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By Spencer S. Shannon

The lanthanide elements from lanthanum (atomic number 57) to lutetium (71) plus yttrium (39) are called the rare-earth elements; scandium (21) is chemically similar to yttrium and the lanthanides, but differs in occurrence. The rare-earth metals were divided into three categories by the chemist, Berzelius, in the early 1800s; however, modern usage defines only two groups. The cerium group is named after the most abundant -element and comprises lanthanum (57), cerium (58), praseodymium (59), neodymium (60), promethium (61), samarium (62), europium (63), and gadolinium (64). Traces of natural promethium were discovered in apatite in Finland (Erametsa, 1965). The yttrium group, also named after its most abundant representative, comprises terbium (65), dysprosium (66), holmium (67), erbium (68), thulium (69), ytterbium (70), and lutetium (71). Yttrium most closely resembles holmium in chemical properties, and occurs most commonly with the heavy lanthanides. The rare-earth minerals may be divided into cerium-group, yttrium-group, or mixed-group classes. A number of rare-earth minerals contain thorium and uranium, but these are variable in content and are not essential to the composition of the minerals. In monazite, a mineral that is a principal source of rare earths, the worldwide average content of thorium oxide is 7.2 % ; however, varieties of monazite contain as little as 0.001% and as much as 31.5% thoria. Monazite is the chief ore of thorium and, until recently, thorium has been the main product; the rare-earth metals were in fact byproducts. However, because of the great demand for rare-earth metals by the petroleum refining and the iron and steel industries since the early 1970s, the roles have been reversed so that thorium is now the byproduct. Uses A 9 to 1 mixture of yttrium and thorium oxides is used for high-intensity incandescent lamps and for high-temperature-resistant windows and lenses. Yttrium oxysulfide and orthovanadate, doped with europium oxide, are used in color television tube phosphors. Yttrium, as well as cerium, praseodymium, and samarium, is alloyed with cobalt to form strong permanent magnets. It hardens magnesium alloys and retards the oxidation of iron-chromium alloys. Yttrium-iron garnets are used for transmitting low microwave frequencies. Yttrium-aluminum garnets are used as host crystals for lasers and as artificial gems. Yttria also forms strong, stable, high-temperature refractories. Gadolinium-gallium garnets are used in substrate wafers on which bubble-memory films are deposited. Rare-earth chlorides, particularly of lanthanum, neodymium, and praseodymium, are used as catalysts for petroleum cracking. Mischmetal is used for lighter flints and to improve the ductility and impact strength of iron and steel alloys. Mischmetal also reduces the fatigue resistance of magnesium and aluminum alloys. Rare-earth oxides are used for polishing glasses and lenses. Individual or specific combinations of high-purity oxides are used as additives in glass to maintain or change its color, dispersion, or refractive index. High-purity oxide combinations are also used to color tile and to opacify porcelain enamel. Rare-earth fluorides and oxides are used in carbon-arc electrodes to provide incandescent white light. Lanthanum or gadolinium oxysulfide phosphors, activated with terbium, are used as x-ray screen intensifiers. Hydrogen can be stored by sorption on lanthanum-nickel alloys (Anon., 1979). Thorium232 is bombarded with slow neutrons in breeder reactors to create fissionable thorium233 for nuclear fuel cells. The 330-MW, high-temperature gas-cooled reactor at Fort St.

Jan 1, 1983

By P. E. Weidmark

"CANMET InformationPART 1-Published PapersAsmis, H. W., ""The dynamic response of caverns in discontinuous rock""; Proc 22nd U.S. Symposium on Rock Mechanics, Cambridge, Mass, June 1981, 272-277; 1981.Austin , M.W., Bray, J.W. and Crawford, A.M., ""A comparison of two indirect boundary element formulations incorporating planes of weakness"" ; Technical Note; Int J Rock Mech Min Sci Geomech Abstr; 19:339-344; 1982.Barrett, J. R., ""Applying geotechnical theory to underground metalliferous mining""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 210-222; 1983.Barron, K., Wright, P.L. and Smales, T., ""Guideline s for the design of coal pillars in the No .4 seam at Mclntyre Mines Ltd ., Grande Cache, Alberta""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of A IMMPE; 559-578; 1983.Bauer, A., ""Wall control blasting in open pit mines""; Mining Engng; 34:155-158; 1982.Bieniawski, Z.T., "" Improved design o f room-and-pillar coal mines for U.S. conditions""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 19-51; 1982.Blackwell, G.H. and Calder, P.N., ""Practical aspects of wall stability at Brenda Mines Ltd., Peachland, BC""; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-A1ME; 3:573-608; 1982.Blake, W., ""Microseismic monitoring for underground stability "" ; Proc 1st Intnl Cont on Stability in Underground Mining; Vancouver , BC, August 1982; SME of AIMMPE; 272-294; 1983.Brawner, C.O., ""Stabilization of rock slopes"" ; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-AIME; 3:289-310; 1982.Bridges, M.C., ""Review of open stope mining in Australia""; Proc 1st lntnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 813-828: 1983."

