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By Alexander May

The U.S. Bureau of Mines conducted studies to determine if phosphate slag stockpiles at Tennessee Valley Authority's National Fertilizer Development Center were hazardous materials. The stockpiles were not hazardous materials as determined by Environmental Protection Agency (EPA) extraction procedure (EP) toxicity test. Radium-226 concentration was 28.7 pCi/g in slag and 2.1 pCi/g in background material. Radium-226 was not leached from the slag. Fluoride concentration was 3.87 pct in slag, 0.18 pct in subsurface material under slag, and 0.08 pct in the background. Slag material permeability was 1.65 x 10-3 cm/s, and subsurface material permeability was 3.24 x 10-6 cm/s. Rain water, trapped in a depression on top of the east slag stockpile, became seepage water at the base of the stockpile. Concentrations of EPA toxic elements in seepage water were much less than concentrations from an EPA EP toxicity test on the slag. Twelve elements-Na, Mg, Ca, Sr, Ba, Cr, Mn, Co, Cu, Cd, AI, and P-had higher concentrations in seepage water than in rain water on top of the slag stockpiles, or in creek water adjacent to stockpile bases, indicating that they were leached from slag stockpiles.

Jan 1, 1990

Attention is drawn to the largest eruptions with dense rock equivalent (D.R.E.) volumes approx-imating 50 km3. These have been strongly clustered during the last 40 000 years, with 11 recognised in the period 35 000 to 22 000 years ago, and 10 in about the last 9000 years, but none in the period 22 000 to 9000 years ago. With the latest such eruption, at Tambora, only 175 years ago, it is likely that we remain in a period of increased activity. During the last 100 000 years, roughly the period during which modern Homo sapiens has existed as a species, there has only been one eruption an order of magnitude larger (>_ 500 km3 D.R.E.). This took place at Lake Toba, Sumatra, about 75 000 years ago, and is estimated to have deposited ash to a thickness of a centimetre or so in parts of Ethiopia, Somaliland, Saudi Arabia and Iran, and to a thickness of a few millimetres in the eastern Mediterranean. The average interval between global eruptions of this magnitude is probably about 40 000 to 50 000 years. Insufficient work on the Quaternary history of volcanoes has been carried out to suggest where the next such eruption might occur. At Yellowstone, which has been well studied, the average interval between very large explosive eruptions is about 700 000 ¦ 120 000 years.As a prerequisite for magnitude-frequency analysis of eruptions, and hazard and risk impact assessments, it is important to classify past eruptions in a consistent manner. In an attempt to find a universally applicable method to estimate order of magnitude D.R.E. volumes from the distribution of airfall tephra, an empirical correction has been derived for the elongation of tephra dispersal fans due to wind. Dispersion distances for various thicknesses of tephra, recalculated for windless conditions, have been obtained from a study of about 40 tephra isopach maps for which D.R.E. volumes have been calculated, and a range of distances derived, equivalent to D.R.E. volumes from 106 m3

Jan 1, 1990

By P. R. A. Andrews, G. Heinrlch, V. I. Lakshmanan

The paper describes a simplified method to chemically modify the surface of industrial mineral fillers. Four industrial mineral samples were taken from feedstock of commercial fine grinding operations. These samples were ground in bench scale ball mills and in the presence of various organic solvents. The ground products were measured for particle size distribution, surface area, surface chemistry by oil absorption and degree of organicJminera1 bonding. Where appropriate, the ground products were compared to commercially available surface modified, industrial mineral fillers.

Jan 1, 1990

Mount Isa mine is the largest underground mine in Australia and is located 2,000 kilometres north-west of Brisbane. This mine has been in continuous operation since 1931 and in 1986/87 the silver/lead/zinc stream achieved the peak annual mining rate of 4.7 million tonnes. At present about fifteen different steeply dipping stratiform orebodies are being mined to maintain an annual production rate of around 3.0 million tonnes. Out of these, only two orebodies (2 & 5) are amenable to sub level open stoping (SLOS) type bulk mining methods. This year only 150,000 tonnes are scheduled from pillars and remnant areas but in future, more sources will be required to meet the budget production targets.

