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Electrochemical investigations of the flotation of sulphide minerals are re- viewed. Flotation with thiol collectors is interpreted in terms of a "mixed poten- tial" model in which the process leading to hydrophobicity is the anodic oxidation of the collector at the mineral surface and this is driven by the cathodic reduc- tion of oxygen. Electrochemical studies have identified the products of anodic oxidation as chemisorbed collector, metal collector compounds, and dithiolates; the products formed in each situation depend on the collector used, the mineral under study, and the pretreatment of the mineral surface. Investigations on galena, pyrite, and chalcocite are discussed. Electrochemical and x-ray photoelectron spectroscopic studies have been used to determine the products of surface oxi- dation of sulphide minerals in order to elucidate the mechanism of collectorless flotation. The mixed potential mechanism allows consideration to be made of the ways in which flotation of sulphides with thiols can be inhibited. Examples of depressant action are presented. The relevance of electrochemical investi- gations to practical flotation is Discussed.

Jan 1, 1984

By J. Fletcher Smoak

Consumption of abrasive materials in the United States increased 22% in value over that of 1982 to $320 million; of which, 59% was manufactured abrasive, 35% was industrial diamond (natural and synthetic), and 6% was natural abrasive. Production value of natural abrasives, excluding industrial diamond, remained virtually unchanged. Production of crude tripol, a porous siliceous rock, decreased slightly; however, shipments of processed tripoli increased 13% in quantity and 32% in value. Production of garnet, an abundant iron-aluminum silicate, continued to increase primarily because of further increases in production from one plant that had completed an expansion program in late 1981. Production of special silica stone, both crude and finished, decreased in 1983 because of reduced demand for oilstones

Jan 1, 1984

By M. A. Schimmelpfennig, A. D. S. Gillies

Loss of visibility due to the occurrence of atmospheric fogging in underground mine airways can lead to longer travel times and loss of production efficiency, an increase in the frequency of vehicular and foot traffic accidents and difficulty in checking rock surfaces for instability and loose material. Where hot and humid surface air meets colder underground air, conditions for fog formation may be present. Further, suspended particulate matter from diesel exhausts or stoping operations together with slow movement of air along passageways may contribute to formation. This study describes an investigation being undertaken with the cooperation of Kennecott's Ozark Lead Co. to identify causes of the problem.

Jan 1, 1984

By John Freer

On 25th November, 1983, nearly forty members of The South African Institute of Mining and Metallurgy, together with Doris Gardner and Judith Money from Kelvin House, travelled by luxury motor coach to Secunda, there to visit the coal-mining and conversion operations of Sasol Limited.

Jan 1, 1984

By M. Karmis

Underground mining will disturb the natural equilibrium of the rock mass, causing significant stress redistributions in the vicinity of the excavation with corresponding horizontal and vertical displacements. Subsidence of the ground occurs when these displacements propagate from the mine opening, through the overlying strata, to the surface. Such ground movements may take either of two general forms: a sudden and sometimes violent collapse, or a more gradual and progressive ground movement. The former, characterized by localized failure of roof or pillar in old, shallow room and pillar workings, is rather unpredictable and difficult to analyze. As a result, most control measures are directed toward the latter type of movement, which is associated with the fracture and flow of the strata overlying longwall and high-extraction room and pillar systems, resulting in horizontal and vertical strains in the affected area. Such ground movements can often cause considerable surface disturbances ranging from simple land settlement to severe structural damage. Due to the increasing incidence of this phenomenon in more populated areas and the rising awareness of the problem, it has become necessary to establish a balance between the development of mineral resources and the protection of the environment and society. This paper presents a summary of the major findings derived from a substantial research effort on mining subsidence carried out, during the past few years, in the southern Appalachian coalfield. The research program encompassed the following major tasks: identification of the most significant factor influencing ground movements above mined openings, collection of subsidence case studies for the southern Appalachian coalfield, development of subsidence and strain prediction techniques for that region and initiation of a subsidence monitoring program in southwestern Virginia.

Jan 1, 1984

By L. B. Pankratz

Thermodynamic data on the halides were reviewed, evaluated, and compiled at the Bureau of Mines Albany Research Center. Values for Cp°, S°, H-H°298, -(G°-H°298)/T, ?Hf°, ?Gf°, and log Kf are given in tabular form. CP°, H-H°298, ?Hf°, and AGf° are also expressed algebraically.

