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By J. B. Hiskey

INTRODUCTION The extraction of gold and silver from ores, concentrates, and various metallurgical products can be achieved by a number of hydrometallurgical techniques. The solvation properties of alkali cyanide solutions on gold and silver were recognized 200 years ago. A cyanidation process for leaching gold from its ore was patented in 1887 and 1889 by MacArthur and Forrest. The solvent action of thiosulfate on gold and silver was observed over 100 years ago. Recently, several patents have been issued for processes using ammonium thiosulfate as lixiviant for precious metals, Berezowsky, et. al (1978) and Kerley (1981). Tozawa and and coworkers also examined the dissolution of gold in ammoniacal thiosulfate solution. Thiourea leaching of gold and silver initially discussed by Plaksin and Kozhukhova in 1941 but has received only limited attention since that early work. Use of thiourea as an alternative to cyanide was the topic of several papers presented at the 1981 AIME annual meeting In Chicago, Illinois. Hiskey provided a review of the fundamental chemistry of the dissolution of gold and silver in acidic thiourea solutions. Pyper and Hendrix reported on the leaching of a finely disseminated gold ore using thiourea as a lixiviant. The review article(6) previously presented was fairly comprehensive covering Important contributions to the chemistry of thiourea and the processing of gold and silver with acidic thiourea solutions. A search of the technical literature was made to determine recent (since 1981) progress and developments in applying thiourea to the processing of gold and silver. This review reveals that Soviet and Eastern European scientists are continuing to make major contributions to our understanding of thiourea/precious metal systems.

Jan 1, 1984

By Alfredo Dammert

The paper presents the results of a model built at the World Bank in order to analyze the aluminum industry. Bauxite demand for the year 2000 is estimated as a function of alumina refineries' requirements and of non-metal uses for bauxite. Bauxite supply by countries or regions depends on economic factors such as investment costs, operating and transportation costs, as well as on tariffs and levies. Various scenarios are considered as a result of varying the assumptions of the model.

Jan 1, 1984

The changing characteristics of raw materials has highlighted the limitations that conventional vibrating screens have in the handling of fine wet sticky materials. These' limitations have led to the development of a totally new concept of screening, the Rotating Probability Screen. In order to illustrate the practical benefits to be gained by the extraction of fine materials ahead of subse quent processes particularly in the coal industry, the experiences gained in Ro-Pro installations in America, Australia, Europe and Britain are drawn upon.

Jan 1, 1984

By R. Michael Craig

Mr. Juvkam-Wold's article is a timely and much needed presentation of the method of depressurization to reduce ground- water inflow into mine shafts. The article is very informative and discusses the effects of depressurization upon shaft inflows adequately. However, the article omits a discussion of another important benefit of depressurization: the reduction of potential for artesian burst or, as it is also called, floor heave. Confined aquifer systems (artesian aquifers) can contain water under several hundred pounds per square inch (psi) of pressure. For example, water levels at elevations of 455 m (1500 ft) or more above the top of the Westwater Canyon member of

Jan 1, 1984

By J. H. Johns, G. R. Stephan

The Climax mine has a history of dealing with ground control problems caused by major stress concentrations in the orebody. These stress concentrations, called weight, can arise in a variety of ways. The general effects of depth, rock type, and mining method give rise to weight problems, but local geologic features and daily cave line management can have even greater effects. Over the years a number of techniques have been developed for identifying weight problems in advance and for cow with them. These techniques all help us to amid interrupting the pace of cave advance and minimize the loss of production.

Jan 1, 1984

By Louis A. Panek

Rock-mass fracturing was measured on oriented drill core and along scanlines in three mines extracting mineralized porphyry deposits. Fracture families identified in the core were consistent with those found along scanlines, but fracture frequency in the core was twice that measured along scanlines. The excess fractures, which occur within 45º of a right angle to the core, apparently are produced during drilling, which implies that fracture spacing in drill core is an ambiguous quantity dependent on the drilling procedures, on the orientation and cohesion of the planes of weakness, and on the actual fractures present in the rock mass.

