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By Yoshiaki Numata

It is a matter of importance to use the lower alkyl monoethers of propylene glycol (polyPGME) as a frother in sulfide mineral flotation, for their compounds are highly soluble in water and are surface active frothers to some extent. The purpose of this study is to clarify fundamental roles of frothers in sulfide mineral flotation by investigating the effects of polyPGME on the floatability of galena with xanthate and adsorption property those ethers at the liquid/air interface. Fundamental investigation on the flotation of sulfide minerals using o,o-dialkyl dithiophosphates has been carried out through galena floatability tests in the following two cases:(l)single use of dithiophosphate for sulfide mineral collection and (2) joint use of dithiophosphates for its collection.

Jan 1, 1991

By James R. Piper

Cumulophyric feldspars, of varying morphology, carry myrmekitic quartz interstitially between microperthitic feldspar lamellae. The size, coarseness, and morphology of these crystals, together with concordant foliation features constitutes evidence that they are a product of primary crystallization, formed prior to eruption from a vent. These crystals occur preferentially along 2 - 5 mm thick tan, vesicular to compressed alteration bands intercalated with more densely welded light grey bands. In perlite with quartz at or below a 0.1% threshold, megascopic feldspars are less than 1%. Perlite with quartz above this level has megascopic feldspar concentrations >3%, typically in the 5-20% range.

Jan 1, 1991

An integrated mining equipment development organisation is typified by Deutsche Montsn Technologic of Essen, Germany. working on improvements in reliability, production and control in coal mines. Examples of recent mining advances are in mechanised roadheading, in different approaches to cutting technology, and in low height roof bolting.On the longwall face the mechanics of cutting are related to supplied energy as well as to dust make. In conveying both armoured face conveyors and conveyor belts are monitored. Roof support is not neglected and the continuous pumping of stowage slurries provides further options for longwall support. Surveying developments, particularly the gyro-theodolite, directional drilling. and shaft vehicle monitoring provide further examples of advances in control in coal mining activities.

Jan 1, 1991

By Victor F. Hollister

This section includes examples of discoveries of Kuroko- and Anyoz-type massive sulfides, and shale-hosted, zinc-lead deposits, and describes exploration models for each group of case histories. Exploration or empirical models can differ from genetic models, because ore guides and controls are emphasized in exploration models. Genetic models may form the scientific basis for exploration or prospecting models, although factors that are important to the localization of ore are stressed in exploration models. The paper by Sato (abstracted herein) on Kuroko deposits can be used as a general exploration guide for that type of deposit. It is clear, however, that no unambiguous stratigraphic control for Kuroko-type ore is given in the Sato paper. The paper by MacIntyre (an excerpt herein) describing Gataga, Midway, and Windy Craggy includes most of the elements of the shale-hosted and Anyox models. Although more recent work by the Geological Survey of Canada has modified the Windy Craggy stratigraphy, the Anyox model as applied to Windy Craggy is well described in the MacIntyre (1983) paper. Discoveries of ophiolite-, Ducktown-, volcanic-associated Ni- Cu-, and Besshi-type deposits are not included in this section. Conformable massive sulfide deposits are generally assumed to be syngenetic. Sulfides in the crosscutting feeder zones, however, are classed as epigenetic. Therefore, volcanogenic massive sulfides can contain both a syngenetic and an epigenetic component. Vital to the development of the epigenetic component is a heat source that propels the convection cycle that forms both components. In all massive sulfide discoveries described in this section, it is assumed that a volcanic magma fueled the hydrothermal fluids.

Jan 1, 1991

By Martin L. Smith, Robert L. Hautala

The objective of blast optimization can be approached either in a qualitative sense of designing a blast which will be "trouble free", or quantitatively in the sense of minimizing overall mining costs. Blast design simulators and fragmentation models have become an accepted tool in blasting over the last decade. Numeric simulators are very useful for solving quantitative problems, but are limited in their ability to address more qualitative problems such as post-blast bench condition. Also, current blasting models are limited by the complexity of site-specific blasting and are not functionally suited to mathematical optimization. As a result a great deal of expertise is still needed in optimizing a blast. The following describes the application of an expert system approach to integrating both a symbolic model of the expertise of the blasting engineer for attaining a trouble free blast, and a numeric optimization model relating fragmentation to unit operations from drilling to grinding. Research into this application of a coupled modeling approach to blast design is being carried out to develop a modeling methodology which will provide a suboptimal design for qualitative design goals as well as minimizing blast related costs.

