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By J. B. Hiskey, G. Ramadorai

This paper presents the kinetics of leaching pure wulfenite (PbMoO,) with sodium sulfide solutions. Wulfenite dissolves in the presence of sulfide ion according to the following reaction: PbMoO , + S= PbS + MOO;. Synthetic galena is formed and molybdenum is released to solution as molybdate ion. The reaction follows the shrinking core model and the leaching mechanism involves mixed kinetics where both diffusion and chemical reaction are rate controlling. Molybdenum extraction is explained in terms of temperature, particle size, and sodium sulfide concentration.

Jan 1, 1977

By Larry D. Patts

Section 317(e) of the Federal Coal Mine Health & Safety Act of 1969 directed the Secretary of the Interior to prepare standards under which all working places in a mine shall be illuminated by permissible' lighting while persons are working in such places. Section 317(e) further provides that such Working places shall be illuminated within 18 months after such standards are promulgated. In accordance with this section of the Act, there was published in the Federal Register for December 31,1970 a notice of proposed ru1emaking which prescribed the illumination to be provided in the working p1 aces of underground coal mines. In 1ight of written comments, suggestions, and objections to this proposed ru1emaking, the proposed standards were with-drawn and reproposed in the Federal Register for Wednesday, October 27, 1971. In light of further comments, suggestions, and objections, a public hearing was held on April 4, 1974 and standards were again reproposed and published in the Federal Register for April 1, 1976. Promulgation of the final lighting standards took place on October 1, 1976 which means that the underground coal mining industry must comply with face illumination requirements by April 1, 1978. As mentioned previously, the first proposed ru1emaking for illumination of underground coal mines was published in the Federal Register on October 27, 1971. In early 1972, Consolidation Coal Company (Consol) and the United States Bureau of Mines agreed to a cooperative study of underground face illumination; Conso1 felt that expertise in this field would become increasingly important. Conso1's initial efforts in illumination were aimed at investigati.ng practical lighting systems for underground face equipment. We were concerned with installing unobtrusive lights which provided sufficient face illumination for safety, but at the same time were readily maintainable, electrically reliable, and physically sheltered from damage.

Jan 1, 1977

By James D. Cribbes

The .paper examines some variables which influence the quality of iron ore pellets, and which may be modified to meet the specific requirements of blast furnaces and direct reduction processes. Quality parameters defining pellet physical strength, size structure and reduction behavior considered important by the operators of blast furnaces and direct reduction processes are listed. Laboratory results are used to illustrate how feed preparation, and pellet chemistry car1 be altered to meet these specific quality criteria and some aspects of the economic impact of quality demands on the pelletizing operation are discussed.

Jan 1, 1977

By Leon J. Perrier

The paper describes the equipment in use, haulage grades, road conditions, tire sizes, tire performance and related problems. Various types of failures and causes, corrective action taken, tire records and reporting for control are also discussed.

Jan 1, 1977

By F. P. Agterberg

"IntroductionTHE KNOWLEDGE about the mineral resources in a region ranges from relatively precise ore-reserve estimates for known deposits to probabilistic estimates concerning the speculative resources which may be discovered in future at greater depths and in the less-explored parts of the region. Previously developed probabilistic methods for regional resource evaluation (1) are based on the following two assumptions.(1) The probability that a specific block of rock, or part of a region close to the topographic surface, contains undiscovered deposits can be estimate d by weighting selected geological, geophysical or geochemical parameters for that block. The weights are computed by considering similar environments which are known to contain deposits.(2) Some of the characteristics of the undiscovered deposits, such as ore tonnages and average grades of metals contained in the ore, can be evaluated by considering probability distributions f or known deposit data. These methods were initially applied to Precambrian deposits in the Abitibi Volcanic Belt of the Canadian Shield (1).Since 1972, statistical methods for quantitative resource evaluation have been applied to the occurrences of the mainly Paleozoic base metal deposits in t he Canadian Appalachian Region. The objectives of this project (Project Appalachia) have been discussed by Leech (2) in a paper that introduces 8 papers with results of the exploratory data analysis. Project Appalachia represents an effort to develop and apply methods of combining information and concepts from regional geology, metallogeny and geomathematics for computer- aided regional mineral resource evaluation."

