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By Jan Visman, James W. Parkinson

GENERAL INTRODUCTION Sample collection, preparation and analysis are all steps in a single process designed to provide information about a much larger amount of material than the sample itself. For example, information about the ash content of a unit train load of coal may be derived from a single, relatively small sample of perhaps a few hundred pounds (liters) extracted from the entire shipment. These three steps can be thought of as links in a chain, allowing the simple analogy that the strength of the chain, or, in other words, the value of the information is only as strong as the weakest link. Sample collection, discussed in Part 1 of this chapter, is critical because analytical procedures can do no more than reveal the characteristics of the sample presented to the laboratory. If that sample does not properly represent the population to be characterized, neither will the analysis of that sample. Sample preparation is also a critical part of the chain. Any change in the nature of a sample between the time it is collected and the time it is analyzed will appear to reflect the nature of the population. For example, sample preparation procedures that allow air to partially dry the coal sample before reaching the laboratory will cause the sample analysis to indicate a lower moisture content than the sample originally had. Other changes can be more subtle. Second only to moisture loss, oxidation reactions generally cause the greatest problems. Oxidation of a coal sample can alter surface properties, changing flotation response. In extreme cases, combustion parameters, such as caking or agglomerating properties or mineral composition, such as pyrite content, can change. Water samples can also be altered by oxidation. For example, ferrous iron can oxidize to ferric iron, possibly changing water quality parameters such as pH. Sample analysis, the subject of Part 2 of this chapter, is the final link in the chain. Obviously, no laboratory procedure can correct for problems created by improper sample collection and preparation. At the same time, poor analytical techniques will create incorrect information about the total amount of coal from which the sample was extracted (the population) in the same manner as improper sample collection and preparation. The key to gaining correct information about the population is to view these three steps as parts of a single process. Following proper techniques through only one or two steps of the process will not produce accurate information.

Jan 1, 1991

By T. Gouri Charan, G. V. Rao

A spherical agglomeration process for the separation of scheelite fines of less than 30 µm in very low concentration of 0.04% WO3 in a binary mixture with quartz fines of less than 30 pm has been described. A concentrate containing 14% WO, with more than 90% recoveries could be achieved by means of anionic sodium sulfo succinate collector at pH 3.5 and also with commonly used anionic sodium oleate at pH 10.5 as per the conceptual flowsheet suggested. Such a process is envisaged as commercial potential for the recovery of fine-grained scheelite present in the tailings of gold plants as found in India.

Jan 1, 1991

By Ware AR, Doyle BJ, Hoogvliet H

The Ladolam deposit lies within the altered volcanic rocks of the caldera floor, part of which now forms Luise Harbour. It was discovered in 1982 in the course of a reconnaissance drainage sediment sampling programme. This was designed to follow up indications of surface hydrothermal activity noted by Government geologists during an earlier survey of the Tabar-Feni island chain. Diamond drilling began in September 1983 and by the end of 1989 a payable and proved mineable reserve containing 19 million ounces of gold had been established. Rock types and structures are masked at the surface by intense alteration and weathering. An extensive drilling programme has enabled the identification of these features and the relationships between them necessary for an understanding of the factors controlling gold mineralisation. It has also led to the recognition of two distinct phases of alteration. The first phase of porphyry-style potassic alteration was followed by violent caldera formation, producing extensive brecciation and veining. The second alteration phase partly over- printed the first phase and was an epithermal one, evidenced by argillic, advanced argillic and phyllic assemblages. During this event, a large volume of fluids circulated under the favourable structural conditions; these fluids included a sulphur- rich, neutral chloride brine believed to have transported the gold. Boiling and mixing of circulating fluids in the open breccias is thought to have resulted in deposition of the gold. There is evidence that this process is continuing at the present day.

Jan 1, 1991

By B. J. Pieters

The paper describes the difficulties experienced with inferior coking coals as Iscor began using larger blast furnaces for the production of liquid iron. Research conducted at Iscor from 1977 to 1979 showed that benefits could be gained from the use of partially briqueted charges, and it was decided to install briqueting plants at the Vanderbijlpark and Newcastle Works. Details are given of the later plant, which was supplied by a consortium consisting of Voest Alpine, Didier Engineering, and Sumitomo Metal Industries. Sumitomo also supplied information on the optimization of coke quality along the lines of their Sumicoal System. The results have been a marked improvement in coke quality, much better blast-furnace operation, and increased productivity.

