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By Thomas V. Falkie, R. Venkataramani

Table 15. Summary of Physical Characteristics of Coal and Shale from Channel Samples. Table

Jan 1, 1972

By F. G. Schora

The Institute of Gas Technology (IGT), under sponsorship of the U. S. Department of the Interior, Office of Coal Research (OCR), and the American Gas Association (A. G. A. ), has been undertaking the development of one of several processes to convert coal to high-Btu gas as a means of supplementing natural gas supplies. It is anticipated that there will be a significant need for such gas in the foreseeable future in order to meet the ever increasing demands for this preferred fuel form. HISTORY The development of the HYGAS® Process is based on various studies conducted at IGT starting back as far as 1945. Initial work was directed toward production of synthesis gas with subsequent catalytic methanation. By 1964 the concept of the direct hydrogenation of coal to produce methane noncatalytically was well-founded and the chemistry was reasonably well established. Work up until this point in time was financed by the American Gas Association. In 1964 the U. S. Department of the Interior, Office of Coal Research joined with A. G. A. to support the program. The objective at that time was to develop the necessary know-how to enable the design of a pilot plant, a necessary step in the ultimate commercialization of the process. Work for the next three years (1964-1967) emphasized investigation of fluidized-bed technology in the hydrogasification step, where moving-bed technology had been previously employed, as well as identification of commercially available catalysts acceptable for catalytic methanation of the CO and hydrogen in the hydrogasifier effluent under operating conditions in the system. By 1967, the preliminary design of a 3 ton/hr pilot plant had been finalized, and IGT received authorization from OCR to proceed with the detailed design and construction of that facility. The pilot plant was designed to study the following problems:

Jan 1, 1972

By Kalanadh V. S. Sastry, D. W. Fuerstenau

Design and operation of a batch balling drum that can be used easily for experimental investigation of the balling or granulation behavior of particulate materials are described briefly. An experimental procedure for ascertaining the growth kinetics of iron ore concentrates or other particulate materials with this kind of apparatus is outlined.

Jan 1, 1972

Table XXXIII itemizes the cost associated with the installation of an irrigation system and the application of latex and water in the three experimental areas at Lanse. There were no external labor charges (non- Research Center) except for the installation of the water meter. Cost of pipe and fitting are high because long lines were required at each of the three different locations; these costs were minimized by using plastic instead of metal pipe. Fifteen of the seventeen drums of latex received were used, five drums for each area. [ ] In tank-car lots latex would cost about $0.25/lb so that raw material cost for a 4000 lb/acre application would be in the range of $1,000 per acre. Equipment costs for setting up and irrigation are sensitive to size of area to be irrigated, design of system, and availability and cost of water. A realistic range is estimated to be between $200-500/acre.

Jan 1, 1972

By L. J. Froisland

Water classification and heavy-media sink-float methods were investigated for concentrating metallic junk automobile shredder rejects initially upgraded to about 75-percent metal content in an air elutriation system. An 8-inch-diameter water elutriation column with a feed capacity of 2.7 tons per hour was constructed and operated. The results obtained were compared with those produced by sink-float methods. Tests made on duplicate samples of an intermediate-grade metal product were successful in upgrading the metal con-tent from 75 percent to 98.7 and 99.1 percent with respective recoveries of 95.5 and 98.9 percent for the water classification and sink-float procedures. Tentative flowsheets for treating junk auto shredder rejects are outlined.

Jan 1, 1972

By S. R. Rao

Interaction of potassium amyl xanthate with pyrrhotite has been studied thermochemically. Heats of adsorption of xanthate on unactivated mineral and the mineral activated with cupric ions have been compared with heats of reactions between potassium amyl xanthate and ferrous and cupric salts. It is shown that xanthate is consumed by stoichiometric exchange with anions present at the mineral surface. The floatability of the unactivated mineral is poor since xanthate is precipitated in bulk without creating a hydrophobic surface on the mineral. At the activated mineral surface, xanthate is adsorbed in certain isolated patches (active spots) and thereby creates a hydrophobic surface. The hydrophobicity of the mineral is greatly improved by lowering the pH to 4.5.