Jan 1, 1977

By V. A. Ettel

Current practices in electrolytic winning and refining of copper , nickel and zinc are reviewed from the point of view of their respective energy requirements. The electrical energy requirements of these processes are broken down in to the individual components, which belong to two basic categories: (a) thermodynamic energy requirements (G of the desired reaction) : (b) energy losses (anode and cathode polarizations, ohmic drops in the electrolyte and in the cell hardware, energy losses due to unwanted side reactions and electrical shorts). The individual energy components are separately examined for each electrolytic process and the potential for energy saving in these processes is discussed. It is shown that many potential energy-saving measures are uneconomical at the present time, as they increase over-all operating costs. The discussion is focused on those approaches which hold most promise for the future.

Jan 1, 1977

By David A. Summers

In May 1975 the U. S. Bureau of Mines contracted with the University of Missouri-Rolla, Rock Mechanics and Explosives Research Center to develop a Hydrominer modification to a long-wall shearer unit, wherein the rotating pick-laced drums and connecting gear drives are replaced by a water jet cutting head.1 The concept of the water jet cutting head is based on using the high localized energy of the water jets to isolate a slice of coal by cutting a slot under, at the back of, and at the top of the web. The plow blade of the head then advances into the cut and wedges the pillar over onto the conveyor (Figure 1). There were several potential advantages foreseen for the system of which perhaps the most significant were the elimination of coal dust from the working area2 and the ability, with a variation in nozzle geometry, to cut webs of greater depth with a small increase in equipment horsepower. The University initially designed the head, based on experiments carried out in the laboratory, under an earlier Bureau of mines contract. The experiments showed that it was more advantageous to work at a pressure of 10,000 psi with an estimated flow rate of 50 gpm than go to the higher pressures and lower flow rates which have been advocated elsewhere.

Jan 1, 1977

By Richard Klimpel

1. Introduction Laboratory and industrial grinding tests have shown that the process of size reduction can be significantly influenced by chemicals added to the powder or slurry being ground. The terms grinding aid or grinding additive refers to a substance which when mixed into the mill contents causes an increase in the rate of size reduction. The increased rate can be used to grind a higher feed rate to the desired product size or it can be used to produce a finer product size at a fixed feed rate. Whether the use of a grinding aid is justified in any given situation depends on the cost of the substance versus the improvement of output or product quality obtained with its use. Obviously, an expensive chemical must be effective in very small concentrations if it is to be economically justifiable; the cost criteria is calculated on the basis of the cost of the grinding additive per ton of material ground. Although there is direct experimental verification of the advantageous effect of grinding additives, no sound scientific explanation has yet been offered which explains or predicts the general behavior of additives. Rose and Sullivan have summarized most of the work undertaken prior to 1950 and Hartley, Prisbrey, and Wick have recently prepared an updated synopsis of the grinding additive literature. Many of the studies reported consist of subjecting materials with simple geometric shapes to some type of hardness or controlled single fracture test. On the other hand, a number of the studies were carried out on operating industrial scale mills, with little control or precise monitoring of the effect of the additives.

Jan 1, 1977

By Z. M. Zavodni, M. K. McCarter

This paper identifies physical conditions responsible for past instability of the Main Hill area in Kennecott Copper Corporation's Bingham Canyon Mine, Bingham Canyon, Utah, and describes successful stabilization techniques employed in this slide zone. Geotechnical highlights of recent slides are presented, including monitoring, geological engineering data collection, hydrology, physical rock properties, and stability analyses. Local conditions responsible for slope movement in the Main Hill zone are: (1) high pore water pressure that causes a substantial decrease in real and effective material strengths; (2) continuous structural systems that allow sliding in the more competent rock zones; and (3) broad areas containing fractured, altered , and incompetent rock and soil- like materials. The failure mode is structurally controlled and involves a circular-type soil failure in the toe region initiated by excessive pore water pressure. A surface mapping method is presented which assigns rock mass quality on the basis of block size and rock substance strength. This site characterization technique has successfully predicted slide boundaries and failure modes; used in conjunction with laboratory determined shear strengths, it has provided basic input for calculating slope safety factors in the Main Hill slide zone.

