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By Hassan El-Shall, G. L. Zucker, T. S. Jordan

INTRODUCTION This chapter will discuss, both from fundamental and practical points of view, the flotation of non-sulfide min- eral s. The flotation characteristics of silicates, salt-type minerals, oxides and coal will be reviewed. Dup- lication of the thorough and excellent presentations by many authors is not intended and a comprehensive list of references is included. GENERAL PRINCIPLES Collectors for Non-Sulfide Minerals : All minerals, with only a few exceptions are readily wetted by water, that is, they are said to be hydrophilic. The purpose of a collector is to coat the mineral surface and render it hydrophobic, preferring an environment of air over an environment of water. Relative to sulphide minerals, the non- sulfides are more naturally hydrophilic and therefore, require a collector with a greater chain length. This is accomplished by using a collector which has a proportionally longer hydrocarbon chain. Both anionic and cationic flotation collectors are used in non- sulfide flotation. Anionic Collectors. These are collectors which ionize in solution to give a negatively charged radical. They have the general structure R-A, where R is a hydrocarbon having 8 or more carbon atoms and A is a hydrogen or an alkali metal. The most common collectors in this group are fatty acids which could have saturated or unsaturated hydrocarbon chains. Such chains may be straight or branched. The configuration of the chains affects their solubility in water and their adsorption characteristics. In general, as the chain length increases the adsorption and the collecting power increases. However, it should be noted that the solubility decreases. The solubility of unsaturated chains is greater than that of saturated fatty acids because double or triple bonds are polar and thus attract water molecules. Solubility data for collector metal salts, even though important for a proper understanding of flotation are not available for all collector systems. Solubilities and structures of different fatty acids are reported by Fuerstenau (1982). Values for the solubility products of fatty acid salts selected from a paper by Du Rietz (1958) are given in Table 1.

Jan 1, 1986

By N. Saracoglu, R. H. Wallis, J. E. Betz, F. L. Jagodits, B. R. Krause

"Geophysical test surveys were conducted with various methods (EM, lP, gravity and magnetic) over the McClean uranium deposits of the Canadian Oxy- lnco Joint Venture. The result s were assessed to judge the contribution each method might make toward further discoveries of graphite-associated uranium occurrences.The best drill targets have proven to be discontinuities in graphitic conductors and locations where the tatter are intersected by fracture zones in the Athabasca. The tests demonstrated that the preferred combination of geophysical survey s is horizontal loop EM to locate graphitic conductors in the basement and VLF-EM to locate the fractures.IntroductionThe discoveries of the McClean North and South uranium deposit s (Fig. 1) are essentially geophysical successes resulting from drilling MaxMin delineations of INPUT airborne electromagnetic responses (Saracoglu et al., 1983). After the initial discovery in 1979, various geophysical methods, techniques and instruments were employed to test their effectiveness in this environment and to guide exploration for other deposit s of a similar nature in the remainder of the 260 km2 property.The McClean uranium deposits lie below 150 m to 180 m of overburden and Athabasca Group. Radioactive signatures might be expected; however, the Athabasca Group acts as a barrier to radioactive emanations. Fortunately, the uranium mineralization is associated with graphite in the crystalline basement. Prior drilling of ground electromagnetic anomalies confirmed that EM surveys could locate and out line basement graphitic conductors. However, as there were many anomalies, most of which could not reasonably be expected to be associated with uranium , there was need to identify additional parameters, related to mineralization, which could be detected geophysically and used to narrow the search."

Jan 1, 1986

By Hochwimmer B, Baxter JL

Heavy minerals are mined from two fossil strandlines on the southern Swan Coastal Plain. The Capel shoreline, 7 km inland, and the Yoganup shoreline, 15 km inland are arcuate, northwest-facing, and remote from the modern coast. Based on foraminiferal and molluscan assemblages, the shorelines are probably of Pliocene age. The Yoganup shoreline is adjacent to the Whicher Scarp, which is cut into the Leederville Formation (Lower Cretaceous) at the southern boundary of the Swan Coastal Plain. Stratigraphic relations and detailed sedimentology have been studied from temporary exposures in the Yoganup Extended and Yoganup North mines, within a strandline complex at 27 m and 18-33 m above sea level respectively. Heavy minerals were deposited in thin, shallowing-upward sequences along a wave-dominated clastic shoreline cut into pre-Cainozoic sediments. Lithofacies units deposited in eolian, foreshore, shoreface and lagoonal environments are the most significant sites of heavy mineral accumulation. The data collected provide a basis for further exploration.