Jan 1, 1972

By Fred Leighton

The least squares method of rock noise source location presented is shown to be more accurate and reliable than standard direct solution methods. This method is particularly effective in improving solutions from rock noise locations outside of geophone array boundaries. A least squares solution for a medium .in which the seismic velocity is the same in all directions is also presented. In this special case, one can solve for both the source coordinates and the velocity.

Jan 1, 1972

By H. V. Makar

An aluminizing dross which is accumulating as a waste material in substantial quantities was tested for possible use as a steel deoxidizer. This material, consisting mainly of aluminum, silicon, and iron, was used to deoxidize laboratory-scale melts ranging from 7 to 100 pounds. Oxygen analysis showed that the aluminizing dross was effective in reducing oxygen levels in steel. A direct comparison with aluminum wire showed the dross material to be at least as effective. Under similar test conditions with 7-pound melts, 3 grams of aluminum reduced the oxygen concentration from 210 to 175 ppm, while 4 grams of aluminizing dross (equivalent to approximately 2 grams aluminum) reduced the oxygen concentration from 250 to 170 ppm. An additional 4 grams of aluminizing dross produced a final oxygen concentration of 140 ppm.

Jan 1, 1972

By Emmet K. Oslen

Kaiser Steel Corporation, the pioneer steelmaker on the Pacific Coast, was founded by the late Henry J. Kaiser. In 1944 the Company purchased from the Southern Pacific Railroad an iron ore property 200 miles east of Los Angeles known as Eagle Mountain. Today the domestic operation of Kaiser Steel Corporation consists of the iron mine at Eagle Mountain; two coal mines, one each in Utah and New Mexico; an integrated steelmaking complex at Fontana, California; and several steel fabrication and erection facilities along the west coast. Kaiser Steel also has interest in Hamersley Iron, Ltd., Australia, and Kaiser Resources, Ltd., British Columbia. Eagle Mountain Mine is located about 80 miles east of Palm Springs and adjacent to the southeast corner of Joshua Tree National Monument. The area is one of the most arid in the world averaging only two inches of rain annually. Geologically, the mine is at the western edge of the Basin and Range Province which covers about one-half million square miles of the western United States. The Province is typified by north to northwesterly trending fault block mountain ranges separated by sediment filled valleys, Production has totaled over 82 million tons of finished products since the first shipment in June, 1947. Over 500 million tons of material have been mined from the deposit to date. Eagle Mountain Mine is noted for the pioneering use of the largest and most up to date equipment to mine and process its ore. In 1961 Eagle Mountain received the first fleet of 100-ton haulage trucks in the mining industry. There were thirteen semi-trailer units in the fleet. The first 12 to 17-yard size shovel in the mining industry was placed in operation at Eagle Mountain during 1962. Rotary drilling was introduced at Eagle Mountain in 1954 to replace churn drilling. Eagle Mountain was the first major mine to use metallized slurry when three aluminum slurries were introduced for primary blasting in 1962.

Jan 1, 1972

By L. L. Oriard

INTRODUCTION In order to make effective plans for the control of blasting effects, it is necessary to understand a few basic principles relating to the behavior of explosives. For the purposes of discussing this behavior, it is convenient to divide blasting effects into two zones. The first zone is the non-elastic zone in close proximity to the explosive charge where rupturing of the rock occurs. For this zone, our discussion will be oriented towards the factors which affect the rock breakage, and the means of controlling the limits of this breakage. The second zone is that zone more remote from the charge location where elastic vibrations are transmitted through the surrounding medium. In this zone, we are interested in the factors affecting vibration intensity, and the means of controlling the intensity so that no damage is done to structures, utilities, or excavated slopes. It has been easier to gather data in the elastic zone, because the stress levels are lower and time durations are longer. The instrumentation for obtaining data in this zone can be less rugged and less sophisticated. Consequently, more information of ad empirical nature has been gathered. In the non-elastic zone, there has been more dependence on theory, fewer measurements, and more questioning of the validity of the measurements. In spite of these questions, there has been an encouraging advancement in knowledge in recent years, both theoretical and empirical, of the effects that take place close to the source of an explosion. When discussing the problems encountered in rock excavation, we can simplify the terminology by referring to the physical phenomena encountered in the non-elastic zone as a problem in "over-break". The phenomena in the elastic zone could be called "vibration effects". Although there is some interdependence between the two, it is possible to control the rock breakage to neat surfaces and still have very high vibration levels. Similarly, it is possible to control the vibrations to moderate levels and still have a great deal of overbreak. THE ROCK BREAKAGE ZONE First, let us discuss the effects in that zone close to the blast source that we might call the non-elastic zone. This is the zone of cratering, breakage, rupturing, and fracturing. These effects will vary with the site conditions, and a meaningful, specific analysis could

