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By G. Thodos, R. B. Grieves

A method has been developed For predicting the critical temperatures and critical pressures of binary mixtures of carbon dioxide, hydrogen sulfide, nitrogen, hydrogen, carbon monoxide and oxygen with the normal paraffin hydrocarbons. For carbon-dioxide and hydrogen-sulfide systems, relations are presented that take into account the peculiar behavior of mixtures with closely boiling components, such as carbon dioxide-ethane and hydrogen sulfide-propane mixtures which exhibit minimum critical temperature points. For hydrogen, nitrogen and carbon-monoxide systems, the extreme critical behavior caused by wide differences in pure component properties is established In addition, those fixed gas-paraffin systems which resemble paraffin-paraffin systems are also accounted for. For a mixture of known composition, the pure component critical temperatures, critical pressures and normal boiling points are all that are required to determine its critical point. Graphical relations are presented relating Tc and PC , of the mixture to the pure component properties. From the treatment of 12 carbon-dioxide and hydrogen-sulfide systems reported in the literature (74 mixtures), the expected error lor the critical temperature is approximately 1.5 per cent, and for the critical pressure, approximately 2 per cent. From the treatment of six hydrogen, nitrogen and carbon-monoxide systems reported in the literature (30 mixtures), the expected error for both the critical temperature and critical pressure is approximately 2.5 per cent. The relationships, which have been developed with only normal paraffins as the hydrocarbon components, may be extended to those isoparaffins and olefins which fall within the allowable volatility ranges. INTRODUCTION Many of the fixed gases — carbon dioxide, hydrogen sulfide, nitrogen, hydrogen, carbon monoxide and oxygen — occur in natural mixtures with hydrocarbons. Carbon dioxide and hydrogen sulfide are frequent components of the fluids produced from underground petroleum reservoirs. Nitrogen, carbon dioxide and hydrogen sulfide are present in varying quantities in most natural gases and gas-condensate well effluents. Hydrogen mixtures are of considerable interest in many phases of refining processes of petroleum. The determination of the critical temperatures and critical pressures of such mixtures is of value in vapor-liquid equilibrium studies, for the prediction of the characteristics of underground reservoirs, and for reduced-state correlations of PVT, transport and thermodynamic properties. The accurate estimation of the critical point for binary mixtures is an important initial step toward a complete analysis for the establishment of the critical temperatures and pressures of multi-component mixtures. Methods for predicting the critical temperatures and critical pressures of binary hydrocarbon systems have already been presented in the literature.8 It is possible to apply these existing methods to fixed gas-paraffin mixtures, but due to their unusual critical behavior, values calculated deviate considerably from experimental values. For systems containing trace quantities of the fixed gases, these methods are acceptable; however, for systems containing more than 5 mol per cent of the fixed gases, these utterly fail to produce reasonable critical values. Consequently, in this study a method has been developed for handling such binary mixtures over the entire composition range. CARBON-DIOXIDE AND HYDROGEN-SULFIDE SYSTEMS The critical behavior and the vapor pressure behavior of mixtures of carbon dioxide and hydrogen sulfide with paraffinic hydrocarbons may be quite similar or quite dissimilar to that of paraffin-paraffin mixtures, depending on the volatilities of the components involved. The critical temperature and normal boiling point of carbon dioxide are very close to the corresponding values for ethane, while its critical pressure is considerably higher than that of ethane. The normal boiling point of

