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By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988

By Ray Heater, Qian Liu, Alan Bauer

The channel effect is a phenomenon that takes place with decoupling explosive charges; an air shock wave propagating ahead of the detonation wave in the annular space around the explosive charge compresses the charge so that the process of detonation is modified and even stopped. For commercial explosives, such as AN/FO slurries and emulsions, the channel effect causes partial detonation under certain conditions. To simulate and evaluate the phenomenon, a hydrodynamic model was developed based on the assumption that the pre-shock wave is produced by Mach reflection at the tube walls. Based on instrumented experimental studies with the above explosives in diameters ranging from 25 to 90 mm in pipe sizes ranging from 35 to 127 mm, it has been possible to demonstrate that a criterion for failure based on a critical impulse concept fits the experimental data well. Critical impulse values for the various explosives tested are presented along with the necessary correlations between charge and borehole diameter required to produce this.

Jan 1, 1988

By G. Barbery

A review is given of the present applications of random sets and integral geometry in fragmentation and liberation models of ores and minerals. Although attempts have been made in the past to apply such mathematical techniques to the comminution of solids, it is shown that it would not result in major progress. In liberation modeling, it is demonstrated that the approach can lead to fruitful results. Following a recent paper by Davy (1984), a model of liberation prediction is developed that can be calibrated for ore texture and breakage using image analyzers. The model is demonstrated for the case of a Poisson polyhedra ore texture and monodisperse fragment size. The model enables prediction of the complete composite particle distribution and thus is valuable for integration of ore breakage models with minerals separation models.

Jan 1, 1988

By C. R. Zegarra

Extraction of manganese, gold, and silver from a low-grade manganiferous-silver ore was investigated by thiourea leaching followed by standard cyanidation. The levels of reagent concentrations in this investigation were 0.0 -1.0 M thiourea and 0.0 -1.0 M sulfuric acid. Temperature and agitation speed were maintained at Z5 °c and 300 rpm, respectively. The dissolution of gold, and silver was shown to be dependent mainly on sulfuric acid and thiourea concentrations. In general, 50.0 % Ag, 98.0 % Au, and 75 % Mn were recovered from a Mn-Ag ore by thiourea leaching. Overall silver extraction of 98.0 % was obtained by cyanidation after thiourea leaching. Thiourea leaching of sodium bisulfite leach residues was also studied, and the total extraction of gold and silver were 97 % and 40 %, respectively. Finally, a two-stage thiourea leach was also investigated.

Jan 1, 1988

By M. E. Gershon

An approach for scheduling the mining of ore and waste blocks in a surface mine is presented. While mathematical programming approaches have been developed to solve this problem optimally, they are difficult to implement and understand. The more simplistic approach presented here achieves practical mining schedules, taking into account both long- and short-term considerations. The key to the approach is use of the concept of ranked positional grade. The program can determine a complete schedule for a specified time period, or it can be used interactively as a guiding tool for the engineer.

Jan 1, 1988

Despite technological improvements and better understanding of the hazards, coal dust explosions stilI occur. Experimental explosions in galleries in various countries extend knowledge with the constant aim of providing safer working conditions. The inadvertent ignition of an accumulation of methane is the traditional initiator of the coal dust explosion.There are specific parameters of coal dust explosibility and explosion propagation, including the important volatile matter in the coal, fineness and dispersibility of the dust and its concentration. Accepting that initiation cannot be absolutely prevented, it is necessary to consider explosion suppression. While both limestone dust and water are the chosen explosion suppressants, in practice water has more limitations to its efficacy when related to the degree of explosion violence. These data give rise to the criteria for explosion suppression, differences in favoured mining geometries, and using the same principles, to differences in suppression treatments.

