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By J. Frenzel

The computation of hydrometallurgical equilibria is very difficult because of the many complex species in solution, the precipitates, condensed species, or solids, and the activity coefficient corrections necessary to non-ideal thermodynamics. Our objective was to tryout recently developed genetic algorithms to minimize free energy and solve the equilibrium computation. We selected test problems that were seemingly unsolvable with more traditional algorithms, and we applied genetic algorithms to them. We were pleased to find that genetic algorithms succeeded where other algorithms did not. We concluded that they are an effective tool for hydrometallurgical equilibria.

Jan 1, 1992

By T. Ueno

Naoshima Smelter & Refinery of Mitsubishi Materials Crop. commissioned a new Mitsubishi continuous copper smelter in May 1991. Process offgas volume of the conventional reverberatory furnace line, one of the previous smelters having been shut down, was very large and thus two acid plants had been operated. It was expected that the offgas volume would, be reduced at the new smelter to about a half of the sum of those from previous two smelters and the sulfur dioxide strength would be increased. So various alternatives were studied to minimize the operation cost. And it was decided to utilize both of the plants with minor modifications by diluting the gas either with air or with dilute gases. The acid plants now receive off gases from the new copper smelter, a sintering machine of a lead smelter and a decomposer of waste acid. The paper discusses plant design, operation, improvements and modifications realized in relation with the retrofitting of the copper smelter.

Jan 1, 1992

By Charles L. Kimbell

Available statistics on 1989 worldwide consumption of selected nonfuel minerals shown in table 5 show increases for 11 of 14 listed nonfuel mineral commodities with 1 unchanged from the 1988 level, a departure from the pattern of the past 2 years, in which each of the listed commodities registered gains. The 1989 results, however, were better than those for 1986 when only seven listed nonfuel mineral commodities recorded gains with one un- changed from 1985. Consumption of the two ferrous metal raw materials listed advanced as functions of increased output of pig iron and crude steel. The increase in iron ore consumption exceeded the increase in iron ore output, suggesting a slight drawdown of world iron ore inventories. The estimated in- crease in iron and steel scrap consumption was slightly greater than the minuscule increase in world steel production, but it is believed that there was little change in the ratio of iron ore to scrap in steel plant feed on a global basis.

Jan 1, 1992

By Yeonuk Choi, Patrick R. Taylor, Lyle Cunningham

Laboratory experiments have been performed to evaluate the potential for metal removal and recovery from river bed tailings by ferric chloride leaching. The lead, zinc, silver and other metals in the river bed occur due to the old method of dumping mill tailings into rivers. This was practiced prior to the introduction of tailings impoundments. The effects of the leaching method, leaching time, pulp density, ferric chloride concentration, and leaching temperature on the rates and recoveries of lead, zinc and silver were studied. The effects of pulp density and leaching temperature were significant on the extraction rates of lead, zinc and silver. The lead content in the leached tailing was reduced to 0.023 percent, when using an 353O K leaching temperature and 0.384 g of FeC13/1 g of sample.

Jan 1, 1992

By R. Spring

"Soft-sensors are a computer software alternative to inadequate hardware instrumentation. Filters are averaging methods that reduce the noise in any sensor's signal. This paper introduces these topics and places them in a mineral processing context using then-product formula.Soft SensorsAs their name implies, ""soft-sensors"" are computer programs that estimate values for process variables (Tham, 1991). This approach is useful when the appropriate hardware sensor does not exist, is deficient, supplies only infrequent values, etc. For example, in mineral concentrators the traditional magnetic flowmeter/ nuclear density gauge instrumentation for measuring slurry flows costs $5,000 or more per flow and requires frequent maintenance. However, metal assays are commonly available from online X-ray fluorescence analyzers and application of the n-product formula (Taggart, 1945) to these assays conveniently provides software estimates of the flowrates (albeit only when the circuit is in steady-state).Soft-sensors are used by inferential controllers that base their control actions on the process values ""inferred"" by the soft-sensor. Such was the case at Brenda Mines where the rod mill feed tonnage controller used an inferred value of the cyclone overflow particle size (Bradburn, 1976). It was also the case at Brunswick Mining where reagent controllers adjusted reagent addition rates throughout the plant according to the various ore flowrates inferred by an expert system (Spring, 1991). A unique feature of the expert system soft-sensor was its dynamic flow models which compensated for residence times, material transport lags, etc. Thus the soft-sensor values were valid under both steady-state and nonsteady- state conditions."