By David C. Oyler, Hakan Gurgenli, Gregory M. Molinda

Historically, miners have known that roof rocks originally composed largely of mud were prone to slaking and deterioration when exposed to water and humidity. Mine Safety and Health Administration (MSHA) records show that roof falls are more prevalent in summer and late fall. Field data shows higher bolt loads and increased room convergence in summer months. Laboratory data shows that very high internal pressures can be generated by significant strain in clay-rich rocks. In summer months humidities ranging from 70-100% can cause rock strains up to 7%, and rock pressures of 14,000 psi, more than enough to break apart weak shales and fireclays. The National Institute for Occupational Safety and Health (NIOSH) conducted wet/dry immersion cycling of clay-rich rocks. Results show that the rocks most prone to moisture deterioration are fireclays, claystones, and sandy shales, all of which have disrupted bedding. Of the 7 mudrocks with a weatherability index above 40%, none showed consistent fissile bedding. Black shales were surprisingly resistant to wet/dry water immersion cycling. Generally, mixed rocks (stackrock), typically susceptible to horizontal stress, are more resistant to moisture-deterioration. Mine roof rocks tested with moisture sensitivity ratings above 50% (moisture sensitivity index ranges from 0-100 with 100 being the most sensitive) all came from mines which had roof skin problems and used supplemental support to prevent rock fall injuries. Some roof rocks showed lateral variability of moisture sensitivity values, suggesting the need for more samples in highly varying roof rocks. Swelling strains of mudrocks showed that almost all of the swelling occurred in the first 24 hours after immersion. The wet/dry immersion cycling test used provides an accurate, quick and inexpensive method for estimating the moisture sensitivity of mudrocks. With this information mine operators can begin to anticipate hazardous ground and prepare appropriate roof support.

By J. Phillip Mackey

A whole new group of non-ferrous pyrometallurgical processes with the ability to utilize tonnage oxygen and capture sulphur dioxide were developed and commercialized over the period 1940s–1980s. Many of these earlier process developments were undertaken with limited knowledge of the process chemistry and influence of key process variables; in many cases, piloting helped provide much new physico-chemical data, but gaps remained. The second generation versions of these technologies of today provide all the primary copper, nickel and lead produced worldwide by pyro-metallurgical smelting. Further, process development has continued and a new generation of copper and lead smelting technologies have also been developed in China since the 1990s. The older reverberatory and blast furnaces have been progressively replaced by the newer technologies—a good example being the introduction in 1992 of the copper IsaSmelt technology at the Mt. Isa smelter in Australia where the former fluid bed roaster and reverberatory furnaces were replaced by a single new smelting unit, together with an acid plant for sulphur dioxide collection. The development of these new technologies was made possible by investment in fundamental and applied research. The lesson for the future is, in order to sustain these improvements, continued investment in research and development capability is required—to do otherwise is to risk obsolescence and lack of competiveness in the world market. Dr. Peter Hayes at The University of Queensland is one of the many researchers and process engineers who have contributed to the fundamental understanding of metallurgical processes over this period of rapid change in technologies. The present paper briefly outlines some of the many contributions Peter Hayes has made to the understanding of kinetics, mechanisms and phase equilibria in metallurgical systems, and metallurgical process development.

An International Ferro-alloys Congress, arranged by the Ferro Alloy Producers' Association of South Africa, the South African Institute of Mining and Metallurgy, and the National Institute for Metallurgy, will be held in Johannesburg, South Africa, in April 1974. The technical programme, occupying five days, will cover the following topics in relation to all ferro-alloys: 1. Burden preparation, blending, pelletization, handling, reducing agents. 2. Electric smelting furnaces-design, operation, management,- smelting optimization, shop practice, refractories. 3. Mineralogy, reduction behaviour, smelting reactions, slags. 4. Automation, Pollution control. 5. Applications, trends in comsumption, trends in composition specifications. There will be no parallel sessions. Papers in the above topics are invited; review papers will also be welcome. Proposed titles and abstracts in not more than 200 words should be submitted before the 30th of November, 1972, to The Chairman, Programme Committee, INFACON 74, Private Bag 7, AUCKLAND PARK, South Africa. The abstracts will be considered during January 1973, and papers accepted for the Congress must be submitted in final form before the 31st of July, 1973. The proceedings of the Congress will be published as a special volume. There will be a series of post-Congress tours to ferroalloy plants and other places of both technical and scenic interest. A full ladies' programme will be arranged. The First Circular, giving further details, can be obtained from: The Secretary of the Organizing Committee, INFACON 74, Private Bag 7, AUCKLAND PARK, South Africa.

By Alexis Baca

La presente investigación busca optimizar la producción y la ventilación en la industria minera, utilizando el método de ratios de energía y producción. Para ello, hace la estimación del consumo de energía en ventilación, obteniendo los ratios de producción en la unidad Huarón y aplicando estos para determinar la eficiencia del consumo en cada zona, logrando un comparativo de costos para conseguir una distribución eficiente de la ventilación. Asimismo, recomienda formas de optimizar el consumo de energía por ventilación mediante el uso de los ratios de energía y producción.

