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By G. H. Billings

There exists an unconfirmed opinion among many ironmasters that the combination of a small quantity of manganese, chromium, titanium, tungsten, aluminium, nickel, and some of the metalloids with iron has a beneficial effect upon the quality. And the impression prevails in some localities that the excellence of steel greatly depends upon the influence of some of these elements. Brit as the recorded experiments are so meagrely described, and made under such various conditions, the student in search of information upon the subject is somewhat bewildered by the contradiction of the opinions expressed. Observing some interesting phenomena while experimenting with an alloy of iron, copper, and nickel, I was led to determine the effect of some of the metals upon iron as free from contamination by other elements as it is possible to procure in practice, in order that the result of an alloy of an individual metal with iron might be more closely studied; for it is almost an impossibility to determine the influence of a small amount of one element upon a metal combined with a large amount of another, and the mere presence of another sometimes makes this difficult. And as most of the experiments recorded upon this subject have been made with iron containing sufficient carbon and other elements to interfere with the effect of that metal the influence of which it was desired to observe, I have endeavored to avoid these sources of error as far as practicable. In determining the specific gravity of the alloys in these ex-

The locality from where these specimens come is distant about 12 miles due south from the township of Bingara New South Wales, and is known locally as Carney's Reef, Barrack's Creek, Top Bingara. The formation traverses the western side of a serpentine spur from the main range, which runs through the country from the other side of Tamworth to Inverell, in the New England District. It has a due north and south trend, with an easterly underlay slightly out of the vertical. The formation has been opened up at different points for a distance of over two miles, and each place showing gold in the stone, and no place more than three to four chlins apart, the whole distance along the line of Reef being leased. The formation varies in thickness, the smallest being about 1 foot and the widest about 10 feet. The following is a list of properties, and description of work done on them at present. First south, and about one and a half miles from Hanion Brothers' old BalIarat claim due north, Court and patty hold a tenacre lease. The formation outcrops near the south boundary, and gold is obtainable in the stone. In the centre of the lease a costeen pit has cut the capping, which shows gold, and about two chains from the north boundary another one cuts the capping, also showing gold. The reef averages, where exposed on this property, 3 feet wide.

By F. N. Kissell, H. K. Sacks

This study examines the accuracy of area sampling for measuring the dust exposure of mining machine operators in coal mines. The specific objective of this research was to find locations where an area sampler might work better than earlier studies have indicated. The results show that fixed-location area sampling cannot accurately predict the dust exposure of a machine operator, even when the best fixed location is sought, the fixed location is quite close to the operator and the bias due to the dust concentration gradient is corrected. Industrial hygienists have known for many years that area sampling is unsuitable for measuring air contaminant exposures in the workplace. Near contaminant sources, the dilution air and the contaminants are not evenly mixed. Therefore, when workers are near contaminant sources, exposure measurements must be taken from the worker's breathing zone to be accurate