Jan 1, 1986

By W. M. Luff

The Brunswick No. 12 Deposit is a large polymetallic massive sulphide deposit, occurring in Ordovician age rocks of the Tetagouche Group. Silver is contained within the sulphide zones and economically it is the second most important commodity produced. Brunswick is one of the largest silver producers in Canada. The distribution of silver within the mine is presented, with examples from various levels. The concentration of silver can be shown to be related to both stratigraphy and structure. The mineralogy of silver in mill products is also presented.

Jan 1, 1986

By Robert B. Parsons

"In all likelihood, Canada's mining industry would be adversely affected by corporate tax reform proposals actively being considered by the Department of Finance in Ottawa. When the next set of proposals for lax reform is released later this year as promised by Finance, the mining industry had better be prepared 10 take a hard look.IntroductionTwo federal budgets ago, in May 1985, Finance Minister Wilson tabled budget papers that were more massive in terms of volume than most federal budgets. Buried in this mass of documentation is a discussion paper entitled ""The Corporate Income Tax System-A Direction For Change"". When the discussion paper was tabled over one year ago, reaction from the business sector was almost nonexistent. By and large, the paper was regarded as nothing more than one more federal publication of mild academic interest.But, recent events suggest that this discussion paper for corporate tax reform could be the cornerstone for a series of changes to the tax laws which would have more profound and widespread effects for all sectors of the economy than any reform since 1971 . No industry in Canada can afford to ignore the movement afoot in Ottawa for corporate tax reform."

Jan 1, 1986

By Gary A. Kordosky, R. Brantley Sudderth

The solvent extraction process as it applies to the recovery of metals from solutions on a comnercial basis is described. The four types of classes of sol vent extraction reagents are explained: 1) solvation, 2) acidic, 3) ion-pair, and 4) chelation, and examples of each type of reagent system are given. The uranium and copper extraction examples, using the ion-pair and the chelate reagent types respectively, are presented in greater detail to illustrate the more subtle aspects of reagent evaluation and selection. Practical experiences in the laboratory and at some operating plants are a1 so discussed.

Jan 1, 1986

By Frank P. Traczyk

INTRODUCTION The process of solid-liquid separation can be an important decision in plant design. It is very important that one must consider not only the most effective means of solids-liquid separation, but also to consider the effects on upstream and downstream processes. A solid-liquid separation is done either to remove the solids £ran the liquids as in copper concentrates or rave a liquid from the solids as in uranium operations. In either case, washing can be an important consideration to clean the solids or recover the liquids. This section will deal with solid- liquid separation other than thermal, sedimntation processes, or hydro cyclones. The three major areas discussed are pressure filters, vacuum filters, and centrifuges that are most cannon in the minerals industry. PRESSURE FILTERS Pressure filters are one common type of solid-liquid dewatering devices. There are my different types of pressure filters that are both continuous and batch operations. They are characterized by using an external pressure to push or force the slurry through porous media to force the liquids out of the solids. Whereas vacuum filters are limited to one amsphere or bar working pressure, some types of pressure filters operate as high as 16 bars pressure. Pressure filters are also effective for hot slurries where a high boiling point can be a problem or precipitation occurs under vacuum. The types of pressure filters most common in the mineral processing industry include plate and frame and recessed plate filters. Some of the new technologies including automatic pres- sure filters and belt presses are also discussed. Plate Frame Filters Plate and frame filters are one of the oldest and most effective means of both dewatering solids and clarifying liquids. Plate and frame filters consist of a skeleton that is used to hang or support alternate plates and frames that are pressed together to form chambers. The filter plates consist of a drainage grid that is covered by sane type of filter media through which a liquid is

Jan 1, 1986

By Agnes Y. Lee

The Bureau of Mines has developed an effective hydrometallurgical method to recover high-purity Pb metal and elemental S from concentrates. This low-temperature process eliminates S gases and Pb emissions, in contrast to the current high-temperature smelting technology. The method consists of (1) oxidative leaching with H202, Pb02, and waste fluosilicic acid at 95° C to produce a solution of PbSiF6 and a residue containing elemental S, (2) electrowinning the PbSiF6 solution at 35° C to produce 99.99 pct Pb metal and H2SiF6, and (3) solvent extraction to recover S, leaving a residue containing Cu, Ag, and other metal values. Spent electrolyte was recycled repeatedly, with impurity buildup controlled by controlling the leach parameters.

