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By Wayne D. Gould

The Cities Service Company's Pinto Valley mine and concentrator lie about 6 miles west of the town of Miami, Arizona at an elevation of approximately 4,000 feet above sea level. The concentrator started its first ballmill in July 74 and all six were available by November. Every effort was made to reduce capital costs, consequently, each unit process was studied critically to eliminate excess capital costs without loss of efficiency. Equipment selection was made on the basis of proven dependability and operating costs rather than on low bids. The result is a very workable plant with some important innovations. The concentrator is nominally 40,000 tons per day. The flowsheet is typical with 3 stage crushing, single stage closed circuit grinding, flotation, regrinding of rougher concentrate and cleaning of the rougher concentrate. The major equipment list is: 1 60 x 89 Traylor Primary Crusher 1 84" x 20' Stevens-Adamson Apron Feeder 3 7' x 16' Double Deck Tyler Screen 3 7' Nordberg Standard Crushers 6 8' x 20' Tyler Screens

Jan 1, 1975

By R. V. Ramani, V. T. Burgos, J. A. McClay

The data for Test I1 describes an underground bituminous coal mine operating in a 72 inch seam, with an estimated production rate of 4,257,000 tons per year. The system includes 15 continuous mining sections, conveyor belt haulage, and a rail network for supply and personnel transportation. The following section includes the input data sequence, annual cost report, and cash flow analysis "report for this data set.

Jan 1, 1975

Organic dyes such as nigrosine and sun yellow act as depressants for carbonaceous particles in the, flotation of sulphide ores. Depression is achieved when initially hydrophobic organic surfaces are made hydrophilic by preferential adsorption of dye molecules. Experimental studies, mainly on Mount Isa ores, indicate that dyes are adsorbed as planar anionic micelles attached to carbonaceous surfaces by van der Waals and ion exchange attractive interactions. Relationships appear to exist between the amount of organic matter on the surface of ground particles, the surface area of the particles, the "saturation" adsorptions of dyes, and the degree of difficulty experienced during froth flotation.

Jan 1, 1975

By Henry N. McCarl

Lightweight aggregates include a variety of mineral and rock materials used to provide bulk in concrete building units (block), light- weight structural concrete, and precast concrete units, as plaster aggregate, insulating fill, and other structural and/or insulation purposes. They are distinguished from other mineral aggregate materials by their lighter unit weight- 80 to 100 pounds per cubic foot (pcf) or less for loosely packed lightweight aggregates as compared to 125 pcf or more for crushed stone, sand, gravel, air-cooled slag, and other more common mineral aggregates. The various lightweight aggregate materials may be classified into four groups as follows: 1) Natural Lightweight Aggregate Materials-prepared by crushing and sizing natural rock materials such as pumice, scoria, tuff, breccia, and volcanic cinders. 2) Manufactured Structural Lightweight Aggregates-prepared by pyroprocessing clay, shale, or slate in rotary kilns or on traveling grate sintering machines. 3) Byproduct Lightweight Aggregates-prepared by crushing and sizing foamed and granulated slag, cinders, and coke breeze. With the exception of processed slag, this group is becoming less important as time passes. 4) Manufactured Insulating Ultralight- weight Aggregates-prepared by pyroprocessing ground vermiculite or perlite. This chapter will focus on the use of natural lightweight aggregates and manufactured insulating ultralightweight aggregates, and both the production and use of manufactured structural lightweight aggregates with some comments on byproduct materials. Detailed discussion of the production and use of both expanded and air-cooled slag is presented in a separate chapter in the utilization section of this volume, and there are separate commodity chapters on vermiculite, perlite, pumice, and volcanic cinders. Discussion of the commodities covered elsewhere in the book will be limited to observations on their utilization and relation to other lightweight aggregate materials. All materials considered as lightweight aggregates are derived from some initial natural raw material. While historical definitions have included such organic materials as straw and peat as lightweight aggregates, the discussion in this chapter will restrict itself to lightweight aggregates derived from mineral or rock materials. Thus while the actual lightweight material in use may be a manufactured product, it is derived from an ore or raw material that is obviously a mineral resource. In this context, then, the reserves of raw materials for lightweight aggregate use may include iron ore and flux stone (the components of blast furnace slag) as well as coal (the raw material from which cinders are derived) as well as those clay, shale, and slate deposits that display the characteristics of bloating or controlled expansion when subjected to elevated temperatures (1600 to 2400°F.).