Jan 1, 1991

By Jinrong Zhang

Fresh cyanide solution was treated by near UV light with the assistance of photocatalysts. Cyanide was oxidized mainly to cyanate. Photochemical behavior of the anatase and rutile forms of TiO2 was compared. It is found that anatase has a much higher activity than that of rutile. Bubbling of oxygen in the reactor showed no appreciable increase in cyanide oxidation, implying that the reaction is surface controlling. A very interesting finding in this study is that a natural mineral, ilmenite, can replace chemical titanium dioxide as the photocatalyst. Ilmenite without any treatment did not catalyze the oxidation of cyanide. But, after being roasted at high temperature with oxygen, the oxidation was enhanced dramatically. The mechanisms of photooxidation of cyanide and the roasting of ilmenite are proposed.

Jan 1, 1991

By Thomas C. Anderson

Tiedback walls are now recognized and accepted as a good solution for a variety of structural problems: ? Retaining Walls and Bridge Abutments in cut situations ? Landslide stabilization ? Repair/support of existing walls Acceptable techniques have been developed for anchoring in cohesive and granular soils and in any kind of rock. Methods have been developed for adequately protecting tieback tendons against corrosion and for testing every tieback to verify its long-term load-carrying capacity. However, the major problem that the industry faces today is how do we get constructable and economical tiedback walls contracted for and built with minimal claims. This paper will explore the issue of "constructability" through a look at specific problems from actual projects. From a research report from the Construction Industry Institute, Austin, Texas (1986), constructability is defined "as the optimum use of construction knowledge and experience in planning, design, procurement and field/operations to achieve overall project objectives." Maximum benefits occur when people with construction knowledge and experience become involved at the very beginning of the project." The design and installation of tiebacks has been developed primarily by specialty contractors; each contractor has evolved its own methods of performing the work, and consequently, many of the techniques are patented and proprietary. The real question is, how do we make effective use of this knowledge and experience during the design phase of the project?

Jan 1, 1991

By W. E. L. Minter

The most important Witwatersrand gold placers occur on extensive unconformity paleosulfaces that were produced during protracted periods of fluvial degradation. The erosional etches on what was generally unlithified sub-strate indicate that low sinuosity erosion patterns prevailed. The transport systems were dominantly braided fluvial with a minor debris-flow component. The placer sediments were non-cohesive sands and gravels. They were evidently transported by fluctuating, yet perennial, discharges across extensive, low relief braid plains, not far from littoral environments. Progress made in understanding heavy mineral transport processes now emphasizes the importance that selective entrainment probably had in producing concentrations. Cognizance that these characteristics are not unique to the Witwatersrand should be taken into account when designing exploration models.

Jan 1, 1991

By Joseph Matoney, B. K. Parekh

INTRODUCTION The term "dewatering" refers to removal of water from coal. Water associated with coal can be categorized as "free or surface" and "inherent or chemically bound" moisture.' The free moisture is found on the surface of coal, in capillaries and small spaces between two or more particles. The inherent or chemically bound water is found in the interior of the coal and as part of coal structure. A significant amount of free moisture can be removed by mechanical dewatering techniques. However, inherent moisture can only be removed by applying energy intensive techniques, e.g., direct or indirect heating. Moisture in the coal offsets some of the benefits of coal cleaning. Extra water in clean coal adds to extra cost in transportation, heat lost during vaporization, and plugging of chutes. From a utility perspective, a 1 % increase in moisture can offset a 4.5% decrease in ash.2 Mechanical dewatering can be classified into two major process categories according to the principles involved, namely, 1. Sedimentation-liquid is constrained and particles move freely. 2. Filtration-particles are constrained by a medium and the liquid flows through. Each of the process categories is composed of various separation techniques shown in Fig. Equipment currently being used by the mechanical dewatering of coal of varying size ranges and final moisture content is illustrated in Fig. 8-2. This figure indicates that sizes larger than 13/, in. (37.5 mm) present no particular dewatering problem. Shaker screens of the very crudest types and designs are capable of producing these sizes at low surface moistures. High-speed vibrators are used for the intermediate sizes and can be used for smaller sizes down to 0.02 in. (0.5 mm) if high moistures (15% surface moisture or greater) can be tolerated in the product. Usually, however, the vibrator is not used below 3/, to 3/, in. (9.5 to 6.3 mm) because of the moisture associated with these fine sizes. At this level, centrifugal force is usually employed to aid dewatering. Centrifuges of various types and designs are used practically

Jan 1, 1991

By Kousik Sinha

The advantage of using a clean coal as a feedstock in a direct liquefaction plant is improved performance of the plant by several factors e.g., increased throughput of coal; reduced wear and tear of valves, pipes, and pumps; increased liquid yields, etc. This paper examines the technical feasibility for cleaning Illinois #6 coal as a feedstock to a direct coal liquefaction plant via selective agglomeration using a coal-derived heavy distillate, Wilsonville V-1074 as agglomerant. Effects of addition of Kerosene or coal-derived Naphtha as conditioner, coal particle size, slurry pH, oil to coal ratio, and operating temperature on ash reduction and clean coal weight recovery have been studied. Results show that about 70% of the ash can be removed from this coal and the clean coal weight recovery over 85% can be achieved by using this technique with suitable selection of coal particle size, slurry pH, mixing intensity and oil to coal ratio.

