimony in its oxide form as fire retardants are broadening the overall demand especially in the chemical, plastic and fabric industries. Other users include the Military for such things as tracer bullets, shrapnel, smoke screens and flame throwers. An unusual property of the metal is that it contracts when heated which has made it a valuable alloying metal in the printing industry, for heat shields on re-entry vehicles used in the space programmes, and also for the manufacture of bearings."

Jan 1, 1977

By E. A. Román

An ion exchange pilot plant, provided by Mesco Inc., was tested for antimony control in the electrolyte at three Chilean tankhouses for copper electrorefining: Chuquicamata, Potrerillos and Enami -Ventanas. The pilot plant, with a nominal extraction capacity of 1.2 kg Sb/day, worked connected to both experimental and commercial circuits, performing a total of 310 loading and elution cycles. An innovation in this process is the use of a chelating organic elution reagent, which presents some advantages over the traditional 6N HCI. This new eluent is amenable to continuous regeneration and recycling with high recovery efficiency. Antimony removal starting at initial, concentrations of 0.5 to 0.6 g/l of Sb down to steady concentrations of 0.1 to 0.0.6 g/l Sb, resulted in the production of High Grade copper cathodes with Sb contents below 0.1 ppm. Anodic slimes showed Sb contents below 1%.

Jan 1, 1999

By M. L. Leblanc, J. F. Burzynski, D. J. Mossman

A strong heterogeneity in the distribution of Sb+/-Au deposits exists within the North Atlantic Acadian-Hercynian domain. This is reflected in the regional disparity in Sb production among the various producing countries. This work focuses on the nature and distribution of Sb+/-Au occurrences in the Acadian-Hercynian domain. A summary listing of the general features of Sb-Au deposits found in this area is given

Dec 1, 1991

By C. S. Simons

Manufacturers of filtering, thickening or clarifying equipment, have been active in developing machines to meet increasingly rigid operator requirements, and the innovations resulting from this effort are moving into commercial applications. In general, the results of these applications are reported to be good. Little has been reported on progress in theory. The growing insistence on the part of pollution control agencies that waste water discharged into streams contain less and less suspended solids is being felt by a broad cross section of industry. A new clarifier, based on the often rediscovered fact that suspended solids settle more rapidly in inclined channels, is being marketed by Neptune MicroFLOC of Corvallis, Ore. This unit employs modules of inclined tubes, mounted in the upper zone of the clarifier, which carry the water flow. These were developed for light solids, such as those encountered in domestic water treatment and in paper mill waste water. In these applications, flow rates up to about three times those permissible in conventional clarifiers are reported to give comparable overflow turbidity. By combining these units with mixed media filters, high clarity may be obtained with minimum capital. Use of such units in the metallurgical industry, particularly where water reuse or effluent quality is important, should grow.

Jan 1, 1970

By Zhihao Yue, Honglie Shen, Yahui Teng, Ye Jiang

"In this paper, manganous nitrate [Mn(NO3)z] was used to assist the etching of silicon wafer in hydrofluoric acid (HF) for the antireflective application, and alumina (Al2O3) layer was deposited on the surface of the etched sample by atomic layer deposition method for further antireflection. The surface morphological and compositional studies of these samples were performed by scanning electron microscopy attached with an energy-dispersive X-ray spectrometer. The surface reflectance measurements were carried out using UV-Vis-NIR spectrophotometer. Binary structures of pyramids and nanopores were obtained by etching the alkaline textured monocrystalline silicon wafer in HF and Mn(NO3)z mixed solution for not more than 15 min. But excessive increase of etching time of up to 30 min resulted in the whole destruction of pyramids. The average reflectances of the 5-min-etched sample before and after being coated with 75-nm-thick Al2O3 layer are 4.62% and 3.47% in the range of 200-1000 nm, respectively.1. IntroductionAs we know, the reflectance of silicon wafer after being sliced is so high that the maximal photoelectric conversion efficiency of silicon based solar cells is limited. Therefore, alkaline texturization process was used for silicon solar cell in industrial production. But the reflectance of this alkaline textured wafer is still greater than 10% and this process can only be used for monocrystalline silicon solar cell."

