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By D. Scott Barr

Whole ore roasting using oxygen fluid bed systems was selected for two roasting facilities constructed for Independence Mining Company Inc. in 1989. Independence Mining Company Inc. (formerly Freeport-McMoRan Gold Company) processes refractory gold ores at two facilities located 60 miles north of Elko, Nevada. The Jerritt Canyon project, a joint venture with FMC Gold Inc, processes 2.8 million tons per year of carbonaceous refractory ore by oxygen fluid bed roasting and aqueous chlorination. The fluid bed roasters have been in operation since July, 1989. The Big Springs project has processed 400,000 tons per year of sulfide refractory ore since May 1989 from the Big Springs Joint Venture between Independence and Bull Run Gold Mines, Ltd.. Freeport Research and Engineering of New Orleans, Louisiana was the developer of the innovative technology used in the oxygen fluid bed roasting systems and have been granted a patent on its use. Environmentally, the roasters have exceeded expectations with lower emissions than designed as measured in compliance testing for the State of Nevada.

Jan 1, 1990

By Lee F. Robinson, Angus W. Morrison, Norman M. Anderson

About 100 years ago the acid and chlorine oxidation routes for gold extraction were abandoned in favour of cyanide/ oxidation processes. Now a return to acid processing is in progress. One publication in particular led HM C Technology to investigate the reaction of dilute nitric acid and alkaline metal chlorides with refractory gold ores.(l) The one stage system of gold and silver recovery from sulphidic ores is described below. It is rapid and does not use large or expensive plant or special pressure equipment. It eliminates calcining followed by cyanidisation and shows a simple way of recovering the gold directly. Patents have been granted in some countries (2).

Jan 1, 1990

By Patricio A. Riveros

Various types of commercial ion exchange resins were evaluated with respect to their ability to extract gold from cyanide leach solutions. Large differences were found among the various resins in terms of selectivity and gold loading. The hydrophi­licity and the charge density appear to be the main factors that determine the resin characteristics. Polystyrene weak-base resins, such as Dowex MWA-1, exhibited the best all-round performance.

Jan 1, 1990

By Pierre Ollivier, Dominique Morin

A general study of gold refractory arsenopyrite pyrite concentrate bioleaching has been carried out including two continuous bioleach testworks at different sizes, namely one at a laboratory scale with a 100 1 unit at a 2 kg/d dry solid flowrate and the other at a pilot scale at a 100 kg/d dry solid flowrate. Both tests show a 80% bioleaching of arsenopyrite in about four days of treatment and with the same kinetic. Pyrrhotite is attacked at the earlier stage of the bioleaching but pyrite remains unaffected. The weak potential of oxidation associated with the decomposition of arsenopyrite and the abundance of arsenite leads to a high grade of elemental sulfur in the bioresidue which consumes the major part of the cyanide during the gold recovery, furthermore, the arsenite and ferrous produced in solution have to he oxidized to obtain a stable precipitate in the waste products and as outlined in previous works of other authors on this subject the addition of iron to obtain a Fe/As molar ratio at least above 3 is necessary. The agitation equipment used in the pilot unit allowed an optimisation study calculation for scaling-up the design and power requirements of an industrial installation, For the pretreatment of a gold refractory As high-graded concentrate the reagent cost has the greatest part in the operating cost of the biooxidation step due to the necessary retreatment of the biosolution, In that conditions the power cost is quite marginal, actually it is significant for the treatment of pure pyrite.

Jan 1, 1990

By Chris A. Fleming, Daan Seymore

The Golden Jubilee Mine in South Africa is the first mine in the Western World to introduce resin-in­pulp technology for the recovery of gold from a cyanide-leached slurry. Located in the Eastern Transvaal region of the country, the plant processes approximately 375 metric tons• of ore per day, of which over 90 per cent is mined in an open pit adjacent to the metaflurgical plant, while the remaining 5 to 10 per cent is trucl<ed in from two small high-grade deposits, located about 10 kilometers from the plant. The gold grade in the open pit is about 1 git, while the values m the two high-grade deposits range between 5 and 15 git. At the current treatment rate, the proven reserves m the three locations will last about another 10 years. Early testwork indicated that the ore was not well suited to conventional filtration processing or to heap leaching because of its high cfay content, and that carbon-m-pulp (CIP) would probably prove to be the most viable metallurgical route. Tcstwork to establish the feasibility of CIP for this application was carried out at Mintek in 1985. This worl<, which was based on batch-leaching and carbon-loading tests, indicated that CIP was technically feasible, but that both the rate of gold loading and the gold-loading capacity of the carbon were inferior to those obtained with Witwatersrand ores. The poor adsorption characteristics of the carbon were attributed to the abnormally high concentration of natural organic compounds (humates and fulvates) in the ore. Batch tests were therefore also carried out with strong-base resins, since resins are known (1] to be far less susceptible to organic fouling than is activated carbon. The results were very promising, and pointed to fast kinetics and a high loading capacity. (Fig. 1 ). Notwithstanding these findings, it was decided to recover gold with activated carbon at Golden Jubilee Mine because the CIP process was, by then, well established in South Africa and elsewhere in the world, whereas resin-in-pulp (RIP) was unproven technology. The r>lant was commissioned in September 1986 and, for 18 months, operated in a carbon-in-leach (CIL) configuration, i.e. with a total of . six leach tanks, the last four of which contained activated carbon. As could have been predicted from the laboratory results, the performance of the CIL plant was generally poor, low gold loadings on the carbon (less than 1500 git) and high losses of soluble gold (0.2 to 0.3 p.p.m.) bemg characteristic of the operation. Consequently, it

