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By D. Laguitton, D. Cimon

"BILMAT is one of the most powerful algorithms in existence for material balance computation in mineral processing flowsheets. It is based on a hierarchical decomposition coupled with the Lagrange multipliers method widely reported in the literature. Flowrates can be calculated optionally for pulp, solid or water. Assays are adjusted for a variety of subnetworks, such as assays of the solid as well as assays of fractions of the solid called level 4 data (l: pulp, 2:solid and water, 3:assays of solid, 4:assays of classes of solid).BILMAT4 is a new implementation of BIU1AT that operates in a new microcomputer environment and makes the method more accessible than ever. Its main features are a full-screen colour editor allowing graphic flowsheet drawing and data entry with automatic error checking. Mass balance equations are automatically generated by analysis of the graphics and corresponding data, thus relieving users from the error-prone definition of networks. Sensitivity analysis is performed to assess confidence intervals of computed flowrates and adjusted assays.BILMAT4 incorporates an option for gold leaching circuits where the element to be balanced appears in both the solid and liquid phases with negligible effect on the mass flows of solids. Recoveries are computed in all streams. This program is currently released by CANMET as part of the CAMP collection for Computer Aided Mineral Processing. A complete sample run of the program is discussed."

Jan 1, 1989

By M. S. Seehra, R. S. Pandurangi

"A comparative study of the intensities of the IR modes in the pjlotoacoustic and. FrIR spectroscopy of amorphous and crystalline SiO2 particles is presented. It is observed that in photoacoustic spectroscopy of amorphous SiO2, IR modes of surface species are enhanced by over an order of magnitude compared to the bulk IR modes of SiO2. This effect, though not yet understood, may find applications in surface science.Since the publication of the Rosencwaig-Gersho theory of the photoacoustic effect in solids in 1976 [1], a great deal of attention has been paid to the development .of photoacoustic spectroscopy (PAS) into an analytical technique for condensed matter studies, especially when combined with the modern Fourier transform infrared (FTIR) spectrometer [2-8]. PAS has now been applied to a variety of experimental situations [2, 3] and it is particularly suitable for opaque powders and for cases where ~ample preparation (e.g. mixing with KBr as is usually done in FTIR spectroscopy) is not desirable. Another area of interest is the depth profiling feature of PAS, which is studied by varying the modulation frequency of the incident radiation [2-8]. The one-dimensional Rosencwaig-Gersho theory for non-porous samples has been extended to other cases [9-12]. Recently it has become known [11, 12] that for porous samples with porosity the IR modes are enhanced by a factor proportional toe. This enhancement is due to the pressure wave set up in the interstitial gas in the porous sample and this enhancement has been reported by a number of groups [12-14].In this Letter we report the observation of anomalously large enhancement of the PAS signal for certain surface IR modes on the surface of amorphous silica particles. This observation differs from the previous reports in that certain surface modes are enhanced by over an order of magnitude compared to the bulk IR modes. Although the reasons for this enhancement of the surface IR modes in PAS are not understood at present, this observation may open up new approaches to the study of surfaces. Results of these initial observations are given in this Letter. ·Experimental studies reported here were carried out on an FTIR spectrometer (Mattson Instruments, Model Cygnus 100) equipped with an MCT detector. The same instrument was used for PAS studies in conjunction with an MTEC (Model 100) PA cell. The sample cell and the spectrometer are continuously flushed with dry, CO2 free air obtained by the use of Balston Instruments Air Dryer Filter System (Model 75-60). Usually data were collected for 32 scans at 4 cm-I resolution, although both scan and resolution can be varied. For FTIR studies, samples were mixed with IR-grade KBr and pelletised. For PAS, no sample preparation is necessary and data are ratioed against dry carbon black [4, 5]."

Jan 1, 1989

By Richard D. Grove

The on-stream analysis of phosphorus and silica has not been possible by XRF techniques and only recently has some success been indicated with quantitative XRD for P. Yet there has been a recognized need for an on-stream analysis of P and acid insoluble to permit the automatic control of phosphate rock flotation plants which produce some 30-40 million tons of concentrate each year in the southeastern U.S. IMC Fertilizer, Inc., the largest U.S. phosphate rock producer, embarked on a program to develop such an on-stream analysis capability several years ago. Following many months of lab and prototype development, the first commercial installations started in December 1986 and now have completed some 400,000 analyses with surprising accuracy, precision and reliability. The use of these devices in the improved control of the phosphate flotation plant is currently receiving some very serious attention at IMC.