Jan 1, 1990

By Scoble M, Peck J

This paper reviews the instrumentation and monitoring of blasthole drills and electric mining shovels at a surface coal mine in western Canada. The drill monitoring component involved the development and implementation of microprocessor-based hardware on Bucyrus-Erie 45R and 60R drills. Over a two year period 3800 metres of blasthole drilling were monitored The drill data was subsequently correlated with core and geophysical logs towards identifying unique and reproducible ranges of performance parameter data for the different rock types penetrated. Using this technique, the geology of the study area benches was characterized in detail. Once these same benches had been blasted, the performance of a P&H 2800XP shovel was monitored as it worked through the blasted ground. In this regard, the influence of different digging conditions on shovel performance were identified in a range of blast and geological environments within the study area. The precise nature of these environments was confirmed by a correlation with the interpreted drill monitored data and muckpile size distributions obtained from a digital photo-analysis study. The excavation of 500 000 bcm of waste was thus monitored and a digging index derived which reflected variations in muckpile diggability. The paper concludes by proposing an integrated monitoring approach which, as a first step, uses interpreted drill data for explosive loading. This capability would permit greater accuracy in explosives loading ie. charge placement within higher strength lithologies, while avoiding weaker units. The performance of an instrumented shovel would then be monitored as it works through the resulting muckpile. Interpretation of the shovel performance data would determine the overall quality of the blast in terms of a digging index (DI), providing an indication of the relative digging effort and the effectiveness of the blast design.

Jan 1, 1990

Carbonate-hosted massive sulfide ores of the American cordillera compose a distinctive genetic class. Discordant fea-tures of occurrence together with measured high-temperatures of formation indicate their essential epigenetic character and close spatial association with centers of thermal activity during evolution of the cordillera. Their metallogenic character is complex from region to region: Cu-Zn-Pb-Ag, Pb-Zn-Ag, and Cu-Zn-Ag-Au represent extremes of composition and each may be identified with specific terranes of occurrence, notwithstand-ing an inferred common process of formation. Beyond the presence of a thermal center, other controls that may be identi-fied include apparent but obscure properties of primary perme-ability or chemistry of hosting strata, and secondary controls are imposed by stratigraphic differences in which permeability is strongly contrasted. Structures that act as channelways may be identified in some instances. Notwithstanding their intrinsic value, search for these ores is difficult and requires the solution of complex geochemical and three-dimensional geometric problems.

Jan 1, 1990

By S. P. Sandoval

Several researchers have shown that the surface of chalcopyrite becomes hydrophobic under oxidizing conditions. Because dissolution of copper from chalcopyrite in dump leaching occurs under oxidizing conditions, the U.S. Bureau of Mines studied the effect of surfactants on chalcopyrite leaching under dump chemical conditions. Surfactants were selected for study because they can lower interfacial tension. The tests were conducted in shaking water baths using 250-mL Erlenmeyer flasks in statistical experimental design formats. The addition of nonionic surfactants increased copper extraction in the fernc sulfate leaching of chalcopyrite when sufficient Fe3+ was present. A positive interaction between Fe3l+ concentration and surfactant concentration was demonstrated. Copper concentration in the leachhing solutions was increased by as much as 100 pct at 25° and 50° C by adding nonionic surfactants. ionic surfactants decreased leaching. The structure of the nonionic surfactants and their hydrophile-lipophile balance (HLB) influenced surfactant performance. The branched hydrophile of an ethoxypolyol was beneficial to surfactant performance. The ethoxypolyol was the superior surfactant at 25° C, but became unstable at 50° C. Four surfactants, an ethoxyalchohol and three block copolymers, performed best at 50° C.

Jan 1, 1990

By J. E. Rourke, O&apos

This paper describes the use of index testing to obtain rock properties that are useful in the design and construction planning of an underground development for civil engineering or mining projects. The index properties discussed include: point load; Schmidt hammer hardness; abrasion hardness; and total hardness. The first two index properties correlate to uniaxial compressive strength (UCS) and Young's modulus. Discussions are given on empirical, normalized relationships of UCS to rock mass properties and the integrated use with semi-empirical, geotechnical design methods. The hardness property indices correlate to construction performance parameters and some relevant experience is cited. Examples of data are presented from an index testing program carried out primarily on siltstone, sandstone and limestone rock core samples retrieved from depths up to 1005 m (3300 ft) in a borehole drilled in the Paradox Basin of eastern Utah. The borehole coring was done for a nuclear waste repository site investigation.