Jan 1, 1992

By Martin L. Smith

Sampling and subsequent geostatistical structural analysis is being carried out on the Bunker Hill Superfund site in northern Idaho's Silver Valley. This paper reports on the findings and methodology used in the initial sampling campaign which had the goal of determining an appropriate sampling grid design, spacing and protocol. Emphasis is placed on those characteristics, of mine wastes which are unique and require special consideration when applying geostatistical analysis. This study represents one of the first applications of geostatistical techniques to the problem of hazardous mining waste site characterization. Remediation of Superfund projects similar to the one described herein represents opportunity as well as liability for the mining industry.

Jan 1, 1992

By Robert R. Beebe

At first glance, mineral processing on an industrial scale might seem entirely in the realm of macro-engineering, with large machines operating on minerals and rocks to achieve size reduction, classification, chemical treatment, separation and dewatering. These operations must be conducted on a large scale to be of practical interest. But the machines and processes may not be designed and operated to take fullest advantage of micro-engineering factors. At the same time, idealized designs based solely on micro-engineering research may require adjustments to gain the desired results in the larger scale, operational context. Using micro-engineering research in this way allows the design and implementation of more efficient versions of the machines and processes currently used, while aiding the revolutionary developments unlikely to come from macro-engineered, trial-and-error solutions. Thus, from an industrial viewpoint, micro- and macro-engineering are complementary functions.

Jan 1, 1992

By J. H. Bernard, K. Zak

Abstract- The three traditional types of Variscan vein Pb-Zn-(Ag) mineralization recognized in the Bohemian massif from historic paragenetic studies are confirmed by modern metallogenic studies. Stable C, S, and 0 isotope data, as well as Pb and Sr isotopic ratios of the deposits, indicate a predominantly crustal origin of the constituents in all three types. Although the data also suggest differences in temperature and pressure of formation, and the oxidation conditions and nature of the hydrothermal fluids, nonetheless they are consistent with prevailing metallogenic classifications of the vein mineralization.

Jan 1, 1992

By Zhao Hengxian

We studied the phase diagram of Na3AlFe-ZrO system, reduction of ZrO2 by aluminium and electrochemical behaviours of ZrO2 in the system. The results show that Na3ALF6-ZrO2 system is a simle eutectic one, that the velocity of reduction of ZrO2 in the system is rapid al 960'C and that the Zr content in the alloy abtained can reach as high as 2.5wt%. Potential scanning shows that there exist new current peaks on the potential scanning plats except for the cuurent peaks corresponding to the oxidation of aluminium. The method of making Al-Zr alloy in our paper has advantages over the traditional method of mixing metals.

Jan 1, 1992

By D. E. Cameron

The Cannon mine, located in north-central Washington is mining gold hosted in silicified Eocene-age arkosic sediments arrayed along a regional strike-slip fault system. Branches of the Eagle Creek fault have broken the Chumstick Formation into blocks and wedges, and have caused intense deformation of stratigraphy in the mine. Mineralization at the Cannon mine (B-Reef) and O-Reef (L-O mine) is a bulk silicification with high grade cross-cutting veins containing principally electrum, silver sulfosalts and pyrite in a gangue of quartz, adularia and calcite. Orebodies have very irregular shapes, but tend to follow stratigraphy and high-angle pre-mineral fault breccias and splays developed adjacent to the major faults. Both B-Reef and O-Reef occur at significant bends in the regional trend of major fault strands. Mean gold grades decrease upward from near sea level to the 300 m elevation at the Cannon mine. A new discovery, the A-Reef is hosted by a moderately dipping structure which is at a low angle to bedding. Fluid inclusion studies of B-Reef ore zones indicate dilute ore-bearing fluids boiled at temperatures between 185 and 2850 C at a depth of 1 km. Many ore zones are bounded by sheared mudstone and claystone and a much broader halo of argillic alteration comprising illite, smectite and sericite. Trace and major element analysis by ICP-ES for 33 elements, LECO for S, Hg by CVAA and gold by AA-FA shows dispersion patterns hundreds of meters outward from the known orebodies in the Cannon mine. Geometric mean comparisons, hierarchical R-mode cluster analysis and single element spatial plots show that Hg, As, Sb, S and K/Al compose a suite of elements which are significantly dispersed away from, and increase toward mineralization. Ba, Ca, Na, Mn, V and Zr decrease toward mineralization. The suite is more selective than gold with respect to known mineralization within the exploration area.