Jan 1, 1991

By J. David Lowell

The discovery of the Kalamazoo (Arizona) ore body was a comedy of errors and coincidences and luck -as most discoveries probably are. The story began in early 1965 when Quintana Petroleum decided to diversify from petroleum into minerals and decided to do this by the route of minerals exploration. Quintana Petroleum is owned by the Cullen family of Houston and has Geen successful over the years in discovering oilfields. In 1965, the president and general manager was Corbin J. Robertson, son-in-law of Harry Cullen, founder of the company and a famous Texas wildcatter. But, in 1965, Quintana's financial advisors suggested that the company go into several mineral commodities, including copper, with Tucson, AZ, as the jumping-off point for copper exploration, and with a geological consultant (me) as the point man. The stage was now set! (See Fig. 1, location map of the San Manuel District, Arizona.)

Jan 1, 1991

By J. E. Meacham

The U.S. Bureau of Mines investigated recovery of manganese from basic oxygen furnace (BOF) steelmaking slags because the slags represent a large potential resource of a metal for which there is no domestic production. BOF slags were leached using fluosilicic acid, a byproduct of the fertilizer industry. Manganese and iron were extracted as soluble manganous and ferrous fluosilicates while the calcium and magnesium remained in the tailings as insoluble fluorides. Treating the pregnant liquor with sodium chloride, precipitated sodium fluosilicate (Na2Sif6) which was recovered as a byproduct. Manganese and iron were precipitated as hydroxide-carbonate salts with the addition of sodium carbonate to the treated liquor. Recoveries for manganese and iron were 73 to 83 and 67 to 70 pet, respectively.

Jan 1, 1991

By J. H. Gasper

The overall success of steep slope (>20°) contour mining is dependent upon many factors. The major factor is the selection of the mining method that best suits the premining site conditions both environmentally and economically. These conditions can be divided into three major categories: 1) Geometric Conditions --machine limitations, slope stability restrictions, erosion capacity, among others; 2) Physical Conditions--material properties, rock strengths, diggability, driving surfaces, among others; 3) Chemical Conditions --acid/base relationships, blending or selective placement of overburden, among others. This paper incorporates these conditions through conceptually modeling compliance oriented contour mining methods; in particular Haulback methods, utilizing: 1) the Front-End Loader (FEL)/Truck; 2) Tractor Scrapers; and 3) Combined FEL-Truck/Scraper. Engineering analyses including machine selection, sequencing, ease of varying production rates, slope requirements (for stability and running surfaces), drainage requirements and many others can be performed after the geometric constraints dictated by in-situ conditions and regulatory requirements have been conceptualized. Once all generalized geometries have been established, reduction to idealized three-dimensional views is achieved. These are then reduced to two-dimensional symbolic models, mainly plan views, but also elevations and sections. Equipment activities and operations are then conveniently overlayed. Without this simple two-dimensional reduction, technology transfer remains awkward and non-analytical.

Jan 1, 1991

By Warren L. J

The recovery of phosphate minerals from the Mt Weld deposit by froth flotation has been studied by many researchers. Most of the flotation experiments were carried out with a tall oil fatty acid as collector and sodium silicate as dispersant and gangue depressant at pH about 10. Several rougher stages and cleaner stages and, sometimes, a desliming stage were included. The major difficulty was to reduce the Fe2O3 impurities in the concentrate to the required level. We used QEM*SEM (Quantitative Evaluation of Materials by Scanning Electron Microscopy) to provide a comprehensive and accurate mineralogical analysis of the flotation products. The analysis indicated that the Fe2O3 impurities were mainly recovered in the second concentrate, owing partly to the incomplete depression of the liberated iron oxides by the sodium silicate and partly to composite particles containing iron oxides. The selective depressing action of sodium silicate was improved by adjusting the variables such as the modulus (SiO2/Na2O), pH and time of standing of the stock sodium silicate solutions or by adding some polyvalent metal salts into sodium silicate solution. The flotation process was optimised to produce a phosphate concentrate with the required grade and recovery (38.6 per cent P2O5, 2.67 per cent Fe2O3, 13.7 for P2O5/(Fe2O3 + A1203), at P2O5 recovery of 81.5 per cent). The possibility of recovering the rare-earth phosphate, monazite, from the Mt Weld deposit by flotation was also studied.