Jan 1, 1989

By Barrie W. Sullivan

The New Celebration Gold Mine near Kalgoorlie in Western Australia was commissioned in late 1986 and the CIL treatment plant currently processes 1.7 million tonnes of gold ore annually. The 1988 geological resource was 13.2 million tonnes grading 2.37 g/t Au in several open pittable deposits with the bulk of gold mineralisation occurring as a stockwork in Archaean quartz feldspar porphyry intrusives along a major regional shear zone. Mine planning, scheduling and operating techniques have focused on minimising open pit dilution whilst maintaining production requirements. This paper describes the successful achievement of this aim in extremely variable ground conditions and orebody widths.

Jan 1, 1989

By Hamilton LH, Campbell PB

Since fundamental research in applied coal petrography is carried out mostly on polished surfaces, backscattered electron microscopy is most applicable for studying coal in the SEM. By employing this technique coal macerals can be easily identified , and information on the relations between maceral groups, mineral matter and trace elements are highlighted by grey level contrasts. This type of information is valuable in coal technology and cannot by normally revealed by the light microscopy (e.g. the distribution of inherent mineral matter).

Jan 1, 1989

By W. S. Fyfe, R. J. Puddephatt, S. Zhou

Gold is easily mobilized at temperatures within range 600-11OO°C by gases such as Cl2, CO, H2S, in gas mixtures, at low pressures. Such gases are relevant to conditions of granulite facies metaomorphism in environments of magma underplating. These observations suggest an efficient mechanism for moving gold to the upper crust during major thermal events. The efficiency of precipitation of gold at lower temperatures is related to available mineral surfaces and pyrite appears to be an excellent substrate for gold precipitation.

Jan 1, 1989

By B. J. Beaudry

Intermetallic compounds are frequently required in the form of thin sheets for magnetic refrigeration and other applications. Progress has been made in the preparation of thin sheets of brittle gadolinium intermetallic compounds by hot rolling of sheathed billets. The effect of fabrication procedures on the Curie temperature of GdPd and its heat capacity at low temperatures has been studied.

Jan 1, 1989

By Steve Kral

"Gold rush" is usually associated the western United States - California, Nevada, and Colorado. The southeast section of the nation is known more for its rice, textiles, tobacco, indigo, and cotton. This area, though, is where it all began with gold in this country. The United States' first gold rush, in fact, is said to have started with the discovery of a 7.7-kg (17-1b) nugget in the Piedmont section of the Carolinas in 1799, some 50 years before the rush to California. The Carolina gold rush continued intermittently through 1942 when the Federal Government shut down all gold operations. Strong gold prices throughout the early part of this decade and new extractive technologies spurred a small resurgence of gold operations in South Carolina. Mind you, this is not Nevada with its flood of geologists and mining companies. Nor are there any 7.7 kg (17 lb) nuggets being discovered. But Ridgeway Mining Co., a joint venture between Kennecott Corp. and Galactic Resources, has set about mining 51 Mt (56 million st) of low-grade ore containing an estimated 43.5 t (1.4 million oz) of recoverable gold. The open pit, carbon-in-leach operation is located near the town of Ridgeway in South Carolina, about 32 km (20 miles) north of Columbia. Carolina gold North and east of Ridgeway, Piedmont Mining Co. operates the historic Haile gold mine near Kershaw, SC. And Brewer Mining Co. operates the nearby Brewer deposit. Between 1829 and 1942, South Carolina gold mines produced 10 t (318,800 oz) of gold. It all began in 1799 when Conrad Reed, son of a German immigrant farmer, found the 7.7 kg (17 lb) nugget in Little Meadow Creek, NC. His father thought the rock was worthless and used it as a doorstop, so the story goes. It took nearly three years before Conrad's father decided his doorstop was indeed gold. Gold was later discovered in the Greenville district of South Carolina. And, in 1828, Benjamin Haile discovered gold in a stream that ran through his property in Lancaster County, SC. Haile's mine became South Carolina's most famous and most productive gold mine, producing more than 7.8 t (250,000 oz). At first, miners worked the stream beds of Haile's property. Later, lode deposits were discovered on slopes alongside the creeks. They would lease 4.6 ml (50 sq ft) lots and mine as deep as 7.6 m (25 ft). During the Civil War, the Confeder-

Jan 1, 1989

By III Kimball

For many years, Arizona merely shadowed EPA's environ-mental regulation of mining operations and waste. During this period, Arizona generally assisted EPA in the implementation of federal programs and enacted environmental laws patterned closely after their federal counterparts. A growing public concern about protecting water quality, particularly groundwater quality, eventually caused the State to depart from this pattern.