Jan 1, 1992

By A. J. A. Janse

The Argyle diamond mine is located in the Kimberley region in the northern part of Western Australia at approximately 16°43'S, 128°23'E in subtropical bush/shrub savannah. The 46 ha (113 acres) pipe is situated in the Halls Creek mobile zone, which was cratonized about 1800 Ma ago and adjoins the Kimberley Block, a plateau upheld by Early to Middle Proterozoic rocks underlain by presumably Archean basement. The crater and upper pipe zones of the diatreme have been preserved within tilted and faulted strata of Middle to Late Proterozoic age. Its age of intrusion is about 1178 Ma. The diatreme rock is not kimberlite but olivine lamproite which was not recognized as a primary diamond host rock until 1978. The Kalumburu Joint Venture, a syndicate of local and overseas mining companies, started in 1972 to prospect the Kimberley Block with a modest annual prospecting budget of $125,000. Annual expenditure doubled each year and reached $1 million in 1975 after which CRA took over management of the newly-formed Ashton Joint Venture with an annual expenditure of $2 million (all figures are in current US dollars). The Argyle diatreme was found near the end of the eighth field season and after a total expenditure of $12 million. Annual production is about 34 million carats which places Australia as the world's number one diamond-producing country, although, because of the low value per carat, it is number four in terms of total annual value. The global cost required for a major diamond mine is between $300 and $400 million, with a discovery every 10 to 12 years. Because Canada contains large areas of prospective platform rocks underlain by Archean basement it is likely that a major diamond deposit does exist there. It is probable that it will be found before the end of this decade and exploration expenditure may be in the order of $100 million.

Jan 1, 1992

By Pilkington T, Noy A

The Yallourn North Extension (YNX) open cut mine ceased mining operations in early 1989. YNX may be used again for coal supply at the discretion of the Coal Corporation Of Victoria (CCV); this has resulted in the need for interim rehabilitation of the site which may last many years, or indeed, permanently.The site has suffered substantial surface erosion over the years with large areas of bare clay and coal batters remaining exposed. The first priority is to reduce the quantity and improve the quality of stormwater runoff from the site. This is best achieved by appropriate revegetation and the use of existing landform depressions as silt trap/wetland areas. Proposed rehabilitation needed to take into account the sensitive fire safety of the open cut and the option to re-open the mine if CCV deems appropriate.The authors detail the factors involved in the rehabilitation proposal and the multi-disciplinary approach to planning including engineers, scientists, a forester, landscape architects and community input. The rehabilitation design included early consideration of land use and ongoing maintenance issues linked to water quality improvement factors including vegetation. Engineering input was required for reshaping and clay covering exposed coal batters and the design of silt traps which will revert to wetlands in future. The integration of each discipline has produced a rehabilitation design pleasing to both the SECV and community alike.

Jan 1, 1992

By Winton J. Gale

The design of the reinforcement systems required to stabilise mine roadways has developed through the application of field measurement techniques. These techniques have allowed the level of security of a given opening to be determined from an assessment of the loading within the reinforcement, the extent of roof deformation and experience. The design systems developed are now used extensively in a wide variety of geological environment. Recent interpretative techniques have been developed to improve the level of confidence when designing roadway reinforcement. The techniques are particularly applicable for roadways subject to either weak materials or extreme stress levels. A second area of application is where roadway advance rates and hence the timing of reinforcement placement are critical. The newly developed techniques include both analytical and computational models. The validated computational techniques allow a more rational approach to investigation of the effect of varying reinforcement type, timing of placement and density on the level of stability achieved.

