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By David R. Macedon

"Through the years, a wide variety of dust control methods have been utilized at mineral processing operations. While some have been successful, many have been highly ineffective. Dust Control systems currently in use include baghouse systems, fog systems, surfactant spray systems, and foam dust suppression. While baghouse systems can be effective, they are capitalintensive and costly to operate and maintain. Chemical dust control programs can be very effective. However, if applied incorrectly, they can have detrimental effect on mineral recovery. Thus, many operations utilize a combination of baghouses and water, often with limited success.Recent advancements in surfactant and polymer chemistry have resulted in substantially improved chemical dust suppression programs. These products range from non-corrosive surfactant/humectant combinations for road dust control to foam-based systems for crushers and transfer points, to advanced polymers for pile binding and soil stabilization. These advances are discussed in detail, citing results from fieldwork in the precious and base metals industries.INTRODUCTIONThe global nature of the mineral processing industry presents a unique set of challenges. Traditional thinking would tell us what works in one place should work in another. This could not be further from the truth in the area of dust control. We learn very quickly that there are a number of factors that can affect the efficiency and success of a dust control program and that these factors are not all chemical or equipment related. Some of these factors include facility maintenance, product selection, water quality and characteristics, and economic considerations.What has been learned from past experience is that each mineral processing plant presents a unique set of factors that will affect the ability to create an optimal dust control program. This paper presents a myriad of treatment options that will highlight the advancements in chemical dust suppression products and equipment."

Jan 1, 2004

By M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterite ores typically extracts 95% of the nickel and 91% of the cobalt. Impurity elements in the feed, such as iron, aluminium and chromium, also dissolve and can be detrimental to downstream processes. Rejection of impurities within the autoclave is highly desirable. Aluminium and iron hydrolyze, and then precipitate in the autoclave leaving only small amounts that are subsequently removed by precipitation in a neutralization step. The concentration of dissolved chromium can range from 200 to 2000 ppm, depending on the feed composition. Chromium in the liquid phase, usually in the hexavalent state, introduces many problems and can limit refining options. For example, chromium poisons the organics in solvent extraction making SX an expensive option. Also, hexavalent chromium must be converted to the trivalent state before it can be precipitated along with iron and aluminium. Bench-scale work confirmed that mixing small amounts of carbon-base additives, such as coke, with the autoclave feed significantly reduced chromium concentration in the autoclave discharge without any detrimental effects on paymetals recoveries and selectivity.

Jan 1, 2004

By Laxman (Lucky) Amaratunga, Hisham Madi

Final disposal of mine wastewater neutralization sludge continues to be one of more pressing problems in the mining industry. The disposal of mining and metallurgical waste products into underground reduces the environment impact and improves the safety of the mining operation and the economics of the enterprise. This current research focuses on an investigation of utilization of mine wastewater neutralization sludge obtained from Kidd Creek Mine site, as a supplementary material for their proposed deep mine pastefill system. Their proposed pastefill consist of combination of rock aggregate in a matrix of imported sand and tailings with binder (Portland cement + Slag cement). Pastefill mixes containing various percentages of the waste sludge 0 (control mix), 1, 2, 3, and 5% by weight as replacement to the fine sand were prepared and tested with different percentages of binder. Hypothesis behind this approach is to study the behavior of sludge as replacement of sand in matrix as well as its ability to act as a binder. Compressive strength, percentage of sludge, binder dosage, slump, water to cement ratio, percentage of solid, and curing time are being observed. The results indicated that sludge can be incorporated into the pastefill and enhance its strength without compromising the pastefill quality and integrity.

Jan 1, 2004

By Kym Runge, Emmy Manlapig

"The objective of an industrial flotation circuit is to separate valuable minerals from non-valuable minerals utilising differences in their flotation recovery rate. Regrinding and reagent addition are particle modification processes which are employed within these circuits to maximise the flotation selectivity of one mineral with respect to the others present in the ore feeding the process.Batch test nodal analysis, or the ability to compare floatability through mathematical combination of laboratory batch flotation test results, is a powerful technique for assessing the effectiveness of particle modification processes on ore floatability in industrial flotation circuits.In this paper, the use of nodal analysis is demonstrated within an industrial flotation circuit. It is used to show that regrinding and staged reagent addition within Teck Cominco’s Red Dog zinc retreatment circuit is beneficial to pulp flotation selectivity. Optimisation of these processes could potentially improve the zinc recovery within the circuit. Lime addition, which is periodically employed to depress pyrite in the circuit, was found to depress sphalerite in preference to pyrite and to result in poorer metallurgical performance in the circuit.INTRODUCTIONThe objective of an industrial flotation circuit is to separate valuable minerals from non-valuable minerals utilising differences in their flotation recovery rate.Different minerals can only be effectively separated using flotation if they are sufficiently liberated from each other (i.e. do not co-exist within the same particles) and have a sufficient difference in surface hydrophobicity. Size reduction processes and chemical addition are utilised before and within a flotation circuit to achieve sufficient particle liberation and to maximise differences in mineral hydrophobicity. In effect, the objective of these processes is to maximise the flotation selectivity of one mineral with respect to the others present in the ore feeding the process."