Jan 1, 1990

By Keith Sarbutt, I. Jackman

The recovery of gold from a high grade telluride/sulphide flotation concentrate was investigated. Conventional cyanidation resulted in very slow rates of gold extraction. Historically, the refractory nature of tellurides has been overcome by fine grinding, the use of excess lime and long leach times. In some instances, pre­oxidation of the tellurides has also been necessary, to render the gold soluble in cyanide solutions. The former conditions did improve the rate of gold extraction from the present sample, but final recovery was still unacceptable. Chemical oxidation of the tellurides and leaching with oxygen improved gold recovery further. However, it was found that simple modifications to the cyanidation conditions overcame the detrimental effects of the complex chemistry involved in leaching a telluride concentrate. The incorporation of a solution change, or the application of a carbon-in-leach procedure increased the recovery of gold to over 97 percent in 96 hours. In every case, leaching was enhanced by the addition of lead salts.

Jan 1, 1990

By Alan Fricker, Bill Owers

Cyprus Gold NZ Ltd will be recovering residual cyanide from their CIT, operation in New Zealand. The process will use air to strip the cyanide from the acidified barren pulp. DSffi. Industrial Development, who were involved in the bench and pilot studies for Cyprus, have extended the concept to pregnant pulp. The stripping of pregnant pulp eliminates the substantial loss of cyanide through carbon catalysed oxidation during the adsorption stage. A 50% increase in cyanide recovery was obtained from an extensive laboratory investigation. The presence of a cyanide recovery circuit enables leaching to be conducted, without detriment, at pHs at least as low as 9, with consequential 50% reductions in the consumption of lime and sulphuric acid. There should be a small reduction in carbon consumption, and a significant improvement in the quality of the final effiuent, at least in terms of cyanide, cyanates, copper, zinc and sulphur. A small but significant increase in gold recovery can be expected too. There is a net economic advantage of NZ$1.20/tonne of ore by stripping pregnant rather than barren pulp.

Jan 1, 1990

By J. F. Rakszawski, Robert P. D'Orazio

The use of cyanide in the processing of gold has been documented for over a century. It is still one of the more effective methods of isolating gold, as witnessed by the fact that in 1987 cyanidation was used in the processing of 91.5% of the gold produced in the United States.

Jan 1, 1990

By Peter G. Mason

Pressure oxidation is now a well estab­lished process for the treatment of refracto­ry gold ores and concentrates. The process utilizes pure oxygen to oxidize mineral sulphides in an aqueous slurry at elevated temperature and pressure. Gold released from the sulphides becomes amenable to subsequent cyanidation. A major component of the operating cost of this process the supply of oxygen. The quantity required is dependent on the sul­phide grade, the extent of oxidation and the percentage utilization of the oxygen. As the sulphide grade is fixed and complete oxida­tion is generally required to maximize gold liberation, the only opportunity for saving in oxygen consumption is to improve its utilization. Under circumstances where the feed material contains substantial carbonate, oxygen utilization can be improved by strip­ping carbon dioxide from the autoclave vent and recycling the associated oxygen. Fluor Daniel Wright included an oxygen recycle circuit in the Getchell pressure oxidation plant, which is operated by First­Miss Gold in Nevada. FirstMiss Gold has applied for patent rights to the process as implemented at Getchell.

Jan 1, 1990

By Hans von Michaelis

ecent events have demonstrated the extraordinary impact of politics on the price of gold.... A rise from the $350/oz. level to $400 has a far greater impact on profitability of a gold mine than does, say, the invention of a way to cut the cost of gold extraction by $1.00 per ton, which in itself would represent a major achievement. Likewise, the discovery of a big, high-grade, easy­to-extract gold ore deposit would have a bigger impact on the fate of a mining company than, say, finding a way to double the energy efficiency of a grinding circuit.

