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Black coals occur in most of the major sedimentary basins in Australia. In addition to the better known Permian coal occurrences of the Sydney, Bowen, Oaklands and Galilee Basins, coals of Permian age occur in the Arckaringa Basin in South Australia, the Bonaparte Basin in Northern Territory and the Collie, Perth and Canning Basins in Western Australia and the Tasmania Basin in Tasmania. Coals of Triassic age occur in the Ipswich Callide and Tarong Basins in Queensland, the Tasmania Basin in Tasmania and the Leigh Creek area in South Aus- tralia. Coal bearing rocks of Jurassic age occur in the Mulgildie Basin and Maryborough Basins in Queensland and in both the Queensland and New South Wales portions of the Clarence Moreton Basin and Surat Basins. They also occur in the Perth Basin in Western Australia. Rocks of Cretaceous age known to contain coal occur in the Styx, Maryborough and Laura Basins in Queensland, the Gippsland Basin in Victoria and both the Queensland and New South Wales portions of the Surat Basin. The coal measures have been deposited in a variety of sedimentary environments and the coals vary widely with regard to thickness, extent, banding characteristics, maceral and ash content. However, they are generally of low rank and most are suitable only for steaming.

Jan 1, 1975

By R. V. Ramani, C. B. Manula, A. Owili-Eger

Recently, a collection of programs that will simulate a ventila¬tion system with extensive analyses and report-generating capabilities and error diagnostics has been developed (Didyk, 1974). It has pro¬visions to handle air injections, methane or gas emissions, and leakage. Additionally, it will solve problems where fixed and/or maximum air quantities are specified for some airways. Finally, the simulator has been structured to be extremely modular so that additions and revisions to the model can be easily made. The general aspects of the information flow and logical structure of the mine ventilation simulator are shown in Figure 14. The output from the methane emission model is input into the ventilation simulator for calculation of the concentrations in all branches of the network. The methane model and the ventilation simulator provide powerful tools for the analysis and planning of mine ventilation systems. INPUT DATA REQUIREMENTS In all of the mathematical models, several coefficients that de¬fine the characteristics of the ventilation system are used. For the ventilation simulator, these include the frictional characteristics of the ventilation regulatory devices. Considerable work has been done on the experimental determination of these coefficients for smooth pipes and well-defined mediums, but only limited data are available for actual mining conditions. FRICTION FACTORS: The frictional characteristics of mine airways affect both the dispersion of pollutants and air flow through the roadways,. They

Jan 1, 1975

By John W. Nebgen

Surface water quality is determined by complicated interactions between water and land. Runoff--the flow of waters in surface streams and rivers-¬represents the total amount of water collected in a drainage basin or watershed that appears at the outlet of the basin. As the water flows through the basin, it is in contact with land and can pick up impurities from the land. Thus, surface waters are not pure--they contain impurities, or "pollutants," in vary¬ing concentrations determined by the nature of the land which they drain. The composition of surface waters thus tends to represent a steady state equilibrium between interactions of water and land. However, when man utilizes the land in the drainage basin or watershed, the natural equilibrium between water in the runoff and the land is disturbed. Such disturbances usually effect adverse changes in surface water quality, as new equilibrium conditions between land and water are established. These adverse changes in surface water quality can be thought of as "nonpoint pollution." Esti¬mation of nonpoint pollutant loads thus ultimately reduces to determining the magnitude of the differences between water qualities before and after man's disturbance of land within a watershed. The important key in making such an estimation lies in the determination of water quality in the natural or "back¬ground" condition of the watershed. In subsequent discussion in this paper, tools for making an estimation of background water quality will be described.

Jan 1, 1975

By Charles Bruce

Three years ago, at a reception given during the Steel Institute meeting in New York, I heard the remark, "A new formula must be found for foreign investment." This was immediately following the takeover of U. S. Steel's Matilde operation in Bolivia. Recently, at the World Mining Congress in Lima, Peru, the subject of foreign investment was still a lively topic of conversation. The nationalization of the copper mines in Chile and recent trends in the "Third World" have made all but a few extremely wary of investment anywhere other than in the ?stable? countries. Now, the fallibility of this philosophy has been demonstrated in such "stable" countries as Canada, Australia, and Ireland. Yet, nationalization is not new to us. The events in Chile were classified as disastrous to the affected companies, but so were the effects of nationalization to the majors in Bolivia in 1952. Mexicanization of the mining industry in Mexico was considered impractical by many. Now, those who accepted it are finding it to be workable.