Jan 1, 1989

By P. M. Lin

A subsidence monitoring program over a longwall panel was established (1) to explore the impacts of dynamic subsidence on the ground surface and structures and (2) to correlate the movements between the structures and their corresponding points on the ground. The program consisted of a transverse line survey and a series of survey points around the structures on the ground surface and their corresponding survey points on the exterior walls of the structures. The vertical displacement of each point can be expressed as: where Si is subsidence at i point; Sif is the final subsidence at i point; F is face location in terms of distance from the i point and SD is seam depth. The development of subsidence can be divided into five stages. Damage to the structures starts at the beginning of the second stage, The maximum damage developed in the middle of the third stage. The relationship of the vertical displacement between ground surface and structures can be expressed as: G = aH + b where G is ground displacement, H is structures displacement, and a and b are constants. The relationship is linear. However, the strain is non-linear and more complicated because of the interaction of the ground surface and structure.

Jan 1, 1989

By S. Neilson, M. G. Demmer, K. McCarogher

The Phoenix Programme takes the Mining and Mineral Processing Industry into the Science Classroom In the early years of mining, methods were crude, simple, labour-intensive, and very slow. Human resourcefulness, however, created innovations (mechanization, and computerization), that resulted in faster development, greater tonnages of ore, more efficient separation, and a superior final product. This expansion occured an ever-increasing rate, and resulted in a booming mining industry and a growing economy.

Jan 1, 1989

By E. Douglas, V. M. Malhotra

"This report presents the results of a laboratory study undertaken to evaluate ground granulated blast-furnace slag from Algoma Steel Corporation, as a replacement for Portland cement in cemented mine backfill. The evaluation was based on the results of compressive strength tests performed on cylinders cast from mixtures made with a granulated blast-furnace slag and tailings from four different mines in the Sudbury basin. Various percent¬ages of slags and various binder to tailings ratios were used.Tests results show that, in terms of compressive strength, the slag performs as well or better than Portland cement as the binding agent in cemented mine backfill. Lime was found to be a poten¬tially good activator for ground granulated slag in mine backfill applications.A field test was conducted at one of the mines, consisting of placing a mixture of 95.5% ground granulated slag and 0.5% lime into a stope, and inspecting the floor slab as it hardened. The slag performed as expected, considering the backfill mixture proportions used and the preparation of the test site."

Jan 1, 1989

By G. W. McDonald

"The mineralogical studies done on Hope Brook ore samples indicated that a heap leach gold recovery process may be possible. In the metallurgicalprogram that followed, column tests confirmed this interpretation. A 9300 tonne demonstration heap leach test, in the late fall of 1985, reaffirmed laboratory results while identifying operating conditions that will have to be addressed in a production heap leach plan. Operating plans, gold recoveries and cost areas will be presented.Another important factor in a successful operation is the environment approach.LocationThe Hope Brook gold deposit is located 5 km inland from Cinq Cerf Bay on the south coast of Newfoundland. Port au x Basques is 80 km west and Burgeo 40 km to the east of Hope Brook. As there are no roads in the area, access to the site is by sea or air (Fig. I). The Hope Brook orebody is near the saddle of three watersheds flowing to Cinq Cerf Brook, Boat Hole Brook and Betty's Pond. Acceptable solutions to several environmental concerns can be obtained by using the relative sensitivities of these watersheds.The terrain at the site is generally rolling to hummocky with numerous small ponds separated with rock outcrops and patches of peat covering. Tree vegetation is sparse except in the sheltered areas around Couteau Bay and Cinq Cerf Brook. GeologyThe Chetwynd deposit is hosted by the Lower to Middle Ordovician Georges Brook Formation of the La Poile Group, a thick sequence of volcanic and sedimentary rocks.The Hope Brook Zone contains the largest concentration of gold found to date at Chetwynd. The zone occurs as an intensely silicified lens 100 m to 550 m long (average 400 m) by up to 60 m in width and forms the eastern portion of a more extensive, 4 km long , alteration zone trending at 053 degrees Az and dipping 70 degrees southeast.The Hope Brook Zone contains massive finely granular quartz, scattered blue quartz eyes, 3070 to 8% pyrite, minor calcopyrite and trace molybdenite. Barren silicification envelopes the gold mineralization. The zone is flanked to the southeast by a 200 metre thick aluminosilicate alteration zone and to the northwest by a 10 metre barren pyritic siliceous fragmental rock . The original lithology may be either a thick felsic pyroclastic sequence or a quartz porphyry sill that has been altered by hydrothermal processes. Silica flooding of the permeable host was accompanied by gold deposition."