Jan 1, 1977

By Karl D. Libsch, Modesto E. Erneta

Both battery design and environmental pressures are forcing the secondary lead industry to consider new and different processes. Trends in battery design are making normal decasing increasingly difficult. Lead in air, sulfur dioxides, and solid/liquid waste heavy metal restrictions are tightening. There is no clearly defined industry trend toward a given process, but it is clear that plants will be larger, less labor-intensive, and automated.

Jan 1, 1977

By L. P. Johnson

Longwall mining has gained acceptance as a safe method of maintaining coal production where conventional systems were unsuccessful or uneconomic due to bad roof conditions (Kuti8). One of the major problems confronting American operators involves the correct choice of equipment which should be selected to suit the local mining and geologic conditions for optimum productivity. To achieve this, factors such as rock strengths, local geology, panel geometry, and panel orientation must be examined to optimize production and minimize down time due to ground control problems. Little quantitative information is available in the literature regarding the effects of geologic conditions on American longwall operations, and past implementations of longwall systems appear to have been based largely on experience. When mining engineers are able to assess the geologic conditions both quantitatively and qualitatively, they can more fully optimize equipment selection and panel design.

Jan 1, 1977

By R. D. Brown

Ever since British Columbia started the ball rolling in 1974 with the introduction of its now-defunct Mineral Royalties Act, all Canada's resource-based provinces have significantly altered their mining tax systems. The last resource-based province to abandon its pre -1974 mining tax structure is New Brunswick, which introduced a new mining tax regime in the summer of 1977 to take effect from April 1 1977. The new structure, which represents the outcome of considerable study and discussions with industry representatives, contains some intriguing concepts which make Nero Brunswick's new mining tax system unique among the Canadian provinces.

Jan 1, 1977

By Kenneth R. Krivanek

In recent years the widespread problems of air and water pollution generated by both population and industrial expansion have become a major public concern. Therefore, many municipalities are striving to achieve more efficient wastewater treatment processes so these wastewater's can be reintroduced into the waterways of our nation with little or no detrimental effects on the future beneficial use of that water. With this, improved treatment comes an ever increasing volume of wastewater sludge which must be disposed of in a manner of minimal impact on the environment. Furthermore, with demand for energy continually accelerating in this nation, our concern over high oil prices and our increasing dependency on foreign oil sources, there has been an ever growing interest in the largest energy source that are nation has, coal. However, surface mining of coal can cause many environmental problems when adequate precautions are not faithfully adhered to. These problems include water pollution from silt and/or clay erosion and acid runoff, produced by oxidation and hydrolysis of pyrite; i.e., FeS2 + 3/02 + H20 + FeSO4 + H2SO4. One method of wastewater sludge disposal which can utilize large volumes of sludge for a beneficial project that may not compound our environmental problems is spray irrigation, to either depleted farmland or to abandoned strip-mined soils. Sludge is characteristically high in organics, as well as having near neutral to alkaline pH properties. With these two qualities it possesses a potential for neutralizing acid strip mine spoils, which would enhance the establishment of a vegetative ground cover. Sludge can accomplish this by lowering the oxidation potential, reducing the solubility of iron and aluminum and by the chelation of metals, thereby

Jan 1, 1977

By Akira Ishizu, Nobuo Matsui, Hideo Yamamoto, Tatsuya Nagahama

At Kamioka Mine of Mitsui Mining & Smelting Co., Ltd., Japan there are three mills, treating a total of 6400 t/d of lead-zinc Ore. In the lead-zinc bulk differential flotation at Shikama Mill the addition of reagents is automatically controlled by the feed rate, the lead and zinc content in feed, froth and tailing, the pH and the concentration of cyanide ion in the pulp. As the zinc thickener overflow at Shikama Mill contains CU(CN)3--, ZnS, CdS, CN-, xanthate and frother, all the ingredients in the over- flow other than CN are floated by using the Nagahm flotation machine, and the water containing only CN- is effectively recycled to the lead- zinc differential flotation circuit. In the lead-zinc straight differential flotation at Mozumi Mill, the overflow of tailing pond is recycled especially to the cleaning flotation circuit by decreasing the pulp density. Thus the integrated recycling of wastewater greatly reduces environmental problem and in addition, it generates sizeable profit.