Jan 1, 1991

By W E. Vance, B H. Ashton

The emission of seam gases into underground workings in coal mines is acknowledged as a major hazard, particularly methane due to its possible ignition. Acknowledge of seam gas parameters is important for the prediction of gas emission rates into the ventilating air current. They are also important as the basis for the evaluation of the likely contained gas as a possible energy source.   Gas content determinations for the Kupakupa seam have been made at the Huntly West Mine.  Applying the method of Creedy (1986) to face samples, gas contents of 1.80 and 1.66 have been determined. Using desorbed and residual gas content data a content of 1.92 m3/t has been derived. These are on an ash included basis. Calculations using the adsorption equation of Kim (1977) and coal quality have given a gas content of 2.19 m3 t. Long-hole exploration drilling at Huntly West Mine has provided information on gas pressure. A pressure rise test has given a reading of 500 kPa (absolute); this is low compared with the pressure given for the determined gas content from theoretical adsorption isotherms.

Jan 1, 1991

By G. N. Nnadi, R. J. Mitchell

"The response of cemented backfills subjected to simulated blast loadings is studied using centrifugal modelling techniques. Scaling requirements for centrifugal modelling are developed and the results of the similitude analysis show that an acceleration field is required to capture the true dynamic response of backfill models. Experiments have been conducted at various centrifugal accelerations. The effects of ring blasting were simulated by an impact loading on the exposed fill face. The behaviour of the cemented backfill was monitored with accelerometers as well as dynamic stress gauges.Cemented backfill response to impact loadings was found to depend strongly on simulated gravitational stress level. Results also show that the characteristics of the response changes with distance from the impact. Finally, the results of the models were used to predict prototype peak accelerations, velocities and displacements. The results reported in this study indicate that centrifuge modelling may be a useful tool for dynamic studies of blast damage to backfills. Centrifuge modelling can be carried out at low costs and can be used to design prototype instrumentation systems. IntroductionThe response of cemented mine backfills to blast loadings is of concern to the mining industry because these backfills provide local and regional support during ore pillar extraction. Considerable research has been reported on the static stability (Smith et al., 1983) and on effects of reinforcements on cemented backfills (Mitchell, 1989). However, information regarding dynamic aspects of cemented backfill is limited. O'Hearn and Swan (1989) reported on the response of cemented backfill to blast loading, but these blasts were not very dose to the backfill . A schematic representation of a rock-backfill system is shown in Figure I.The mechanics of transfer of explosive energy to rock and subsequently to the backfill, and the resulting responses, are complex. Achison (1968) listed more than twenty factor s affecting the blast fragmentation of rock and grouped these into the categories of explosive parameters, charge parameters and rock parameters. Although significant advances have been made, during the past two decades, in understanding the mechanics of blasting, the degree of uncertainty associated with predicting the behaviour of backfills subjected to dynamic loadings makes the application of simple design safety factors insufficient. Comprehensive testing programs or prototype instrumentation is required to evaluate the risks associated with blast or earthquake loadings on backfill."

Jan 1, 1991

By R. G. Reddy

To better understand the behavior of bacterial-mineral interfacial reactions, a thermodynamic model based on the- studies of bacteria adhesion on mineral surfaces has been evaluated. The bacteria adhesion to the mineral surface would be increased by l ' d1;1creasing the change in Gibbs free energy of adhesion and it would be reduced if the change in Gibbs free energy of adhesion of the system is increased. From the combination -of Young's equation and equation of state, the change in Gibbs free energy of adhesion -for bacterium-mineral system- was calculated. Influence of liquid surface tension, mineral surface tension on the change in Gibbs free energy of adhesion and consequently bacteria behavior on mineral systems- has been discussed.

Jan 1, 1991

By Rogerson R, Queen L

The petrology and age of mid Cretaceous to Palaeogene marine volcanics may provide important clues to the palaeogeography of the period, particularly for tectonic elements and events outboard of the Papuan Basin. This initial survey of known marine volcanics of this age reveals a paucity of reliable data on isotopic ages, geochemistry and syngenetic mineralisation on virtually all units. Existing data allows a tentative subdivision of known marine volcanics into either MORB-like early Palaeogene rifts/ marginal basins, early Palaeogene ensimatic arc rocks overlying ?Late Cretaceous and Palaeogene fore-arc/marginal basin crust, late Palaeogene ensimatic arc rocks, and mid to Late Cretaceous ensialic rift rocks. Due to lack of data, some units are difficult to classify into these categories.