Jan 1, 1990

By R. S. Shoemaker

It is said that there is nothing new under the sun and this is certainly true about refractory gold Ores. Ores which have been refractory to treatment have been the bane of the Metallurgist's life ever since gold has been recognized as a metal valued for its indestructability, malleability and beauty. Webster's Dictionary defines "Refractory" as; "Resisting control or authority, stubborn, resistant to treatment or cure, unresponsive to stimuli, difficult to corrode or draw out," And gives as a synonym the word "unruly." I don't think any metallurgist would disagree with these definitions as they quite accurately describe refractory gold ores as we know them and I wouldn't be a bit surprised if many of you in this room today had applied far stonger language to your own refractory ores in the course of your metallurgical test programs. Pliny the elder put it very well when he wrote in 79 A.D., Gold is the first of man's follies, Silver the second." Perhaps Pliny was speaking of "unassayable gold" or "incipient gold." These are truly refrac tory ores which probably existed before Pliny's time and although many people have claimed to have solved their metallurgy the untold wealth that lies within them has never been bankable. On the other hand, Virgil is his Aenead, could very well have been speaking of refractory ores when he wrote; "Quid non mortalia pectora cogis, auri sacra fames!" which translates as, Accursed thirst for gold! What doest thou not compel mortals to do. Certainly, gold was extremely rare at that time because it had to be recovered by much labor from the then refractory ores and their refractoriness caused the early metallurgists (or alchemists if you will) to seek an easier way to produce it; thus the long and fruitless search for the "philosopher 's stone" which would aid in turn-

Jan 1, 1990

Tectonic subsidence plots have been calculated for well, extrapolated-well and significant off-well (seismically-based) locations in the Vulcan Sub-basin and adjacent highs (western Timor Sea). The subsidence curves have been normalized to a common datum, the distinctive "near top Permian" marker, and corrected for sediment compaction, palaeobathymetry, eustatic sea-level change and loading effects.Four principal phases of post-Permian basin development are recognised and quantitatively described by integrating the results of the sub-sidence analysis into the regional (e.g. recent Ocean Drilling Program-derived) framework of the tectonic evolution of the North West Shelf. They are1. the Triassic-mid Jurassic Westralian Superbasin intracratonic phase,2. the late Jurassic-early Cretaceous North West Shelf rift phase,3. the mid Cretaceous-Palaeogene North West Shelf subsidence phase, and4. the Neogene-present Timor collision phase. Rapid Triassic tectonic subsidence occurred in an intracratonic setting, possibly subsequent to aborted late Palaeozoic rifting. Intracratonic sub-sidence mechanisms such as deep crustal metamorphism and/or intrustion and regional tectonic compression are invoked in addition to any post-rift thermal subsidence which may have occurred.

Jan 1, 1990

The paper examines the value of very small-scale indigenous gold mining operations to developing countries. The paper looks particularly at this type of activity in two neighbouring countries, Papua New Guinea and the Philippines, considering technical, economic, social and environmental aspects.

Jan 1, 1990

By James A. Brierley, Rong Yu Wan

Bacterial pretreatment was evaluated as a process for enhancing gold recovery from a refractory ore from Newmont Cold's Cold Quarry deposit. This ore is refractory due to sulfide locking of the gold and preg-robbing carbon. The microbe Thiobacillus ferrooxidans effectively oxidized the sulfide component of the ore, but the preg-robbing carbon continued to be active. Thiourea was examined as an alternative to cyanide for extraction of the gold from the biooxidized ore. The thiourea, coupled with CIL, was effective for gold extraction resulting in up to 89% gold recovery for the sulfidic-carbonaceous refractory ore. The thiourea gold complex appears not to be bound by the preg- robbing carbon of the ore when in the presence of recovery carbon (CIL)

Jan 1, 1990

By W. S. Versluis, G. W. R. Kuzyk

Atomic Energy of Canada, Ltd. (AECL) is constructing an Underground Research Laboratory (URL), a major component of-the Canadian Nuclear Fuel Waste Management Program. In July 1988. AECL and the US Department of Energy commenced a cooperative research program that included extending the URL shaft by 190 m (623 ft) to the 443-m (1,453 ft) depth. The shaft extension, 4.6-m- diam (15-ft-diam), was excavated by full-face blasting using a burn cut. A Galloway stage accommodated the research activities and the sinking contractor's requirements. Blast designs incorporated controlled blasting techniques to minimize blast-induced damage on the shaft walls. The full-face method has been very effective, with 3.5-m (11.5-ft) rounds being advanced.