Jan 1, 1984

By B. C. Johnson, K. L. Sublette, F. L. Prestridge

A problem common to the petroleum and mining industries is the resolution into its component phases of mixtures composed of a polar liquid dispersed in an immiscible, continuous nonpolar liquid. In the petroleum industry the polar liquid is water or brine and the nonpolar liquid is crude oil. The source of the entrained aqueous phase is connate water and/or condensed steam used in secondary and tertiary recovery methods. In the mining industry dispersions of polar liquids in immiscible, nonpolar liquids are created in solvent extraction (SX) systems. In these systems the polar, dispersed liquid is leachate or stripping solution while the nonpolar, continuous liquid is the extraction solvent.

Jan 1, 1984

By Richard E. Bischke

Computer assisted finite element model analysis, originally developed to study stress distributions in aircraft, has been modified into a versatile mining program, that can be used to assist the engineer with predictions of mine subsidence. International Exploration, Inc. has developed an in-house finite element model program which incorporates a multitude of factors influencing mine subsidence such as mine design, physical rock properties, structure, faults, joints and topography. Finite element analysis of a mine model can mathematically determine the magnitude and direction of the principal stresses within each of the elements forming the model. By comparing the calculated in-situ stresses to the actual rock strengths, high risk regions within a mine can be identified. These potentially unstable regions of the mine can be allowed to fail within the model and the resultant stress redistribution and element movement calculated. Thus, the effects of the mine collapse at the surface can be predicted for the purpose of determining the potential damage, if any, that could occur to surface structures from deep mine failure. Stabilization materials can also be mathematically inserted into the model to design and analyze the effectiveness of subsidence prevention programs. Two examples are presented of the finite element program being used to predict mine subsidence at substantially different geologic and mining provinces in Pennsylvania.

Jan 1, 1984

By E. C. Simmons

Uranium is an incompatible element with respect to the major rock-forming minerals crystallizing from granitic magma, entering instead trace minerals such as zircon. The relationship between the saturation limit (SL) for such a mineral and the bulk distribution coefficient (Do) for U is central to understanding the distribution of U and its availability to late-stage fluids that can form ore deposits directly, or labile U that can be remobilized later. Low SL values imply early crystallization of zircon, but in very small proportions, minimizing Do and maximizing the degree of enrichment of U in late-stage fluids. Thus, granitic rocks with low Zr contents (due to a low saturation limit for zircon) are most likely to evolve U-enriched differentiates; this will be reflected in a high U content of the zircons (but not necessarily high U abundances in whole-rocks). Thus, the ratio of the U content of zircon to the Zr content of the corresponding whole-rock is potentially a very useful parameter in identifying granitic rocks most likely to have U-enriched solutions associated with them. The granitic rocks associated with the U deposits of the Midnite mine area, Washington, have geochemical characteristics that fit the model presented very well. The rocks are very low in Zr (100 ppm) and contain zircons with extremely high U contents (3,000-4,000 ppm).

Jan 1, 1984

To B. K. Martus I discussed several points raised by Mr Martus in my reply to Professor Krige*. Mr Martus discusses several possible interpretations of optimum South African sales, but in my paper these sales refer to the sales level that maximized the working profit of the whole South African gold-mining industry over the past eleven years. Mr Martus also seems to be under the impression that the paper deals with the future. While there may be references to the future, and some implications for the future may be obvious, the paper deals essentially with the past eleven years.

Jan 1, 1984

By L. W. Saperstein

Public Law (PL) 95-87 contains explicit demands for land use planning in its reclamation and designation sections. Both sections require recognition of local land use plans; however, they are not well integrated. Accommodation to these planning requirements affords an opportunity to create better links among local land use planners, the state's permitting authority and designation office, and mine designers. Mining companies should take a more positive interest in local land use plans and in resource inventories. States should coder handing down to local government the responsibility for accepting mine permit applications and designation of unsuitability petitions.

Jan 1, 1984

By L. C. Binon

Exploration budgets are commonly determined by rules of thumb, such as a percentage of earnings or other fiscal measure. An appropriate exploration budget is the amount needed to achieve company goals. It can be determined by discounting the income expected from achieved goals. Budgets for individual projects are determined in a similar manner except that risk of failure is included in the computation.

Jan 1, 1984

By R. N. Schulz

The recently completed modifications and additions to Reserve Mining Company's taconite concentrating process incorporate a totally new control system. Design of the new control scheme is centered on reliability, versatility, centralization, and optimization. The design objectives were achieved through a distributed control system based on a network of independent field located microprocessor based control system connected to a central control room. Operation of each micro-processors can be interrogated and modified from the central control room by the operator or by either of two computer systems. The two computer systems handle logging, alarming, specialized sequenced controls, and complex process optimization routines.