Jan 1, 1988

By P. R. Richardson

"Milling is the weak link in the process chain of many mineral operations. While this activity accounts for only a relatively small proportion of the direct costs of most mineral processing complexes, there are intangible and indirect costs associated with milling which are extremely large. For example, significant opportunity costs are associated with the relatively low yields which characterize this stage of the process.There are changes abroad in the world which I believe are going to cause us to reformulate the whole concept of milling. Increased competition in mineral markets are going to force managers to look anew at the high mineral values reporting to tailings which are a high opportunity cost for many operations. Tailings recovery plants are not the ultimate solution to this problem. Greater environmental concerns are going to increase the costs associated with tailings disposal and force the mining industry to look for other ways to dispose of waste products. Technology changes currently underway in manufacturing and other process industries, such as the automated 'lights-out' plant are going to be brought into this industry, and the changes will be dramatic.These are major long term changes which probably seem rather remote to many managers and professionals in existing operations which are faced with much more mundane challenges arising from day-to-day operations. However, I believe that milling is increasingly a 'lean and keen' operation involving fewer and fewer people, but who are increasingly skilled and professional. Traditional cost management approaches are no longer adequate and the industry has to take a new look at the nature of cost reduction in this core activity. This stage in the mineral process provides opportunities for value creation leading to a significant unit cost advantage for the corporations willing to adopt a total cost approach."

Jan 1, 1988

By Jean-Yve Tremblay, Michel Prud'homme

"IntroductionIndustrial minerals include a group of more than fifty minerals which are marketed into almost all the sectors of industry; they are the backbone of many manufacturing industries. Table I shows major end-uses for industrial minerals in manufacturing sectors.At Energy, Mines and Resources, industrial minerals are divided in three major categories: (I) agro chemicals and chemicals, (2) construction mineral s, and (3) ceramics and specialty minerals. A listing of the major groups of minerals is shown in Table 2.Agro-chemicals and chemicals are sold on the basis of their chemical content and purity. Construction minerals or structural minerals are distinguished by their performance as low cost and bulky commodities. Ceramics and specialty minerals are performance-specific and are sold for their property on imparting functions on end-products. Industrial minerals have unique characteristics that are useful in many stages of processing; from crushed size to micronized fillers a single mineral ca n serve a broad range of industries because of its intrinsic properties.The Industrial Minerals Industry in CanadaCanada has a large industrial minerals base and is a world leader in the production of some of them. The total value of product ion of these minerals has grown by 115% over the last 10 years despite the misfortune of asbestos.Industrial minerals have shown remarkable growth in the past 20 years at an average annual rate of 9.2%, compared to 7.8% for metallic minerals. In 1986, the value of industrial minerals rose to $4.9 billion, or 14% share of the Canadian mineral production. Figure I shows the value of production of the mineral industry for the period 1966-1986.The leading segment in industrial minerals segment since 1976 is the chemicals and agro-chemicals sector which has an average annual growth rate of 5.75 % in terms of value of production. During the same period, the growth rate for the whole Canadian mining industry was 1.37% per annum. The chemicals and agro-chemical s sector increased its contribution to the total value of production of 2% to 6070 despite the growing share of fuel minerals with 59%."

Jan 1, 1988

By A. E. Raddatz

Previous Bureau of Mines research has shown that tungsten ores containing as little as 40 pct W032-can be processed by a high-temperature molten-salt extraction technique to produce a tungstate-bearing sodium chloride phase with 99 pct W recovery and little impurity contamination. The objective of this work was to demonstrate that the tungstate-bearing sodium chloride phase can be a suitable feed material for preparing am-monium paratungstate (APT) by a modification to the present industrial solvent extraction process. A combined crossflow-count·ercurrent flow solvent extraction technique to extract tungsten is presented. APT produced by this new technique contained 88.6 pct W032-and the following impurities, in percent: Mn02_ 0.0007, Mo02 0.017, P205 <0.010, and Si02 0.012. Implementation of this processing technique would improve tungsten recovery from concentrates and simplify processing operations.

Jan 1, 1988

By J. F. Edwards

In situ extraction of copper through borehole injection presents a new technology for the mining of copper. For the successful application of this technology, copper recovery at the surface must be specifically designed for borehole injection and the general conditions of the well field. This paper describes the design of a solvent extraction / electrowinning facility specifically designed for in situ leaching of copper. This design is based on commercial solvent extraction / electro-winning with considerations of the requirements of this specific application.