Jan 1, 2004

By Christian Ottergren

"Modern crushers offer double the capacity and performance of classic models. In some cases crushers are replacing SAG circuits, the advantages being smaller investment and lower operating costs. Is Tertiary crushing replacing SAG milling as the most optimal grinding method? Does tertiary crushing achieve the same outcomes as SAG milling? This paper considers these questions and provides an assessment of the strengths of tertiary crushing in comparison to other methods. Two case studies: a Scandinavian Platinum Project, and CODELCO, are also presented.INTRODUCTIONResearch on basic parameters in crushing started at Chalmers University in 1993. The initial project has developed and now involves several related areas. Modelling in accordance with new theories has resulted in modified designs which have been implemented and shown improved performance at operating mines in Chile. Sandvik Rock Processing is a partner and a major supporter of this program. This paper will cover some of the achievements and give references to the research reports.The mining industry has for many years mainly used crushers of the traditional 7’crusher concept, with thread adjustment of the setting and with a spring or hydraulic overload system. This machine type has been the workhorse for crushing throughout the world. The explanation for the dominance of this machine is that it has a reliable mechanical design. It can be estimated that about 2000 crushers of this design are still at work.Technical development in all fields utilizes new technologies like high-strength materials, advanced control systems and more extensive use of hydraulics. This is the reason why today’s motorcars, for example, are more efficient, more reliable and more environmentally friendly than their predecessors in the 1950s. Crushers are no exception. This paper will cover experience from the latest-generation cone crushers developed by Sandvik Rock Processing.The parts in this paper related to the CODELCO ElTeniente copper mine in Chile are coauthored with responsible personnel from the operation at the mine."

Jan 1, 2004

By R. S. Bowman, G. S. Austin, J. M. Barker, P. S. Freeman

The physical, chemical and mineralogic characteristics of zeolites allow commercially important applications. While adoption of zeolite technology is slow in the United States compared to other regions of the world, continued testing and research has shown a wide range of uses for these minerals. They are important catalysts in petroleum refining, molecular sieves able to separate gases, and chemically inert carriers of reactants. The zeolite clinoptilolite produced by St. Cloud Mining Company (clino) (SC) is used in animal hygiene and animal feed, especially concentrated animal feeding operations (CAFOs), horticulture, water treatment, floor dry, aquariums, air and other filters, and odour control. Clino can remove cations from solution, and surface-modified zeolite (SMZ) is a sorbent for the removal of anions and neutral organics from water. Specific clino applications are: control of chemical pollution in groundwater, removal of organic compounds from oil field waters, and elimination of pathogens from sewage effluent. Combining the sorption capabilities of SMZ with chemical or biological transformations can yield complete removal of toxic materials from contaminated water. Continued development and marketing of zeolite products will be a growth market far into the future. The CAFO market for zeolites is the most significant growth area in the United States over the next few years. SMZ, currently less than 1% of St. Cloud sales, will continue to gain market penetration for many years.

Jan 1, 2004

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By J. Walker, G. E. Kim

Since May of 2000, Mogas Industries, in partnership with F.W. Gartner Thermal Spraying Co. and using the services of Perpetual Technologies, has invested time, energy, and resources towards developing novel ball valves for high-pressure acid-leach (HPAL) service. In addition to developing new valve designs, an aggressive coatings development effort has been undertaken to improve the protective quality of the coatings so as to enhance the performance and extend the life of valves in severe HPAL conditions. In 2001, Mogas Industries qualified and applied a nanostructured titanium oxide (n-TiO2) coating for gold and nickel/cobalt HPAL services. The n-TiO2 coating provided dramatically superior protection against abrasive and erosive wear, fared very well against high-pressure autoclave corrosion testing, and has performed well in HPAL service.

Jan 1, 2004

By W. Beres, Li. J.

The finite element method (FEM) has been applied to investigate the stress fields and deformation of a TiN/Ti-6A1-4V coating/substrate system subjected to nanoindentation. MSC Patran and MSC Marc were used to prepare the three-dimensional finite element models and to perform the simulations of the Vickers nanoindentation experiments. Pure silicon and TiN/Ti-6A1-4V coating/substrate system were analyzed. The properties of the materials were assumed to be homogeneous and isotropic with a linear hardening behavior. The reverse method was used to extract material properties, such as the yield stress and strain hardening coefficient, from the numerical results by comparing the simulated indentation load vs. penetration depth (P-h) curves with those obtained experimentally. Both non-linear elastic and non-linear elastic-plastic analyses were carried out for the coating/substrate system. The results are given for four different coating thicknesses.

