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Sinter mixes of three iron ore types were prepared with a range of water contents in a laboratory investigation. The mean diameter of the granulated mixes and the void fraction of beds of the mixes were determined experimentally. Pressure drop measurements over a range of flow rates were made in a laboratory permeameter with pressure tappings at several depths in the bed. The Ergun equation was applied to the results to determine the shape factor of the granulated mixes. The pressure readings down the bed were used to estimate the local void fraction in the bed using the Ergun equation and the calculated granule shape factors and it was found that there was a decrease in void fraction with depth in the bed. The significance of this and the variation of the shape factor values with the amount of water used for granulation is discussed in relation to the strength of granules of the sinter mixes.

Jan 1, 1984

By Mahesh C. Jha

Arsenical gold ores occur in many parts of the world, including numerous mines in Canada and the western United States. Free gold is often finely disseminated in the grains of sulfide minerals, arsenopyrite, pyrite, orpiment and realgar. Generally a sulfide concentrate is produced by flotation. Arsenical ores or concentrates are not amenable to direct cyanidation and therefore are considered refractory. A wide variety of roasting equipment and conditions have been used by the mills to remove arsenic and sulfur from these concentrates. The resulting calcine is easy to cyanide and gold is recovered from the cyanide solution by zinc dust cementation. Room-temperature potential-pH diagrams and high-temperature phasestability diagrams are presented to discuss the chemistry of the gold cyanidation, cementation, and roasting steps in the presence of arsenic. The environmental aspects of arsenic discharge are also included.

Jan 1, 1984

Roller seed screens were installed at The Broken Hill Proprietary Company Limited (B.H.P.) Whyalla pellet plant to replace vibrating screens on the green ball circuits. The installation of roller screens was justified by improving the sizing of the green balls. This improved sizing increased the yield of fired pellets produced from green balls thus decreasing the fuel consumption. The fired pellet sizing was improved also. This paper discusses the configuration of the roller screens installed at Whyalla, quality of green balls produced, advantages of roller screens compared with vibrating screens and future development of roller Screens.

Jan 1, 1984

By P. R. Bremmer

As part of a program to devise alternative technologies for producing alumina from domestic resources, the Bureau of Mines investigated the leaching of calcined kaolinitic clay to form basic aluminum chloride solutions. Bench-scale experiments were conducted for single-stage batch leaching with AICl3 solution and three-stage countercurrent leaching with substoichiometric HCI. Variable conditions of clay calcination and leaching were studied to determine their effects on aluminum extraction and pregnant liquor composition,

Jan 1, 1984

By R. Augsten, K. K. Feng, K. C. Cheng

"Methane emission and the desorption characteristics of vertical borehole coal samples of Greenhills multiple seams in the vicinity of Elkford, British Columbia were investigated. Three vertical boreholes at depths of 335 m, 380 m and 395 m were drilled along the west wall of an active open pit mine and 44 core samples from various coal seams were obtained for desorption studies.The results are presented in three tables and illustrated with six figures. The methane content was found to increase significantly at depths greater than 200 m. The adsorption equation by Kim and the properties of the coal have been used to predict the methane content and these were compared with the measured values by the direct method.IntroductionThe coalification of plant material in the sedimentary rock produces different ranks of co al and gases of various composition. The gas mixtures are retained in coal beds and rock strata under pressure. The gas content in a coal bed varies considerably depending on the rank of coal and the depth of overburden. The gas content is defined as the volume of gases adsorbed in a unit weight of coal materials. The net amount of gases remaining in a coal seam depends on the difference in the rate of generation of methane by geo-thermal heat and the rate of diffusion of the gases out of the coal bed through sedimentary cover. The major factor that causes the change in rank and the liberation of gases is the temperature, which is governed by the thermal conductivity of sedimentary cover and the heat flux through the underlying rocks. The rate of diffusion of the gases out of the coal is governed by the porosity of the overlying rocks and the degree of fracture. The measured values of gas content in major North American coal beds are from zero up to 24 cm3 per gram of coal(1,2). A gas content of 2.5 to 9 cm3/g is considered ""gassy"" and that of 9 cm3/g or higher is considered ""very gassy"" for underground mining(3). Normally, the gas mixtures released from bituminous coal in Canada contain 90 to 98% methane and the remainder is made up of CO2, N2, 02, H2, He and other hydrocarbons(4)."