By C. R. McEwen

This paper presents a technique for calculating the original amount of hydrocarbon in place in a petroleum reservoir, and for determining the constants characterizing the aquifer performance, based on pressure-production data. A method for doing this based on a least-squares line-fitting computationwus proposed by vanEverdingen,Timmerman andMcMahon in 1953. We found that their method would not work when there is error in the reservoir pressure data — even moderate error. The technique presented here appears to give reasonable answers when pressure data are uncertain to the degree expected in reservoir pressure determinations. The major change introduced in the present analysis is to limit the least-squares line-fitting to yield only one constant— the amount of hydrocarbon in place. The water-influx constant is then taken as proportional to the oil (or gas) in place. The constant of proportionality can be computed from estimates of effective compressibility and reservoir water saturation. It is also pointed out that the commonly used least-squares analysis assumes all of the uncertainty to be in the dependent variable. The material balance should be arranged so that this condition is fulfilled if correct inferences are to be made from statistical calculations. Examples are shown of the application of the new technique to gas reservoirs—both hypothetical and real—and to the oil-reservoir example of van Ever-dingen, Timmerman and McMahon. INTRODUCTION The amount of hydrocarbon originally in place in a petroleum resenroir can be estimated by means of the material-balance calculation. Simultaneous observations of pressure and amounts of produced fluids are required, together with the PVT data applicable to the reservoir fluids. If water encroachment is occurring, it is desirable to try to infer the behavior of the aquifer, as well as the original hydrocarbon in place, from the pressure-production data. This imposes additional demands on the method of calculation, and uncertainty in the data can result in large uncertainty in the answer. In addition, if the size of a gas cap is to be established, the whole problem becomes indeterminate, as pointed out by Woods and Muskat.1 Brownscombe and Collins2 simulated a gas reservoir and its aquifer on a reservoir analyzer and derived quantitative information on the effect of uncertainty in pressure and aquifer permeability on computed gas in place. Among the various techniques of estimating the performance of an aquifer, the method of van Ever-dingen and Hurst? based on compressible flow theory, seems to have been the most generally successful (see Ref. 4, for example). In this paper we shall confine ourselves to their representation of the aquifer. In 1953,' van Everdingen, Timmerman and McMahon5 introduced a statistical technique for deriving the amount of oil originally in place and the parameters which describe the aquifer. (We shall refer to this technique as the "VTM method'', as suggested by Mueller.6) Their example reservoir had no gas cap. It has been our experience that the VTM method gives a reasonable answer when the data are very accurate, but that inaccuracy (particularly in pressure) can cause the method to break down. The effect was first observed in gas reservoirs, but has since been seen in oil reservoirs also. In this paper we present another statistical method which has been successful in achieving a reasonable answer where the VTM method has failed. In the new method, one less parameter is derived from material-balance computations. It is assumed that values can be established for effective compressibility in the aquifer and reservoir water saturation independently of the material-balance calculation. The water-influx constant can then be obtained from these data and the quantity of hydrocarbon in place.

By Denis Shishin

The pyrometallurgical production and recycling of non-ferrous metals involves the use of complex feed stocks, having awide range of chemical compositions from sources that include mineral sulphide concentrates, high value obsolete materials and process wastes. The commercial viabilities of these operations hinge on the ability to extract value from these materials. Increasingly, modern computer-based tools are used to describe and predict process outcomes, including mass and heat balances, the partitioning of elements and phase equilibria. At the heart of these predictive tools are thermodynamic databases that describe the fundamental chemical properties of a system and all the components present. A comprehensive research program has been established to develop an accurate, self-consistent thermodynamic database describing all gas-slag-matte-metal-speiss-solid phases in the system Cu2O-PbO-ZnO-Al2O3- CaO-MgO-FeO-Fe2O3-SiO2-S-(As-Bi-Sb-Sn-Ag-Au). The database can be used in conjunction with the FactSage computer platform. The accuracy of the database and its application to industrial practice is demonstrated.

By Fred N. Kissell

The U.S. Bureau of Mines was established in1910 to reduce .the high accident rate in the nation's coalmines. For 85 years, it conducted a wide variety of tasks related to mining before it was abolished in 1995. The BOM had many technology transfer successes in its lifetime, including more than a dozen "R&D100" awards. This essay identifies and discusses five "transfer factors" that can explain the success (or failure) of many Bureau of Mines projects. These five factors are termed "pressure, pitfalls, path, price, and profit."

By Thomas Novak, Jeffrey L. Kohler, Joseph Sottile, Steve J. Gnapragasam

Modern underground coal mines can be very large, having a total connected load in excess of l5 000 hp. These mines generally have many miles of high-power conveyor belts and 15 or more miles of high-voltage power cables at distribution voltages of 12.47, 13.2, 13.8, or 14.4 kV. The shielded cables used in mine power distribution systems have a significant level of capacitance, on the order of 110 pF/ft. This level of capacitance, in an extensive power distribution system at today's voltage levels, can cause significant charging currents during a ground fault. This paper addresses the potential detrimental effects of capacitance charging currents during line-to-ground faults in mine power distribution systems. A representative mine power system is modeled, and simulations with faults at various locations are conducted to evaluate the effects of this capacitance on the level of fault current and relay selectivity. This paper also includes results of capacitance measurements made on mine power feeder cables used to validate the simulation model.