Jan 1, 1972

1. What Effect Has Sulfur Or Vanadium (In The Oil) On The Steel With Your Burner? 2. Also, what is the decibel rating on the floor when your burner is on? AUTHORS' REPLY 1. There is no effect. 2. The decibel rating is 98-99 decibels.

Jan 1, 1972

By Inkap Choi

Asbestos is a broad term embracing a number of fibrous silicate minerals. These minerals look extremely fragile, yet their fibers have a tensile strength equal to that of piano wire. Chrysotile asbestos is the only mineral that can be woven into cloth, and its fibrous structure is, if anything, even more amazing than its remarkable ability to withstand heat. Because of its unique physical properties asbestos has achieved great industrial importance, and more than 3,000 current uses are known, ranging from use in the kitchen to use in space missiles. Because their minuscule fibers are eminently respirable, asbestos minerals have also found their way into the lungs of humans, where they apparently produce serious biological effects such as asbestosis and lung cancers. 1, 2,3 Because of both their usefulness and their hazardous properties, these minerals have attracted a good deal of attention from research workers during recent years. For example, the surface properties of asbestos minerals have been studied by many investigators. 4, 5, 6, 7, 8, 9 However, even for the important mineral chrysotile, the literature data are more or less conflicting. Pundsack4 measured a PZC (point of zero charge) of 10.1; Martinez and Zucker5 measured 11.8; Chwastiak reports 10.8-11.0; and Raddick measured three sepa-rate apparent PZCls at about pH 8.3, 10.0 and 10.9. More recently Trivedi8 reports 10.11. Naumann and Dresher9 have studied surface charge enhancement of chrysotile by metal ions, and describe how the mineral reacts with contaminantions. In the present paper, the mode of dissolution of magnesium and hydroxyl ion from asbestos minerals placed in water was studied by kinetic experiments involving rate at which these items leave the minerals. Also, some study was made of interaction between dissolved species.

Jan 1, 1972

By R. L. Tobie

The degree of automation that has evolved in the dumping and hoisting of ore at the 3A and 3B hoisting shafts of the San Manuel mine is discussed. Motormen underground now dump their own trains at shaft pockets with rotary car dumps which operate semiautomatically. The ore is then drawn out of the 1200-ton shaft pockets into measuring baskets in skip loading stations, loaded into bottom-dump skips, hoisted, and dumped into coarse ore bins on the surface, in a fully automated operation. In an underground control room on the 2075 level midway between 3A and 3B shafts, car dumping, skip loading, and hoisting systems are monitored on lighted control panels which mimic each step in the operation. Here skip loading and dumping are viewed on closed-circuit television.

