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By Chris Joyce, Peter Ryan

Investigation of the occurrence and significance of acid drainage from mine sites in Australia has received a degree of attention in recent years. For contemporary and future projects, particularly those in hi1;1her rainfall areas, the focus on prediction and resolution of acid drainage issues is. likely to increase. This paper describes the preventative and remedial measures adopted at three metalliferous mines in northern Australia at which acid drainage was identified as a key issue with respect to project environmental management and rehabilitation. The thre case studies respectively comprise an active, ·1 recently decommissioned and an abandoned operatiou which was rehabilitated in the mid '80s.

Jan 1, 1991

By Barry J. Hansen

Mining can make two major contributions to the cleanup of the environment. The first of these is the extractive technology that has become highly developed as a result of centuries of development. Of equal impor­tance are the methodology of analysis and the development of engineering solutions that are the stock in trade of the mining industry. Despite the differences between the industries, the processes for the development of a mine and the cleanup of a hazardous waste site are similar. The characteristics that impact the ability to develop a suitable process for treating an ore body or correct­ing an environmental problem are those relat­ed to the distribution of the contaminant or metal in the host material.

Jan 1, 1991

By Marshall A. Koval

The future of mining in the United States is in question. The cumulative effects of federal, state and local environmental legislation threaten its survival as the cost of compliance skyrockets. Legislation has created pol ari zat ion between government and industry followed by court action, further increasing costs and delays on permitting and remediations. Regulations often call for excessive and rigid requirements that result in unrealistic compliance goals costing tens of millions of dollars. The costs often exceed the value of the remedy. A growing concern is that proper scientific methodologies and engineering practices are being sacrificed because of political and public pressures.

Jan 1, 1991

By Robert Dunne, Paul Gelfi, Vernon Martins

The New Celebration Gold Mine is located 32 km south of the regional mining centre of Kalgoorlie. The current mill throughput is 1.7 million tonnes per annum with a gold production of around 120,000 ounces per year. The main source of ore for the mill comes from the Hampton Boulder and Pernatty pits. Over the last two years the oxide reserves from these pits have been depleted and the harder primary sulphide ores are now being processed. This change has led to a decrease in cyanide extractable gold.

Jan 1, 1991

By H. N. McLeod, B. C. Butler, S. R. Rice

Tius paper describes the key considerations for design of impoundments for gold mine tailings. Design options available for construction are presented. The key considerations for design of a safe, economic and environmentally sensitive design are discussed. The dam design must also balance these conventional considerations with the pragmatic aspects of construction and operations and the risk of system upsets. Case examples of tailings facilities in Canada and Papua New Guinea are discussed.

Jan 1, 1991

By R. Z. Pyrih

Pressure/ ,acuum lysimeters were used to instrument column tests containing several lifts of tailings slurry, and to sample pore water as the tailings lifts dried. The results of the column testwork demonstrated that air oxidation of sulfide minerals associated wilh the tailings residue neutralized the alkalinity of the tailings pore water. Neutralization of the alkaline pH volatilized cyanide which, in turn, destabilized copper-cyanide complexes and caused the precipitation of insoluble copper from solution. Analyses of pore water samples for microbial activity indicated high plate counts. The presence of viable microorganisms in the pore water implied that degradation of cyanide was enhanced by growth and activity of cyanide-consuming microorganisms in the tailings material.

Jan 1, 1991

By S. J. Chadwick

The majority of small gold plants constructed around Western Australia were designed for short lives and treatment of oxide ores. The crushing plant frequently bore the brunt of capital cost savings resulting in inadequate design and equipment selection. The exhaustion of oxides and progressionto more competent ores is _ resulting in plant operators seeing their he majority of small gold plants constructed around Western Australia were designed for short lives and treatment of The net result of many of extended operating hours, low inability to achieve fine mill blow out in operating costs, the above is throughput, feeds and a oxide ores. The crushing plant frequently bore the brunt of capital cost savings resulting in inadequate design and equipment selection. The exhaustion of oxides and progression to more competent ores is resulting in plant operators seeing their operating costs spiral upwards. Steps taken at Jubilee mine to improve plant productivity and lower mechanical failure will be discussed. operating costs spiral upwards. Steps taken at Jubilee mine to improve plant productivity and

Jan 1, 1991

By W. J. C. Meynink

In drier regions of the world, total containment of cyanide liquors for rainfalls less than a specific design value is often required by government regulation. For example, in Queensland total containment is required for rainfalls up to 'the 1% annual exceedence probability. In equatorial regions, where rainfall greatly exceeds evaporation, a total containment requirement is unrealistic and this is recognized by regulatory authorities. Regulatory constraints typically require that cyanide concentrations at an agreed downstream compliance point not exceed a specific value more than a specified fraction of the time. While the excessive rainfall prevents total containment, it does provide substantial dilution. This paper outlines a methodology for assessing the distribution of cyanide concentrations at a downstream compliance point in an equatorial region with limited hydrometeorological data. Consider the hypothetical mine environs depicted in Figure 1. The mine is located near the catchment divide and draws its water supply via a gravity line. Tailings from the process plant are piped to a tailings dam on a sub-catchment below the plant site. The objective is to determine the distributions of cyanide species concentrations at a compliance point just upstream of a major settlement to ensure they do not exceed regulatory limits.