By P. B. Baxendell

The appraial of producing properties and profitability ntzalysis of a proposed capital expenditure are based on the same principles. In both problems a projection of future cash income is. cornpared to one or more capital expenditures. Several different methods have been in use either to compute a price to obtain a given earning power on the investment or to compute the earning power which will result from a given capital expenditure. One of these, the "Average Annual Rate of Return" method, computes in a simple manner the ratio of the present value of the future earnings after amortization to the present value of the undepreciated balances of the investment over the life of a project. This method, not well known generally, appears to have some rather unique advantages in reducing the computation work required, eliminating trial-and-error solutions, and providing a more accurate answer when applied to oil industry investments subject to the unit-of-production basis of amortization. Its derivation is given and its versatility demonstrated in the solution of certain everyday investment problems. A number of charts, useful in applying this method to profitability analysis and appraisal work, are provided. The current trend in the market values of producing properties is shown. INTRODUCTION Making sound capital expenditure decisions requires an objective means of measuring the productivity of individual investment proposals. Since the best measure of the economic worth of such proposals is their ability to produce profits, it is common practice to grade proposed capital expenditures according to their annual earning power as a percentage of the outstanding capital. The same principles which govern the determination of the rate of return of proposed capital expenditures also apply generally to the problem of determining the appraisal value or purchase price of income-producing oil and gas properties. Both problems are of prime importance in the producing phase of the oil business, where management is faced daily with decisions to drill or not to drill certain development wells, or with the determination of the appraisal value of producing properties. The common feature in both problems is that a projection of future cash income is compared with a known or estimated capital investment to determine itsiearning power or annual rate of return. In the case of development drilling, the cost of the proposed well can usually be estimated with a fair degree of accuracy and the problem consists of finding the rate of return on the invested capital. In the case of appraising producing properties, on the other hand, the desired rate of return is usually known in advance and the problem consists of determining the purchase price which, for the given income projection, results in the fequired rate of return. Certain accounting procedures common to the oil and gas producing business make these two problems and their solutions somewhat different from corresponding problems in other industries, and, in certain ways, simpler. The main difference is in the amortization policy which, for oil and gas production, is frequently on a unit-of-production basis, compared to the amortization on a time basis used in many other industries. The purpose of this paper is to discuss briefly the various methods currently in use for the measurement of productivity of invested capital in producing properties and, in more detail, the derivation and application of what will be called the "Average Annual Rate of Return Method". This rather interesting and not too well known method has some very definite advantages in the solution of many problems common to the oil industry. For the sake of simplicity, federal income tax considerations have been disregarded in the examples used, since they do not affect the principles involved. The use of the production payment route in the sale or purchase of producing properties, which has been amply covered in many other publications, has also not been included in this analysis. METHODS FOK MEASUKING THE EARNING POWER OF INVESTED CAPITAL, Of the many different methods used to measure the earning power of invested capital, four are applicable to oil or gas production ventures. Depending on whether these four methods utilize one or two interest rates, and whether a fixed amortization pattern is used, they may be classified as follows.

By Mark K. Larson

A constitutive model for rock interfaces based on the principles of static fatigue is proposed. The model is applicable to weak rock or joints with cohesion. Friction and dilation are decreased as plastic work increases. At equilibrium, the creep time increases by one time-step interval, and interface cohesion at each node decreases according to a power function. A constant-load, direct-shear simulation showed that the model is cap- able of mimicking constant-rate and tertiary creep and predicting failure. Tests on core from a coal mine showed constant-rate and, sometimes, tertiary creep, but also weak transitory creep. The cohesion deterioration function may need modification to simulate primary-phase creep. If model parameters are known for a site, the model can predict the onset of tertiary creep and failure. Such predictions can help engineers make better entry design and support decisions, which will reduce the likelihood of roof falls and increase safety for underground miners.

