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By L. E. Schultze

The Bureau of Mines has devised techniques to recover lithium from geothermal brines as the chloride. More than 99 pct of the lithium was precipitated from a brine containing 170 mg/L Li by adding a solution of AICl3 and increasing the pH to 7.5 with lime slurry. The Li-Al precipitate was dissolved in HCl and sparged with gaseous HCI to recover the AlCl3; this resulted in a solution containing LiCl and CaCI2. The solution was evaporated at 1000 C to obtain a mixture of the chlorides from which 97 pct of the lithium was recovered and 90 pct of the calcium was rejected by leaching with tetrahydrofuran. The LiCl recovered by evaporation of the tetrahydrofuran was purified by dissolution in water and treatment with oxalic acid. The final LiCl solution contained 89 pct of the lithium originally present in the brine and had a purity of 99.9 pet.

Jan 1, 1984

By R. F. Shurtz

This note calls attention to a contradiction in current eatistical theory and to corresponding difficulties in practice. These are significant concern in evaluating almost all ore deposits. The theoretical contradiction is that the commonly used spherical model for the semivariogram is not consistent with the usual definition of a "regionalized variable" as a mathematical function, the direct study of which "is excluded because its spatial variability is usually extremely erratic, with all kinds of discontinuities. . ." (Journel and Huijbregts, 1978). Specifically, this means a grade function that is too "rough" for interpolation to be useful. The practical difficulty is that the spherical semivariogram interprets the data upon which it is based in a manner that is, more often than not, demonstrably inconsistent with reality. This is attributable to the widely disregarded interaction between the sample pattern and the grade function. Each sample pattern "blurs" the grade function in its own particular way. It is as though the grade structure of the deposit were seen through a lens of poor resolution or reflected in a warped mirror, such as those found in amusement parks. The fitted spherical model embeds this sometimes dangerously blurred and distorted image in the Krige regression. A full analysis of these inconsistencies is to be presented later but, in the meantime, it seems urgent to communicate their effects so that those engaged in estimating ore reserves may be on guard. The spherical semivariogram has a sill and can be replaced by the corresponding covariogram. The equation of the spherical covariogram in normalized form, that is, variance and range both equal to one, is represented as: [ ]

Jan 1, 1984

By Elizabeth A. Johnson

Minor-element behavior and interaction in the copper matte-iron silicate slag system have been studied by the Bureau of Mines. In the present work, the possibility of interactions among the minor elements As, Sb, Bi, Se, and Te was investigated. Equilibrations of matte, slag, and one of each of the five minor elements were performed at 1,250° C under typical matte smelting atmospheres of CO, CO2, and S02 for mattes containing 40, 50, and 60 pct Cu. Results are compared with those of a previous Bureau of Mines study in which all five minor elements were present simultaneously.

Jan 1, 1984

By Terry R. Neumann

During 1983, U.S. Bureau of Mines personnel examined mines, prospects, and mineralized zones to evaluate the mineral resources and potential of the Funeral Mountains Wilderness Study Area (WSA), Inyo County, California. Eleven mineral properties and two mineralized zones were examined during this study. Of these, six are within the study area and seven adjacent. There are no active mines, in the WSA, nor is there evidence of past production from any claim within the study area. The WSA contains no identified mineral resources. However, occurrences of bentonite, zeolites, and strontium were found in the area. There is little likelihood for resource development of any occurrence in the WSA. The area, in the Basin and Range Physiographic Province, is dominated by a Paleozoic marine sequence. Segments of Tertiary continental fluviolacustrine sediments, including volcaniclastic rocks, abut and overlie the Paleozoic rocks in fault controlled basin areas. Significant concentrations of bentonitic clay and zeolites occur as alteration products in Tertiary tuffaceous sedimentary rocks. However, they are generally low-grade, thin, and discontinuous, precluding commercial development. Limestone, quartzite, and sand and gravel in the area are suitable for many types of construction uses, but similar deposits outside the WSA are closer to markets. No energy resources have been identified in the WSA.