Jan 1, 1991

By P .. F. Ziemkiewicz, T. E. Rymer, J. J. Renton

Prediction and quantification of acid mine drainage (AMD) from a given rock unit is in its infancy. Acid Base Accounting is the current procedure. II is a useful screening procedure and is designed to indicate whether a rock unit will or will not produce acid. In this sense, Acid Base Accounting is qualiwtivc. Researchers at West Virginia University arc developing a prediction method to estimate how much acid will be produced over the life of a rock unit's AMD production. TI1c AMD prediction procedure can also evaluate the required rates and effectiveness of various AMD control amendments. This presentation discusses the WVU AMD prediction procedure in the context of historical approaches and indicates the mechanics and applications of this new technology.

Jan 1, 1991

By Ivan Hunter, Gary Johnson

In many comminution circuits based on SAG mills, an operating cost penalty is incurred in terms of high unit power consumption. By the addition of a crusher to the circuit, to crush part of the so­called critical size fraction extracted from the mill charge, the power efficiency of the circuit can be significantly improved. Dominion Mining has now incorporated pebble crushing into three of its comminution circuits. The improvements in circuit performance have in all cases been significant, and in some cases dramatic.

Jan 1, 1991

By W. P. Staunton, K. Jones

INTRODUCTION The increased activity in the Aus­tralian gold industry over the last decade has resulted in a concomitant increase in the use of sodium cyanide, with a projected consumption of 80,000 tonnes in 1991. Growing environmental awareness by government, industry and the public has generated increased interest in the fate of cyanide near gold mine tailings dams and has highlighted the lack of basic knowledge in the area, particularly for Australian conditions. In 1989 the Chemistry Centre (W.A,) commenced a' project, under the auspices of the Australian Mineral Industries Research Association entitled "Fate of cyanide in the Enviroment Near Mine Tailings" to investigate some of the issues arising from the management of tailings containing cyanide, The project, which has been supported by thirteen companies has three broad aims:

Jan 1, 1991

By David E. Peterson, F. Merz

The Waihi Gold Mining Company Limited, Martha Hill Project was the first major hard rock mining operation following the resurgence of the mining industry in New Zealand. Because of its location adjoining a town and at the southern part of the sensitive Coromandel Peninsula, the operation received a high level of public scrutiny. Very srrict limits for effluent criteria had to be met and led to the necessity for advanced wastewater rreatment technology. The process technology selected was the copper catalysed oxidation of cyanide using hydrogen peroxide, with subsequent removal of heavy metals by precipitation and filrration. This paper discusses the adoption of environment limits together with the detailed description of the plant and design criteria. Data of the one year's operational history is also presented.

Jan 1, 1991

By L. D. Jayaweera, R. G. Robins

The pocessing of gold bearing sulphide minerals wr ich contain arsenopyrite and other complex arsenic sulphide minerals results in arsenic containing emissions and effluents which must be given careful consideration in relation to clean air and clean water standards. The sources of arsenic and the various process options for treating arsenical gold ores and concentrates are briefly reviewed. The problem relating to the removal of arsenic from gaseous emissions from roasting processes is considered. Residues from aqueous processing contain a variety of arsenical materials which have not been characterised, and the long-term stability of these is suspect. 'rhe use of lime to stabilise aqueous residues as either calcium arsenate or calcium arsenite has been shown to be inadequate for long term disposal since both compounds are converted into calcium carbonate due to the influence of carbon dioxide in the atmosphere. Ferric ion solutions have been used to precipitate ferric arsenate or to form ferric hydroxide which binds the arsenic for short term disposal, The long term stability of these ferric materials is poor, but could lead to the acceptance of a slow release option rather than complete containment of residues.

Jan 1, 1991

By W. Hopkin

INTRODUCTION Necessary science and technology are not well established for the design of responsible treatment and disposal of arsenical residues from refractory gold ores. Specifically, there is uncertainty about the precise composition and behaviour of oxidised arsenic species in these wastes, and an analysis of possible chemical behaviour suggests that potentially difficult control and disposal problems remain to be so 1 ved. In tackling these the undoubted toxicity of arsenic in excess and its bad press should not blind one to the realities of actual behaviour in the environment, and that some adverse behaviour inevitably has to be to 1 erated as a cost in return for the recovery of an operation's gold for society. The problem is to minimise any such cost. Each refractory ore will be different. Many will contain so little arsenic that it will cause only trivial problems in disposal, but there remain others with significant arsenic content, say in the order of 1% or more, to cause concern. As already implied, concern can be over emphasised but equally underestimated. The balance which must be struck in the design of responsible disposal in the widest sense requires objective and practical assessment of a complex range of chemical, biochemical, engineering and economic design factors, all of which should involve the process design team in constructive dialogue with the 1 oca l regulatory authorities. In British terms, the general objective should be the Best Practicable Environmental Option. Arsenic is ubiquitous in waters, rocks and soils and all living things. Its compounds undergo natural geochemical and bi ochemi cal cycles including powerful adsorption and precipitation processes which return to nature all leakage from the inevitable disturbance of mining and extraction operations. Within limits, all life is tolerant to its presence, and adaptation and detoxication processes occur to deal with local excesses.