Jan 1, 1972

By K. Blower

"Since there was no representative from Wesfrob Mines Limited, the information on their infra-red concentrate drying operation, which had been prepared by Mr. K. Blower, was presented by Mr, Dorland. Mr. Blower, in submitting the information, emphasized that their objectives in this operation were (a) to guarantee less than 90%, of flow-moisture in their copper concentrates and thus satisfy marine shipping regulation• and (b) to minimize capital costs, The infra-red dryers have satisfied these objectives.To control final moisture in the copper concentrate, current practice is to preheat the filter cake with steam in the disc filter hood and then conveyor-0r7 the concentrate with infra-red calrod heaters. The application of steam aids the system as follows:1) Improves vacuum pump efficiency.2) Lowers viscosity of filtrate (increased temperature},3) Preheats the cake prior to radiant heating. (150°F)The hot cake discharging from the filter ranges from 10.6 to 10.9% moisture. After radiant heating the moisture level is reduced to 8.5% - 9.7% depending on production rate. Further moisture loss occurs during conveying and transferring to the stockpile for a final shipment moisture ranging from 8.1% to 9.5%. Production rate is frail J to 5 dry short tons per hour.1) #23 Conveyor 18"" flat belt covered from filter discharge to transfer point with 7 heaters end-to-end. Drive - Reeves Vari-Speed, 31:4 ratio, type 332-10-18, class ""D"", driving through a 24:1 ratio Dodge reducer. Speed of Conveyor - 3,9 feet per minute to 19.6 feet per minute. (Speed has been established and is not changed as a rule from the present level of a1:out 15.)2) #23 Conveyor 24"" wide, 20° troughed belt covered with 21 heaters, end-to-end from loading point, Speed - Constant at 54,2 feet per minute."

Jan 1, 1972

By John C. Nigro

Bench scale and pilot plant research was conducted using dolomites (CaO,MgO) lime as the basic additive in the preparation of self-fluxed pellets from a typical magnetic taconite concentrate (5.57 S_2). The specific objective of this investigation was to ascertain the viability of the magnesia lime pellets in high temperature oxidizing and reducing atmospheres. Pellet basicity and induration temperature were major parameters affecting fired pellet quality; temperatures ranging from 1,200° to 1,250" C appeared to be the most favorable for production of self-fluxed pellets with basesities (B) above 1.0. Comparison of the mechani¬cal and metallurgical properties of regular (acid) and self-fluxed pellets (B 1.55) produced under similar conditions in a modified grate pelletizing machine showed that the self-fluxed pellets were more resistant to abrasion and to high and low temperature reduction disintegration, an important consideration in commercial application. The Plus 3 mesh Linder index increased from 68 percent (regular pellets) to over 90 percent (self-fluxed pellets). The reducibility and swelling indices of the self-fluxed pellets were found to be comparable to the regular pellets.

Jan 1, 1972

By W. Linwood Haden

Fullers earth has been mined since about 1920 in southwest Georgia and the adjoining area of Florida. In 1935, the mineral was named "attapulgite" after the source of a sample near the town of Attapulgus, Decatur County, Georgia. Mining and processing of the clay was described in a 1930 publication1 at a time when petroleum refiners were the major users. In the years since then, the uses and users of attapulgite have multiplied, and both mining methods and processing methods have been changed to optimize the clay for the new uses. A comprehensive review of the properties and applications of attapulgite 2 has been published. Only a brief review will be given here to explain the properties being sought and to show how these properties are optimized by mining and processing practices.

Jan 1, 1972

By G. W. Phelps

This discussion deals with the geology o£ the Tennessee-Kentucky ball clay deposits; their mineralogy and chemistry; methods of finding, mining and refining; and makes observations on reserves of and future prospects for these clays. Ball clays appear in ceramic formulas for manufacture of vitreous china sanitary-ware, electrical porcelains, floor and wall tile, dinnerware and artwares(l). This type of clay is used for refractory (2) and abrasive products(3), and as a suspending agent for ceramic glazes(4), engobes(5) and porcelain enamel slips(6). Although some ball clay is imported, probably 85-90 percent of ball clay used in the USA(7) is obtained from deposits in Weakley, Henry and Carroll Counties in Tennessee(8), and in adjacent Graves County, Kentucky(9). The term "ball", as applied to clay, probably derives from former mining practice in England whereby conveniently-sized blocks of clay were cut from moist clay beds by spading(10), The expression "ball" has no other technological significance. ASTM(11) defines ball clay as "a secondary clay, commonly characterized by the presence of organic matter, high plasticity, high dry strength, long vitrification range, and a light color when fired." This, and similar(12) definitions, applies to English ball clays but is not satisfactory for many American ball clays. Geology of the Tennessee-Kentucky Ball Clay Deposits Figure 1 shows that most commercial clay areas of the eastern United States lie near the edge of the Coastal Plain; a skew-shaped configuration of its landward boundary outlines the Mississippi Embayment(13), Near the apex of this basin a broad plain, with a rolling, Bullied topography(14), dips gently westward from the Tennessee River to bluffs at the edge of the Mississippi River flood plain.