Jan 1, 1984

Introduction to high temperature oxidation of metals, by N. Birks and G. H. Meier, London, Edward Arnold, 1983. 19S pp. R30,25. Reviewers: M. B. Cortie and G. G. Garrett Seam gas drainage with particular reference to the working seam, edited by A. J. Hargraves. Woollongong, The Australasian Institute of Mining and Metallurgy. 370 pp. $A30. Reviewer: C. J. Fauconnier New books Solvent extraction Part I, by G. M. Ritcey and A. Ashbrook. Amsterdam, Elsevier, 1983. Elektronishche Steuerungen und Mikroprozessoren im Bergbau. Sicherheit und Zuverlassigkeit Environmental impact control. Philosophical and procedural guidelines for the planning professions Mineral processing and extractive metallurgy. Reagents in the minerals industry.

Jan 1, 1984

The 87th Annual General Meeting of the South African Institute of Mining and Metallurgy was held at Kelvin House, Johannesburg, on Wednesday, 15th August, 1984. Professor R.P. King (President) was in the chair, and declared the meeting open at 16h00.

Jan 1, 1984

The following pages contain valuable information about the products and services offered by our advertisers

Jan 1, 1984

By R. Simkus, J. K. Gowans

Polaris Operations, a Cominco Ltd. lead-zinc mine, is located on Little Cornwallis Island, Northwest Territories, at Latitude 75°23' N and Longitude 96°75' w. When the Polaris Mine went into operation in late 1981, it became the world's most northerly base metal mine.The Polaris Concentrator, housed in a unique process barge, is a basic lead-zinc concentrator where flotation is used to produce the lead and zinc concentrates.The paper describes the ""coarse lead"" flotation feature incorporated in the concentrator flowsheet and describes the start-up problems and continuing operation of this circuit.

Jan 1, 1984

By Felix Schmid

ABSTRACT Lateritic bauxite deposits of economic size and grade in Sierra Leone occur on granulites of the Kasila series. The high grade trihydrate ores of Mokanji are exploited by SIEROMCO since 1964. Remaining reserves are small (2 million tons) and operation moved over to the Gondama deposits of similar grade. Port Loko bauxite reserves are estimated at 100 million tons and are of relatively lower grade. It is planned to treat this ore locally into alumina. Guinea's bauxite reserves exceed those of any other nation. They occur as hard lateritic bauxite covers on plateaus of the Pre-Cambrian sedimentary formations and on doleritic intrusions. The genesis is still controversial. The Sangaredi mine has produced high grade ore for the last 10 years. Friguia exploits a relatively lower grade ore at a rate of about 2 million tpy to be treated in their local alumina plant. Kindia ore is mined at a yearly rate of 2,5 million tons since 1974. Untouched reserves at Ayékoyé and Tougué/Dabola are estimated at 6,000 million tons.

Jan 1, 1984

Reduce dust exposure of longwall shearer operators by keeping them upwind of the primary cutting drum. Approach Use a different coal cutting sequence by cutting from headgate-to-tailgate, making the cleanup pass from tail-gate-to-headgate. How It Works The cutting action of the shearer drum is usually the primary source of respirable dust at longwall shearer faces. Dust exposure of the shearer operator is deter-mined by his position relative to the lead drum, which is normally in the raised position taking a full sump. On long-wall faces where the cut pass is taken from tail-to-head, against the primary airflow, the shearer operators must remain at their controls, on the return-air-side of the primary dust source, to maintain proper control. A simple method to lower shearer operators' dust exposures is to extract the primary coal from head-to-tail, thus positioning the operators up-wind of the lead cutting drum. The bottom coal is then cut, and the floor cleaned by the trailing drum during the tail-to-head cleanup pass. This sequence places the primary dust source, the cutting action of the shearer drums, on the return-air side of both shearer operators, except when cutting out at the longwall headgate.

Jan 1, 1984

By R L. Mayville

The author explains why the strategic location and important limestone reserves at Chattanooga Quarry led to a decision to extend operating life by continued benching down to lower levels. He discusses the steps taken to accomplish this objective. These include relocation of the primary crusher from the second level to the fourth level, pre-testing of explosives designs and powder factors, control of a substantial water problem, and computer monitoring of stone production costs.

Jan 1, 1984