Jan 1, 1991

By L. E. Reed, I. G. L. Sinclair

An exploration program seeking kimberlite pipes, the common primary hosts for diamonds, Was' conducted during the years 1979 through 1982 in the James Bay Lowlands of Ontario by Selco Mining Corporation (now the Mining Division of BP Resources Canada) and Esso Minerals Canada. The area to be explored was selected on the basis of its regional geological setting, and because of the known presence of kimberlite indicator minerals in the region. The primary exploration technique was low level airborne magnetic surveying, followed by detailed ground geophysics. This work located many pipe-like bodies, with diameters of a few hundred metres, as well as several dykes. Targets located by these geophysical methods were drilled, intersecting a total of45 intrusions, consisting of34 alkaline diatremes containing tuffisitic breccias, 7 carbonatites, and 4 massive alnoites. K-Ar determinations indicated ages of 152 Ma and 180 Ma for two of the massive alnoites. The texture and general mineralogy of the tuffisitic breccias are similar to those of diatreme facies kimberlites, but detailed examination of their mineralogy and chemistry demonstrated that they lie within the alnoitic rather than the kimberlitic compositional field. Although the exploration program did not lead to the discovery of true kimberlites, it did demonstrate the presence of a large, previously unknown province of alkaline volcanic activity, which has no surface expression.

Jan 1, 1991

1991 New Zealand Branch Annual Conference û Appendix

Jan 1, 1991

By Richard R. Klimpel

This article introduces the basic definitions and philosophy behind process hazard evaluation procedures and the determination of risk as being a function of accident probabi1ity and accident consequence. The general concepts of good engineering practice and predictive hazard evaluation are discussed. The most commonly employed methods used in the processing industries are reviewed with an eye towards briefly presenting what each method offers as far as information, time and resources required, etc. Some initial references on the actual practical use of each technique in the processing industries are also given.

Jan 1, 1991

By Smith T. N, Wild M. B, Elliot B. J

The process of flash smelting of nickel sulphide ores, as practised at the Kalgoorlie Nickel Smelter, is described. The critical variables in the operation of this process are identified. The design of a pilot-scale, turbulent-jet flash reactor which models the essential features of the industrial smelter is described. A report of its operation and application to an investigation of the ignition of particles of sulphide species is given.

Jan 1, 1991

By Karel SPIRKO

The one-dimensional mathematical model of unsteady-state heat conduct ion through multilayer (wall and floor of airway consist of several layers of material and rock) and two-surface (dry and wet surfaces) airway wall and airway floor with convective heat and moisture transfer between their surfaces and mine air with time dependent changes of temperature and humidity has been developed on the basis of introduction of acceptable simplifications of description of heat and moisture transfer between rock mass and mine air. The analytical solutions for calculation of the surface temperature of any type of surface of airway wall/floor and for calculation of water vapour pressure near the wet surfaces at given time are obtained by means of the model presented. These solutions are illustrated for the case of general harmonic course of air temperature and humidity. Balance of heat and moisture transfer between surfaces of airway wall and floor and mine air is solved by an iterative method in the partial sections of airway. The temperature and the humidity of mine air on the outlet of each partial section of airway at given time are its resolutions and they are the input data for following partial section. By this way it is possible to solve complicated dynamic changes of mine air temperature and humidity in an air way system by relatively simple mathematical apparat.

Jan 1, 1991

By W. R. Sharp

The ability to target, delineate, excavate, and produce local resources is essential to the establishment of man's long-term presence in space. Many procedures and equipment utilized to mine resources here on Earth may be directly applicable on the lunar surface, while others may need extensive redefinition and development. This paper compares, for a lunar base, the alternative of burrowing into and below the lunar surface with that of surface mining. A conceptual underground mechanical excavator is presented.

Jan 1, 1991

By Dunn J, Nguyen G, Graham J

A pyritic gold concentrate from the Golden Mile, Kalgoorlie, was roasted over a range of temperatures in a pilot scale fluid bed reactor. The calcines were subsequently cyanide leached. Mineralogical studies of the con- centrate, calcines and leached residues were also undertaken. Calcines produced at 500'C gave the poorest gold extractions and high cyanide consumptions. Gold recoveries of approximately 90 per cent were obtained from calcines produced at 550-600'C but higher roasting tempera- tures resulted in an increase in the residual gold content of the leached calcine. There is some evidence of flash smelting of the pyrite at the higher roasting temperatures and encapsulation of gold particles. Mineralogical examination of the calcines shows that the mechanism of oxidation is temperature dependent. At 500'C pyrite is directly oxidized to hematite with a concentric layered texture which appears to inhibit lixiviant access to enclosed gold particles. At higher temperatures the conversion sequence pyrite-pyrrhotite-hematite produces a spongy calcine which al- lows easier penetration by the leaching medium.

Jan 1, 1991