Jan 1, 1975

By E. S. Shedd

Amenability studies were conducted by the Federal Bureau of Mines on an electrooxidation technique for the extraction of mercury from cinnabar ores, particularly those that are too low in grade to be furnaced or retorted economically. Oxidation was accomplished by electrolysis of the ore while slurried with brine. Mercury was dissolved through the formation of the soluble tetrachloro mercury complex, HgC142-. Mercury extractions ranged from 90 to 98 percent in 4 to 6 hours of processing time when tests were made on eight different types of cinnabar ores containing from 0.7 to 18 pounds mercury per ton ore. Salt concentration was varied from 4 to 10 weight-percent depending on whether Pb02 anodes and iron cathodes were used or whether graphite was used for both electrodes. Power consumption ranged from 17 to 64 kilowatt-hours per ton of ore treated. Ninety-nine percent of the mercury was recovered from pregnant solutions by precipitation on an active metal such as zinc, followed by distillation of the resulting amalgam at 600° C.

Jan 1, 1975

By John L. Shafer

A process for the conversion of stibnite (Sb2Sj) concentrates, crude antimony oxide, or metal to a pure cubic antimonous oxide (senarmontite) has been developed on a laboratory scale. The conversion of stibnite to senarmontite has been piloted. The high purity of the final product is the result of forming antimony trichloride as a low temperature distillable intermediate. To obtain the antimony trichloride the stibnite, or crude oxide is slurried in molten antimony trichloride and reacted with gaseous hydrogen chloride. Antimony metal is oxidized to the trichloride with chlorine. The hydrogen sulfide produced from the hydro- chlorination of stibnite can be upgraded to a strength of 95% or greater for further treatment. The crude antimony trichloride is separated from the gangue by a preliminary evaporation and then is fractionally distilled and the trichloride distillate has less than 50ppm of arsenic and lead combined (the most troublesome impurities in antimony processing). The purified antimony trichloride is then hydrolyzed with sodium or ammonium hydroxide to produce the cubic form of antimonous oxide (senarmontite) to the exclusion of the rhombic form (valentinite) which is photosensitive. The advantage of this process is the ability to treat a wide range of antimony ores, concentrates, and metal to yield a high purity oxide in a controllable range of particle sizes.

Jan 1, 1975

By William M. Warren

Recent sinkhole activity in carbonate terranes of Alabama has resulted in damage to transportation lines, structures, utility lines, and property in general. Active sinkhole development and subsidence has been well documented in Alabama, Florida, Pennsylvania, and South Africa. An excellent example of the potential danger resulting from this activity is the spectacular collapse under a South African gold ore crusher plant that resulted in the death of 29 men in 1962. Due to the severity of the problem in certain localized areas in Alabama, a detailed investigation is being undertaken by the Geological Survey of Alabama and the U. S. Geological Survey. One of the most promising techniques is the application of aerial photography and thermal infrared imagery. Conventional and modern remote-sensing techniques are being used in Alabama to locate and define areas of sinkhole activity and to determine which areas are most prone to its occurrence.

Jan 1, 1975

By Ron Board

"Probably the only thing that can he said about conveyor belt scales without fear of contradiction is that they have been responsible for as much or more puzzlement, argument and frustration than almost any other piece of equipment commonly found in ore processing facilities. To be sure, there are certainly a good number of satisfactory installations, some of these having been achieved through forethought and careful consideration in the early stages of plant design, while others seem to owl their success to what seems to be little more than good luck or white witchcraft; and it might also appear that black witchcraft or other gremlins are solely responsible for the poor performance of many belt scales that enjoy well-designed installations with apparently good operating conditions.This paper is intended to acquaint users with the major operational reasons why belt scales seem so fickle (and downright ornery too), and establish some reasonably simple test standards against which the performance of scale hardware can be measured. Then it shall be shown how the design flexibility of electronic scale systems can offer particular advantages in overcoming some of these everyday problems in a practical way, and without undue inconvenience to plant operations."