By J. R. Goode

There are at least a dozen methods of selectively removing cerium from a mixture of the rare earth elements (REE) including separation techniques based on the oxidation of cerium to the quadrivalent state. Several of the oxidation processes have been operated on a commercial scale, others have been tested and in some cases are part of proposed flowsheets. In this paper, we describe and compare the various methods. We also present preliminary estimates of the costs of early Ce removal and discuss recovery and purity aspects of the options.

By William C. Laubengayer, Robert R. Godard, Harry Dobroski

A whole mine, computer-controlled communication and monitoring system for both normal and emergency use is installed and operating in the U.S. Steel Robena Mine complex near Uniontown, Pa. Portions of the system, including the coaxial cable and the key underground and surf ace phones, have been operating for over a year and a half. During this time the basic concept has been modified and new line amplifiers with directional switches have been developed to eliminate some problems in implementing the loopback feature. The quality of the audio and the availability of the system have been outstanding. Since early summer almost all subsystems have been completed. The experience with the telephone system itself, the pocket-pager call alert, section wireless radio, hoistphone, television, environmental monitoring, control and monitoring of equipment, voicedownlink/code uplink post disaster communications, post disaster through-the-earth monitoring, and the system center failure diagnostic routines are reviewed.

By Kathleen Madland Kowalski

In recent years the issue of human stress response in emergency workers has begun to receive attention. This paper presents a rationale for considering human stress as a significant factor in the management of emergencies. It discusses the concept of stress, Critical Incident Stress in emergency responders, and introduces the Critical Incident Stress Debriefing (CISD) process. It is suggested that, in a disaster, the CISD process can improve the effectiveness of response teams on site, their turnaround time on site, and post disaster time off the job. This paper, prepared by a US Bureau of Mines research psychologist, offers some ideas to the mining industry in general, mine rescue trainers, and more universally, to those responsible for developing emergency management plans.

By Zizheng Zhou

The separation of cobalt from other base metals can be achieved using diffusion dialysis in a two-compartment reactor separated by an anion exchange membrane. In this work, a Neosepta AFX membrane was used to study the separation of various metals in an acid-chloride solution. The separation of one metal from another was investigated on the basis of the various chloro-complex stabilities. The metals investigated included cobalt, nickel, copper(II), iron(III), aluminum, zinc and cadmium. The impact of several critical experimental conditions, including the initial metal and chloride concentration in the feed solution and their initial concentration in the receiving solution, on the separation factor and the metal transfer rate is reported in this work. Effective separation of different metal pairs was achieved under the experimental conditions.

By D. B. Robinson, J. Lukacs

A knowledge of the equilibrium water content of hydrocarbon systems under pressure is important to the natural gas industry. The information available on the solubility of water in hydrocarbon, hydrogen sulfide, and carbon dioxide systems is reviewed in this paper and the influence of the more important variables such as temperature, pressure and molecular structure on solubility in liquids and gases is discussed. A suitable cbromatographic technique has been developed for determining low concentrations of water. Tailing of the water peaks has been elim inated by adding water to the carrier gas stream The method is applicable for both gas or liquid samples and is effective in the presence of hydrogen sulfide. The experimental study of water solubility in methane-hydrogen sulfide systems at a temperature of 16oF has shown that the presence of hydrogen sulfide causes only a modest increase in water content at pressures up to 1,400 psia. Theoretical considerations and data on pure hydrogen sulfide and carbon dioxide suggest that the effect of both these compounds will be greater at higher pressures and in the liquid phase. INTRODUCTION Before transporting or processing natural gases and gas condensates, it is usually necessary to dry them using suitable dehydration equipment. The design and operation of this equipment requires a knowledge of the amount of water present in the fluid at the reservoir and operating conditions. This is influenced by temperature, pressure and composition, particular1y when certain non-hydrocarbon components are present. Field experience indicates that hydrogen sulfide and carbon dioxide, for example, alter the usual water solubility relationships appreciably. However, an extensive search of the literature does not reveal any quantitative data on such systems. For sweet natural gases, generalized empirical correlations such as the one proposed by Katz, et al,6 can be used to predict water solubility with confidence at most temperatures and pressures of interest. However, existing theoretical relationships do not permit a calculation of the deviation from these curves when polar substances like hydrogen sulfide are present in the system. Thus one must resort to an experimental approach to obtain the necessary information. The fact that laboratory experimental methods frequently involve the use of mercury which reacts with hydrogen sulfide in the presence of water, and that hydrogen sulfide interferes with many chemical reactions specific for water has contributed to the difficulty of studying water solubility in systems containing hydrogen sulfide. In this investigation the water content of a limited member of methane-hydrogen sulfide mixtures was determined using a special technique with gas chromatography. REVIEW OF PUBLISHED DATA Experimentally determined water solubility data have been reported for methane, 14 ethane, 15 propane, 9 n-butane, 16 1-butene, 11 hydrogen sulfide 18 and carbon dioxide. 19 These studies report the effect of pressure, temperature and molecular structure on water solubility in single component gases and liquids. Fig. 1 compares experimentally determined water solubilities in several hydrocarbons, carbon dioxide and hydrogen sulfide at l00F as taken from this