Jan 1, 1984

By C. H. Bloomster

This study estimated (1) radon and radon daughter emissions from underground uranium mines; (2) the reduction in radon that would be released to the surface by using control techniques such as bulkheads, sealants, backfilling, and positive pressure ventilation; (3) the cost for radon and radon daughter removal from total exhaust air; and (4) total radon and radon daughter discharge for lower occupational exposure limits. For 13 large underground uranium mines, estimated yearly radon emissions from each mine ranged from 900 to 3,400 Ci. The estimated age of air emitted from the mines ranged from 11 to 37 min. Potential radon removal methods for the total mine exhaust were evaluated. The cost of these methods was prohibitive. Diurnal and seasonal changes may affect radon emission over short periods of time, but do not affect the total emissions over the long run. Radon and radon daughter emissions would be little changed by increased ventilation requirements needed to achieve lower occupational exposure limits. The concentrations in the exhaust would be lower, but the total release would be the same

Jan 1, 1984

ABSTRACT' The first references to gold in New Guinea were by the Portuguese in 1525. The first significant discovery and gold rush was on Sudest Island in 1888 and was a natural extension of the rush that surged up Australia's eastern coast and ended at cook- town. Prospectors made a series of minor discoveries in coastal regions before the first large discovery at Wau/Edie Creek/Bulolo in 1925. Major post war gold discoveries were made at Bougainville, Frieda River, Porgera and Ok Tedi. On Misima Island a large bulk low grade deposit has been recognised surrounding old gold workings. Gold exploration has increased drama- tically since the lifting of a 3 year moritorium on new exploration areas in Noverrber 1982. A new bulk low grade gold discovery has been made on Lihir Island, north of Bougainville and a number of other promising areas are being drilled. Gold production is also expanding dramatically from current levels of 600,000 ounces to an anticipated 1.3 million ounces in 1985 with the opening of Ok Tedi. Other potential developments are likely to increase output above 2 million ounces by 1990. Papua New Guinea's world ranking as a producer is likely to move from 9th to 7th in 1985 reflecting the favourable geological potential, stable political environment and attractive development terms offered by the Government.

Jan 1, 1984

By A. E. J. Gallagher

There are many influences which have a bearing on the economics of industrial minerals production. The purpose of this paper is to discuss briefly three factors which have economic significance in the production of these mineral commodities. The three items of discussion include 1) the nature and relative value of the industrial minerals group, 2) project planning, and 3) market analyses. General aspects of these factors are familiar to most of us. However, an attempt will be made to give some current details regarding each. Also, in reality, project planning and market studies are usually so closely associated that they will be discussed jointly, rather than separately. This will be done by way of examples which show how these two activities actually evolved for two industrial minerals projects.

Jan 1, 1984

By Thomas R. Scotese

A rock mechanics instrumentation and monitoring program was implemented during pillar extraction at Gulf Mineral Resources' Mt. Taylor Mine, the deepest uranium mine in the U.S. Three types of monitoring were employed: (1) drift convergence around stopes (using a portable tube extensometer), (2) stress changes in pillars (using vibrating wire stressmeters in horizontal boreholes), and (3) load changes in haulageways under stopes (using vibrating wire load cells in jack stands). Results include convergence-time graphs, convergence contour maps, stress-time graphs, a stress increase contour map, load-time graphs, and abutment load limit maps. Major factors influencing results include (1) size of pillars around the extraction area, and (2) presence and orientation of a major fault adjacent to one extraction area. These factors, combined with pillar extraction, produced evidence of load transfer over 120 m from a stope measuring only 55 m x 45 m. Vertical stress increases of 7 to 17 MPa (1000 to 2500 psi) within 60 m of the stope were obtained using the stress- meter manufacturer's method. The fault apparently prevented load transfer in the down-dip direction but increased load transfer in the up-dip direction. Convergence rates of up to 1.3 cm/day (0.5 in/day) were measured at two stations. Instruments were generally reliable despite adverse underground conditions. The instrumentation and monitoring program at Mt. Taylor provided a warning system against ground control problems and a characterization of ground behavior for future development and extraction of pillars. Recommendations are made for future mining and instrumentation practices.

Jan 1, 1984

By Herve Duplaine, Charles H. Dowding

Calculation of response spectra for blast induced vibrations is necessary to fully understand and in some instances comply with frequency or distance related safe blasting criteria. Fortunately, micro-computer systems costing less than $5000 (such as that described herein) can be programmed to calculate response spectra. This system will calculate response spectra from paper as well as FM tape records. It both digitizes (prepares the record for computer calculation) as well as calculates. Programs for the calculation have been written in BASIC, an easy to understand language used with word processors. In addition to describing the equipment and operation of the micro computer the paper will discuss the process of and rules for digitization, use of the computer for record production and will present a simple physical model for understanding dynamic structural response.