Jan 1, 1991

By Sie A

After completing a feasibility study in 1987, Niugini Mining Limited (NML) obtained five Gold Mining Leases within PA 632, covering the Mount Victor and Clarkes Ridge gold deposits. Reserves prior to mining were 260 000t at 3.63g/t Au for Mount Victor and 40 000t at 2.8g/t Au for Clarkes Ridge. Ore was mined from the two deposits by NML from November 1987 to January 1990. A total of 645kg of gold and 346kg of silver were produced from 198 000 tonnes of ore pro- cessed. Mining and milling operations ceased in February 1990. Since then, there has been significant progress in rehabilitating and revegetating the site. Plant and workshop facilities have been dismantled and removed from site, exposed parts of the pit have been landscaped and replanted, tailings water has been neutralised and discharged, and the dam filled. All remaining personnel and equipment left the site in November 1990. It is envisaged that the replanted areas will be rapidly revegetated, leaving little evidence of mining. Niugini Mining did not recoup the initial investment for Mount Victor, but the mine produced a positive cash flow and made a significant' financial contribution to the local communities and Papua New Guinea as a Whole.

Jan 1, 1991

By Victor F. Hollister

This first section of case histories of mineral discoveries, Vol. 3, covers some of the milestones in porphyry copper and skam exploration successes. It was during the era of these discoveries that large, complex exploration departments emerged as permanent adjuncts of large mining companies. The discoveries helped shape how and where exploration activity was conducted. Probably the most important factor in exploration success is management. Few management people are mentioned in this section or in any exploration history, yet the distinction between success and failure ultimately rested with the decisions they made. One of the most successful groups was initiated by Roger Straus and Herbert Brownell when they sought to make Asarco into an important metal producer. Relying on Clem Pollock and L.H. (Bill) Hart to identify and push worthwhile projects, the Asarco management remade the company. Asarco will benefit from exploration successes com- pounded by that team for years to come. Duval is an example of a management that decided to add metal production to its industrial minerals output. When Page Morris was president, that company opened three major porphyry copper mines and became an important factor in metals. Under the Monis management team, Duval became a leader in exploration. At the other end of the scale are managements that snatched defeat from the jaws of victory and by so doing changed the character of their companies in other ways.

Jan 1, 1991

By Dan McCutchen, Oettmeier

Kelly bar drilling and blasting is unique to Florida, the' Bahamas and other marine limestone areas in the world where blast holes are required but will not remain open for the loading of explosives. This type of rock formation usually yields 1.5 tons of recoverable rock compared to 2.2 tons per cubic yard for competent limestone. The loss of .7 tons per cubic yard is due to voids and sand in the formation. These deposits all contain water to the top of the blast holes which are collared only a few ft. above the ground water level. The working pit is a water filled lake which is excavated from the bank by draglines. These drills have been used in Florida for many years to depths of 65 ft or less.

Jan 1, 1991

A strategy is presented for a relatively. "low-tech" means for decontamination of streams . containing .low concentrations of toxic metals. Metal ion solutions were . circulate through fluidized beds of activated carbon which support bio-films ?of bacteria .that naturally excrete exopolysaccharides. The attached 'biomass is shown to significantly enhance nickel, cadmium and silver extraction from dilute solutions (5- l00mg/l). By heat treating (at 300º C) the metal/biomass/carbon particles, bio-sorbed silver was subsequently fixed to the carbon surface. This approach to metal decontamination may therefore also provide a route for dispersing and fixing catalytic metal particles over an activated carbon surface.

Jan 1, 1991

The central thickened discharge system of tailings disposal takes advantage of the natural beach slope formed by sub-aerially discharged tailings, and the non-segregating properties of thickened tailings, to create a homogeneous conical stack. The need for containing embankments can be largely avoided leading to capital and operating cost savings. Methods for estimating beach slopes and tailings density, essential parameters for the design of such a system, are described. Case histories from three mining operations are used to illustrate the application of the technique, There are also seen to be potential advantages in the areas of water management, seepage, and rehabilitation. Laboratory and in-situ testing enable parameters to be determined.