By Benjamin Cebrian

Traditional dilution control systems range from computer modeling, use of physical markers on the field as polypipes to a technology that marks some control points where displacement is measured. The latter includes walking over a muckpile which is prohibited by some mining companies as a safety measure. The new technology presented in this paper is a patented system that is installed on board excavators (backhoe or front shovel types). Several control points are set along ore/waste contacts and their position is uploaded on the corresponding shovel. The operator proceeds on mucking until he is alerted when reaching any of the several control points previously located in the blast patterns and that have moved with the muckpile. A case study is presented at a high grade copper mine, were unique 3D shapes are showing as a result of using an on-board excavator dilution control system. Both ore-loss or dilution cost of opportunities are analyzed.

By Eugie Kabwe

The velocity of detonation (VOD) is a significant property considered when rating an explosive. It may be quantified as a confined or unconfined velocity. The confined velocity is the rate at which the detonation wave propagates through an explosive within a blast hole or any restrained space. The unconfined velocity emanates when an explosive is detonated in the open. However, the confined velocity is more significant as explosives are usually employed under a definite degree of confinement. This paper evaluates the increment of air deck volume and its effect on the VOD. The air gap (air deck) volume is increased stepwise from 10 to 30% of the total blast hole volume by reducing the stemming height in the collar zone. Thereafter, the VOD estimation in the 172-mm-diameter explosive column is conducted using the Dáutriche technique. It is observed that the VOD reduced with the increasing air deck volume and detonation failure is high when 30% of the blast hole volume is replaced with air deck. It is deduced that the increment of the air deck volume has an effect on the attenuation of the steady-state VOD.

By Alistair Burrows

Situated in the oblast of East Kazakhstan, the Ust-Kamenogorsk Metallurgical Complex has spent the past twenty years renovating and remodelling itself as a modern polymetallic sulphide smelting facility, and a regional centre of excellence for custom smelting. Along the way there have been changes to the company structure, introduction of new technologies, investments in expanded capacity, environmental improvements, and addition of new metal products and by-products to the site’s repertoire. These changes have been gradual and incremental, but taken together they represent a significant contribution to placing Kazakhstan’s sulphide smelting industry on a strong foundation for enduring success in the international custom smelting market. In achieving these changes, a workforce that was historically isolated from much of the world now has recognised expertise, internationally competitive skills, and confidence to embrace the future. Further improvements in energy efficiency, environmental compliance and polymetallic processing capabilities are challenges that UKMC stands ready to face.

By Alejandro Rosario, Ricardo Dumuihual, Guillermo Silva, be nito Danial Valde, Carlos Scherpenisse