Jan 1, 1991

By Richard E. Deery, Reginald E. Reid

A large portion of the public lands in the United States is managed by the U.S. Department of the Interior, Bureau of Land Management (BLM). Public lands administered by the BLM comprise about 39 per cent (270 million acres) of the entire Federal surface estate or about 1/8 of the surface of the United States. Most of this land, located in the 11 Western States, including Alaska, is available for mineral exploration and development. The BLM is a multiple-use land management agency responsible for the balanced management of the public lands and their resources. The BLM's task is to ensure the balanced and sustainable development of the public lands and resources. This task translates into the management of people and their use of the public resources. As a result, the BLM manages a diverse group of programs including recreation, range lands, timber lands, fish and wildlife habitat, watershed, wilderness, scientific, cultural, and historic properties, and most importantly for this paper, energy and mineral resources. The BLM has developed several new policies with respect to mining, including policies on inspection and enforcement, financial guarantees for reclamation, and the use of cyanide. The goal of these policies is to demonstrate to the American public that mineral exploration and development can be an integral part of sustainable development on public lands in an environmentally sound manner.

Jan 1, 1991

By Alan G. Fricker

Cyprus Gold NZ Ltd will be recovering residual free cyanide in barren gold pulp by air stripping. Laboratory investigations by DSIR have indicated additional advantages by recovering the cyanide from pregnant pulp. These are a lower leach pH, a greater cyanide recovery and less carbon consumption. They have a net economic advantage of $1.20/tonne over recovery from barren pulp. The realisation of these advantages is dependent on three crucial technical aspects -optimum pH for dissolution, the absolute loss of cyanide and the stability of the aurocyanide ion. The laboratory investigations described herein address these aspects. Earlier work had indicated that the rate of dissolution of freely revolving gold discs at constant cyanide ion concentration increased with decreasing pH from 11 to 8. Attempts to repeat the work in a more controlled manner by measuring the corrosion potential and current density have, to date, not been reproducible, but do not contradict the earlier observations. Cyanide recoveries and balances were obtained on leaches at pH 10.5 and 9 at the same cyanide ion concentration -the lower pH requiring three times as much total cyanide. Unaccounted-for losses, unfortunately, exceed the accounted-for losses, making interpretation of the balances difficult. Nevertheless, it appears that the additional amount of cyanide at the lower pH of 9 may not be fully recoverable. It may not, however, prove necessary in practice to use more cyanide at a lower pH. Both the gold and silver cyanide complexes remain available for carbon adsorption, as do mercury, copper and iron. Zinc, and probably cadmium, nickel and lead, may precipitate during stripping, which is an environmental advantage.

Jan 1, 1991

By H. N. McLeod, M. J. Thom

The use of cyanide in gold mining requires the careful handling and storage of cyanide rich tailings. Cyanide in groundwater can frequently be both persistent and mobile, so that tailings basins need to be designed to limit and collect seepage. Assessment of the potential environmental impact requires an understanding of the hydrogeologic regime, both before, during and after mining. Groundwater monitoring wells provide a basis for monitoring tailings pond behaviour and for assessing the impact of mitigative measures to reduce or control seepage. A case example of Cheni Gold Mines Lawyers Project in Canada is presented to illustrate the use of groundwater monitoring to determine the amount of cyanide degradation and attenuation between the tailings pond and the receiving environment.

Jan 1, 1991

By Des B. Bolton, Neil P. Boland

Typically, environmental work on mine sites in Northern Australia involves addressing an individual problem as it arises. However, individual mining companies are moving toward a more holistic approach to managing the interactions between the environment and the mining process and are thus pre-empting environmental problems. This paper presents a broad overview of this holistic approach and provides a few examples, drawn from our own experience, which illustrate some of the tangible benefits to be gained from Environmental Planning.

Jan 1, 1991

By Jacob D. Baker

Sulphur dioxide is a versatile gas which has many uses throughout Pulp & Paper, Chemical, specialty Chemical, Mining and other industries. During recent years, S0 2 consumption and distribution patterns have resulted in renewed interests for liquid S0 2 and on site gaseous S02 manufacturing facilities. one relatively new use for S0 2 in the Mining Industry is its use for cyanide detoxification. Our purpose in this paper is to describe the process steps, economics and general technical features of so 2 gas generation using a Jet Type sulphur Burning System.

Jan 1, 1991

By E. A. Devuyst, G. Robbins

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by G.J. Borberly et al. (1984). The process uses SO2 (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst which can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops wastewaters. The SO.jAir process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful by-products species exist. Consequently final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991