Jan 1, 1986

By Song Xiaotian

Studies have been carried out to optimize the VCR's mining sys- tem on the basis of synthetic analysis at Fankou Pb-Zn mine in Southern China. The synthetic e- valuation method is proposed for selection of mining alternatives and stope dimension optimization techniques. Theoretic calculation and computer optimization of the fragmentation of rock blasted by multispherical explosive charges are discussed. The mathematical and optimal fragmentation models are built. The optimum model is built for the main mining operations such as drilling, blasting and haulage. Lt can be used to evaluate VCR?s mining projects, select mining parameters and provide design fundations. From the point of view of system research on the geomechanical process, stoping technological process and benefit, the complex method of optimization is proposed for VCR's mining. Using computer simulation, based on this model, the optimal parameters are established and analysed. An effective approach is provided for research on the mining method optimization and getting better economical benefits from the application and improvement of VCR's method.

Jan 1, 1986

By Jean Descarreaux

"The Rexspar uranium deposits are located near Birch Island in central British Columbia. The property lies within the Omineca crystalline belt of the Cordilleran Orogen. Gneiss, schist, tuffaceous and porphyritic trachyte are the main rock types encountered on the property. These rocks are of pre-Late Triassic or probable Mississippian age.Lenticular bodies of mica and pyrite-rich rock are the host of three closely spaced uranium deposits and are found close to a fluorite deposit. The altered trachytic rock as well as the fluorite and uranium deposits are found in the upper part of the trachyte unit. The latest tonnage estimates are 1,441,820 tonnes averaging 23.46% CaF, for the fluorite deposit, 490,966 tonnes of 0.084% U10afor the 'W' deposit, 164,290 tonnes of 0.074% UP8 for the ""B"" deposit and 459,124 tonnes of 0. 071 o/o UP8 for the ""BD"" deposit.A hydrothermal replacement origin was first proposed for the fluorite and uranium deposits. The mineralizing and altering solutions would have been genetically related to a felsic batholith outcropping a few kilometres south of the property. Another hypothesis has been proposed more recently. A volcanic centre has been tentatively identified in the upper part of the trachyte unit, close to the mineral deposits. The fluorite and uranium deposits could possibly be volcanogenic, rather than related to the Cretaceous felsic batholith.IntroductionFluorite and uranium mineralization occur on the property of Consolidated Rexspar Minerals and Chemicals Ltd. in central British Columbia. The exploration and development works executed over the years are summarized in this paper. The deposits and their geological environment are described but the origin of the mineralization has not been definitely established."

Jan 1, 1986

By Larkings RH

The high gas emissions associated with the depth of mining and very high coal extraction at some Australian Collieries have provided a need to investigate the influence of geological and mining conditions on levels of gassiness. The introduction of longwall extraction in particular is associated with complex strata control problems and quick changes in gassiness. To this stage of Australian coal mining, no standard method has been developed to predict the different levels of gassiness associated with the various geological and mining conditions; and the relationship between coal output and total methane make has not been established. For local conditions, with a large number of coal seams lying in close proximity to the working seam, the significant contribution of gas emissions from adjacent strata was expected, especially as strata relaxation occurred during longwall mining. This depends mainly on geological conditions, strata control and coal production. For the deepest of the B.H.P. Collieries in the Newcastle region, the relationship between coal output and total methane make has been investigated by systematic gas balance measurement during longwall extraction. The computer method of iteration was used to approximate the mathematical equation from the initial graphs of coal production versus quantity of methane in the ventilation system for various strata conditions. The angle of caving was established for local geological and mining conditions, for planning and design of the positions of cross measure boreholes.

Jan 1, 1986

By J. E. Pahlman

Spontaneous oxidation and combustion of sulfides and resultant fires are serious problems in underground mines. The Bureau of Mines has con-ducted fundamental thermal gravimetric analysis (TGA) research to deter-mine the mechanisms and factors governing the rate of low-temperature pyrite oxidation, and to identify possible inhibitors to spontaneous oxidation and combustion. The mechanism of low-temperature pyrite oxidation was found to be topochemical, meaning that the oxidation process is controlled by the chemical reaction at the interface between pyrite (FeS2) and iron sulfate (FeS04)' An activation energy of 8.9 kcal/mol FeS2 was obtained for oxidation of minus 500-mesh pyrite in an atmosphere of 60 vol pct water vapor and 40 vol pct . Water-vapor content of the atmosphere was found to be the critical factor in the rate of spontaneous oxidation of pyrite, with a water-vapor content greater than 20 vol pct needed for accelerated oxidation. An atmosphere of pure oxygen resulted in negligible oxidation. The rate of pyrite oxidation is also greatly affected by the particle size of pyrite. Pyrite-oxidation rate increased drastically for particles less than 40 ~m. Room-temperature pyrophoric behavior was observed for freshly ground unoxidized pyrite (55 pct minus 5 ~m) upon exposure to air. Addition of water-adsorbing materials such as activated alumina (Alz03) decreased the rate of pyrite oxidation.