Jan 1, 1975

By Woods PW

Consulting Engineers have been used in the mining and metallurgical industries for many years. The traditional role of the consultant overseas has been one of assisting with conceptual design right through to con- struction and commissioning as well as on occasion acting solely in specialist fields. This role developed because mining companies wished to concentrate on building up the permanent organisation they require to operate their mines and treatment plants without the traumas of increasing staff for the design and construction period and reducing it on completion. In Australia where there have been few individual minerals projects of magnitude (until recently) companies have looked after their own detailed engineering and construct- ion management employing consultants mainly in specialised fields.

Jan 1, 1975

By Donald N. H. Chi

This Bureau of Mines report is concerned with a theoretical study of the aerodynamic response of a single mine entry to flame-induced disturbance. The unsteady, one/dimensional, compressible flow equations were solved using the method of characteristics. This study was primarily undertaken to determine the feasibility of extending the method of characteristics to study the aero-dynamic response of complex mine networks. It was demonstrated that although the technique has merit in studying the complex wave interaction in single entries, it appears to be too unwieldly and too expensive for network analysis. Effort was also directed at a further study of the dispersion and filtering characteristic of aerodynamic disturbances in mine passageways.

Jan 1, 1975

By Shiels O. J

The major Permian coal deposits of N.S.W. are in the Sydney-Bowen Basin and associated small deposits occur in structurally isolated areas; a further deposit is present in the Oaklands Basin. - The Sydney-Bowen Basin in New South Wales comprises the sub basins, the Sydney Basin and the Gunnedah Basin. Coal measures in these basins are near the top of the Permian succession and within and below an underlying marine sequence. The coal deposits can be conveniently described in units in which the coal geology is homogeneous. The Clyde Coal Measures and Yarrunga Coal Measures contain no seams of economic significance and occur beneath the marine beds in the south of the Sydney Basin. The Greta Coal Measures are economically significant and represent a brief interlude in the marine sequence in the north of the Sydney Basin and equivalents are present in the east of the Gunnedah Basin. The Tomago Coal Measures crop out above the marine sequence east from the Lochinvar Anticline and dip southeast to uneconomic depths. The Newcastle Coal Measures are historically and economically very important and overlie the Tomago Coal Measures and these measures will continue to be important although future mining will be faced with greater depths. To the west of the Lochinvar Anticline the Singleton Coal Measures, equivalent to the Tomago and Newcastle Coal Measures, crop out. This unit represents the thickest development of coal measures in the State and has a very large potential for both open cut and underground mining. Equivalents of the Singleton Coal Measures, the Black Jack Coal Measures and the Booroomin Group crop out on the east side of the Gunnedah Basin and probably are widespread across the Basin. They have less economic potential than the Singleton Coal Measures. In the southwest of the Gunnedah Basin, Illawarra/Singleton Coal Measures crop out over extensive areas and possibly have a large potential for underground mining under low cover. The Illawarra Coal Measures are exposed along the western margin of the Sydney Basin and thicken as they dip into the Basin across a shelf. The outcrop area is currently mined and the shelf has considerable potential for future mining. The highest rank coals in the State are in the Illawarra Coal Measures in the south of the Sydney Basin. The deepest coal mining is in this area and its continuing success is of great importance to the future exploitation of the resources of the Basin. The Tomago, Newcastle, Singleton and Illawarra Coal Measures extend into and meet in the central area of the Sydney Basin but they are under thick cover and are not considered to be economic at present. Permian coal measures occur in isolated areas in the New England Fold Belt and have limited economic potential. The Oaklands Basin in the south of the State contains a large reserve of low rank coal.