A monitoring campaign to record dynamic pressures generated by detonation of a single blasthole was implemented at Barrick Gold´s Pueblo Viejo Open Pit mine (PVDC), located in the Dominican Republic. Pressure amplitudes beyond the dynamic compressive strength of the electronic detonator´s capsules have the potential to damage these electronic devices, generating misfires along with all the associated risks and entailed safety implications. In most instances, misfires generated from high dynamic pressures are a direct consequence of drilling deviations resulting in blasthole distances smaller than originally designed. Tourmaline Crystal Sensors specifically designed for high dynamic pressure measurements in aqueous media were selected to address the challenge. These sensors are custom-made and require additional instrumentation for proper operation, including signal conditioners and recording equipment capable of capturing simultaneous events, both in their amplitude and frequency components. Field-testing comprised detonation of a single blasthole using current explosive loading practices along with an arrangement of sensors positioned within water-filled drillholes in a spiral configuration. Distances, explosive weights and all 23 dynamic pressure record amplitudes are included along with additional data regarding arrival time and P-Wave velocity estimations. As with typical vibration models, the Scaled Distance concept (D/W1/2) was used to construct an attenuation model relating Dynamic Pressure as a function of Distance (D) and explosive Weight (W). The resulting model, adjusted to a 95% statistical confidence limit (covering 100% of the recorded data) was used to generate a series of curves (Abacus) estimating dynamic pressure as a function of distance for different explosive charges. These curves, in association with permissible pressure limits defined at 50% (FOS = 2) of the dynamic pressure strength reported by manufacturers for both, the 1000bar (Al) and the 1400bar (Cu) capsules; allow for the determination of critical (safe) distances between blastholes. Tests were implemented to cover a variety of field scenarios, accounting for different rock mass types, qualities and water conditions; however, preliminary analysis indicate the convenience of developing a unique trend that considers said variability. This approach allowed construction of a single, simple, unambiguous and operationally applicable design tool to address entailed safety issues.

By Travis Davidsavor, David Provost

A segment of high-pressure steel petroleum pipeline needed to be replaced on a hillside and beneath a waterway within an existing right-of-way containing multiple petroleum pipelines. The pipeline replacement required excavation of sedimentary rock to allow placement of the new pipe. As a result of an existing right-of-way limitation, steep slopes, and hard rock, blasting would be required as close as 7.8 meters (25 feet) from two operating pipelines. Existing pipeline company standards would have effectively precluded the construction of the replacement pipe by blasting rock. To facilitate the required construction and evaluate actual pipe stress during blasting to ensure pipeline integrity, a comprehensive evaluation methodology was developed by a team of pipeline, mechanical, geotechnical, instrumentation, and blasting engineers. A total of 60 strain gages were affixed to the steel pipe and seismographs were buried at the surface near the blasting area. Test blasting allowed pipe stresses with corresponding ground motion to be monitored. A conservative analysis approach evaluated individual peak strains and revealed that only small pipeline strains, and therefore stresses, were induced in the pipeline as a result of blasting. This evaluation allowed specific procedures to be developed to inform the blasting operation of maximum explosive loading and minimum charge distances. Additionally, this effort provided the pipeline operator with appropriate pipeline operating pressures during blasting activities to limit total stresses in the pipeline to be below allowable stresses imposed by code, regulators, and company operational limitations. Recommendations were developed to measure the blast generated ground vibrations with seismographs buried at the depth of the pipe, near the pipe, and limit the ground vibrations from blasting to 150 mm/s (6 in/s). If ground vibration intensities of 120 mm/s (4 in/s) or more were observed, additional engineering review is recommended. Finally, all blasting would be suspended and all activities reviewed at peak ground vibration intensities of 230 mm/s (9 in/s). The evaluation effort resulted in effective and efficient construction of the pipeline replacement and allowed the pipeline operator to better understand blasting induced stresses on their assets.

By Fred Turin, Kim Cornelius, Lisa Steiner

NIOSH researchers have been examining underground coal mining activities in order to evaluate work crew hazards. In 1994 a continuous mining machine operator was killed by falling roof during extended cut mining. Many aspects of the incident were used by NIOSH researchers to develop a scenario interview. The goal was to provide a realistic framework for acquiring frank and detailed insights. The interview consists of two sections. The first describes the underground mining conditions. The second recounts the fatal incident. Each section is supplemented by a diagram and a set of questions addressing relevant safety issues. The interview was administered at three mines that actively take extended cuts. Researchers found the scenario approach to be an effective interview tool as well as an effective hazard awareness and safe work practices training platform.