Jan 1, 1986

By Christopher J. Bise

INTRODUCTION Perhaps no other area reflects the art as well as the science of mining-engineering design quite as obviously as strata control. This is due to the fact that the design of mining structures is difficult because rock rarely behaves as a homogeneous medium. Further, the original state of stress and the mechanical proper- ties of the in situ rock are somewhat difficult to deter- mine. However, those aspects that are hard to treat mathematically can and have been successfully approached by model studies and in situ measurements. This chapter will review the fundamentals of strata- control design and will provide examples of applications to typical problems. STRESSES AROUND MINE OPENINGS A close examination of Fig. 1 reveals that, prior to mining, stresses exerted in the overburden can be in both the horizontal and vertical directions. In the example problems of Chapter 1, it was shown that the maximum compressive stress (uv) at any depth (D) below the surface can be approximated as follows: [ ] Further, the lateral stress (oh) is related to the maxi- mum compressive stress by utilizing Poisson's ratio (µ): [ ] As soon as a heading is driven, such as the one in the coal seam shown in Fig. 2, the stresses shift to the sides, or abutments, of the opening. Clearly, these compressive stresses around the opening exceed the pre-mining conditions. The problem of designing an underground opening, therefore, is to determine the maximum stresses and to note if they exceed the ultimate strength of the rock. Table 1 lists several rocks with their corresponding strengths. Figs. 3 to 5 depict the boundary stress concentrations around circular, ovaloidal, and rectangular openings. M is the ratio of the horizontal stress to the vertical stress, or as defined above, p/(l-p). This text will concentrate on the state of stress represented by M = 0.33, which corresponds to the condition of no lateral deformation in a rock having a Poisson's ratio of 0.25. For an ovaloid with an opening width-to-height ratio of 2.0 (Fig. 4), the boundary stress concentrations are at their maximum values at the comers of the opening, with values in excess of 3.0. If the depth of overburden is 500 ft, then the maximum boundary tangential stress ([ ] ) of the ovaloid is: [ ]

Jan 1, 1986

By Robert B. Parsons

"A joint federal/provincial/industry subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWG) has published an informative and readable report on taxation matters concerning Canada's mining industry. The report, which was presented to the federal and provincial mines ministers in September 1986, identifies and discusses key tax issues relating to this industry. The report is mandatory reading for anybody with an interest in mineral exploration or production in Canada.IntroductionIn 1986, Canada's federal and provincial mines ministers were presented with an important report concerning the taxation of this country's mining industry. This document is important for a number of reasons, two of the reasons being: first, the report contains an objective analysis of the key mineral taxation issues of the day; and, second, the report is the product of a cooperative exercise involving representatives of various facets of the industry and government. The report should be regarded as compulsory reading for anybody who has an interest in fiscal matters affecting mineral exploration and production.The ""Report on Fiscal Proposals"" was prepared by a subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWO). IOWO is a group of senior federal, provincial, and territorial government officials concerned with the analysis of mineral policy issues in Canada."

Jan 1, 1986

By R. J. Batterham, P. W. Roller

Granulated sinter mixes of three iron ore types were prepared with a range of water contents in a laboratory investigation. The mean diameter of the granulated mixes and the void fraction of beds of the mixes were determined experimentally. Pressure drop measurements over a range of flow rates were made in a laboratory permeameter with pressure tappings at several depths in the bed. The Ergun equation was applied to the results to determine the shape factor of the granulated mixes. Pressure readings down the bed were used to estimate the local void fraction in the bed using the Ergun equation and the calculated granule shape factors. It was found that there was a decrease in void fraction with depth in the bed. The significance of this and the variation of shape factor values with the amount of water used for granulation is examined in relation to the strength of granules of the sinter mixes. The experimental and mathematical techniques presented may be useful in interpreting the behavior of the permeability of sinter beds after ignition.