Jan 1, 2004

By M. Rigaud, K. Sankaranarayanane, X. Zhou

The effect of varying fine alumina/ultra-fine alumina ratio on the Bingham to dilatancy transition in alumina based, self-flowing refractory castables has been studied in detail employing rheological tests and particle size distribution measurements. Analysis of flow resistance and torque viscosity values has shown that Bingham to dilatancy transition is strongly influenced by fine alumina/ultra-fine alumina ratio in the castable, as well as by the nature of ultra-fine alumina. The calculated values of rheological constants and the viscosity coefficient were found to increase at higher fine alumina/ultra-fine alumina ratios.

Jan 1, 2004

By L. Szecowka, M. Poskart, Siwka M. . J.

Oxides of nitrogen, created during combustion, are the most hazardous components of atmospheric pollution. However, it is possible to limit the negative influence of hazardous components on the natural environment. An experimental appartatus was built to determine the influence of the following "primary methods" on the reduction in concentration of NOx: air staging, reburning and flue gas recirculation. The influence of the simultaneous usage of the primary methods on reduction in NOx emissions was also examined. A significant increase in the efficiency of NOx reduction was achieved in two cases.

Jan 1, 2004

By S. G. Shabestari

Thermal analysis is a tool that is generally employed to predict the structure of the alloy before the actual casting is carried out. By cooling a sample of the molten alloy and recording the temperature-time curve, important solidification events may be analyzed by using the first derivative-cooling curve. In this research, strontium is added to (AS5U3G) 319 aluminum alloy and its influence on the formation of intermetallic compounds e.g. Al15(Mn,Fe)3Si2, Al2Cu, Al5Mg8Cu2Si6 formed during pre- and post-eutectic reaction have been investigated. Also any changes in solidification parameters such as temperature of Al-Si eutectic under cooling and temperatures of nucleation and growth of each phases caused by strontium addition, have been determined via the first derivative cooling curves. The effect of strontium on the formation of various intermetallic compounds has been studied by using very accurate thermal analysis equipment and the microstructures were analyzed using an optical microscope. The various phases reported in this paper were identified using Scanning Electron Microscopy (SEM) and linked to Energy Dispersive Spectroscopy (EDS). Formation of all pre- and post-eutectic phases was interpreted by comparing the phases formed in the microstructure and the reactions detected by using cooling curves. The results of this research indicate that thermal analysis technique can be used as an on-line process control in the production lines in aluminum casting industries.

Jan 1, 2004

By R. W. McConnell, R. P. Racher

High quality steel production requires extended treatment of the steel in the steel ladle. This has a remarkable impact on the steel ladle refractories, e.g. the need for high performance functional refractories like purging plugs. Operational changes such as increasing tapping temperatures, longer hold times and more aggressive secondary metallurgy are countered by the need for thinner refractory linings and longer refractories life. These combined factors have led to a resurgence in interest in magnesium aluminate spinel raw materials. Magnesium aluminate spinels have been used in steel-making refractories for many years, in a variety of different forms. This paper reviews the production, properties and performance of spinels. Recent developments in the applications of spinels will also be discussed.

Jan 1, 2004

By S. J. Buckler

Many metallurgical processes use submerged gas injection to increase the contact area between gas and liquid phases in order to promote faster overall reaction rates. The work presented in this paper is part of an experimental investigation to measure the gas-liquid interfacial area available in bubble plumes within molten metal baths. Measurements of the nitrogen absorption rate during submerged injection into molten iron baths have been used to estimate the interfacial areas of the bubble plumes. A theoretical model was used to predict the superficial nitrogen transfer rate under mixed liquid phase mass transfer -interfacial reaction control. The interfacial area was calculated by dividing the overall nitrogen absorption rate by the superficial rate. Reasonable agreement was obtained between the interfacial areas measured in our laboratory with data from a comparable system reported in the literature. The experimental results were compared with the predictions of three theoretical models and one empirical correlation. The models of Turkdogan (3) and Zhao and Themelis (5) gave the best agreement with our data.