By G. C. Naveen

Punatsangchu Hydroelectric Project Authority is constructing 1020 MW underground hydroelectric project in Bhutan. The project envisages construction of concrete dam, Desilting Chamber, Head Race Tunnel, Power House Complex and Tail Race Tunnel. Tunneling is one of the major activity in any underground projects as they are driven for multiple activities. By and large the tunnels are a major part of connecting networks from surface to caverns/underground working sites. Many tunnels in hydropower project are part of water conducting systems and one such important tunnel is the Tail Race Tunnel in this project and had to be excavated in thinly foliated rockmass conditions by D&B method. The rockmass is traversed by three to four joint sets and few minor shear seams. Rock Class “Q” values were between III and IV. Tunnel was excavated by full face parallel hole drilling blasting method. The adopted blasting method consisted of drilling 45mm (1.77 inch) diameter holes to a depth of 2m and the drilled holes were charged with 40mm (1.57 inch) diameter cartridge explosives and charges were initiated with half second non electric initiators. The perimeter holes were drilled at closer spacing of 30cm (1 feet) and alternate holes were charged using 32mm (1.23 inch) diameter cartridges explosive. Low dipping foliation joints present in the rockmass tend to slab in crown portion and erratic occurrence of intrusive bodies lead to unpredictable behavior of rock mass posing a major challenge for the safe excavation. Stability was a major issue through controlled blasting under constant supervision too could not limit the overbreak in certain weak rockmass conditions thereby exposing cavities of about 2.5m (8.2 feet). The stabilization of these cavities and handling the overbreak due to rockmass condition was time consuming and warranted additional supports. With systematic measurements and controlled blast designs the Horse Shoe Shaped Tail Race Tunnel of 9.1 m (29.85 feet) diameter and 304m (997.37 feet) length to connect with Downstream Surge Gallery of 314m (1030 feet) length, 18m (59 feet) wide and 58.8m (193 feet) height in thinly foliated and jointed biotite gneiss rockmass was successfully excavated.

By JeffreyS. Vipperman, Daniel R. Babich, EricR. Bauer

In response to the continuing problem of noise induced hearing loss NIHL among mine workers, the National Institute for Occupational Safety and Health NIOSH has conducted numerous noise surveys in coal preparation plants. The research, consisting of worker dose monitoring, task observations, and equipment noise profiling, was completed in eight separate preparation plants. Worker dose monitoring was conducted for three shifts in most cases. Workers experiencing higher than allowable doses were task-observed for one full shift to correlate dose to noise source(s). Finally, noise levels on all floors, and in lunchrooms and control rooms, were characterized. Results indicate that only workers who routinely spend a significant portion of their shift in the plants (away from the control rooms) are susceptible to overexposure from noise. Certain pieces of equipment (screens, centrifuges, sieve bends) are the loudest primary noise sources responsible for the worker noise exposures.

By I. D. Schleicher, L. H. Rorden, F. B. Curry, T. C. Moore

The purpose of this program is to extend electromagnetic (EM) techniques for use in locating miners trapped in mines as deep as 1000 m. A previously developed EM system is considered adequate for use at mines less than 300 m deep where it has a probability of detection of 54%. A system for deep mines must keep underground equipment simple, and use extremely low frequencies (ELF), sensitive receivers, and noise cancellation. The proposed location method, developed by Develco for other applications, is based on vector field measurements from two or more static sensors and computation of source location by iterative techniques. During Phase II, very sensitive search coil sensors were built and used in a separate test to verify the feasibility of atmospheric noise cancellation. A "Breadboard" location system version without cancellation, which is a fieldable test bed to evaluate receiving and location functions, was tested and supplied. Very good results were achieved from the first in-mine test with the transmitter at a depth of 380 m. It is expected the results of this work, and additional evaluation tests in the future, will be used to define the requirements for a prototype operational system.