Jan 1, 1986

Appropriate roof control is the most important requirement in underground coal mining and, in the case of longwall panels or second mining in room and pillar extractions, this can be simply expressed in terms of good and predictable roof caveability. Studies of roof caveability have been undertaken in many coalfields around the world. Most of their conclusions. however, are directly related to the mining and geological conditions experienced in these areas and as a result, may not be applicable to the conditions encountered in the Appalachian coalfield. Furthermore, some of these studies appear to be theoretical and conceptual, ignoring many important parameters of the geological environment, whereas others rely heavily on geological information but lack a rigorous foundations upon which quantitative design guidelines can be built. The objective of this study is to analyze caving and mass deformation characteristics above longwall panels in Appalachia and includes: - Analysis of the effects of the geological and geomechanical characteristics of the strata on the caving height and the bulking of the caved-material. - Testing of the applicability of the various theoretical and empirical models of roof caving. Formulation of a numerical around- deformation model for ion-elastic material behavior.

Jan 1, 1986

By George W. Luxbacher

The inclusion of a new term "planned subsidence" in the Surface Mining and Reclamation Act of 1977 has lead the U.S. coal mining industry into a new aspect of engineering: subsidence planning. Subsidence planning has necessitated the integration of geotechnical, civil, and mining engineering disciplines. Although much of the foundation and application work has been completed, subsidence planning is still a developing area. This paper discusses the application of subsidence planning in several brief case studies (a high voltage transmission tower, a sewage treatment plant, and a slurry impoundment), emphasizing the risk assessment aspects necessary to account for some of the uncertainties that may exist.

Jan 1, 1986

By E. Goodwin

"Maclaren Forest Products Inc.Lime is commonly used for the neutralization of acid, and the removal of heavy metals in mine waste waters. However, the precipitation of heavy metals as hydroxides must take place under conditions of controlled pH, to produce minimum concentrations of dissolved metals. An account is presented explaining the concepts applied to lime-treatment processes at Bell Mine during the period of a supernatant discharge to Babine Lake; October 18, 1982to January 25, 1983. IntroductionBell Mine of Maclaren Forest Products Inc., Babine Mining Division, an open-pit copper mine, is located on Newman Peninsula, Babine Lake approximately 65 kilometres northeast of the town of Smithers, British Columbia (Fig. 1).A depressed market for copper metal in 1982 forced a management decision to suspend operations at the mine for an indefinite period from October 3 I, 1982. For some time prior to the mine closing date, mine management was concerned about the increasing level of supernatant in the tailings pond , and its possible effects on the stability of the dam when cycloning of mill tailings ceased. Consideration of these potential hazards led to an application being filed with the Provincial Waste Management for a permit to discharge the excess water to Babine Lake. This large lake, an important link with several significant salmon spawning sites, is a major contributor to the British Columbia commercial fishing industry. Jurisdiction for the environmental affairs in the area is shared by the Department of Fisheries and Oceans, the Environmental Protection Service, and the Provincial Waste Management Branch. These agencies were directly concerned in the formulation of discharge permit following joint consultation, and exchange of information with the company on environmental concerns. An approval was finally granted to discharge approximately 1,000,000 cubic metres of supernatant from the tailings impoundment at Bell Mine into Hagan Arm, Babine Lake from October 18, 1982 with a daily discharge not to exceed 9000 cubic metres. Provisions were made that a particular discharge procedure be followed, and that the company would be responsible for setting up a sampling and monitoring program to safeguard the quality of the effluent."

Jan 1, 1986

Mineral Sands - "An Industry for the Future"The mineral sands industry is matched only by the gold industry in relation to its current buoyancy. The strong demand for the various mineral sands products, creates a positive environment in which to review the technical and commercial factors affecting the future of this industry. This conference is clearly being held in the right place at the right time.My role today is to put forward a few ideas that may help Australia to assert its rightful role as a major downstream player in an industry which it has dominated for 25 years as a raw material supplier.

Jan 1, 1986

By G. Paquet, E. Godin

"Since the mid fifty's, worlwide pellet production capacity has constantly risen (Fig. 1, Ref. 1 l. There was however at that time no real incentive to decrease production costs but only to produce as many pellets as possible. State of things changed with the iron and steel market recession, starting in 1975, and is currently leading producers to improve pellet quality and to reduce fuel and power consumption.At the Port-Cartier pellet plant, the energy needed for the induration of pellets ranks first in overall operating costs. An important step was made when starting admixing coke breeze in 1980. Oil prices justified the use of coke breeze as a direct replacement in terms of dollar/ton, however, while gaining expertise in using solid fuel a significant decrease in energy consumption was observed (Fig. 2, Ref. 2).In 1985, the ""Centre de Recherches minérales"" was commissioned to undertake research work to investigate the effects of further increasing coke addition to the pellet mix. The positive results of that work led to a 1,5% coke addition plant trial during the fall of 1985. Both laboratory and industrial results are discussed in this paper."

Jan 1, 1986