Jan 1, 1984

By Thomas M. Tharp

INTRODUCTION Attempts to analyze the stability of slopes, foundations and underground openings in discontinuously jointed rock have generally assumed full joint continuity or ignored the role of stress concentration at the tips of discontinuous joints. The most common approach in rock slopes is to consider a failure plane consisting of coplanar, but discontinuous joints separated by intact rock. The intact rock is assumed to fail in shear as a Mohr- Coulomb material and to contribute a strength component proportional to the fraction of the failure plane that is intact rock (Jennings, 1970). An alternative approach by Stimpson (1978) applies Lajtai's (1969) theory for shear strength of discontinuously jointed rock masses to slopes. Lajtai allows tensile failure in the intact rock of a composite surface. This theory yields lower shear strength than that of Jennings (1970) except in the presence of high normal compression, however it also fails to account for the stress concentration at the tip of a discontinuous joint. For a given slope geometry, stresses increase with slope height, but in both of these models rock mass strength is independent of size. A fracture mechanics analysis shows that particularly for small slopes, rock mass strength decreases with size. A continuous stepped failure surf ace produced by propagation of preexisting joints may develop at lower shear stress than predicted by the Jennings (1970) or Lajtai (1969) models. This fracture mechanics model applied to slopes in competent rock is more realistic in its assumed failure mechanism, and for large slopes more conservative than the Jennings (1970) or Lajtai models (1969).

Jan 1, 1984

By Ypma PJM

The Westmoreland uranium deposits occur on the northern flank of the Murphy Tectonic Ridge in the upper member of the Westmoreland Conglom- erate. Uranium mineralization is spatially associated with the contact of the overlying basaltic Siegal Volcanics and the margins of in- trusive dolerite dykes which are geochemically similar to the Siegal Volcanics. Thermoluminescence (TL) measurements on 800 samples from within the orebodies and surr- ounding host rock (up to 8 kilometres away from the deposits) have indicated that all of the Westmoreland Conglomerate has suffered major radiation damagg attributable to at least 10 ppm uranium over 10 years. The underlying rhyolitic Mid Proterozoic Cliffdale Volcanics have distinctive TL glow curves indicative of radiation sensitization caused by high uranium contents. These vol- canics are part of the Mid Proterozoic volcanic event known to be enriched in uranium. The Westmoreland Conglomerate has been derived by erosion of the uranium-rich Cliffdale Volcanics and associated Nicholson Granite Complex which makes it likely that the Westmoreland Conglom- erate had a high inherent uranium content.

Jan 1, 1984

By R. P. Mahant

"Extensive pilot plant investigations were conducted both on partial roasting an d electric furnace smelting from September 1973 to August 1975.The objectives of the pilot plant investigations were:(I ) to confirm the application of available process technology to treatment of Falconbridge concentrate.(2) to examine partial roasting variables.(3) to investigate electric furnace smelting of roaster calcines .(4) to develop process design and operating parameters for a commercial plant.This part of the paper will cover the following topics:Partial Roasting InvestigationsPilot Electric Furnace InvestigationsPartial Roasting InvestigationsThe specific objectives were to:1. establish process variables for maximum oxygen efficiency and bed fluidi ation.2. determine the product distribution between the roaster and the various gas cleaning stages.3. produce a mass and thermal balance."

Jan 1, 1984

By Bruce H. Gardner

This paper describes the application procedure of the Stress Control mine design method. This procedure has evolved over the past 20 years of the practice of this Method in trona, potash, salt, and, most recently, in coal mining. The Stress Control Method of mine design has been defined and amply described in previously-published work (1,2,4) -- likewise, the associated system of in situ instrumentation (3,4) and the computer modelling technique (2,3,4) which are the principal tools of this method. The present paper defines the procedure by which the in situ instrumentation and computer modelling cools are combined in adapting the general concepts of Stress Control to produce site-specific design solutions. This procedure is illustrated by means of case examples from three mines. The Stress Control Method utilizes the geometry of underground excavations, particularly through the time sequence of the creation of yielding pillars, to control stresses. The time sequence is devised such that all the primary stress envelopes are transformed into a single secondary stress envelope, surrounding the group of rooms separated by the yielding pillars. The secondary stress envelope provides protection to the roof and floor boundaries from all the external stresses. This stress relief effect removes the cause of roof and floor failure -- high shear stress in the weakly confined boundaries of underground openings. It thereby replaces artificial support with ground self-support, enabling simultaneous in¬creases in stability and percent recovery. Within limits which are still being explored and extended, the Stress Control Method has proven capable of overcoming the trade-off between stability and extraction ratio which has afflicted conventional mining methods. The application procedure of the Stress Control Method is outlined below in terms of the objectives, structure, and stages of a generic mine rock mechanics program for the site-specific adaptation of the time control yield pillar design technique.