Jan 1, 1975

A review of major mineral processing and extractive metallurgical developments is made and current areas for research are discussed.

Jan 1, 1975

By Michael L. Boucher

Copper and nickel sulfides occurring in the Duluth Complex of northern Minnesota were examined at the Bureau of Mines, A microscopic study was undertaken to determine the mineralogy and paragenesis of the ore minerals. Eighty-two samples were taken from one deep diamond drill core located near Babbitt, Minn. Modal analyses are presented for the Duluth Complex rocks and for the are minerals in the major mineralized zone. The major sulfide minerals are chalcopyrite, cubanite, pyrrhotite, troilite, and pentlandite. Results of this investigation suggest that the mineralization is related to the structural features of the enclosing rocks: pores, open fractures, and cavities. The pyrrhotite-troilite-pentlandite assemblage is believed to have formed from an immiscible sulfide melt, probably associated with the troctolitic rocks. Most of it settled to the very porous base of the Duluth Complex, and to the other porous zones near xenoliths; small portions were trapped higher in the section. A later introduction of a copper-rich sulfide melt replaced some of the pyrrhotite-troilite and oxides, and filled in the remaining open spaces and fractures in the Duluth Complex and those of the adjacent footwall rock.

Jan 1, 1975

By Barnett LJ

The Kellogg slag fuming model is extended to apply to the Port Pirie plant which uses recuperative heating of secondary air. Exten- sive investigations of plant operations pro- vide parameters for use with the model, and verification that the resulting model provides simulation which is very close to actual plant performance. The model is used to_deter- mine optimum slag fuming operating conditions, and the results of several other investigations with the model are briefly described.

Jan 1, 1975

A review is presented of techniques cur- rently in use, or being developed, to enable the determination of virgin rock stress at consid- erable depth (> 1000 m) from small diameter sur- face drill holes (

Jan 1, 1975

By Eric S. Cheney

Sulfur isotopes are best used in conjunction with other geological studies to determine the origin of known deposits; concept-oriented exploration programs can then be developed to find similar deposits. Geochemical processes are capable of causing different S '41S" ratios in the minerals and fluids participating in natural reactions. Because the magnitude of the resultant isotopic difference is inversely proportional to temperature, sulfur isotopic studies can be used to determine the source of the sulfur in high temperature deposits. The narrow spread of sulfur isotopic values from ores related to cupolas of felsic intrusions suggests that the sulfur in the ore-forming fluids was derived from a fairly uniform source (such as the intrusions) rather than by heated ground water from the adjacent country rocks. However, geologic and isotopic evidence suggest that the sulfur of many nickel sulfide ores may have been derived from the country rocks rather than the associated mafic igneous rocks. This sulfurization hypothesis implies that mafic intrusions in sulfur-rich country rocks should be prime exploration targets. Sulfur isotopic analyses of sulfides in the mafic rocks may indicate whether sulfurization has occurred. In equilibrium geochemical reactions S" is concentrated in the minerals with the greater bonding strengths. Thus the isotopic compositions of coprecipitated sulfides that have not undergone exsolution may be used as geothermometers and to distinguish multiple periods of mineralization, post-ore metamorphism, etc. The sulfur isotopic compositions of coexisting sulfides at Butte, Mont., indicate that the copper minerals did not originate by simple replacement of pyrite. Geologic and isotopic evidence suggest that the mineralogical and isotopic zoning at Butte formed almost isothermally during the geochemical evolution of the ore-forming fluids upward and outward from the Central zone. Unidirectional reactions cause enrichment of S" in the products. At low temperatures the isotopic effects of bacterial and inorganic reactions are difficult to distinguish. Anaerobic sulfate-reducing bacteria apparently were responsible for the sulfur of Gulf Coast salt domes and for diagenetic pyrite in sandstone-type uranium deposits. Sulfur (and carbon) isotopic data suggest that the roll ore bodies of sandstone-type uranium deposits originated by limited inorganic oxidation of diagenetic pyrite rather than by bacterial activity. Accordingly roll ore bodies should be most numerous and thickest against those portions of the sandstone aquifer that contain pre-ore pyrite.