Jan 1, 1989

By H. R. Cooper

Refinements and increased sophistication in modeling and simulation, and introduction of advanced techniques in automatic control made feasible with digital processor handling of data, represent the most significant fields of advancement during the past ten years. Extensions in capability to predict performance of beneficiation and other mineral extraction techniques now provide powerful assistance to developers and and designers of minerals processing unit operations and complete plant flowsheets. Computer aided advances are categorized by work in the following fields: - Steady state modeling and simulation of processes - Dynamic modeling and simulation of processes - Optimization methodology in crushing, grinding, and flotation - Optimal process control methods - Expert systems in process control

Jan 1, 1989

By Charles C. Y. Chen, Duane R. Skidmore

Batch leaching of Ohio #1, Ohio #4A and Ohio #5 coals was conducted with the thermophilic. sulfur, oxidizing microorganism: Sulfolobus acidocaldarius. Four different size fractions of each coal, with median sizes of 508, 200, 90, and 49 microns, were subjected for 10 days to leaching in a 5% coal-water slurry at 72°C and a pH of 2. Release rates and extent of sulfate and iron I1 and I11 ions from the coals during the leaching process and distribution of sulfur forms (sulfate, pyritic and organic) in the coal samples before and after treatment were determined. Data indicated that Ohio #1 coal, with an initial sulfur content of 0.6%, showed no significant changes with leaching in total sulfur content or forms of sulfur. The Ohio #4A coal, with initial total sulfur content near 5%, yielded product, for sizes below 200 microns with 90% reduction of pyritic sulfur while the extent of organic sulfur removal varied with coal particle size. Results similar to those for Ohio #4A were observed on the Ohio #5 coal, which had an initial total sulfur content of 3% and a final sulfur content near 1%. The findings were interpreted in terms of basic biological, chemical and physical mechanisms.

Jan 1, 1989

By P. Umadevi

In the light of the discovery of the new super-conducting YBa2Cu3O7-x (YBCO), reactions in the Y2O3¬CuO-BaO system at 1300°C was investigated. The search was for any new phase that may be formed in the system at 1300°C (only 950°C reactions are known so far). 35 mixtures of different compositions were prepared and heated at 1300°C. No new phase was obtained. It was found that YBCO is decomposed at this temperature and Y2O3 and BaCO3 are the major components in the solid obtained after firing in air. However, on cooling the melt slowly and annealing at 950°C YBCO reforms. Such reactions on cooling might have implications on processing of the superconductor YBCO for practical applications as well as on its crystal growth by flux method.

Jan 1, 1989

By Jean-Louis Briaud

The following is a summary of a very recent report prepared at Texas A&M University for the National Cooperative Highway Research Program and entitled "Downdrag on Bitumen Coated Piles". Anytime the soil settles more than the pile, downdrag or negative skin friction will develop. The load in the pile increases with depth up to a certain point and then decreases down to the pile point. This phenomenon has been quoted as being the number one culprit for deep foundation failures. In Chapter 1, an introduction to downdrag is given. The most common criterion for downdrag is to consider it in design as soon as the settlement of the soil surface after pile driving exceeds 0.5 in. Coating piles with bitumen is an effective way of reducing downdrag forces and therefore allows to use smaller piles for the same load. This results in cost savings. Coating piles with bitumen increase the cost of piles by about 33% and therefore the decision to use bitumen is generally based on economic considerations.

Jan 1, 1989

Thank you for that introduction and especially thank you to the organisers for inviting me. I've had a considerable interest in this area and I've had the advantage of an education from Neil on the subject of offering documents as a result of our collaboration together on the Securities Information Review Committee.

Jan 1, 1989

By Bruno Paponetti, Luigi Toro, Carlo Abbruzzese, Maria Y. Duarte, Anna Marabini

A bioleaching process has been developed to extract manganese from low grade domestic resources not amenable to conventional mineral processing operations. Between the different strains of microrganisms tested, Thiobacillus ferrooxidans has appeared poor over manganese, Aspergillus niger allowed to obtain high recovery, probably due to the metabolic production of citric and oxalic acids, showing a remarkable complexing and reducing action. The growth of microflora has been correlated to the MnO dissolution as confirmed by SEM observation.

Jan 1, 1989

By Houchin MR, Jenkins DH

This paper examines the importance of processing to the properties and performance of high purity zirconia ceramics. Many of the principles discussed, however, apply to ceramic processing in general. For fabricated ceramic articles to display their wide range of high performance properties, they must be made fully dense. The precursor powder and postpowder processing requirements necessary to achieve full density in the fabricated body are discussed. Brittleness, the anathema of ceramics, can be overcome in zirconia by incorporation of toughening mechanisms. Transformation toughening and microcrack toughening and their origins in partially stabilized zirconia are reviewed.

Jan 1, 1989