Jan 1, 1977

By R. T. Saxon

Prior to November 1975 there were several failures of front -wheel spindles on large haulage truck s in B.C., attributed to fatigue cracks. Since that time, a non-destructive test program has succeeded in detecting the cracks before catastrophic failure, However, the author regards the failures as just one example of a. general unreliability in large high-strength steel castings and urges the industry to look to forgings for sensitive components of heavy equipment.

Jan 1, 1977

By E. D. Palmes

This report was prepared by New York University Medical Center, Institute of Environmental Medicine, 550 First Avenue, New York, New York under USBM Grant Number G0133066, Personal Samplers for CO, NO and NO2 in Air. The grant was initiated under the Coal Mine Health and Safety Program. It was administered under the technical direction of the Pittsburgh Mining and Safety Research Center with Dr. George H. Schnakenberg acting as the Technical Project Officer. Mr. L. Young was the contract administrator for the Bureau of Mines. This report is a summary of the work recently completed as part of this grant during the period 3/1/73 to 11/30/76. This report was submitted by the authors in March, 1977.

Jan 1, 1977

By Jeffrey N. Deisher, H Y. Fang, Richard P. Scheller, Robert M. Koerner

The need to adequately quantify cracking in structures in the vicinity of blasting activity becomes more important each year. This urgency comes about through a growing number of complaints and lawsuits between the various parties involved, i.e., operator/owner, government, and complaintant. It is felt that existing rules and regulations (mainly based on peak particle velocity of the soil or rock adjacent to the structure in question) fall short of such quantification and lead to confusion in adequately assessing structural damage.