Jan 1, 1983

By Runge IC

The mine planning process is reviewed and appropriate software considered in terms of "line process" or "support function". The mine planner's requirements of a geological model and the elements of and requirements of a computerised mine planning system are all discussed. The use of "support" software for mine planning is considered and general rules for its development are given. Important changes involved in implementing a computerised mine planning program are listed.

Jan 1, 1983

By Bobby J. Timmons

Luck; blind, beginner's, fisherman's, or whatever type, plays an important role in romance, racing, football, gambling, and mineral exploration. However, for each of these; education, training, technique, and experience are necessary for a long, continuous, successful relationship. Success, no matter how obtained, is easier to defend than almost success, regardless of the education or the degree of refinement of the seeker. Similarly, investment dollars are more readily available to a successful, uneducated and unscientific practitioner than to his beginning or unlucky professional counterpart.

Jan 1, 1983

By R. R. Potter

"IntroductionAlthough iron formations were recognized in western New Brunswick about 1820, commercial production was not achieved until 1848. The Jacksonville deposits near Wood stock were developed first, and ore was treated at a blast furnace constructed 5 km to the southeast on the Saint John River. Several charcoal burners were also constructed. Pig iron was produced sporadically until 1884, when operations were finally suspended. There was little further interest in the area until 1953, when Stratmat Ltd. initiated an ambitious exploration program. At the same time, the company carried out research on an electric-reduction process to produce metallic iron and ferromanganese. The technical feasibility of this process (Udy process) was confirmed, however the high energy costs were prohibitive and work ceased in 1957. Some metallurgical research was carried out by Mandate Refining Ltd. about 1970 and more recently by the New Brunswick Research and Productivity Council.The Years Prior to 1848New Brunswick became a separate province in 1784, shortly after the influx of a large number of Loyalists from the United States. Man y of these people sett led along the Saint John River, including the area of excellent farmland near the present town of Woodstock.There were indication s that some of these earl y settlers recognized iron formations in the vicinity of Woodstock about 1820, however the nature of the deposits was not known until 836 when Dr. C.T. Jackson, a geologist commissioned by the Stat e of Maine, investigated the mineral potential of the area. Jackson (1836) described the ""ore"" as compact red hematite yielding 44 per cent pure metallic iron, and suggested that sizable tonnages may be present. It was about this time that an extensive limonite deposit was found in north-central Maine, near Mt. Katahdin. Other iron deposits were found in the Nictaux area of Nova Scotia, and a few years later at Londonderry."

Jan 1, 1983

By Jack Parker

There are some simple theoretical approaches to pillar design but they leave much to be desired. There are also more complex theoretical approaches, but at this time the most realistic approach is to go into the mines and observe and measure how real pillars are performing under real conditions; to allow the information thus gathered to ferment in our minds - then to project the behaviour of those pillars into our new designs and mining techniques, probably with no formulas at all. Examples, from half-a-dozen different mines, show how a simple- minded approach, through observation and measurement, led to changes in pillar design which often contradicted the textbook but made very significant contributions to mining safety, efficiency and costs. The good news is that we know a lot more about pillar design than we realize. We have, between us, looked at millions of pillars of all kinds, under all conditions, but we have overlooked what they are trying to tell us. We can take problem situations and turn them into opportunities and, in that way, become better stewards of the resources which have been given to us.