Jan 1, 1990

The geologists at the Zinc Mine in Broken Hill have developed a method of logging core using portable MS-DOS computers and LOTUS 123. The computer based logging system has almost halved both the time and cost to produce a completed log. The system is fast, flexible, easy and pleasant to use.

Jan 1, 1990

By Erickson M. E, Smith C. K, Carswell J. T

Thirteen holes totalling 3200m were surveyed using a downhole time domain Geonics EM37 system at the 830 metre level within the CSA Mine, Cobar, New South Wales, in order to search for blind, electrically conductive sulphides at some distance from exploration drillholes. A significant off-hole conductor was detected in only one drillhole.Geophysical modelling and interpretation of the survey results indicated that this off-hole conductor was caused by a sulphide lens 30 metres from the drillhole at a hole depth of 220 metres.

Jan 1, 1990

By Jr. Gabler

World resources of cobalt appear ample for the foreseeable future; however, political and economic events have caused concern over the availability and reliability of an uninterrupted supply. Because of this concern, the U.S. Congress requested that the U.S. Bureau of Mines initiate a study of the flow of cobalt in the economy that would delineate and quantify the production areas where metal values are lost. As a result, the Bureau has developed a computerized commodity flow model. A major attribute of this model is that it is amenable to updating as supply, demand, and/or production data change. This report follows the flow of cobalt through its metallurgical and chemical applications and highlights areas where significant losses occur due to downgrading, export, or disposal. The study indicates that about 4,300,000 lb of cobalt-bearing materials are lost each year, representing 24 pct of U.S. domestic demand.

Jan 1, 1990

Green policies have gained momentum since the 1972 Stockholm Environment Conference. The environmental movement has influenced political initiatives both in New Zealand and abroad. Governments and international institutions have addressed local, regional and global environmental issues with varying degrees of success. New Zealand so far has not supported the United Nations' call for sustainable development in a,consistent manner.New institutions and new rules for resource management mean there are opportunities to look after the land in different and more ecologically sensitive ways than has happened in the past.The increasing influence of regional councils in resource management planning will have important implications for mining and mineral exploration. These trends are discussed and possible future events outlined.

Jan 1, 1990

By M. A. Bronston

A drill system configuration capable of working in the arctic offshore environment was developed to evaluate the placer gold resources contained in the glacio-fluvial sediments offshore Nome, Alaska. This system is capable of working on the shore fast ice during the winter months and is deployed on a drill ship during the summer. Transfer of the drill between its summer and winter configurations is accomplished with a minimum of modification to the design. The system is designed around the Becker drill. This percussive, reverse circulation drill is capable of penetrating the indurated glacial sediments present in the offshore Nome environment. This drill has operated effectively to depths in excess of 50 m (164 ft) below sea level. Since early 1987, in excess of 2000 holes have been drilled using the system. The drill system often operates in extreme weather conditions. It has averaged approximately 10 holes a day of drill production. The ore reserves defined during these drilling programs have resulted in the recovery of more than 70,000 oz (2.18 t) of gold to date, by the mining vessel Bima.

Jan 1, 1990

By William Petruk

The behaviour of sphalerite during mineral beneficiation of base metal ores has been studied at CANMET and other institutes for at least 15 years by determining the liberations of sphalerite in mill products and calculating the recoveries of liberated and unliberated sphalerite in zinc concentrates. Sphalerite in base metal ores commonly occurs as layers and as interstitial material between pyrite. Layered sphalerite is generally liberated during primary grinding, but interstitial sphalerite requires re-grinding to achieve liberation. Around 95% of liberated sphalerite is generally recovered in zinc concentrates frau zinc circuit feeds. A series of tests was conducted on sphalerite in the ore of Brunswick Mining and smelting during a continuous fine tuning operation of the concentrator. It was found that a grind of 80% minus 37 micrometres was required to liberate the interstitial sphalerite. The fine grind increased Zn recoveries from 75% to 78-80%, but produced liberated slimed sphalerite which was lost. Since regrinding to a fine grain size is needed to obtain the desired sphalerite liberation, a method of recovering the slimed sphalerite is required.

Jan 1, 1990

By D E. Siskind

The Bureau of Mines performed a comparative study of nine sites at eight surface coal mines to determine if the presence of near-surfaced underground abandoned workings resulted in the generation of adverse long-duration, low-frequency blast vibrations. Six of the nine sites had underlying workings, and two had thick layers of low-velocity unconsolidated surface material.

Jan 1, 1990