Jan 1, 1990

By B. R. Green, Ms. M. H. Kotze

Ion-exchange fibres (IEF) were prepared by the ir­radiation grafting of styrene onto polypropylene, which was then subsequently functionalized. Strong- and weak-base exchangers were prepared and evaluated Tor their ability to extract gold cyanide selectively. The IEF prepared had loading capacities similar to those of the corresponding resins and they had good selectivities for gold cyanide when contacted with a mixed metal-cyanide solution. The expected advantage of IEF over granular exchangers, that of faster kinetics, was illustrated. The strong-base Iibre in particular seemed to be very effective for the extraction of gold cyanide from dilute solutions such as return-dam waters.

Jan 1, 1990

By Tim Haldane

Cyanide consumption at the Gold Fields Operating Company Mesquite Mine has shown a steady decline since the heap leach operation started up in 1986. A series of solution strength changes and equipment design improvements have resulted in a reduction of sodium cyanide consumption from peak levels above 1.0 pounds NaCN per ton of ore in 1986 to current levels at 0.15 - 0.20 pounds NaCN per ton of ore. Aside from the obvious cost benefits associated with this reagent consumption reduction, the property has also enjoyed environmental benefits which go hand-in-hand with these cost savings.

Jan 1, 1990

By Donald R. East

The impacts of the economic storage or disposal of mill tailing wastes are becoming more important to the mining industry as environmental regulations become more demanding. Mill tailings have long been considered the stepchild of the extraction process and have not, until recent years, been treated as a separate entity of the mining and milling process with distinct and complex physical and chemical characteristics. As a waste product, the economic value of mill tailing is usually very small whilst economic and the environmental liabilities can significant. be Disposal of tailing is commonly identified as the single most important source of environmental impact for many mining projects.

Jan 1, 1990

By James McMaster

The Kamyr Countercurrent Tower Leaching Process is intended to combine, in a single tower, thickening, leaching, separation and clarification of pregnant solution, and washing of leaching chemicals from the tailing pulp. For a gold or silver metallurgical plant, the flowsheet would consist of crushing and grinding, cyclones for size control and partial thickening, the Kamyr tower, and a gold or silver recovery system of either carbon in solution, zinc precipitation, or direct electrowinning. Ancillary systems for the Kamyr metallurgical plant would include cyanide preparation, fiber preparation and recovery, and flocculant preparation.

Jan 1, 1990

By James R. Arnold

With all of the publicity, criticism, and notoriety that the mining industry has received over migratory birds, it is diffi­cult to remember that six years ago no one even suspected that this issue would'emerge. After all, cyanide had been used in Nevada mining for 20 years without significant effects on wildlife. Although the mining industry has been buried in unjustified criti.cism for not having a clearer crystal ball, most of those critics forget that no one else predicted this problem either. In fact, the Nevada Department of Wildlife reviewed and had no objections to the Paradise Peak Plan of Operations before they began production. As we now know, Paradise Peak had one of the first and most severe avian mortality prob­lems in the State. It should also be noted that Paradise Peak has done more to research and solve the migratory bird problem than all of the rest of the Nevada mines put together. It is not possible to review all of the research and field work that has gone into investigation of the avian mortality problem over the past five years in this short paper, but a synopsis can be presented. In most instances we can say that we have solved the problem, We have learned what works and what does not. Let's start with what does not work. Unfortunately, the list is long and elaborate, but can easily be summed up in one word: hazing.

Jan 1, 1990

By Ralph P. Hackl

Biooxidation processes for treating arsenical and other types of refractory gold ores are touted by many as being simple, inexpensive and environmentally friendly. One of the advantages claimed by proponents of biooxidation is that arsenic is disposed of as insoluble ferric arsenate which is suitable for long term disposal in tailings ponds. However, there is considerable controversy as to the stability of ferric arsenate with respect to re-dissolution of arsenic. In particular, there is concern that the amorphous ferric arsenate produced at low temperature is not stable, especially at the alkaline pH's required for cyanidation. There is a general lack of published information on the stability of arsenical bioleach tailings. Past work on ferric arsenate stability has usually involved purely chemical systems and the use of synthetically prepared precipitates. Upon completing the Salmita bioleach pilot plant campaign (Hackl and Wright, 1989) the author had the opportunity to test the stability of the arsenical bioleach/cyanide tailings which were produced. This paper summarizes the results of that work.