Jan 1, 1984

By G. Czupryna, S. Natansohn

Electrowinning is the prevalent technique for recovering silver from wastes generated in silver-tungsten electrical contact fabrication. Such scrap is placed in a permeable plastic basket, which constitutes the anode compartment, and is suspended in a larger cell where the cathode is mounted. A silver nitrate solution is used as the electrolyte and, upon application of an electric field, the silver migrates to the cathode where it deposits. At times, there is tungsten migration to the cathode compartment and consequent co-deposition with the silver. This W contamination, which may amount to several thousand mg/L (oz per gal), necessitates additional purification of the deposited Ag and its removal would, therefore, be advantageous. Eliminating the W impurity also extends the operating period of the cell with corresponding increases in the Ag output and savings in labor costs. The solution to this problem lies in the selective removal of the W from the AgNO3 electrolyte either by liquid-liquid or liquid-solid extraction. Although W extraction in the liquid-liquid mode with a quaternary amine or other reagents as extractants appears feasible, particularly in view of the low pH (about 1.5) of the system, this approach was not considered because it is essentially a batch-type process. It is a more elaborate industrial operation than extraction by ion exchange resins. Implementing the latter process consists of passing the electrolyte from the electrowinning cell through an ion exchange column which would extract the tungsten selectively and returning the tungsten-free stream to the cathode compartment. This process continues until the W extraction efficiency decreases (as a result of resin loading) below an acceptable value. The electrolyte is then directed through another, similar column while the W values are eluted off the first one and the resin is regenerated for another cycle. Thus, two columns in a parallel flow pattern provide the means for continuous processing of the electrolyte feedstock.

Jan 1, 1984

By Eupene GS, Cheong GE

Operations at the Mount Bonnie gold/silver project are described. The project is based on the gossan of a stratiform and stratabound polymetallic sulphide deposit. The gossan contains approx- imately 100 000 tonne of ore grading 8g/tonne Au and 230g/tonne Ag. This is mined in an open cut, and transported to a stockpile area lkm away, from which it is fed to the treat- ment plant. The ore is crushed through two stages and fed to a fine ore storage shed, from which it is reclaimed, milled and cyanide leached in draft tube agitators. The pulp is filtered using a horizontal belt filter to recover a pregnant solution. Silver sulphide is precipitated using sodium sulphide solution, and collected as a mixed sulphide/precoat concentrate on a drum filter. The solution is then passed through carbon columns where the gold is adsorbed and is subsequently recovered by methanol desorption using a process developed by Micron Research, and electrowinning. Modifications to the treatment plant circuit based on operational experience are Described.

Jan 1, 1984

By Bernard J. Steblay

Millions of mechanical anchor roof bolts are used each year for mine structural support. The benefit of this bolting depends on a number of factors including rock density, bolt length, in situ stresses, time elapsed between mining and installation, rock properties, bolt patterns, and tension (Lang, et al., 1979). Installation tension is a major determinant of support quality. Postinstallation tensions indicate both the usefulness of the individual bolts and the behavior of the reinforced rock structure. The importance of short- and long-term bolt tension measurements is well recognized, and such measurements are required by regulations (Fed. M/NM Nine Safety and Health Reg.). These regulations also take into account the difficulty of practical tension measurements. Only a statistical sample of the bolts installed is required to be measured using current torque wrench technology. Drawbacks to this practice are that the anchorage is disturbed and perhaps weakened, accuracy is limited by friction to about 30% (Lang, et al, 1979, and Barry, et al., 1956), and the procedure is relatively time intensive.

Jan 1, 1984

By Robin G. Burn

An orebody is a mining company's greatest asset; without it there can be no mine. Yet, by the very nature of the industry, orebodies are wasting assets whose progressive depletion must be balanced by continued discovery of new ore to enable both the industry to survive and the raw material demands of society to be satisfied. Although mineral exploration may be viewed as any activity which leads to the creation of investment opportunities in the mineral industry, ultimately new ore can only be generated through discovery. The process leading to discovery may involve a long chain of independent and interdependent events. It will almost always be repetitious and require the examination of many prospects or trials before the goal, a commercially successful discovery, is satisfied. Long term survival of a mining company through regular discovery of new ore, requires a continued commitment of funds and effort to mineral exploration.