Jan 1, 1975

By John F. Papp

The Bureau of Mines has sampled microstructure of low-pressure flat flames by mass spectrometer for normal methane-oxygen-argon and for methane-oxygen-argon-bromotrifluoromethane flames. The physical and chemical phenomena, and the method of analysis of mole fraction data to evaluate net reaction rates are here considered in detail. Included is a computer program listing with output on one flame. Chemical species considered are CH4 , CO, CO2, H, H20, OH, Ar, H2, O2 , O, H2CO, CH3 , CF3Br, HF, HBr, Br, CH3Br, HCO, F2CO, CH2 CF2 , H02.

Jan 1, 1975

The Bureau of Mineral Resources has been engaged in regional geological and geophysical field work in the Alligator River and Cobourg Peninsula area since 1971, following the discovery of major uranium deposits. Geophysical work commenced with a regional airborne magnetic and radiometric survey which was followed up by some helicopter and ground work in August 1973. The interpretation of the earlier radiometric work is presented in conjunction with the results obtained from the follow-up work. Analyses of 100 outcrop and drill core samples collected have provided basic information on the physical properties and concentrations of uranium and thorium in various rock types. The uranium determinations were made by X-ray fluorescence and delayed neutron analysis, good agreement being obtained between the two methods. X-ray fluorescence was the main analytical technique used because of its ability to produce both uranium and thorium determinations.

Jan 1, 1975

By R. A. Busch

Sludge ponds of fine coal, fine soil, and water created behind large piles of coarse coal waste can present hazardous conditions; this is a Bureau of Mines report of the subsurface physical property data developed on the fine coal waste materials that make up the core areas of two typical coal waste impoundments. These data will help define more completely the engineering properties of this problem area of the structures. Additional calorific, chemical, and mineralogical data were obtained on the coal waste materials to determine possible uses or development of byproducts. The possibility of extracting alumina from coal ash was also investigated.

Jan 1, 1975

By Thomas V. Falkie

The new international fact of life that has emerged in the 70's is that foreign energy sources can no longer be considered either reliable or low in price. As a result, the United States is turning its full attention to its domestic energy resources. The figures about proved domestic reserves are often used to reassure us about the Nation's energy future: assuming a 50 percent recovery factor, there are at least 219 billion tons of recoverable bituminous coal and lignite, of which 31 percent is available by surface methods; proved reserves of crude petroleum and natural gas liquids total 34.3 billion barrels and 6.4 billion barrels, respectively. There is also about 4 billion tons of recoverable anthracite coal, a premium low-sulfur fuel of high heating value, which is all but priced out of the market because of the high costs of producing it. Total fossil fuel resources are even larger, although there are no guarantees concerning how much might become usable, and when, and at what cost. The figures, however, are impressive. They include the equivalent of about 200 billion barrels of oil potentially recoverable from high grade oil shale; 100 billion barrels in "heavy oil" deposits; and the equivalent of 25 to 35 billion barrels of oil in domestic deposits of "tar sands," and substantial quantities of conventional oil and gas resources. There is also the prospect of a significant increase in electric power generation

Jan 1, 1975

By Paul Kents

The Canadian Javelin Limited Cerro Colorado copper-porphyry deposit in Panama, possibly the largest known copper-porphyry, contains between 1350 and 450 meter elevations, drill proven and probable ore in excess of 3.0 billion tons averaging 0.65% of copper equivalent. The deposit is located in the Central Cordillera Range, straddling the Continental Divide at 1500 meter elevation. Local topography is very steep. Accessibility is difficult, all logistics made by helicopter, and only recently a 52 km. road from the Pan-American highway was completed into the area. The deposit was discovered in 1969, and since then 75 shallow exploratory holes and 98 deep holes, the deepest 1340 meters, totalling 45,000 meters have been drilled. Deep holes were drilled at the corners of a regular rectangular 150 meter grid.

Jan 1, 1975

Guide Io Ihe Preparailon Of Papers For Publication In The Journal Of The South African Institute Of Mining And Metallurgy The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal. All papers must meet the standards set by the Council of the Institute, and for this purpose all papers are referred to at least two referees appointed by the Council.