Jan 1, 1991

By Keith G. Wallace, Justus B. Deen, Daniel J. Brunner

This paper describes the impact of natural ventilation pressure (NVP) on the Nuclear Waste Isolation Pilot Plant in New Mexico (WIPP). The WIPP site is a U.S. Department of Energy underground facility for the disposal of low level radioactive transuranic defense generated waste. Because the facility is designed for the storage of nuclear waste, special design considerations are necessary to ensure containment of potential radioactive releases. The main design considerations which influence the ventilation system are the requirements of separate air splits for mining and storage operations and of air filtering before atmospheric discharge in the event of a radioactive release. The leakage between the two air splits must always be from the mining area to the storage area. The transient effects of natural ventilation pressures, caused by seasonal and diurnal surface temperature changes, impact the ventilation characteristics throughout the facility. This paper discusses the measurements taken to quantify the changes in NVP and the engineered systems designed to mitigate against the effects of NVP.

Jan 1, 1991

By Victor F. Hollister

The great increase in post-World War I1 use of molybdenum was made possible by discoveries of that metal in porphyry molybdenum and porphyry copper deposits. This section documents significant porphyry molybdenum discoveries of the post-war period. The most important discovery was Henderson in Colorado. It is not only one of the world's largest and richest, but it was found by a team of geologists who defined the hood model and tested it successfully at Henderson. Under the leadership of Stewart Wallace, these scientists established a set of criteria for exploration for Henderson-type de- posits that was copied by the industry. The discovery bf vertical cylinder type porphyry molybdenum deposits was less renowned. Boss Mountain in British Columbia and then Mt. Pleasant in New Brunswick were given relatively scant notice, compared with the Henderson discovery. However, these deposits have geometrics distinct from that found in the typical hood, which directly affects their exploration characteristics. Mt. Pleasant, included in this section, is a well defined, near vertical breccia pipe. Both the Henderson and Mt. Pleasant discoveries were made by relatively small groups operating independently of the bureaucracy that characterizes large corporations. The management role in each case was one of encouragement. In addition, Wallace had the beneficial experience of working for Climax, whose objective was the discovery of porphyry molybdenum deposits. Henderson was the natural outgrowth of the exploration effort by those who studied and understood the Climax deposit.

Jan 1, 1991

Prof C T O'Connor holds the degrees of BSc, BSc Hons, University of Cape Town (UCT), where he started his academic Lecturer in the Department of Physical Chemistry in 1976. Mr P Smith, educated in England and the former Southern Rhodesia, joined Gold Fields of South Africa in 1966 as a Metallurgical Learner Official. After obtaining a BSc Eng at the University of the Witwatersrand in 1972, he returned to Gold Fields. Mr P D K Robinson was born in Zimbabwe, and was educated at Dale College in Kingwilliamstown, matriculating in 1952. He holds a Mine Surveyor's Certificate obtained in 1961) and a Mine Manager's Certificate (obtained in 1966), as well as an EDP from the University of the Witwatersrand.

Jan 1, 1991

By C. J. Beyke

The U.S. Bureau of Mines has developed a process for the selective recovery of Pb metal from a mixed Pb-Zn concentrate. The concentrate was leached in recycled H2SiF6 at atmospheric pressure and 95° C with a redox potential of 570 mV (Eh). Eighty-five pct of the Pb was selectively leached from the concentrate while 87 pct of the Zn remained in the residue. Pressure leaching of the concentrate was slightly less successful, with 78 pct of the Pb leaching from the concentrate and 80 pct of the Zn remaining in the residue. Pure Pb metal was successfully electrowon from a purified PbSiF6-H2SiF6 solution with 96 pct current efficiency and 0.69-kW.h/kg energy consumption.

Jan 1, 1991

By Kanau JL, Kilgour I

This paper describes the metallurgical processes at the 80 000tpd Ok Tedi Mining Limited concentrator, which treats copper- gold ore by single-stage crushing, SAG and ball milling and flotation to produce over 500 000tpa of concentrate. Plant and process developments, including installation of column cells, reduction of fluorine in concentrate, use of sulphidisation and process control improve- ments are also discussed.

Jan 1, 1991

By P. S. Newall

As part of a much larger research project, factor analysis was employed to help interpret and compare the geochemical signatures produced by two different sample media; a traditional -80# soil fraction, and a coarse float. Both sample types were collected by hand auger from the extension zone of the Redmoor sheeted-vein complex and analyzed -for 19 major and trace elements. The rationale behind the study infers that the geochemical anomalies produced by wallrock alteration around such targets can be better detected in the lithogeochemical rather than the soil environment, sometimes at considerable distance from their source.

Jan 1, 1991