Jan 1, 1992

By C. H. Tsau

The intermetallic compounds of Ni-25Al-xFe, x is 20-40 at.%, were prepared by arc melting and drop casting into ingots, and were rapidly solidified into ribbons by melt spinning. The microstructure evolution of these alloys with varied Fe content were examined by the x-ray diffraction, optical microscope, scanning electron microscopy and transmission electron microscopy. The results reveal that two phases, {y'} and {B} phases, are existing in the alloys with low Fe content, and the microstructure changes from the mixture of y' and {B} phases to a single 0' phase when the Fe-content reaches to 40 at.%. Also, the formation of y' phase will be suppressed by rapidly solidified process. For annealing both of the melt-spun and the cast specimens, a disorder 0 phase was revealed in both of the ribbon and the cast ingot of Ni-Al-Fe alloys with higher Fe content. In addition, increasing the increment of iron which substituting nickel in this alloys results in increasing the lattice parameter of both {y'} and{B} phases.

Jan 1, 1992

By M. B. McClenaghan, O. P. Lavin, Ian Nichol

"Abstract-Exploration in most areas of Canada has to contend with problems posed by glacial overburden. In many areas exploration for gold has been based on the sampling of tills, frequently by deep overburden drilling, and analyses of heavy mineral concentrates. Notwithstanding the significant role that till geochemistry has played in the discovery of some important gold deposits over the last few years, increased appreciation of the nature of the glacial history and stratigraphy and the character of gold within till has led to the recognition of a number of ways whereby the effectiveness of exploration can be improved upon.In order for till geochemistry to be useful in exploration, a number of conditions must be fulfilled, including:1. mineralization, or alteration halo related to mineralization, subcropping at the bedrock /over­ burden interface; 2.glacial erosion and dispersal of a recognizable signature of mineralization into the glacialsediments; 3, preservation of glacial sediments containing this geochemical component (trace metal or mineral) at positions subsequently selected for sampling (normally drill sites); 4. correct identification of specific till units and associated ice movement history; 5. collection of adequately large and representative samples; 6. appropriate sample preparation and processing; 7, appropriate geochemical analyses; and 8. correct data processing and interpretation.While we have no control over the first two geological conditions, and only limited controlover till availability, we can control the quality and thoroughness of sampling, sample identification, sample preparation, analysis and interpretation. In particular attention needs to be focussed on obtaining a large enough sample to be adequately representative, an unbiased sample must be collected, together with appropriate sample processing, analysis, data processing and interpretation. It is considered that by modifying or extending existing approaches to gold exploration the chances of exploration success can be increased. In particular, analyses of both the heavy mineral and minus 63 ?m fractions of till is recommended because gold in till may occur in different size fractions."

Jan 1, 1992

By Steve R. McCutcheon, Cees R. Van Staal, John P. Langton, Leslie R. Fyffe

Abstract -The volcanic-dominated Tetagouche Group in northern New Brunswick contains numerous massive-sulfide deposits and intimately associated metalliferous sediments. The massive sulfides are generally hosted by Llanvirnian-Llandeilian volcaniclastic sedimentary rocks of the Nepisiguit Falls, Patrick Brook, and Boucher Brook formations. These formations are intercalated or closely associated with rhyolitic-dacitic flows and/or domes, and minor continental tholeiites of the Flat Landing Brook Formation. Pyroclastic rocks are relatively scarce in the silicic volcanic complex. Tuffites and epiclastic sandstones, of the Nepisiguit Falls and Patrick Brook formations, respective­ ly, generally occur along the fringes of the silicic volcanic complex. The flows and tuffites are intruded by quartz- and feldspar-phyric rhyolite (porphyry) dykes, sills, and domes. Although the volume of the silicic volcanic complex is large, evidence for a previously proposed collapsed-caldera model is lacking. On the basis of host-rock type and stratigraphic position, the sediment-hosted massive sulfides have been divided into three groups: the Brunswick-, Caribou- and Halfmile Lake-type deposits. Syngenetic feeder pipes and asociated alteration zones are generally not present beneath the Caribou- and the Halfmile Lake-type deposits and, if present at all, are poorly developed underneath the Brunswick-type.