Jan 1, 1984

By Richard P. Walters

This Bureau of Mines report reviews and assesses the technology for preparing electrodeposited coatings of the platinum-group metals from molten alkali metal cyanide baths. Methods are described for the preparation and purification of the cyanide electrolyte. Vacuum drying, fusion, and purity of the cyanide salts are discussed. Use of a sodium borosilicate test tube as a sodium-ion-conducting membrane for the addition of the desired platinum-group metal is described. The optimum plating parameters of potential and current density for Pt, Pd, Rh, Ru, and Ir coatings that result in the best deposits are given. A method for producing platinum-rhodium alloy coatings of predetermined composition is also described. The importance of careful substrate surface preparation is illustrated. While problems still remain with respect to coating porosity, careful application of the methods described permits the preparation of adherent, coherent electrodeposited coatings of the platinum-group metals.

Jan 1, 1984

Western Mining Corporation (W.M.C.) operates a nickel refinery at Kwinana, 30 km south of Perth. The refinery commenced pro- duction in May 1970, with a rated capacity of 15 000 tpa of nickel metal. A hydrometallurgical route was chosen as the most expedient way to produce nickel metal at a time when world demand for nickel was outstripping the supply. Later events dictated that an increase in production from the refinery be achieved. To this end, matte produced from Kalgoorlie Nickel Smelter, which was commissioned in 1972, was used in varying proportions as a complement to the concentrate initially utilised as input to the refinery. The effect of matte addition was to increase the capacity to 30 000 tonnes of nickel per annum. This was accompanied by other benefits which were 1. reduction in energy consumption per unit of nickel produced, 2. improved metal extraction, 3. improved precious metal recovery, 4. reduced production of ammonium sulphate by-product. Refinery operating results for the years 1970 to 1983 show how matte feed has improved refinery performance in these areas.

Jan 1, 1984

By D. Ott

Results of a research project on investment or lost wax casting will be presented. The project was concerned with various aspects of the process as they are typical for the production of jewellery from gold alloys. During these investigations testing methods for investment quality as well as for casting quality and the various process parameters were developed and charateristic defects as they occur in practice were traced back to their origin in the process. Investigated were various static casting and centrifugal casting methods in different atmospheres as well as vacuum casting in devices of different design. It was shown that independent of the method a close control of the many process parameters interfering with each other is essential for a quality casting.

Jan 1, 1984

Recent geological mapping has indicated changes to the stratigraphy of the Pine Creek Geosyncline. The new stratigraphy and interpreted depositional environments are examined in relation to the distribution and genesis of stratabound mineral deposits. Basinward correlations are made with near-shore carbonate and psammite-rudite units in the Rum Jungle region. Most other units in the same region are condensed, indicating long- lived supratidal, intertidal or shallow conditions during most of the depositional cycle. Units containing most of the mineralisation represent the earliest near-shore developments of strongly reducing partly pelitic and evaporitic conditions and contain mainly uranium and base metals. Restricted distal, strongly reducing facies with associated felsic volcanics are also well mineralised, and mainly contain gold, silver and base metals, although some deposits are probably genetically related to synorogenic or postorogenic granites. Mineralisation in other facies is almost all epigenetic hydrothermal in origin, although minor mineralisation is related to volcanics, or dolomitic parts of the sequence. Areas of potential mineralisation include near-shore environments in the north, and carbonate reefs along growth faults. Two suites of postorogenic felsic volcanics and related sediments deposited in shallow water within and around northwest and east-northeast rift systems, overlie the metasediments of the Pine Creek Geosyncline in the south. The suites have potential for volcanogenic deposits, mostly of uranium, gold and copper.

Jan 1, 1984

By J. H. Curran

In this paper, a numerical model for determining the stress and displacement fields around a crack of arbitrary geometry in a linear elastic medium is described. Accuracy and computational speed were the main considerations in selecting the numerical method and Propagation criteria used to model the growing crack. Some results regarding the stresses and displacements around a two-dimensional crack of arbitrary geometry are discussed.