Jan 1, 1984

Data recently released indicate substantial improvement in mineral industry performance for 1984. Business plans to increase plant and equipment spending in 1984 by 14.8 percent, according to a recent survey conducted by the Commerce Department's Bureau of Economic Analysis (table 1). In contrast, capital spending by all industries declined 4.8 percent in 1983 and 2.3 percent in 1982. The latest estimate of planned expenditures for 1984 is $2.2 billion higher than the comparable estimate based on the survey conducted in late January and February 1984.1/ [ ] Of particular significance to the U.S. mineral industries are the 15.5-percent increase in capital spending planned by manufacturing in 1984 and the planned 18.6-percent increase in spending by durable goods manufacturing, where the largest increases are planned in the transportation equipment (26.4 percent) and electrical machinery sectors (23.5 percent). Capital expenditures in manufacturing declined in both 1982 and 1983.

Jan 1, 1984

By Clarence O. Babcock

Since Vicat in 1833, the width to height ratio of a mine pillar has been taken as the fundamental variable in pillar design. From work in the laboratory by many investigators testing rock, Coal and concrete samples, it has been concluded by some that pillars with a width to height ratio of 10 to 1 are indestructible. It has also been concluded that a constrained core exists within the pillar which increases the pillar strength. The role of the roof and floor, if mentioned at all, is often noted in an incidental way. In the present work on laboratory testing of model pillars on concrete, coal, and rock instrumented with special strain gages, it was concluded that the end constraint and not the width to height ratio is the significant variable in determining the pillar strength. In tests where the end constraint is steel, a large compressive stress is produced on the horizontal plane of the pillar, and this effect increases as the width to height ratio is increased, resulting in an increase in pillar strength. If the end constraint is not steel but something with a small Young's modulus, the state of stress in the horizontal plane may be tensile, increasing as the width to height ratio increases, resulting in a decrease in pillar strength. Related to mining, the results are that a large width to height ratio pillar is strong for strong roof and floor and weak for weak roof and floor. That is, the roof and floor and not the width to height ratio determine the pillar strength. The confined core condition should be verified by testing if large pillars are to be used. If there is no confined core or the pillar is in tension, smaller pillar sizes should be used. The final conclusion is that the geometry alone is meaningless in pillar design.

Jan 1, 1984

By W. Petruk

"D. Doyle How large is the beam to which you referred? Are we considering Watts, Griffis the probe of a 1 micron sized particle?& McOuatReply Yes. The beam would be about 1 micron. We could enlarge or reduce it depending on the current in-put.D. Doyle Then chemically bound material we might not see. If you are restricted to 1 micron then you would not be able to separate things smaller than this. Is this not so?Reply We won't be able to analyse it but we will see it as the scanning electron microscope has a resolution down to about 0.1 microns. We should be able to get the general composition of such a grain plus its surrounding grains. We feel we can then make a reasonable estimate if it were as small as 0.1 microns. An accurate analysis would be achieved with grains of 3 and 4 microns.D. Doyle Would this have an application in the hydrocarbon field?Reply The lowest atomic number would be sodium. We wouldn't be able to go below that atomic number. Anything with sodiumor a larger atomic number would enable us to analyse the carbon.M. Fairwether Do you have any policy relating to priorities. For instance areCominco companies going to be limited in the amout of samples permitted to give everyone a chance because quite frankly our company, and I'm sure all base metals companies can hardly wait for the installation of this equipment. I can forsee two years back-log of work in the first month.Reply Quite frankly, I haven't looked at this. At the present time the work is under the START program but I suppose we will have to look at possible changes. Anything under the START program has first line priority.B. Thorndycraft Will the briquetting of samples be automated as well? Pinson MiningReply No, not at this point. Our polish section laboratory is first-class and can turn out 18 polish sections a day which is more thar we can handle.B. Thorndycraft With the capability of this machine to operate in a hands-off manner perhaps it could start to look for the 5 micron gold particle in tailings?Reply I have such a program using a wave-length spectrometer rather than the energy dispersive. The wave-length spectometer is about 10 times as sensitive and would scan the section much faster. A one inch diameter polished section would be scanned in about 7 hours for anything 1 micron or larger."

Jan 1, 1984