Jan 1, 2013

By Brad Wells, Wayne Bull, Wayne Dickinson

"Antiscalants were evaluated for control of calcium carbonate (CaCO3) in gold processing applications. Under severely supersaturated conditions, 100 percent inhibition was achieved with 30 ppm antiscalant. Laboratory and field testing established that an antiscalant could both inhibit scale buildup and remove an estimated 0.5 kg/m2 per annum of pre-existing scale. A program was developed to control CaCO3 at a gold mill experiencing severe scale buildup. Annual accumulation of as much as 3 cm of scale in process piping was reduced to unmeasureable levels when 10 ppm antiscalant was applied. No scale-related upsets in mill operation occurred during a five-month trial period.INTRODUCTION Inorganic mineral scale is a crystalline deposit that forms when dissolved mineral constituents exceed the solubility of the respective mineral phase. Formation of mineral scale adversely affects a wide range of industries and is of particular interest in mining and metals processing. Scale affects numerous stages of metal extraction processes. Restricted flow in piping, nozzles, valves, screens, pumps and other components used to transport mineral slurries, metal concentrates, and tailings as well as scale in millwater and thickener overflow circuits are primary concerns (Alfano & Boffardi, 1994). Heap leaching, comminuation, flotation, vat leaching, carbon adsorption, and heat exchangers as well as oxidation steps used in processing sulfidic ores are among key unit operations that may be adversely affected (Simmons & Gathje, 2003). Antiscalant chemicals are designed to prevent formation and growth of mineral scales such as CaCO3. These chemicals, which include two primary classes – phosphonates and anionic carboxylate polymers and copolymers - are added to the gold processing stream at low parts-per-million (ppm) concentrations to interfere with nucleation and growth of scale forming crystals and to disperse fine particulate material. Application points may be located throughout the gold extraction process. Evaluation of the performance of antiscalants plays a critical role in determining the best product for a specific application. Performance evaluations include laboratory testing, pilot scale studies, in-plant trials, and ongoing performance monitoring during mill operation."

Jan 1, 2014

By W. H. Dickinson

The performance of seven antiscalants spanning a range of chemistries was evaluated for control of calcium carbonate (CaCO3) formation in gold processing applications. Three preferred chemistries were identified which provided up to 100 percent inhibition in static jar tests when applied at 30 ppm dosage. The three products were further evaluated using a model carbon extraction circuit developed for this application. The test circuit enabled direct measurement of calcium carbonate formed on the carbon from a supersaturated solution under dynamic conditions. The antiscalants lowered CaCO3 buildup on the columns by 15 - 26 percent compared to untreated controls. Impact of the antiscalants on the rate and extent of gold loading onto a carbon adsorbent was evaluated in laboratory carbon-in-pulp (CIP) studies. The antiscalants generated a 25 - 35% increase in gold loading at gold extraction efficiencies up to 65%. On-site testing at a gold processing facility demonstrated that 10 ppm of the preferred antiscalant was able to fully suppressCaCO3formation in thickener overflow water.

Feb 27, 2013

By James H. Nulty, Joseph S. Roti

INTRODUCTION During a recent panel discussion on the topic of millwater antiscalants, the question was posed: "What would you like to see in the future?" Answer: 'We need an antiscalant that: can be fed without a pump (no maintenance), functions on residual basis (no fault), can be tested for colorimetrically in sub-part-per- mi 11 ion concentrations (no guessing) and will recycle back to the mill from tailings (no cost).” Impossible? Based upon today's level of technology, such a product does not exist. However, a few of the qualifications listed above are certainly food for future thought. Meanwhile, progress is being made in upgrading three essential elements in this critical area of ore processing. They are: 1. Antiscalant reagent research and development. 2. On-line monitoring programs. 3. Reagent storage and feed systems. The objective of this paper is to out- line the current direction being taken in each of these areas and to present case histories as examples of how theory has been applied in field situations to better improve operations. LABORATORY SCREENING TESTS Recent technical papers have explained the various generic chemical raw materials which are available in the marketplace. While the merits of each chemical component are open to debate, the processes used by most major reagent suppliers to evaluate products in the laboratory are fairly standard. Common techniques incorporate both static and dynamic conditions in the search for the most cost effective product. Static Test Perhaps the most common test procedure used is based upon NACE Standard Test Method 03-74, which is "a laboratory screening test to determine the ability of scale inhibitors to prevent precipitation of calcium sulfate and calcium carbonate from solution." The objective of this test is to measure the change in calcium ion concentration in a container of saturated stock solution prepared from calcium chloride and sodium carbonate which is heated in a water bath. After 12 hours at constant temperature (160°), the mother liquor is pipetted into a beaker and a titrated for gm/l of unprecipitated calcium ion. A simultaneous test is performed on stock solution with antiscalant added. The results are then charted to determine the most effective antiscalant (with respect to preventing precipitation of calcite). It should be noted that this procedure examines only the ability of a chemical additive to retain calcite in a saturated solution where thermal stress is applied. This is commonly referred to as sequestration or stabilization. It has been documented that products which act in this manner (i.e., inorganic and organic phosphates) are good scale inhibitors. However, low molecular weight anionic polymers function in a much different manner by distorting calcite crystal size, shape and charge density, thus preventing scale formation. Because of this different mode of operation, static tests may not prove conclusive where polymers and sequestrants are being compared. The simplicity of this test makes it easily adaptable for field use, although modifications are often made.