Jan 1, 1988

By Jr. Stokowski

Topsoil for revegetation projects is in demand in many urban areas. In this case history, a large aggregate producer manufactured a topsoil from three waste materials. The topsoil was produced in a 200,000 m2 (50-acre) abandoned gravel pit that still had additional gravel under 10 m (30 ft) of overburden uneconomic to strip directly. The topsoil was produced by rotary mixing of sludge, overburden, and a lime admixture; solar drying; and stripping and stockpiling of the product. A major problem was an increase of topsoil drying times for stripping from 40 to over 100 hours when it was rewet by storms. The problem was solved by a research project that evaluated over 50 formulations and over 20 waste materials. . The final formula dried in 15 hours and contained 3-parts sandy mine spoil, 1-part sewage sludge, and 2 % spent-bed, a granular quick-lime produced during power-plant flue-gas desulfurization.

Jan 1, 1988

By T. P. Riordon

"Major swings in the silver price since 1979, along with the ever constant fight to maintain ore reserves has forced United Keno Hill Mines Limited through several unique series of events in order to survive in the 80s.This paper is specifically meant to be a description of safety and productivity improvements achieved to ensure the survival of a silver mining community ill the Yukon. There are, however, other events and conditions that must be described to complete the story and this paper attempts to do that as well IntroductionUnited Keno Hill Mines Limited, a subsidiary of Falconbridge Limited, is the only silver producer in the Yukon. Operations are located in north central Yukon, in and around the small town of Elsa, latitude 62.5 °, about 275 road miles from Whitehorse. The Arctic Circle is about 185 miles due north of the town.Temperatures in 1986 ranged from a high of 28.5°C in July to a low of -37.0°C in November, however, much lower temperatures have been recorded in previous years. Due to the mountainous terrain the town of Elsa is completely in the shade from mid-November until early February, a period of about 12 weeks.The Elsa area, as is most of the north, is considered semiarid with an average precipitation level of about 15 inches. Vegetation, however, is quite abundant though slightly dwarfed at the townsite elevation of 3200 feet above sea level: Many of our operating and exploration portals as well as our open pits are above the tree line. Permafrost in the area has been recorded up to 400 feet below the surface."

Jan 1, 1988

By D. K. Ingram

In situ horizontal stresses were measured to determine the influences of geologic anomalies on the regional horizontal stress field in two coal mines in southern Illinois. Stress measurements were obtained near a normal fault having a 121-ft displacement at the AMAX Wabash Mine and a large coalbed want at the Kerr-McGee Galatia No.5 Mine. Horizontal stress measurements were completed using a Bureau of Mines borehole deformation gauge. The average maximum and minimum horizontal compressional stresses at the Wabash Mine were 1,400 and 800 psi, with the direction of maximum stress ranging from N 78° W to N 83° E. At the Galatia No.5 Mine, the averages were 1,500 and 500 psi, with the direction of maximum stress ranging from N 85° E to N 75° E. Generally, the geologic anomalies appear to have no dramatic effect of the regional horizontal stresses. However, subtle differences between stress measurements suggest an influence by the fault zone at the Wabash Mine. The larger anisotropic stress conditions at the Galatia No.5 Mine could be responsible for the increase in kink zones and directional roof failures.

Jan 1, 1988

By H. McSorley

"I note that many of you are involved in the production of zinc, lead and copper concentrates and metal, which I am the most familiar with among the non-ferrous metals. This afternoon, I will describe briefly the responsibilities of a commercial manager within a mining/metallurgical company, the basic framework of a non-ferrous metals concentrate agreement and lastly, a brief discussion of the copper, zinc and lead concentrate and metal markets.I hope this talk will contribute to a better understanding of the business between all of us and look forward to a discussion after the presentation.First of all, I work for Noranda Sales, which is the marketing and sales agent for Noranda Minerals' three operating units: Noranda Copper, Noranda Zinc and Mining Corporation. In addition, Noranda Sales acts for other mining companies in the marketing of their raw materials and metals. Noranda Sales is responsible for procuring all raw materials for Noranda's metallurgical plants, such as the Copper Group's Forne and Gaspe smelters, as well as the sale of surplus concentrates and by-products and metal products. In addition, Noranda Sales trades metals and concentrates and owns a metal brokerage business, Rudolf Wolff, a founding member of the London Metal Exchange. It does $3 billion of business in 60 countries, exporting some 80% of Noranda Minerals' output to the world.What are the responsibilities of commercial management in resource marketing to the mine and metal producers?Resource marketing and commercial administration involves assistance in establishing exploration priorities, contributing to feasibility studies, pre-production planning, product promotion and realization of income for many properties and metallurgical plants through completion of supply and sale agreements with other companie"