Jan 1, 1984

By D. Laguitton, D. Hodouin, V. K. Gupta, R. Spring

"The CANMET SPOC project aims at inducing progress in process evaluation and optimization by developing user oriented software based on state-of-the-art theory. The present work is the result of a joint effort by CANMET, Noranda Mines and Université Laval to develop two computer packages: one (RTD) to calculate the residence time distribution that best describes the material transport through the mill, the other (FINDBS) to estimate the rate of breakage and distribution function of the population balance model in a ball mill. The RTD package can handle data from various experimental methods (impulse or complex tracer feed, with or without recycling, etc...). The FINDBS package provides options for the functional description oj both model parameters Band S. The full detail of the methods and programs appears in a users guide. The program capabilities and several sample runs are presented.IntroductionSimulation of mineral dressing operations by computer has been largely contained within academic and research circles and has not yet gained a status of routine practice in the ore and coal industries. It is however a matter of time before process simulators are available on every process engineer's desk to assist process optimization tasks, flowsheet design and professional training. The CANMET SPOC project (Simulated Processing of Ore and Coal) was initiated in 1980 to assist the Canadian industry in integrating computer-based methodology for process evaluation and optimization(1). Software development, documentation and transfer is one of the main priorities of the project which will mature in 1985 by releasing a complete package of manuals and programs covering sampling, material balance computation, unit modelling, flowsheet simulation and optimization . This paper is a condensed description of a typical project element in its 1982-1983 state of development. The required methodology for ball-mill modelling and simulation was consolidated an d merged to other project elements during a joint study under contract financed by CANMET and Noranda Mines Ltd . The first part of the study dealt with documenting experimental methods and software for ball-mill computer simulation. Université Laval GRAAIM (Goupe de Recherche en Automatistion Appliquée à l'Industrie Minérale) acted as sub-contractor for this part of the study(16,17). A second part dealt with applying the model calibration techniques to a large industrial data base and is reported elsewhere(2,18,19)."

Jan 1, 1984

By F. J. Arriagada

A conventional technique used to process auriferous sulfidic concentrates involves a pre-leach oxidative-roast step. The structural characteristics of the calcine have a strong influence on the eventual recovery of gold by cyanidation. Surface analytical techniques such as scanning electron microscopy and BET gas adsorption have been utilized to determine quantitatively the structural morphology of calcined pyrite and arsenopyrite samples in the range of 450 to 750 °C under an oxidizing atmosphere. In the case of. pyrite calcines a highly porous hematite product was found below 500 °C; at higher temperatures, a coarser oxide network , was observed. The surface area of these calcines was found to decrease sharply with increase in temperature. In contrast, the surface area of arsenopyrite calcines was found to follow a bimodal-type behavior with roasting temperature with maxima at 500 and 625 °C. In the case of pyritelarsenopyrite mixtures, the surface area was observed to increase dramatically as the content of pyrite increased. The appearance of pyrrhotite as an intermediate phase in the oxidation reactions is postulated to have important structural implications.

Jan 1, 1984

By Hosking JW, Muir DM, Ruane M, Smith I. Hinchliffe WD

Maintaining carbon activity is critical to the satisfactory recovery of gold in the Carbon-in-Pulp (C.I.P.) process. Reduced activity can lead to gold losses in tails and lower tonnage throughput.Carbons from a number of W.A. C.I.P. circuits have been examined for the extent of fouling by inorganics such as calcium, magnesium, copper, nickel and silicon. Many of these carbons have exceedingly low activity leadingto low gold loading and excessive contact times. The relative importance of these fouling agents and cyanide levels on carbon activity is discussed. Mathematical modelling shows that relatively small improvements in kineticactivity lead to much lower tank volume require-ments and carbon residence times.

Jan 1, 1984

By Paul H. Lu

This paper proposes an unconventional, simple, and practical method of measuring mining-induced ground stresses with hydraulic borehole pressure cells. The method is a direct ground stress measuring technique. It does not require the value of deformation modulus for back-calculation of stresses; instead, it directly measures the ground stress in situ. The applicability and practicality of the technique are shown by two case studies. The technique may be applied to monitoring a stress buildup that may lead to mine roof failure or to rock and coal outbursts.

Jan 1, 1984

By R. D. Mollison

"For his contributions to mining which are highlighted by perseverance; successful exploration, particularly the Kidd Creek deposit; technological advancement and sound management policies; and for his lecture, "Exploration-The Diversificiation and Development of a Mining Company." Recipient of the 1983 D.C. Jackling Award