Jan 1, 1990

By Terry Mattioli, Buck Bradshaw, Terry Fagg, Larry G. Nisle

Deposition of calcium carbonate scale on activated carbon in the Pinson Mining mill carbon column circuit was causing erratic gold recovery rate, long acid wash time, high carbon attrition and long strip times. Continuous addition of a blended antiscalant into the mill thickener overflow at 8 ppm reduced the average carbon acid wash weight loss from approximately 10% to < 2%. Cleaner carbon improved the gold loading rate in the mill column. The loading on Column I was increased to 175-225 oz/ton carbon from 125-150 oz/ton for a two-day carbon advance cycle. The higher loading capability has given Pinson more flexibility and better control of gold flow through their carbon adsorption, stripping and electrowin­ning processes. Preventing calcium carbonate build-up on activated carbon with this antiscalant reduced acid wash batch time. This enabled Pinson to acid wash and regenerate every batch of stripped carbon for all the adsorption circuits. Shorter strip times have also resulted from the lowering of the calcium carbonate scale level in the loaded carbon. Carbon consumption has been reduced and is now averaging 0.046 lb/ton ore for the first six months of 1990 compared to 0.072 and 0.083 lb/ton respectively in 1989 and 1988.

Jan 1, 1990

By Jim McMaster, Charles W. Kenney

The role of oxygen in cyanide leaching ia well understood in the gold industry. Oxygen enrichment has taken on a real, practical meaning to operators with the were to evaluate the effect of oxygen enrichment on the kinetics of heap leaching gold ores, to examine methods of oxygen application in the heap, and to develop preliminary economics for the process. Several series of column tests were completed increasing preaeration, applications. use of pure oxygen for leaching, and in CIL in the test program. Oxygen enrichment may have a significant place in heap leaching as well. In preliminary column tests sponsored by Kamyr at Hazen Research, Inc. , oxygen-purged columns showed an increase in both the leaching rate and maximum recovery of gold and a reduction in cyanide consumption compared to columns run with air. Potential benefits of using oxygen in heap leaching include faster leaching kinetics, shorter cycle time, higher recoveries, and more efficient use of permanent or reusable pad space. The concept requires confirmation of technical and economic feasibility on a commercial scale.

Jan 1, 1990

By Peter A. Spencer

Much criticism has been levelled at bacterial oxidation over the quantities of air required for successful operation. Examination of the oxidation reactions and the assumptions concerning oxygen transfer made in the literature (1) indicate that the aeration requirements can be much less than those beirig suggested. Observations made on a large scale pilot test have confirmed reasonable aeration levels in extended site operation over a six month period. These aeration levels have implications for the engineering design and the power needed for aeration and agitation. Thus, these parameters effect both capital and operating costs as well as influencing the complexity of the design and normal operation. A number of companies have developed bacterial oxidation cultures intended for commercial ·expl oi tat.ion ( 2, 3, 4). Most of these cultures have been based on Thiobacillus and operate at temperatures between 30°c and 40°c. This temperature range limits their application in hotter regions unless means for both heating and cooling are provided in the design. Thiobacil!us cultures are also reported as not able to oxidize arsenic (III), which may limit the application of these cultures to successfully treat arsenopyritic ores and concentrates (5). BacTech (Australia) Pty Ltd has developed a culture which operates at temperatures above 4o0 c and which has been tested in a large site based continuous pilot plant at up to 55°c over a six month period. The culture showed resistance to high levels of soluble arsenic, allowing the arsenic to be retained in solution for control led precipitation and disposal. Data for. the arsenic precipitates indicated that these waste solids were relatively stable and, under the correct circumstances, were suitable for disposal into tailings dams without causing environmental problems.

Jan 1, 1990

By Roger Nendick

The recent developments in refractory precious metal ore processing (Bio-oxidation, Autoclaving), and the revitalization of the more traditional roasting processes have attracted great attention in recent years and are indeed the focus of todays symposium. It must always be remembered, however, that the term refractory ore by definition means that the material 'must be capable of being treated at a profit". Given the high cost of the refractory processes, the requirement to be treated at a profit requires very close scrutiny during the evaluation phase of the property development. The M.G.M. film company has the latin motto Ars Gratia Artis meaning Art for Arts Sake. Ingeniatore Gratia Ingeniatoris (a very crude attempt at saying Engineering for Engineerings Sake) should not be the motto for mining companies intent on exploiting refractory gold deposits, but rather the wittily tilted heading for this paper "Take the money and run like a thief". The following hypothetical case studies show that the high technology solution is not always the best financial solution.

Jan 1, 1990