Jan 1, 1975

By A. Himsley

"There is an ever-increasing demand these days for efficient methods of removing metals from solutions especially for selectively recovering a particular metal from a mixture of metals in solution.Up until the mid l 930's the only methods widely practiced for such separations involved precipitation techniques or electrolysis. Both these methods have limitations and indeed can only be used for certain metals.It is only within the last 40 years or so when synthetic ion exchange materials became available that chemists in industry and universities have been able to apply ion exchange techniques to a wide variety of separations that not only would be impossible by precipitation methods but which are now achieved with much greater efficiency.Ion Exchange TechniquesIon exchange is a unit process that can be applied using either liquid ion exchangers or solid resin particles. Liquid ion exchange - or solvent extraction as it is often referred to - is used in a number of special areas dictated mainly by the nature of the separation.On the other hand, ion exchange resins are much more widely used and consequently a great deal more is known about their application to a variety of metal separations.In both systems there is a loss of the ion exchange material which in the case of solvent extraction results in hydrocarbons going to waste. The ion exchange resin systems lose resin in the form of small particles, referred to as ""resin fines"", and these are insoluble.The loss of liquid ion exchanger is due to the fact that it is slightly soluble in water and consequently the loss is a function of the volume of liquid with which it comes into contact and is not related to the amount of metal processed."

Jan 1, 1975

By Thomas M. Turner

Open pit mining, always a demanding task, faces two relatively new problems today: 1. Availability of equipment. Moderate to large draglines can take as long as 6 years from date of contract to date of operation. 2. Environmental restrictions. Strip mining in the minds of environmentalists compares unfavorably on the scale of social desirability to the activities of Jack the Ripper and Attila the Hun. Specifically, lowering of the water table to allow strip mining in the dry is being looked upon with increasing disfavor. The modern dredge offers relief in both problem areas. Delivery on a major dredge might run 18-24 months rather than 60; and lowering of the water table is precluded, thus minimizing environmental objections. In addition, a lower first cost and potentially increased efficiency may offer real advantages to the miner who is forced away from his traditional mining methods. This talk is dedicated to acquainting the miner with dredge types, advantages, and limitations.

Jan 1, 1975

By Robert B. Fulton

Commercially, celestite (SrSO,) is the only significant strontium mineral. Among other strontium-bearing minerals, only strontianite (SrCO,) occurs commonly; however, it is not an item of commerce. The principal production of celestite is in England, Mexico, and Spain. New production is now coming on stream in Canada. Consumption is mainly in the United States. Lesser quantities are consumed in Japan and Europe. Main uses are for the manufacture of strontium carbonate and nitrate. The carbonate is used in glass for TV tube face plates and in ferrites for magnets. The nitrate is used in pyrotechnics to which it imparts a characteristic brilliant red color, mainly in safety flares. Minor amounts of strontium compounds are used in electrolytic zinc manufacturing and very small quantities in greases, ceramics, soaps, alloys, and pharmaceuticals. Specifications and Prices Typical celestite specifications for the carbonate and nitrate markets are as follows: [ ] Celestite currently shipped from Mexico for carbonate manufacture tends to be slightly better than these industry specifications, assaying about 92-93% SrSO, with less than 1% BaSO, but it is generally below the 95% minimum required for nitrate production. Contract prices for celestite are approximately $32-34 per st at U.S. Port of Entry in 50 to 60-ton carload lots for Mexican material. Spot prices are generally reported as low as $20 per st but are for minor volumes. A recent sale of surplus from the U.S. stockpiles, announced by the General Service Administration (GSA), was 4005 st sold to Du Pont for $140- 455 or $35.07 per st. British celestite, ground, washed, and graded, 95% SrSO, bulk, ex- works, 240 mesh, is quoted at £ 28.75 per mt in British trade journals, and a recent figure quoted for crushed lump material was $36.00 per st f.0.b. vessel Bristol Channel port (1973). Specifications of manufactured carbonate made from celestite and sold in two grades, one to the glass industry, the other to the electronic industry for ferrites, are given in [Table 1]

Jan 1, 1975

By J. J. Harrington

The pH control system at Kennecott Copper Corporation's Nevada Mines Division concentrator consists of two independent systems, lime dilution and lime addition. Lime dilution is accomplished in a mixing tank where slaked lime and water are introduced proportionately. The desired dilution of the milk of lime is determined by the electrical inputs provided by eight pH probes, one per grinding section. The inputs are averaged and applied to a time base generator. The summation output of the time base generator determines the proportion of lime and water that are to be mixed and applies this input to a voltage sensitive switching device. The switching device provides a signal to one of two relays which will add either slaked lime or water, dependent upon the summation output. The entire cycle is based on a two-minute repetition rate to allow for sufficient mix time. Responsivity is controlled by maintaining a limited maxi- mum solution level in the mix tank. Lime addition is controlled independently within each grinding section. The electrical input from the pH probe in a given section controls the solenoid valves which provide lime to each of the ball mills. The valves remain open within a time range capable of maintaining the pH of flotation feed at a given set point.