Jan 1, 1983

By M. Grun, A. C. Marlowe, I. Littleford

SYNOPSIS A Wirth tunnel borer owned by Anglo American Corporation completed a 1150m long tunnel some years ago and was subsequently extensively modified by Technical Development Services. In 1982 this borer provided new and particularly interesting information In the field of hard rock boring. The abrasive quartzltes traversed proved to be a challenge to the cutter manufacturer and the project team. This paper examines the problems faced, the solutions found and the lessons learnt.

Jan 1, 1983

By D. D. Hogarth

"IntroductionThe Hull iron range, comprising the Forsyth, Scott , Baldwin and Lawless properties (Fig. I), is in Gatineau Park, on the outskirt s o f the city of Hull , and about 6 miles (10 kilometres) northwest of the Federal Parliament Buildings.The deposits have been known many years and described numerous times, although the history has been treated lightly in former publications. Total ore shipments have been calculated at 122,700 long tons, of which over 80% were mined before 1900 and 74% in two brief periods: 1870-74 and 1880-82. It is surprising that the period 1870-74 has been overlooked by most authors and 1880-82 ignored altogether. More surprising, the essential data for these two periods are contained in manuscripts of the Robert Bell collection, which must have been available to officers of the Geological Survey o f Canada.The period 1801-1874 ha s already been covered by the writer in ""Pioneer mines”, but much information has come to light since publication. The present paper is therefore based o n new data and a fresh appraisal. However, little additional data were found for the early history (1801-1854) or for the legal cases involving A.H. Baldwin, and these parts were mainly summarized from the relevant sections of the above-mentioned publication.GeologyThe ore deposits are all situated somewhat below the middle of a graphitic, calcitic marble horizon, here folded into a northeast-plunging synform. The Forsyth, Scott and Baldwin deposits are on the south limb of the synform; the Lawless is on the north limb. The marble is underlain by three non-carbonate groups: biotite gneiss with interlayered quartzite (top), granite gneiss and skarn (middle), and biotite-garnet gneiss (bottom). Below these groups is a lower horizon of graphitic, calcitic marble. The whole sequence is Precambrian and has been subjected to high-grade (Grenvillian) metamorphism, but, in the north, is cut by an unmetamorphosed Cambro-Ordovician diabase dyke. For further information, the reader is referred to the summary by Baird."

Jan 1, 1983

By S. N. Sinha

The distribution coefficients of lead and silver between copper and matte phases have been measured at two different temperatures. Experiments covered the ranges of 0.009-1.8, 0.07-0.13, and 0-11 wt pct lead, silver, and iron in matte, respectively. The distribution coefficients of lead have been measured at 1405 and 1505 K and correlated with lead and iron concentrations in metallic copper and matte. The values of the distribution coef¬ficient of lead between copper and iron-free matte, at infinite dilution of lead, have been determined to be 3.60 and 4,06 at 1505 and 1405 K, respectively. The distribution coefficient of silver between copper and iron-free matte is independent of silver concentrations and has been measured to be 2.13 and 2.21 at 1400 and 1500 K, respectively. For an iron-bearing matte, the distribution coefficient of silver has been correlated with iron concentration in the matte at both 1400 and 1500 K. From the measured values of distribution coefficients, the Raoultian activity coefficients of PbS and AgS0.5 in copper-saturated matte have been calculated. At infinite dilution, the following equations correlating the Raoultian activity coeffici¬ents of PbS and AgS0.5 with matte- composition and temperature have been obtained: log Y° PbS =1.515 + 1080/T 0.14 NFes lbS Fog YAgS = -0.074 - 425/T + 0.09 NFes. - 0.5

Jan 1, 1983

By Haydn H. Murray

Although alumina constitutes about 15% of the earth's crust, it is expensive to separate and purify for the production of aluminum with the exception of the alumina in bauxite. The United States has a variety of nonbazurite resources that could substitute for bauxite, including high alumina clays, alunite, dawsonite in oil shale, anorthosite, and nepheline venite. Each of these resources is discussed from the standpoint of geology, geography, processing, and potential recovery. Potential byproducts include alica from clays, potash and sulfuric acid from alunite, soda ash from dawsonite, and soda ash and potash from anorthosite and nepheline syenite.

Jan 1, 1983

By Louis Schaffer

The objectives of the research were to determine whether a model health and safety program could be defined in terms which would enable its application to mines of all types, and, if such a model program could be defined to determine through evaluations in two mining companies whether it would achieve measurable improvements. This volume describes the model, how it was applied in the field, and how it was evaluated. Anecdotal data to illustrate common kinds of safety problems and their solutions are included. The literature and field research that preceded the model definition is discussed in Vol. 2, which covers the period of September, 1980 to September, 1981.