By Harry Dobroski, Larry G. Stolarczyk

Theoretical and experimental research sponsored by the U.S. Bureau of Mines shows that medium frequency (MF) electromagnetic (EM) signals propagate great distances in an underground environment such as a tunnel or mine. This propagation is enhanced by different mechanisms associated with the geology, and with the existence of metallic conductors in the entryways. In stratified geologies, a transverse electromagnetic (TEM) mode of signal propagation is possible if a low conducting layer is bounded above and below by higher conducting layers. In general, the difference in conductivities must be at least several orders of magnitude. Such geological waveguide conditions often exist in underground mines. Propagation via the waveguide effect is known as the "seam mode" of propagation. Another mode of propagation, the "tunnel mode," exists in underground entries with electrical conductors such as power cables, metal pipes, and phone lines. A monofilar mode of propagation exists when signals are impressed upon conductors and return via the surrounding rock. A bifilar mode of propagation exists when all signals exist only on local conductors. In a given location there is a combination of monofilar and bifilar modes that make possible an interaction between the conductors and a transmitting device in a tunnel or entryway. Signals can be impressed on or received from local conductors via magnetic dipole antennas (loops) or line couplers.

By Julie Mitchell, Robert King, Len Eros

The Bureau of Mines has studied the Deserado Mine computerized monitoring and control system, located in Rangely, Colorado, to acquire knowledge about the overall costs and benefits of mine monitoring systems. The Deserado system is a complex system monitoring environmental parameters, electrical power, and operation of all mine equipment, and controlling the entire conveyor haul age system. This paper discusses the evaluation of the Deserado monitoring system from initial design through system installation and operation. It also examines the costs, benefits, and performance of the monitoring system.

By C. O. Karacan

Underground longwall mining of coal causes large scale disturbance of the surrounding rock mass. The disturbance can increase the rock mass permeability through a reduction on the stress as well as formation of new fractures in the rock. Methane gas contained in the disturbed rock mass can migrate towards the low pressure mine workings and present an explosion hazard. This paper describes the application of a finite difference program to develop a geomechanical model that predicts permeability changes within the rock mass. The calculated permeabilities are used as input to a reservoir simulator that models methane desorption from the coal matrix, methane release from the rock layers and flow towards the mine excavations. The model also considers the basic characteristics of the mine ventilation network. The geomechanical model uses empirical relationships between fracture permeability and stress to calculate permeability changes around a longwall face. The extent of rock failure is determined using a strain softening model that considers both rock matrix and bedding plane failure. The cave rock (gob) is modeled as a compressible, granulated material. The calculated horizontal and vertical permeabilities around the longwall face are averaged and used as one of the inputs to the reservoir model. The reservoir model was developed and calibrated against records of methane flow at a study mine in southwestern Pennsylvania. Good correlation between actual gas production and model outputs has been achieved. The modeling approach provides a basis for estimating methane inflow and optimizing control measures.

By Stephen C. Tadolini, Thomas M. Barczak

Roof support systems, longwall shields in particular, have persistently grown in size and capacity for the past 25 years. Why is this? Is it a good thing or is it unnecessary? What are the consequences of this “bigger-the-better” design philosophy? Rarely do we see a “one size fits all” approach to roof support except when it comes to longwall shields, where the historical trend for new procurements is to simply purchase the highest capacity support you can buy. Does high capacity ensure failures will not occur? The answer is no! The highest capacity tailgate supports are typically the ones that fail the most often. What does this tell us? It tells us that there are fundamental aspects of support design and ground control that we still do not understand or recognize when designing a support system. This paper provides an interesting evaluation of these issues and proposes a different approach to support design that attempts to match the support performance characteristics to the ground behavior. Along the way, some of the old premises of support design will be discarded, and new “controversial” ideas developed. Thinking outside the box never hurt any industry. Mining has made it a common practice.