Jan 1, 1975

By A. J. MacKellar

The economic viability of any project is generally assessed on an evaluation of the total capital constructed costs along with operating costs, owner's costs and market conditions. This paper will be directed to the role that Cost Engineering plays in the development of the capital costs and the cost control techniques applied thereto.

Jan 1, 1975

By E. G. King

Enthalpy increments above 298 K were determined by the Bureau of Mines for magnesium hydroxide (brucite) between 298 and 900 K by the method of drop calorimetry. Enthalpy and entropy increments from this investigation were combined with other data from the literature to calculate absolute entropies, free energy functions, enthalpies of formation, Gibbs energies of formation, and equilibrium constants of formation from 298 to 900 K. By the use of published PVT data for water, a table of Gibbs energy change was given for the reaction MgO (periclase) + H2O = Mg(OH)2 (brucite) as a function of temperature and pressure.

Jan 1, 1975

By James L. Hendrix, Pat Vreeland, Hamilton Vreeland, Marcel F. DeGuire, Peter L. Comanor

A study of the ground area surrounding the Getchell, Nev., gold mine mill tailings was conducted so that a better understanding of the effects of arsenic toxicity on Upper Sonoran vegetation could be obtained. The Getchell area was selected because of the known high values of arsenic currently contained in the tailings waste (1% or higher). Mill wastes as well as the scrubber product As2O3 are contained in the tailings pond. In order to determine the effect of the tailings disposal on the surrounding vegetation, plots and line-transect techniques were employed to obtain plant ecological information on the area surrounding the ponds, and also non-affected control plots. Data for percent ground cover, species frequency, and plant vitality as a function of distance from the tailings ponds were collected. In an attempt to isolate naturally occurring factors for varying plant communities from induced factors derived from the close proximity of the tailings, soil cores were

Jan 1, 1975

By Thomas A. Simpson

Heretofore, underground coal mines in Alabama have operated under only 60 to 360 meters of cover: however, new mines (at least 5 in the early opening or development stages) will be operating under cover ranging from 600 to 660 meters. With increased rock confining pressures, roof stability problems will become more critical. Initial studies in two 7 ½ -minute quadrangle areas in the Warrior coal basin of Alabama indicate that the orientation of certain lineament and fracture-trace modes mapped from ERTS-1 (Earth Resources Technology Satellite) imagery correlate closely with the strike of joint and fault modes. High altitude (118,000 m) U-2 aircraft data were used to support these findings. In addition, over 50 percent of the normal faults mapped in the study area could be directly correlated with ERTS and U-2 lineaments and fracture traces. These correlations provide clues to the structural development of the Warrior coal basin and may, in turn, be used as a guide to the prediction of roof-stability conditions in advance of mining.

Jan 1, 1975

By R. E. Pennington

My subject this morning is coal liquefaction technology. Actually, coal liquefaction involves a number of technologies in a very complex system. The first slide shows the major components of such a system with arrows to indicate appropriate flows. The components are the facilities for coal feed preparation and handling; the coal hydrogenation or base liquefaction section; facilities for product separation and recovery, and in addition, facilities for the production of hydrogen from coal-based sources. A very rough break- out of the investments involved in these areas is given at the bottom of the slide. Investment is spread about equally among the three areas of operations Another way of looking at it is that the investments in what might be called support facilities are of the same magnitude as the base investment in the hydrogen facilities. Therefore, it is appropriate in a discussion of coal liquefaction technology to treat it as a system composed of a number of technologies. The next slide lists the various functions in the feed preparation section along with an indication of technology status. Storage, crushing, grinding, drying of coal all have been in commercial practice for a number of years. The slurrying and pumping of coal at least in water slurries, is practiced commercially also. The heating of coal slurries in oil to high temperatures under pressure is not in commercial practice and development and testing is going on by a number of people in this area. Some rather complex phenomena occur when coal oil slurries are heated to high temperatures.

Jan 1, 1975