Jan 1, 1983

By Moorrees C, Everson P

A detailed examination of carbonic acid leaching of crude iron-containing magnesia derived from Savage River magnesite shows that the rate and extent of magnesium and iron dissolution are affected by the slake time, leaching temperature, carbon dioxide pressure, pulp density and rate of agitation. In order to produce high-purity magnesia from the leachate by precipitation and calcination, the optimum leaching conditions, which are those that yield maximum magnesium and minimum iron dissolution, have to be a compromise in terms of the above parameters. For example, iron dissolution can be limited by leaching at an elevated temperature (-45°C), but because the maximum concentration of magnesium biearbonate decreases rapidly with an increase in temperature, it is necessary to use a low pulp density (-2 per cent solids) in order to achieve an acceptable degree of magnesium dissolution.Evidence is obtained that iron dissolution involves the formation of a soluble ferric bicarbonate complex that decomposes at elevated temperatures. The extent of iron dissolution is much higher than might be expected and it is probably because the original magnesite contains siderite in solid solution with the magnesite; on calcination, the hematite whieh is formed is in a very finely divided condition and hence more reactive.

Jan 1, 1983

By E. H. Cho

INTRODUCTION Activated charcoal has been used for several centuries in many capacities including the recovery, isolation and purification of various materials (1). The first use of charcoal in a gold metallurgical system was in the extraction of gold after chlorination (2, 3,4). The gold was dissolved in a chlorine system and subsequently filtered through charcoal. The application of charcoal with cyanide extraction was patented by Johnston (5) in 1894 and adopted commercially in Australia in 1897. The process consisted of dissolving the gold and silver in a potassium cyanide solution and passing it through a series of charcoal filters. The charcoal was subsequently smelted to recover the gold and silver. The interest in the use of charcoal diminished in the first part of the twentieth century as the practice of the use of zinc as a precipitating agent increased. However, in 1916, the Yuanmi Mine in Australia replaced their zinc precipitation plant with a charcoal adsorption plant. In 1926, Scott and Gross (7) of the U. S. Bureau of Mines con- ducted extensive research on the adsorption of gold and silver from cyanide leach solutions. Among their findings was the result that the most important factor in improving the adsorptive power of charcoal was heat treatment with oxidation by air or steam. The work of Zadra (8) in 1952 stimulated renewed interest in the use of activated charcoal in gold and silver recovery with the development of a method of recovery of the gold and silver from the charcoal other than its destruction by burning. The process involved simultaneous desorption

Jan 1, 1983

By B. N. Whittaker, C. J. Bonsall

The paper gives an account of the factors influencing the stability of coal mining tunnels and goes on to examine various bases of support and lining design of such tunnels in relation to geological and mining conditions. The different types of coal mining tunnels are compared and comments made regarding the factors influencing their choice and basic design features. Foremost amongst design considerations is the design method and special thought has been given to the validity of different formulae as related particularly to UK Carboniferous geological conditions. Emphasis is placed on the role of the stress field in relation to tunnel stability. Shape of mining tunnel has been investigated and conclusions drawn regarding the merits of different commonly excavated geometries from a stability point of view. Detailed design aspects pertaining to determination of tunnel lining strength and resulting stability are critically examined and current design methods are compared. Data from UK mining tunnels are included as the basis for comparison of these design methods.

Jan 1, 1983

The design of mine ventilation systems for the BHP Steel Division Collieries is based on the acquisition of ventilation survey data for the establishment of a realistic computer net- work model. The branches which form the net- work for the computer models are calculated from a range of resistance factors incorporat- ing both a frictional and shock loss component. Since shock losses can account for up to 30 per cent of the total energy losses in mine airways the use of friction factors alone without accounting for shock losses will result in the choosing of an insufficiently performing fan. Published tables of friction factors have in- variably been taken from metalliferous or single entry studies and consequently are not reliable for Australia's mining conditions where multiple entries with regularly spaced cut-throughs are the normal practice. Typical resistance factors for roadways of rectangular cross-section 5.5 m x 2.0 m, with coal sides, have been found to vary from 0.11 Ns2/m8/km where no timber supports are used, to 0.98 Ns2/m8/km where double centre legging together with wooden chocks is used. In addition to the range of resistance factors due to varying support methods, the nature of use for a roadway is very significant because of the condition of repair and upkeep maintained.