Jan 1, 1975

By Smith I. W

Australia has, and faces, a growing problem with regard to the ability to meet the demand for liquid fuels from indigenous petroleum resources. The position for natural gas is better but there is no room for complacency. Since the coal resources are relatively extensive, interest in the prospect of producing liquid fuels from coal is in- creasing. The approaches to the production of gaseous and liquid fuels are briefly reviewed and the present status of coal conversion technology is discussed. Many problems remain to be solved and it is estimated (in the USA) that another 8-10 years will be required before any of the processes for liquid fuel production are considered sufficiently efficient and viable to go to a demonstration plant. Coals represent complex feedstocks and the effects of variations in coal properties on oil-from-coal processes are not fully understood. The thermal efficiencies of various coal conversion processes are considered in relation to their impact on coal requirements. The production of Australia's present requirement for liquid fuels by the only commercial process in operation would require a four-fold expansion in the local consumption of coal. Any assessment of the suitability of oil-from-coal processes currently under development overseas for Austra- lian coals and requirements must take heed of the differences in coal properties and motivation. The economic via- bility of processes for producing oil from coal will continue to be uncertain because of the large difference between the World price for crude oil and the actual production cost.

Jan 1, 1975

By J. D. Miller

The processing of residues derived from various operations in the mining and metallurgical industry for by-product recovery is becoming more prevalent. A principal target for by-product recovery is flue dust produced by conventional smelting operations. Flue dust from zinc smelters has been processed for many years for the recovery of cadmium (1,2). The cadmium recovery technique which consists of a selective sulfation roast, followed by a water leach and zinc dust cementation, produces a lead cake residue (see chemical analysis in Table I), which consists primarily of lead sulfate.

Jan 1, 1975

By Harold E. Thomas, Samuel S. M. Chan, Nicholas Bada

The U.S. Bureau of Mines has developed a technique for locating and evaluating bedding plane cracks in mine roof by an air-injection and hot-film flow logging technique. It is ultrasensitive to cracks and is especially useful for detecting the early stage of crack development. Potential applications include: (1) correlation with roof sag measurements, (2) locating cracks for grouting, (3) comparison of mechanical and resin roof bolt effectiveness, and (4) possible delineation of the fracture zone to confirm the arch hypothesis. The required equipment is inexpensive and simple to operate.

Jan 1, 1975

By Ernest L. Corp

Seepage forces computed by a finite-element flow program are combined with gravity forces in an elastic-plastic stress-analysis program to determine the stability of mine-waste slopes. Computer output provides a cross-sectional plot of the dam or embankment showing the safety factors for each element. The combined finite-element program called SEEP-SLOPE was used to analyze several trial embankments and the 1972 Buffalo Creek Dam failure Safety factors computed by the finite-element method (FEM) were compared with those computed by Bishop limiting-equilibrium method. For individual slip circles, there was little correlation between the factors of safety computed by the two methods. Both predict failure, but FEM shows a different mode of failure plus development of potential failure zones not indicated by conventional methods. Besides having a better theoretical basis than the Bishop method, FEM requires no assumptions regarding the location or geometry of the failure surface. As a result, the program will show progressive development of a failure zone, and areas can be pinpointed where remedial measures should be taken. In addition, nonhomogeneous cross sections can be analyzed, and zones of potential piping can be defined.

Jan 1, 1975

By H. R. Appell

The Bureau of Mines studied the conversion of a variety of cellulosic wastes, for example, sawdust, bovine manure, sewage sludge, urban refuse (free of metal and ceramics), etc., to heavy oils. The objective of the investigation was to determine the scope of the reaction and elucidate the chemistry involved. The reactions took place in the presence of synthesis gas and water or carbon monoxide and water under conditions of elevated temperatures and pressures. Waste conversions above 90 pct, often near 99 pct, with oil yields in the range of 40 to 60 pct, were obtained in the temperature range of 250° to 425° C and pressure range of 1,500 to 4,000 psig. Because mild conditions were sought, most of the experiments were conducted at temperatures of 250° to 350° C and pressures of 1,500 to 3,000 psig. In general, lower viscosity products were obtained at higher reaction temperatures. Conversions and oil yields were significantly increased by operating in the presence of a high-boiling oil; either anthracene oil or oil recycled from the process was satisfactory. Synthesis gas containing 50 pct carbon monoxide gave satisfactory results as a replacement for carbon monoxide. Cobalt molybdate on alumina catalyst, used with sodium carbonate, gave a product of lower viscosity and lower oxygen content than sodium carbonate used as the sole catalyst. The waste-to-oil process has been successfully investigated in continuous flow equipment as well as in batch autoclaves.

Jan 1, 1975