By Tapan Goswami

The main objective of the blasting phase in a coal mining operation is to maximise the coal recovery. However, coal loss due to blasting is a serious problem. The Australian Coal Association Research Programme (ACARP) reported in 2011 that in Australia one in every ten coal mines is completely wasted due to such losses. Coal is either lost in the spoil, largely due to the blasting operation or becomes diluted and cannot be recovered entirely. The major coal loss mechanisms include losses from the coal seam roof, the floor, the front edge and from dilution. Coal damage and loss mechanisms during cast blasting that have been observed by various authors include: •Excessive cast dragging the coal edge in the cast direction. Movements of this nature are oftenassociated with the formation of trenches. •Spatial movement of overburden where rock shears and moves in a plane above the coal seam,which damages and dilutes the coal. •Rock falling over the coal during the blast often producing indentations in the exposed coal. •The inappropriate use of bulk and initiating explosives that often results in coal damage. •Insufficient stand-off distances from the coal. The Australian coal mining industry has gone a long way towards addressing the coal loss issues since 2011: almost all operations now deploy touch-coal drilling and sporadically use gamma logging for loading overburden. A study was conducted to compare the effectiveness of touch-coal information in which some touch-coal blastholes were drilled on a fixed or random pattern. In another study, some blastholes were drilled to the touch-coal, gamma-logged and mapped to determine stand-off distances. It was found that the coal roof surface created by gamma-logged holes was the most effective option for minimising coal loss. As a result, a variable stand-off distance was found to be the key to minimising losses. This paper discusses the importance of coal mapping, the rock properties of the roof and floor interface of the coal seam, and the significance of loading and initiating designs in minimising coal damage. Furthermore, the importance of using electronic initiators cannot be emphasised enough. This paper also discusses how a cast blast can be initiated from many locations by mitigating geological abnormalities and thereby avoiding spatial movement of rock shearing in a plane above the coal seam.

By Henry D. Hibbard

At the beginning of a Henry M. Howe lecture it seems fitting to refer to Howe's great contributions to steel metallurgy, and particularly to the literature thereof. Most of my predecessors in this role have been able, from their association with him, to give direct testimony as to his great services; but although connected with him for years in a business way, I am less familiar with what might be called his academic side, except as it is embodied in his utterances, written and oral. Howe was adept in his genial way in extracting information in any line which, at the time, was of interest to him. In a technical lecture one expects as a rule new knowledge—something about recent advances relating to the subject. On this occasion, however, I will ask you to go back with me to the primary department of steel lore, as the title of my lecture shows, to review the more fundamental features in that field for the purpose of seeking some gaps which we can fill and so give the subject renewed interest. In thus going back one must inevitably repeat many familiar facts, but that seems to be necessary in order to reach a clear understanding of the unrecorded matters. The full interpretation of a steel analysis is at present unattainable, though much progress toward that end has been made. The ultimate analysis, giving the percentages of the five commonly determined elements, does indeed usually give a fair idea of what the steel is, and is ordinarily enough, with knowledge of its history and physical condition, to enable it to be assigned to some purpose or use for which it is reasonably suitable. But discrepancies arise. Every maker and every user of steel knows, from at least occasional examples in his own experience, that the ultimate analysis is insufficient by itself to enable one to tell positively, from its interpretation, either the mechanical properties of the steel or its adaptability to the purpose for which it was made. Further, if, while having the specified composition, it is abnormal or unsatisfactory, why it is so. Good, bad and indifferent steels may have substantially the same ultimate analysis.

By H. E. Cross

Metallurgical considerations in the automation of gold-recovery plants By H. E. CROSS. Pr. Eng., B.Sc. (Eng.) Hons. (Fellow) The advantages of the automation of gold-recovery plants are examined. The various sections of a gold-recovery plant are analysed, and the extent to which instrumentation can usefully be employed is described. INTRODUCTION The scope of this paper is restricted to the ore-treatment and recovery plants on Witwatersrand gold mines. To extend the field to plants that process base metals and industrial minerals would result in a paper that would be too lengthy. However, the subject matter of this paper is applicable to most mineraldressing and recovery plants and will, it is hoped, be a foundation on which to build somewhat more sophisticated control systems required in the base-metals field.

By M. A. Jensen, J. J. Bettencourt

SYNOPSIS An analysis was made of records of accidents involving Bantu mineworkers and which resulted in either minor injuries or hospitalizations to determine patterns in underground accidents from which to formulate priorities in accident prevention in gold mines. The results showed that: (i) specific labour categories, such as inexperienced men, are exposed to certain types of hazards the extent of which warrant the separate design of safety programmes to meet their specific needs; (ii) the systematic study of minor accidents provides a dependable source of. information of which safety departments could make greater use in their efforts to control and prevent mining accidents.