By John F. Blandy

Although the question of the "waste of anthracite coal mining " has been so frequently discussed, and a committee was appointed at the first meeting of this Society to consider and report upon the subject, still but little progress seems to have been made in arriving at a conclusion as to how it ran be reduced. That committee made a preliminary report at the August meeting, 1871, in which it divided the question into three parts, namely: Waste in mining, in preparing for market, and in transportation. I shall not here refer to the first item, as so much depends upon the peculiar features of each separate mine, and the skill of those in charge; but in reference to the second, that of preparing the coal for market in breaker and screens, I wish to make some remarks. There is no use considering the question, whether the coal should be broken up to suit the fancy of consumers; all miners are satisfied that it should not be, but the consumers decide that they want it that way, and the miner must submit, and simply utter his maledictions upon the head of the man who first suggested a breaker or screen, if that is any consolation to him. What is called waste in this process of preparation, is the dust and fine coal, which results from the breaking and screening, and, as we all know, this is a very important percentage of what passes from the slope to the top of the breaker. Now, if this dust and fine coal can be utilized—the slate which is picked out is not to be taken into consideration as waste—then we get rid of this item entirely. There is no question in my mind that this article can and will be used as a steam generator at least, and I think, therefore, that in depositing

By Zhuo Sheng

We have designed a high-temperature Raman micro-furnace and cell that is suited for the electrochemical process study of the NO3 − in molten NaNO3– KNO3 (fraction of NaNO3 50 wt%) salt. During the cycle voltammetry and constant potential electrolysis process, the Raman laser beam was focused near the electrode; subsequently, the Raman spectra are obtained and the reduction process of NO3 − is analyzed. In the CV cathodic scan process, the new peak attributed to the ν1 mode of NO2 − emerges, and the peaks assigned to superoxide ions (O2 −) and peroxide ions (O2 2−) are not found. In the constant electrolysis process, the peaks at 1130 and 800 cm−1 appear when the potentials are between −2.0 V and −3.2 V (vs. Pt). The results show that when the NO3 − is reduced in molten the NaNO3–KNO3 mixtures, the reduction product O2− cannot stably exist, and O2− will react with NO3 − to form of superoxide ions (O2 −) and peroxide ions (O2 2−).

By R. J. Matetic, David S. Yantek, David K. Ingram

The National Institute for Occupational Safety and Health (NIOSH) has investigated engineering noise controls to reduce sound levels in cabs on air-rotary drill rigs. A recent investigation revealed that some drillers are exposed to A-weighted sound levels exceeding 85 dB even though a cab is used. NIOSH studied the in-cab sound levels of one such rig. First, preliminary tests were conducted in a controlled environment using accelerometers and microphones with spectral analysis to identify the dominant noise sources for in-cab sound levels. The results indicate that vibration transmitted from multiple hydraulic pumps to the control panel produces a dominant spike in the sound level spectrum in the 400 Hz 1/3-octave band. Next, field tests were performed in a production environment to evaluate noise controls to reduce in-cab sound levels. It was found that utilizing hydraulic noise suppressors reduces the structure-borne noise transmitted to the control panel. Further, using hydraulic noise suppressors and enhancing soundproofing reduced the in-cab A-weighted sound levels by as much as 4 dB.

By Katsunori Yamaguchi

Secondary materials, that contain relatively high concentrations of platinum group metals, (PGMs) are treated in copper smelting process. The PGMs lost in the slag is increasing with increasing quantities of scrap treated amount. To determine the portion of the PGMs chemically dissolved and that associated with the mechanically trapped matte in the slag will be a key factor to improve the recovery of those metals. An experimental study was carried out to determine the distribution of palladium between the FeOx–SiO2 slag and the liquid Cu2S–FeS matte at 1573 K and a fixed partial pressure of SO2 of 0.1 atm. It was found that the distribution ratios are around 10−3 for platinum and palladium. The distribution ratios show a tendency to increase when the grade of matte is increased above 60 mass% Cu. In addition, the solubility of platinum in FeOx–SiO2 slag equilibrated with a pure palladium and the Pd-Cu alloy was determined at 1573 K and the range of oxygen partial pressure from 10−9 to 10−7 atm. The solubility of palladium in the slag tends to increase with increasing oxygen partial pressure and activity of CuO0.5 in the slag.