Jan 1, 1988

By P. D. Kovscek

The Bureau of Mines has tested a low-thrust water-jet-assisted rotary drill. This work was performed to evaluate the performance of a water-jet-assisted drill operated at thrust levels typical of a handheld manual-thrust operation. Prior work by the Bureau had indicated that using water-jet assist with high-thrust drilling applications would increase drilling rate. Small-diameter holes were drilled in five different types of rock. Thrust and water pressure were varied as the drill rate was monitored. The test results indicate that drilling rates increase with increasing water pressure and thrust. The water jet has more effect on reducing the specific energy when drilling in the harder rocks than in softer rocks. Variation in drill rate for a given rock sample is attributable primarily to the material heterogeneity within the sample. One rock type (Greenwich sandstone) could not be drilled efficiently with the water-jet-assisted drill.

Jan 1, 1988

The application of single liquid cement for fracture grouting in base rock may have history more than 120 years. The disadvantage of it is difficult to increase the grouting efficiency, because the jelling time of it is very long and hard to control. The double liquid grout, such as chemical grouts and cement water glass grout was developed at the end of 1960.&apos;s Although the jelling time of this kind of grout can be controlled, it mast adopt double liquid grouting technology, use complicated equipment and is not easy to control component&apos;s ratio of the grout. Another disadvantage for chemical grout is high price, and have pollution to environment. OCE series single liquid grout is the effective grout material developed recently by making large efforts in Ohina. Main feature of it is that the jelling time is easy to control, materials from cement and clay are very cheap and without pollution to environment, and the grout can be injected by single liquid technology. The effect of QCE series grout has been proven by its application in China. It can be believed that QCE grout has great economic efficiency and will give a push to develop grout material.

Jan 1, 1988

Conventional logging tools such as density, neutron, and acoustic have ranges of investigation of tens of centimeters. The borehole gravimeter, however, has a range up to hundreds of meters. For example, from the center of a cylindrical ore body 0.20 g/cm3 denser than its surroundings, one can detect the boundary of the ore body at a radius as large as five times its height. More complex structures can be investigated with computer programs. We can predict the usefulness of proposed gravity surveys, or decide which suggested structure is most likely to have caused the results of existing surveys.

Jan 1, 1988

By Thomas M. Barczak

he stiffness characteristics of longwall shields were investigated in this Bureau of Mines study. Since longwall strata activity is characterized by roof-to-floor and face-to-waste displacements, a model with two degrees of freedom was used to describe the load-displacement relationship of the shield structure. The model considers the support as an elastic body and relates horizontal and vertical resultant forces acting on the support to associated displacements as a function of the stiffness of the support structure. Stiffness coefficients under full canopy and base contact configurations were determined by controlled displacement loading of longwall shields in the Bureau&apos;s Mine Roof Simulator (MRS). Three two-legged longwall shields of different manufacture were investigated. The stiffness characteristics of these shields were evaluated relative to two parameters, namely, shield height and setting pressure. The test results indicate a reduction in shield stiffness for increasing height. Setting pressure was found to have less of an effect on shield stiffness, producing only a slight increase in stiffness as setting pressure increased. Similar trends were observed for all three shields, indicating a similarity in stiffness characteristics for shields of the same basic configuration.

Jan 1, 1988

By S. Donges, P. L. Dunstan, B. J. Huls

The commissioning of a distributed digital control system for the grinding circuit at Cuajone was completed by mid-August 1985. Development of a successful strategy, excellent operator acceptability, and the visual aspects offered by the display of the central console improved mill through- put significantly. The inherent features of a digital system enhanced the flexibility in grinding control and allowed the milk and classifiers to be operated at maximum capacity. This paper discusses the strategy development and the production restrictions encountered, and evaluates the overall performance of the digital control system.

Jan 1, 1988

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT&apos;s) of the dried coal-additive mixtures were determined in the Bureau&apos;s adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT&apos;s of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988