Jan 1, 1986

By A. J. Chellew, Robert Condit

THE Company maintains a port agency at Antofagasta for dispatching copper and also for receiving from ocean vessels the vast variety of materials and supplies required at the plant. Copper shipments from the oxide plant refinery to Antofagasta amounted to 162,000 metric tons during 1951, while incoming freight totalled 175,000 metric tons. Electrolytic market copper in various shapes is currently loaded at the plant upon 20 or 30-ton cars of the meter-gage Antofagasta-Bolivia Railroad, to be transported a distance of 165 miles to the company's yard at Antofagasta. Here it is unloaded by cranes at the rate of about 175 tons per hr. Copper not scheduled for immediate shipment is stocked in tiers within the yard, but most of it is reloaded and sent to port works or a wharf serving lighters. Some of the vessels entering Antofagasta tie up at the port works, while others anchor inside the breakwater. In the latter case, all of the loading into the hatches is from 50-ton lighters towed to the vessel. When the vessel is at the dock, about half of the copper is loaded by port works cranes and the other half is loaded by ship's tackle from lighters. Fuel Oil Requirement Expands One of the innovations caused by the construction of the sulphide plant has been the necessity to provide facilities at Antofagasta for receiving and storing greater quantities of fuel oil than in recent years. From here it is loaded into tank cars for transportation to Chuquicamata. The older installation consisted of a 10-in. submarine pipe line, heating, and pumping facilities, a 67,500-bbl storage tank, and railroad loading rack, located at Antofagasta's northern limits. Two new tanks, of 80,000 and 30,000-bbl capacity respectively, have now been added and a second submarine pipe line will shortly be installed. Fuel oil requirements for the sulphide plant are estimated at 39,000 bbl per month, in addition to which 9000 bbl per month are required for the operation of the oxide plant. The company has a special lighter which is used by its diver for connecting the oil line with the oil tanker when disembarking oil, this lighter also being used for inspecting and overhauling buoys, as well as for recovery of bars of copper which are sometimes dropped into the bay when loading vessels during periods of rough weather. Transport of oil to Chuquicamata is by 76 tank cars of, 20-ton capacity and 20 of 30-ton capacity, all assigned to the company's fuel oil shipments excepting six for Diesel oil and one for gasoline. Incoming Freight Other freight received by the port agency has been averaging about 4800 metric tons per month of operating supplies for the oxide plant (renewals of equipment, spare parts, lubricating oils, and greases, etc.), some 1900 metric tons per month for the company stores, and about 6000 metric tons per month of materials and equipment for the construction of the sulphide plant. The greater part of these shipments (particularly the operating and construction supplies) originate from abroad, and must be handled through the Chilean Customs. Hence the company maintains a Customs storage warehouse (goods pending appraisal of Customs duties) in addition to its other storage facilities at Antofagasta. Not the least of the Port Agency's duties is to meet air and steamer passengers en route to Chuquicamata and to arrange for their trips up the hill. Landing in a strange country with a strange language, the first impressions of a new employee might otherwise be indeed confusing when facing Antofagasta's unique setting of brown barren hills.

Jan 1, 1952