Jan 1, 1984

By Gennaro G. Marino

Site conditions at several shallow room and pillar mines in Illinois are described and compared with the charac¬teristics of the subsidence profiles at the ground surface. The shape and magnitude of the subsidence profiles were found to be closely related to the thickness of the soil and rock over-burden the percent extraction of the coal, and the shape of mine pillars. The room and pillar mines were located at a shallow depth (from 112 to 220 ft), beneath flat to gently rolling terrain. Thickness of the coal seams ranged from 5 to 9 ft and at all sites was underlain by underclays. This information has been developed in order to improve techniques for evaluating the subsidence potential at sites within the Illinois coal basin. he results presented form a small portion of the work carried out by the University of Illinois with Illinois Abandoned Mined Lands Councils and the U. S. Bureau of Mines at the Minneapolis Research Center in Minnesota (Marino and Mahar, 1985). Presented in the paper are the modes of mine failures observed for Illinois room and pillar mines, an overall summary of the site geologic and mining condi¬tions, case histories of each mode of failure, a comparison of sag profiles, and then an empirical relationship between the site conditions and the maximum sag subsidence. The most ideal case histories are presented to illustrate fundamental behavior. A brief of the Paper is given in a summary and conclusions section.

Jan 1, 1984

By G. O. Kesse

The Republic of Ghana, located on the West Coast of Africa, is one of the West African countries rich in bauxite deposits. The main occurrences of bauxite deposits are at Sefwi Bekwai in the Western Region, Aya-Nyinahin in the Ashanti Region, Atewa Range near Kibi and at Mount Ejuanema both in the Eastern Region of Ghana. These bauxite deposits belong to the so-called blanket deposits as they are associated with erosion surfaces of old peneplains and occur as cappings on the flat tops of hills or mountains whose heights are generally greater than 600 metres above sea level. These deposits can also be classified as laterite-silicate bauxites since they have been formed under tropical weathering conditions. Genetic and mineralogical investigations have revealed that all bauxite deposits of Ghana are the result of indirect bauxitization processes, for the minerals of the weathering parent rocks have not been transformed directly into gibbsite. In all cases, lithomarge of kaolinitic clay can be recognised. The geology of the major occurrences of bauxite in Ghana shows that the Mount Ejuanema deposit is the only deposit associated with the Voltaian System of rocks. This rock System consists mainly of sandstone, shale, mudstone, conglomerates and pebbly beds. All the otter deposits are associated with the Birimian System of rocks which are made up of metamorphosed lavas,pyroclastic rocks, hypabyssal basic intrusives, phyllites, schists, tuffs and greywackes.

Jan 1, 1984

By He BQ

Static attachment of bubbles to solids is contrasted with dynamic attachment in flotation cells. The times of contact during particle-bubble collisions in dynamic attachment are compared with the induction time determinations and the kinetics of thinning of the liquid films separating solids and bubbles. The thinning is examined mainly in terms of electrostatic and dispersion (van der Waals) contributions to the disjoining pressure existing in the films. The local heterogeneity (on a molecular scale) of charge distribution invariably present at all interfaces (even at conditions of zero zeta potential) calls for some means to minimize possible electrostatic repulsions which arise when the electrical double layer at the air-bubble interface begins to overlap that present at the solid surface, on encounter between particles and bubbles. It is postulated that dipoles of frother molecules, owing to their ability to "flip over" (polarise), replace localized electrostatic repulsion by attraction within fractions of a milli- second, as long as the structure of the frother molecules is sufficiently "bulky" to maintain diffuse films (of mixed collector-frother) at the air/liquid interface of bubbles. The relaxation times of dipoles (signifying their "flipping over" ability) have to be shorter than the collision times between particles and bubbles for particle-bubble attachment to be facilitated under dynamic Conditions.

Jan 1, 1984

By Sloan GJ, Lysnar RD

Since the of Bergstrand's Geo-dimeter in 1946, and Wadley's Tellurometer in 1956, there have been numerous Electromagnetic Distance Measurement (EDM) instruments produced throughout the world by a variety of companies.This form of measurement has not merely replaced other methods of measurement, but has caused considerable change of emphasis in survey techniques. Major control surveys are now being accomplished using trilateration instead of triangulation. The surveying of open cuts or engineering work may be done in a fraction of the time and, in the majority of cases, to a greater degree of accuracy than with older methods.It is surprising that with this new tech-nology and development of EDM equipment which is compact, easy to use and no longer so expen-sive, no advance has been made in underground surveying. If we look at equipment being used by the majority of mining companies, we see that there have been very few changes since the Second World War. Very little research has been carried out to enable the surveyor to do his work more easily in conditions which, at the very least. are hazardous.