Jan 1, 2004

By A. Yousefpour, M. Hojjati, M. Simard, M. Laramée, M-A. Octeau

The need for effective and reliable joining methods grows as the use of advanced thermoplastic composites becomes widespread in aerospace industry. An experimental investigation of resistance welding of APC-2/AS4 thermoplastic composite laminates is presented. In this method, a heating element is placed between the bond-surfaces then the interface is heated by passing electrical current through the heating element. The polymer at the weld interface is melted due to resistance heating, then diffuses and consolidates under applied pressure, resulting in a weld. APC-2/AS4 prepreg, APC-2/AS4 commingled, and different grades of metal mesh heating elements were considered. A custom made resistance welding rig was designed and developed to perform lap-shear welds. The mechanical performance of the welds was quantified using single lap shear tests. The effects of different heating elements on the mechanical performance of the resistance-welded parts were investigated. Also, quality of the welds was examined under optical microscopy.

Jan 1, 2004

By H. Ito, T. Takasu

A leaching process for recycling small car motor scraps dismantled from End- of - Life -Vehicles (ELV) was investigated using waste pickling acid in steel work. Steel parts of mortar scraps were leached by waste pickling acid and Cu wire was recovered as pure Cu in the process. Pickling acid solution after leaching could be recycled in an ordinary process for waste pickling acid solution. High grade FeSO4 agent could be produced using H2SO4 as a pickling solution.

Jan 1, 2004

By J. Qi

Based on the commercial steel 42CrMo (4140, SCM440), a new generation of CrMo steel was developed by increasing the content of Mo, adding the alloy element of V and Nb, and decreasing the content of P and S. This new CrMo steel has higher strength of 1500MPa and better delayed failure property. TEM and EDS were used to study the distribution and function of the alloying elements in this steel. A new EELS technique was developed to study the bonding strength of the grain boundary in the steel. The mechanism of strengthening of the new steel has been studied.

Jan 1, 2004

By D. L. Chen, Q. Zhang

The effect of particle sizes on the low cycle fatigue (LCF) life of discontinuously reinforced metal matrix composites (DR-MMCs) has been widely studied. However, how the particle size affects the LCF life of DR-MMCs quantitatively is still lacking. The aim of this investigation is, therefore, to present an analytical model linking the LCF life to the particle size. This model, based on the enhanced dislocation density in the matrix and the load bearing effect of particles, showed that a decreasing particle size results in a longer LCF life, and the results predicted are in good agreement with the experimental data.

Jan 1, 2004

By S. P. Cashin, D. Kashuba, W. Esplin

Barrick has had 6 autoclaves in operation at the Goldstrike Mine, North of Carlin Nevada, since 1993. The 6 autoclaves operate in parallel, processing slurry of gold ore. The gold in the ore is predominantly associated with, and encapsulated by, sulphide minerals. It is necessary to oxidize at least 90% of the sulphide mineral before the gold can be concentrated using a cyanide/carbon-in-leach (CIL) circuit. Sulphide oxidation chemical reactions occurring in the autoclaves are exothermic; however, the sulphide content in the ore is not high enough to operate the autoclaves in an auto-thermal mode. Heat from steam is added to the first 2 of 5 autoclave compartments to initiate the sulphide oxidation reactions. The steam used to heat the autoclaves is supplied by three boilers, which are fuelled with propane gas. The completion of a few operations and maintenance projects in the last 2 years has resulted in a 50% reduction in propane energy requirements. The autoclave operating temperatures were minimized. Excess oxygen addition was held as low as possible. The material of construction for the compartment walls inside the autoclaves was changed from brick to Titanium metal. And, the speed of the autoclave slurry agitators was increased. All of these activities had an impact on the propane energy requirements of the autoclaves. Presented below is a description of the autoclave systems, and a discussion of how the energy needs were reduced, resulting in significant operating cost savings.

Jan 1, 2004

By G. Bellefleur, K. Stevens, E. Adam, D. Synder, G. Perron, C. Müller

The Downhole Seismic Imaging consortium was initiated by the Geological Survey of Canada and three Canadian mining companies to assess the usefulness of borehole seismic techniques for the exploration of massive sulphide deposits within areas of steeply dipping stratigraphy. Field tests were conducted over two sub-economic massive sulphide deposits located in Norman West, Ontario, and Halfmile Lake, New Brunswick, using various shot configurations and a three-component borehole receiver array. The Norman West deposit, or structures associated with the deposit, produce detectable seismic reflections as far away as 1500 m. However, these reflections are difficult to distinguish from fault reflections and lithological contacts near the base of the Sudbury Igneous Complex. At Halfmile Lake, the rock properties are favourable for direct orebody detection. The Halfmile Lake deposit has a clear but relatively complex seismic signature on the downhole data, showing not only P-wave reflections, but also strong reflected S-waves and modeconverted waves. Such prominent S-waves and converted waves have not been recognized previously in borehole or surface seismic data acquired over massive sulphide deposits. These waves add complexity to the interpretation but provide additional imaging capabilities. Reflected S-waves and converted waves should be considered when designing seismic surveys for mineral exploration.

Jan 1, 2004