Jan 1, 1984

By A. C. Headon, K. W. Lam, D. P. Dautovich

"Microbiological activities affecting the performance of materials have been encountered in diverse situations within Ontario Hydro. Case histories of bacterial problems which are presented include ground rod corrosion at transformer stations, corrosion of a bare steel cooling water intake structure in Lake Huron and corrosion of steel components in a nuclear generation station vacuum building. Possible microbiological activities which may affect the corrosion behaviour of containers for the disposal of nuclear fuel waste in the future are discussed, as are bacterial actions suspected of causing an odour problem in residential water heaters.IntroductionBacteria are ubiquitous. Except by use of sterilization methods, bacteria -free environments are no t possible to find. Bacteria lie dormant in hostile environments, spread easily through air and water currents and reproduce rapidly under favourable conditions. Although different types of bacteria have different preferable conditions for growth, they are highly adaptive and in general, whenever there is a source of water and carbon (carbon dioxide or organic matter), there will be bacterial activities . These activities often induce or enhance costly metallic corrosion in industries and water odour problems in rural water supplies . Underground structures and systems in contact with natural water or water containing organic matter are most susceptible to bacterial attack.The types of metal-degrading bacteria , their characteristics and the conditions for growth have been reviewed extensively in the literature(1,2,3). There are several often encountered groups of bacteria which, through their metabolic processes, may lead to the degradation of metals. A large variety of bacteria produce corrosive in organic or organic acids as waste, such as the well known formation of sulphuric ac id by aerobic sulphur oxidizers . Anaerobic sulphate reducers produce hydrogen sulphide which is corrosive and has an obnoxious smell, slime-forming bacteria from slime which shelters sulphate reducers and iron bacteria oxidize ferrous to ferric ion which precipitates as hydrated oxides creating oxygen concentration cells . The following are bacterial problems encountered in Ontario Hydro. Although the number of recognized cases has been few, they show the diversity of location and environment where bacterial problems could arise. These include ground rod corrosion at transformer stations, corrosion of bare steel in a water intake structure, corrosion of steel in a nuclear generation station vacuum building and an odour problem in residential hot water tanks. In addition, possible bacterial- enhanced corrosion in containers for future disposal of nuclear fuel wastes are also discussed."

Jan 1, 1984

By John M. Pitt

A rapid in situ stress measurement technique was developed for exposed underground surfaces. The method applies radial stress in small diameter (38mm) boreholes, initiating fracture propagation which is monitored by measuring ultrasonic pulse velocity. Theoretical relations for stress concentrations near boreholes provide independent expressions for unknown principal field stresses at incipient fracture; fracture orientation defines principal stress orientation. Accuracy and precision were evaluated using blocks of brittle material subjected to known stresses. Results were comparable to those obtained by other in situ stress measurement techniques.

Jan 1, 1984

By M. E. Gershon

The development of long-term plans and schedules for strip mines now faces many companies, especially those developing large properties in the West. The rule of mining the lowest strip ratios first, while delaying equipment acquisitions and recouping investment the fastest, sometimes creates the situation where stripping ratios are too high in the latter years of mining operations. A program concept taking life of mine return on investment into account is developed in this paper to optimize mine scheduling and equipment acquisition. In addition, quality considerations (heat content, ash, sulfur, and washability) can be considered by including the appropriate blending constraints to meet contract requirements.

Jan 1, 1984

By James R. Jones

The purpose of these opening remarks is to establish a viewpoint, which will form part of the basis for later discussion between panel members and between the panel and the audience. Important issues will be identified. These ideas in the form of questions and answers, hopefully, will provide the necessary background for the ensuing dialogue. Is There An Urgency? We do not believe there is the urgency for immediate control legislation that has been depicted by some Congressional sources, environmental groups, and certain segments of the press. Emissions of sulfur oxides in the United States have decreased 15% during the 19701s, even though the use of coal by electrical utility power plants increased nearly 80%. That trend will continue as the older plants are phased out of operation and are replaced with newer plants, which must meet the New Source Performance Standards (NSPS) requiring the use of "scrubbers" to reduce sulfur dioxide emissions by 70% or 90%. The present Clean Air Act Amendments of 1977, by allowing the logical progression of economic events- -depreciation, retirement, replacement, and growth--will produce approximately a 50 % reduction in SOX emissions by the year 2015.

Jan 1, 1984

By Virgil J. Stachura

The Bureau of Mines conducted a series of delayed blasting experiments at a West Virginia contour coal mine that resulted in smoother highwalls. The 17; were smoother due to reduced overbreak and inherently safer A, to reduced likelihood of rockfall. Reduced overbreak was accomplished by an increase in the highwall hole delays, which changed the effective delay pattern geometry and the direction of burden movement. The blast delays in the highwall holes were 50 to 100 ms longer than the mine's nominal design pattern (flat V, 17- by 42-ms surface delays, 200-ms in-the-hole delay). The burden movement was effectively changed from a 45* angle to 90* with respect to the highwall. The results of the blast delay changes were evaluated using terrestrial photogrammetry to generate vertical profiles at regular intervals. This evaluation showed that delay changes produced generally smoother vertical profiles.