Jan 1, 1972

By Norman A. Jull

"Factors which affect the separation achieved in a hydrocyclone are discussed and illustrated with graphs of some mathematical relationships.Definitions of separation and sharpness include comment on use of elutriation devices.A plea is made for better evaluation of field data prior to their reporting or use in calculations. Methods of evaluation are suggested, with samples of the relevant calculations.An example of the effect of percent solids errors is given, with computer printout and plotted corrected recoveries.INTRODUCTIONThe range of interest in cyclones runs from a simple demand for classification results to a detailed study of published equations defining cyclone characteristics. Probably this group covers as broad a range and, in an attempt to offer something for everyone, I will begin with general operating comments, then move on to more analytical topics. Ideally, an author would compose his paper after the discussion period, when he would have a better idea of the areas of special interest to his audience.Sor'1e of you may share our incurable fascination with classification, especially as performed in cyclones. It is amazing that such a simple device could be in use for more than 20 years and retain as much mystery as it does. Substantial parts of the mystery have been solved but some remains, to keep up our curiosity. There is at least one valid reason: the unusual compactness of this device, which makes internal observation very difficult. What other unit can you think of which performs such a complex separation between particle sizes, shapes and specific gravities at such high capacity? Retention time in a cyclone is typically 3 seconds!Mutual Agreement - In a cyclone, every parameter of geometry and of operation interacts with every other. In an orderly discussion of individual parameters it would be necessary to repeat, in every section, 11 if all other factors are equal"". Could we agree now, for our mutual convenience, that that phrase is clearly understood between us during the remainder of this paper?"

Jan 1, 1972

By Paul H. Lu, Fred D. Wright

Numerous laboratory tests and field measurements conducted by different persons have indicated that most mine rocks behave viscoelastically rather than elastically. Hence, for an accurate and realistic design of underground structure, the time factor should be taken into account, and the theory of viscoelasticity can be used. By considering the time factor, the time-safe-strength may be used for economical design instead of liberal safety factors with design based on the elasticity theory. The deflection and moment distributions on an elastic roof slab resting on elastic pillars have already been studied.l In this chapter, the stress- strain analysis for a viscoelastic mine roof resting on pillars of the same material or on supports of different material is first considered theoretically. Viscoelastic solutions for deflections, moments, and shears are de- rived from the elastic plate theory on the basis of the elastic-viscoelastic correspondence principle. The Laplace transformation technique is employed as the operational method in the mathematical treatment. The roof slab materials are represented by four different rheological models and four different loading histories are considered. The method of finite difference equations is employed for solving the partial differential equations, using FORTRAN programs to calculate roof deflections, moments, and shears. Numerical examples are given for one of the four models under two of the four loading histories with regular and staggered pillar patterns. The results are discussed in terms of the variance with time of deflections, moments, and shears as well as their variation in space due to the dimensions and configuration of the structure system. A viscoelastic slab resting on viscoelastic pillars or on elastic supports

Jan 1, 1972

By G. W. Reimers

Metastable pyrophoric wüstite (FexO, with x between 0.89 and 0.95) was found to be much easier to grind to colloidal state than were its stable disproportion products magnetite or iron. The grinding of polycrystalline magnetite appears to be complicated by the magnetic flocculation arising from interparticle attraction. This is superimposed on the attraction of a fluctuating electric dipole for a neighboring induced dipole. More than 85 pct of the tumbling time was saved by grinding antiferromagnetic wüstite instead of the ferrimagnetic oxide of iron (Fe304). Disproportionation of colloidal wüstite to the stable ferromagnetic and ferrimagnetic colloidal particles of alpha-iron and magnetite, respectively, was accomplished rapidly at temperatures above 250° C but below 570° C, the eutectoidal stability point of the wüstite phase.

Jan 1, 1972