Jan 1, 1983

By Louis Schaffer

The objectives of the research were to determine whether a model health and safety program could be defined in terms which would enable its application to mines of all types, and, if such a model program could be defined, to determine through evaluations in two mining companies whether it would achieve measurable improvements. Volume 1 describes the model, how it was applied in the field and how it was evaluated. This, Volume 2, describes the literature and field research that preceded the model definition.

Jan 1, 1983

By James E. Aplin

Previous studies have shown that fracturing of roof strata precedes ultimate failure, and that the fracture development causes an accompanying increase in the apparent resistivity of the strata. Using this principal, a microprocessor controlled resistivity roof fall warning system (RRFWS) was developed that automatically sequences through and records up to 32 electrodes that may serve as either voltage or current electrodes. This capability permits increased coverage with a minimal number of required electrodes. The data is stored in a nonvolatile memory and on an optional printout, making the system nonsusceptible to loss of mine-power. To further save battery power, the system's electronics shut down between readings, except for a carbon molybdenum steel real-time clock. At a preprogramed interval, the RRFWS reactivates and repeats the sequence. If the absolute change or the rate of change of resistivity exceeds a predetermined limit the system is capable of sounding an alarm. In addition to the monitor, a stainless steel mod led split-set electrode was also developed that permits long-term corrosion-free contact.

Jan 1, 1983

By John F. McCoy

The United States Bureau of Mines (USBM) awarded a contract to Foster-Miller Associates, Inc. (FMA) to develop guidelines for designing, constructing, stocking and maintaining rescue chambers in underground mines. This report develops information and recommendations which could be used by a mine operator who desired to install a rescue chamber. Volume I covers the following major areas: atmospheric life support, configuration and construction, chamber location, power and lighting, equipment and supplies, communications, and psychological aspects and training. Volume II contains the following appendices: History of Barricading, Chamber Pressurization Considerations, Diffusional Infiltration of Gas, Compressed Air Storage, Location Examples, and Psychological Aspects.

Jan 1, 1983

By Sandip K. Mukherjee

This report presents the results of the economic analysis of several applicable alternatives to increase airflow in four underground coal mines. Pressure-quantity surveys were conducted underground and measurements were also made at the main mine fan(s). The existing ventilation networks were modeled using the modified Penn State ventilation simulator. The applicable alternatives were simulated. Performance data obtained from these simulation runs were utilized to conduct the cost-effectiveness analysis. The costs for each of the alternatives included capital, operating and operating costs. These costs were expressed as annual ventilation costs per active section in terms of dollars per cfm taking into account the economic life associated with each of the alternatives. The benefits were expressed as increased airflow quantity in the critical sections. A section of this report also deals with comparison of simulator predicted air quantity values against air quantity values measured under-ground. This volume constitutes Volume II of the report and contains the outputs of the computer simulation runs.

Jan 1, 1983

By Terry Muldoon

In conventional noncoal, room-and-pillar mining, the cutting machine is frequently a major source of airborne dust. Water is often used for dust control. An evaluation of typically used water systems during this program showed that they reduced dust levels by 60 to 70 percent over dry cutting when at least 0.5 gpm of water was applied. These systems, however, are only marginally effective in maintaining compliance levels and the added moisture causes operational problems. During the program, three additional dust control systems were designed, fabricated, and evaluated. The first, a hollow cutter bar, was designed to capture dust in the kerf at the cutting zone. The system was only marginally effective in reducing dust levels due to its lack of control of other sources. Large quantities of material captured by the system made it operationally questionable. The second, a machine mounted exhaust system, was extremely effective in capturing virtually all the dust generated in the heading. The captured dust was ducted out of the heading and exhausted downstream in the crosscut. Exhausting the dust without scrubbing, however, creates problems for personnel working downstream of the cutting machine. Successful application would require changes to the mine ventilation system and mining sequence. The third, foam, injected foam from an onboard generator through a channel to the cutting zone at the tip of the bar. Test results showed that foam, using 1/3 to 1/2 the total fluid quantity, was equally effective when compared to the mine's current water system.

Jan 1, 1983