Jan 1, 1984

By Y. A. Topkaya

The placer gold occurrences at Sart Çayl, Manisa, Turkey, the legendary River Pactolus of King Croessus, were evaluated in this study to determine if this deposit contains sufficient recoverable value to justify development and exploitation. The gold occurs both in the upper Neogene conglomerates and the alluvium derived from these conglomerates. The total reserve in the whole region is estimated to be 500 million cubic metres. Samples were taken of the upper conglomerate and in the alluvium in an attempt to determine the amount and the physical nature of the gold. The gold in samples was recovered by screening out barren oversize followed by washing the sand and gravel through riffled sluices. The resulting sluice concentrate was later panned and amalgamated at site. Laboratory cyanidation testing of some samples for control purposes was also done. The average calculated free gold was found to be about 90-100mg/m3 and the size of gold flakes found was quite small. The field as well as laboratory testing of the samples of Sart Çay1 indicated that the potential reserves in this region could only be developed as a sand and gravel operation and the gold could be recovered together with the heavy minerals as a byproduct.

Jan 1, 1984

By B. (Mamas) Das

A project to evaluate the suitability of point Load strength tests for testing and classifying coal measure rocks for coal mining application was initiated by Canada Centre for Mineral and Energy Technology (CANMET). A summary of this study with emphasis on the important findings is presented in this paper. The instrument as used in this study is a Robertson Research Rock Strength Index Log. Because of the variation in the correlation ratio between uniaxial compressive strength and point Load strength index for hard rocks and soft rocks it was decided to establish this corre¬lation initially on cement concrete specimens specially prepared for this purpose following ASTM specifications. These specimens are expected to represent soft rocks and at the same time would be of uniform quality. Once a general trend of this correlation was established tests were performed on coal and rock samples from the sub-bituminous and bituminous coalfields in Canada. The most important results may be stated as follows: (i) Generally, the common value of the ratio between the uniaxial compressive strength and the point load strength index ranges between 8 to L4. (ii) The Robertson Research Rock Strength Index Log proves to be quite suitable for testing sandstone, siltstone and some coals from the bituminous coalfields but problems have been experienced when testing weathered samples or samples from the sub-bituminous coalfields. (iii) In some cases tests were successful if Larger samples from weathered zones or from sub-bituminous coalfields were used. However, a magnified load gauge for 0-3KN or 0-5KN is expected to be the best solution for soft and weathered rocks in most of the cases. Some mudstones and some rocks from weathered zone do not appear to be suitable for these tests. This aspect of the study is still under investigation. (iv) Deterioration of rock properties due to weathering has been determined through tests on samples collected from weathered and unweathered samples.

Jan 1, 1984

By George M. Potter

Precious gold and silver markets support substantial activity in the search for and development of improved and unconventional ore and tailing processing methods. The need for such methods 1s strengthened by consideration of increasingly low grade and refractory ores and old tailing reserves. As background for this review of new and unconventional precious metal processing, recent USBM data (1981) show annual world gold production of about 40.8 million troy ounces. In the U.S. about half the 2.8 million ounce consumption was used for jewelry and the arts, 39 percent for industry, and 8 percent for dental purposes. World silver production in 1981 was about 365 million ounces. Domestic usage the same year was about 117 million ounces. More than $ was used for photography and 30 percent for electrical and electronics. By process, about 1 percent of U.S. production of gold came from amalgamation, 66 percent from cyanidation, 31 percent from smelting ores and concentrates, and 2 percent from placers. As for silver, about 11 percent is from cyanidation and 89 percent from smelting ores and concentrates. Evidently the search for innovative and unconventional precious metal processes must include gravity concentration, froth flotation, hydrometallurgical, and electrometallurgical methods. Although smelting processes are equally important, they largely comprise nonferrous metal technology, and are not discussed here.

Jan 1, 1984

By W. E. Pittman

The Bureau of Mines, as part of its Health and Safety Technology Program, is conducting research on the use of ground penetrating radar (GPR) for mine hazard detection. GPR offers a possibility of mapping immediate below-surface geologic conditions, including faulting and other anomalies, thereby exposing potential safety hazards to miners. This report summarizes a literature review of the current status of GPR research in and outside the Bureau.

Jan 1, 1984