Jan 1, 1977

By R. D. Lord

The search for the best practical means of storing sulfide bearing tailings, where there is no residual excess of carbonate material is discussed in this paper• Usually the sulfide content decomposes, with the aid of bacterial action, and the resulting sulfuric acid escapes, along with any heavy-metal solutes, through embankments that are usually porous to some degree• The problem is typified in the tailings of the uranium operations of Elliot Lake, Ont., where mining started some 20 years ago• The approach to tailings disposal paralleled the practice for other hydrometallurgical plants treating gold and base-metal ores• Impoundment areas were designed to retain solids, and a clear and neutral overflow was considered satisfactory practice• Now experience has shown that these areas, some of which have been idle for over a dozen years, release acids in seepage and overflows to an unacceptable degree• To protect natural water courses, neutralizing plants are operated wherever required• Lime slurry is fed continuously into the tailings outflows in a quantity sufficient to raise the pH to 8•5 and precipitate heavy metals that may be in solution• The objection to this procedure is that the plants will require servicing indefinitely, unless a better remedy is found• The problem differs only slightly from that common to base-metal concentrators in that here the ore has been leached with sulfuric acid for the recovery of uranium• Any native content of calcareous material has been digested, and only that added for final neutralization is available to maintain a pH unfavorable to bacterial activity• Chemical oxidation slowly lowers the pH and when this reaches a level of 4•5 or less, bacteria become active and greatly accelerate the formation of acid. The bacterial process is probably at least ten times as fast as the chemical oxidation• Location and Processing The operations referred to, uranium and one copper mine, are located at approximately 46°N and 82°W longitude• This is typical Canadian Shield country, a land of lakes, deeply glaciated and rocky, with sparse soil which supports mixed forest cover• Drainage is to Lake Huron, 25 miles to the south• Average temperature is 45°F, ranging from -40° to +95°F• Annual precipitation is 38 in•, about half of which is snow• The ore is Precambrian, quartz-pebble conglomerate, with mineralization in the matrix• From 5 to 10% pyrite is present• All known means of pre-concentration have been tested, but a bulk sulfuric acid leach has proved the most efficient. Tailings have from the outset been neutralized before release• Current practice is to add ground limestone to bring the pH to 4•5, and then lime to raise the value to 10•5• Environmental regulations have recently been increased and the foregoing meets the new standards• Separate measures are taken to precipitate radium• Remedial Measures Since the outstanding environmental problem is the oxidation of pyrite by bacterial action, the solution is to contain the products, or arrest the process• Given the ambient temperature, favorable half of the time, four items are essential to the activity• 1) Pyrite• 2) Moisture pH < 4•5. 3) Oxygen• 4) Bacteria• Removing any one of these out of the range of tolerance will bring the reactions under control• A variety of proposals considered, and a number tested for the arrest of the process, are: (a) render embankments impermeable, (b) provide an impermeable cover, (c) cover with an oxygen absorbing layer, (d) provide a vegetative cover, (e) flood the site, (f) remove pyrite from current tailings, (g) add excess limestone to current tailings, (h) poison the bacteria• Bank Seal-On existing impoundment areas, where the embankments are several thousand yards in length, it is believed that any program of injecting sealants can have small chance of success• However, a moisture barrier is an indicated specification for future construction, and this can be highly expensive• Surface Seal-Depending on the configuration of the deposit, the downward travel of water should be prevented, and oxygen excluded• Burying a plastic membrane just below the surface has been considered, as has the application of a liquid sealant that would penetrate the surface. The objection to these remedies is the excessive cost of dealing with large areas and the expectation of only temporary benefit as a result• Frost penetration is over 4 ft, and frost action breaks up asphalt paving and all but heavy concrete in a few years• Organic Layer-An oxygen-absorbing layer, such as bark fines from paper mills has been proposed as a surface treatment• Cultivated into the tailings such material might be expected to arrest subsurface oxidation for some years• Estimates are 100 tons per acre of bark fines, or 35 tons per acre of sawdust, and these enormous quantities do not so far give assurance of providing a long-term remedy• Vegatative Cover-Several obvious benefits would result from a good growth of grass or other vegetation on abandoned tailings• While restoring the natural green of the tract the growth would prevent wind-blown dust and reduce erosion• Subsurface oxidation should be reduced, as well as the upward movement of ground moisture as occurs in dry weather. To this end, considerable research and field testing has been carried out to arrive at a formula - a prescription which will provide a self-sustaining growth on the tailings surface, or at least one that would survive with reasonable maintenance attention. Many test plots have been run with different combinations of surface treatment and seed mixtures. Generally, by addition and close cultivation of limestone, lime, and fertilizers, technical success has been demonstrated• Plants with a high tolerance for acid soil seem the more hardy, and a pH above 3 is indicated so that nutrients can be absorbed• Recommendations are for 12 to 15 tons of

Jan 1, 1977

By Beeforth C. G

The use of Non-Linear Programming to obtain improved schedules of future activity in two specific cases of mining and treatment of minerals is described. The two cases were (i) reclamation of gold, uranium and sulphur from old surface tailings dams and, (ii) underground mining of gold. The method used an augmented Lagrangian device to reduce a constrained Non-Linear Programme to a sequence of unconstrained hill- climbing procedures. The main advantages of the method appear to be those of (a)flexibility of modelling of industrial characteristics and constraints and, (b) reasonably modest computation times.

Jan 1, 1977

By Boden A

A procedure was developed for recovering metal values from copper-smelter fume. The fume is first leached to neutrality with dilute sulphuric acid to obtain a solution of zinc sulphate containing a low level of impurities. The tailings from this leach are treated with hydrochloric acid in two stages, in which tin and zinc are quantitatively leached and recovered as a tin concentrate and a zinc sulphatelzinc chloride solution.About 80 per cent of the lead sulphate is converted into lead chloride, which can be recovered as a pure product.Data on the effect of temperature, acid concentration, aeration, and solid/liquid ratios on the hydrochloric acid leach are presented, and the fate of the most important metals during the recovery process is described. Alternative treatments of the tailings from the neutral sulphuric acid leach were briefly investigated.

Jan 1, 1977