Jan 1, 1984

By Wilfried Ufer

[1. Einführung in die Problematik 1.1 Die Bedeutung des Schildausbaus Seit fast 30 Jahren ist die Konkurrenzsituation auf dem Primärenergiemarkt der Bundesrepublik Deutschland durch einen von Erdöl and Erdgas geführten and insbesondere gegen die Steinkohle gerichteten Verdrängungswettbewerb gekennzeichnet, der den Steinkohlenbergbau zu tiefgreifenden RationalisierungsmaBnahmen zwang. In diesem Zusammenhang kam es Anfang der 70er Jahre zur Einrührung des Schildausbaus, der eine erhebliche Produktivitätssteigerung in den Strebbetrieben zur Folge hatte and damit die Uberlebenschance des Steinkohlenbergbaus in der Bundesrepublik Deutschland enorm verbesserte. Der Grund hierfdr lag darin, daB der Schildausbau im Vergleich zu dem vor ihm eingesetzten Rahmen- and Einzelstempelausbau eine wesentlich hdöhere Ausbauleistung erbrachte, weil er sich weit weniger empfindlich gegen Hangendausbruche and aus dem Alten Mann hereinbdschende Bruchberge erwies. So erklärt sich auch die stürmische Entwicklung and die schnelle Verbreitung des Schildausbaus. Bereits 1975 stammte rd. 50 % der Fdrderung aus Schildstreben, 1990 waren es fiber 75 % and heute sind es fiber 90 %. 1.2 Die Staubentstehung beim Schildausbau Die Erfolge des Schildausbaus sind unbestritten. Jedoch nahmen :nit seiner Einführung die Probleme der Staubentstehung and Staubbekämpfung im Vergleich zum Ein zelstempel- and Rahmenausbau erheblich zu. MaBgebend dafür sind hauptsächlich folgende Gründe: - Abbau von dozen nit gebrächen, weichen Hangendschichten, die erst durch Schildausbau abbaubar wurden, - Zerkleinerung des auf den breiten Kappen aufliegenden Bergematerials infolge der höheren Ausbaustiltzkrafte des Schildausbaus, Zermahlen der sick in die Spaltabdichtungen hineinarbeitenden Bergestückchen, - Erhöhung der Wettergeschwindigkeit infolge der durch die Baufarm des Schildausbaus bedingter. Verkleinerung des Strebquerschnitts verbunden mit der Aufwirbelung and Aussichtung von Staub, - Aufwirbelung von bereits abgelagertem Staub im Bruchraum beim Hereinbrechen der Dachschichten. Die genannten Gründe treten zumeist nicht in jedem Abbaubetrieb gleichzeitig auf. Sie rind vielmehr u.a. abhängig vom Ausbautyp, von den Gebirgsverhältnissen and von der Abbaugeschwindigkeit. Trotzdem ergeben sich beim Vorrücken des Ausbaus in der Regel hohe Staubkonzentrationen, die deswegen besonders kritisch sind, weil es sich um quarzhaltigen Feinstaub handelt, der besonders gesundheitsschädlich ist. Die Hauptzutrittsstelien]

Jan 1, 1984

By Graham Jones

During 1982 Ash Grove Cement Company contracted with Wagester, Walker, Thornton & Company to convert a Calcimatic rotating hearth kiln at its Portland, Oregon lime plant from gas/oil to coal firing. Increasing costs of natural gas and No. 6 fuel oil made this conversion mandatory if the plant was to remain competitive. Unique features of this project are 1) the distributors of pulverized coal to eighteen small burners around the inner and outer perimeters of the doughnut-shaped kiln, and 2) the attrition-dryer-pulverizer mill. Ash Grove, a century-old lime and cement producer headquartered in Overland Park, Kansas (Kansas City area), looked at various schemes for multiple burner firing before employing Wagester, Walker, Thornton & Company. W.W.T. of Pitts- burgh, Pennsylvania was formed in 1980 by acquiring the Solid Fuels Division of the Pullman Swindell Corporation. This division had been active in developing solid fuel firing for brick tunnel kilns, principally in the Southeast. They continue to supply such systems firing wood waste as well as coal to the brick industry and have also converted two Calcimatic lime kilns for Dixie Lime, Sumterville, Florida, a fluid bed calciner for Texas Gulf in Aurora, North Carolina, and a chrome concentrate kiln for Diamond Chemicals at Castle Hayne, North Carolina. Testing and a proposal have been made for INMETCO, Elwood City, Pennsylvania, on an annular hearth furnace for direct reduction of iron ore to metallic iron.