Jan 1, 1992

By Whittaker B. N, Reddish D. J

This paper presents the physical modelling results of subsurface fracture development associated with Iongwall mining operations and an application of image processing techniques to interpretion of the results. Physical modelling results haióbeen obtained by employing a large sand and plaster model loaded purely by gravity as a means of fracturing the subsurface strata above the longwall excavation. The results have shown fracture development and crack propagation as a longwall face advances and demonstrated that the strength of stratified rocks, the presence and position of a weak band-, and the extraction thickness, have significant effects upon the overall fracture patterns above the excavation. Binary images of fracture patterns were scanned from the black and white photographs of the tested models using an image analyser coupled to a video camels. These images were manipulated by a custom written C program which allows the images to be processed in both vertical and horizontal direction. The images were filtered to quantitatively differentiate between vertical and horizontal fracture intensities. The vertical fracture intensity is particularly important as vertical fractures are considered to provide the main avenues for surface and subsurface water inflow into the excavation. The use of the image analysis techniques has shown a promising improvement in image enhancement and in model results interpretation in a quantitative manner. The numerical nature of the image analysis results will allow further statistical comparison with other modelling techniques to be undertaken and significantly increase the scope for use of the modelling technique results.

Jan 1, 1992

By Kennewell G. J

This paper aims to present the evolution of the mining method in the Prince Lyell orebody. Initial strategy and practical experience are detailed as are the reasons for and benefits of changes to the method since 1972 when underground mining began. This section of the paper starts with ten series and concludes with 40 series which was completed in 1989/90.In addition, to update the series of papers written by various authors over the past ten years on Mount Lyell, a review of the experience in the current 50 series lift of mining will be given. As well, the basic planning guidelines are discussed for 60 series - the final lift of the Prince Lyell orebody.

Jan 1, 1992

By Don W. Lake

Of all the blast monitor& instrumentation systems and techniques av&able today, highspeed photography and videography remain as the most valuable, stand alone, diagnostic techniques to evaluate full scale blasts in the mining and explosives industries. Highspeed image data, coupled with information from other instrumentation systems, such as continuous VOD records, seismographs, laser surveying systems, refraction seismographs, etc. can eIiminate many assumptions about what actually took place in a blast. Thus, diagnostic confidence in evaluating both good and bad blasts is increased, and optimum blast designs are achieved considerably faster when compared to the trial and error approach or relying on just the experience factor.

Jan 1, 1992

By Marek Niec

Native sulfur deposits in Poland occur in Upper Miocene strata on the northern (platform) border of the Carpathian foredeep. Systematic exploration since 1953 has resulted in the discovery of seven stratifom-stratibound sulfur-bearing limestone deposits that together contain about 0.6 billion tons of demonstrated sulfur reserves and about 0.5 billion tons of inferred and hypothetical resources. One open pit and three Frasch mines are currently in operation; another is under construction and one has been abandoned. Total production is about five million tons per year from ore containing on the average about 25% sulfur. Field, isotope, and micropaleontological data indicate that the sulfur-bearing limestone was formed through the bacterial reduction of gypsum in the presence of methane discharged from source beds and traps in the Carpathian foredeep. Subsequent recrystallization of the sulfur-bearing limestone, tectonic activity, jointing, karstification, and partial leaching of the sulfur has transformed the sulfur deposits and has altered the thickness and content of the sulfur-bearing strata, and their porosity and permeability, affecting the productivity and water consumption of the sulfur wells. Caputerized borehole logging techniques and geostatistical reserve estimates are used in mine planning. Great environmental impact constrains the development of sulfur mines.

Jan 1, 1992