Jan 1, 1984

By J. P. Bennett

Based on previous Bureau of Mines research indicating that improved high-temperature properties could be achieved for periclase refractories through chemical additions, the Bureau investigated the properties of full-size bricks produced from chemically modified periclase refractory grains and the suitability of making such chemical additions to Mg(OH)2 slurries prior to production of the periclase grains. In full-size brick testing, strength values, both hot and cold, for the optimized bricks were superior to those for a commercial 98-wt-pct-MgO refractory. The best results were obtained for a natural magnesite with an adjusted CaO:Si02 (C:S) ratio of 3.0 and a 1.0-wt-pct addition of Zr02 and for a seawater periclase with an adjusted C:S ratio of 2.5 and a 0.5-wt-pct addition of Mn02. For samples produced from chemically modified Mg(OH)2 slurries, additions of both Mn02 and Zr02 and an increase in C:S ratios produced significant increases in hot flexural strength, similar to those resulting from chemical additions made to periclase grains. The most effective modifications were additions of Mn02 to brine-derived periclases having a C:S ratio adjusted to 3.0. These results on chemically modified magnesia refractories indicate that such material could potentially substitute for magnesiachrome refractories containing imported chromite.

Jan 1, 1984

By R. J. Sweigard

Productive and beneficial use of reclaimed surface-mined land is a concern of industry, government, and the general public. An investigation was conducted of current mined-land planning practices to aid in the development of a procedure for evaluating postmining land use potentials. This investigation considered both the industry and public planning approach to mined-land planning and was based primarily upon three case studies conducted in various regions of the United States. The site planning process that was developed during the investigation is iterative in nature and has been designed specifically for the mining industry. It centers around preliminary studies and data collection, development of land use alternatives, and the evaluation of alternatives. Use of this process facilitates the evaluation of economic, environ- mental, and social impacts of postmining land use alternatives. In this paper, the process is presented along with a description of its development, application, and significance.

Jan 1, 1984

By T. M. Olson, B. G. Lewis

The adsorption of selenite on bentonite, kaolinite, and an iron--coated illite was studied to determine the importance of several soil variables on selenite removal from uranium mill tailings pond seepage. Adsorption capacities of the clays of selenite varied by orders of magnitude and decreased in the following order: illite > kaolinite > bentonite. Maximum adsorption of selenite on the clays was observed between pH 2.5 and the clay's zero-point-of-charge. Substantially less selenite was adsorbed on these clays in actual mill tailings solutions than in model systems. Virtually all selenite was removed from the tailings at pH 7. The principal removal mechanism at this pH is suggested to be the adsorption of selenite on freshly precipitated metal hydroxides. It is concluded that selenite can be removed from tailings seepage in soil or in clay liners in the presence of kaolinitic clays and iron oxides. Selenite would also tend to be removed from tailings seepage in calcareous strata.

Jan 1, 1984

By Roger C. Ilsley

The $2.1 billion Milwaukee Water Pollution Abatement Program (MWAP) requires the construction of several miles of underground openings at depths up to 350 feet for the conveyance and storage of sewage and storm water overflows. The system will include approximately 27km (17 miles) of deep tunnels ranging from 3m (10 f t.) to 9m (30 f t.) in diameter, 26 shafts and a pumping station cavern. The facilities will be located primarily in Silurian Age dolomites of the Niagara Group. The rock is characterized as competent with vertical to sub-vertical orthogonal jointing and predominantly thin shale bedding planes. The site investigation was carried out incrementally, commencing on an area wide basis, becoming site specific as facility plans were developed. To achieve cost savings through uniformity and continuity, a computerized data bank was established. Software was developed during the initial stages of the program for the production of borehole logs, structure contour maps, geologic profiles and summaries of data for statistical evaluations. This paper discusses in general terms the collection, compilation and presentation of data necessary for the characterization of the rock mass.

Jan 1, 1984