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By R. E. Johnson, L. V. Araújo, B. R. Palmer, L. M. Abrantes, G. W. Warren

The behaviour of chalcopyrite - mineral specimens and a Portuguese concentrate - in 2M chloride solutions prepared from hydrochloric acid and sodium chloride, has been characterized by cyclic voltammetry. The study has shown the influence of the potential and of the presence of impurities in the reaction schemes and their relative extent. The dissolution of chalcopyrite concentrate under potentiostatic control has been investigated and found to confirm the effect of the selected potential on the surface modification/rate of dissolution. An attempt has been made to correlate the information obtained with the response of the concentrate electrode to constant current treatments.

Jan 1, 1993

The occurrence of metallic minerals in Australia to the time of the proclamation of South Australia as a Colony in 1836 was unknown. It is, therefore, perhaps, surprising that British settlers arriving in the Coromandel included among their number a German scientist Johannes Menge who had been appointed by the South Australian Company to the post of Mine and Quarry Agent and Geologist on 1 July 1836. His instructions were to `explore the natural productions of the Colony above and below ground and to superintend the working of quarries of stone and slate, the boring for water, metal, lead, coal and other mines at a salary of ú150 per annum for one year and for as much longer as the Company require your services not however exceeding five years'. In the event, he was to have little influence on those matter.

Jan 1, 1993

By P. M. Jones

Introduction The success of in situ leaching depends upon: • maintaining adequate injection and recovery flow capacities in wells, and • distributing leach solution effectively to contact and leach ore minerals within the target zone. Solution balance is an important indicator of the capability of a particular in situ hydrologic design to efficiently and effectively control and distribute leach solution within the target ore zone. As part of ongoing hydrological investigations into in situ leaching, the US Bureau of Mines (USBM) is studying factors affecting solution balance in an unsaturated copper ore deposit at the Cyprus Casa Grande Mine. The purpose of this study is to assess the effect of hydrogeologic features and in situ operating conditions on changes, during leaching, in: • solution storage within the deposit, and • solution balance. At the Casa Grande Mine, In-Situ-Leaching Test Facility, solution balance estimates are obtained for 10 selected intervals during 17 months of leaching under a variety of well configurations, pressures and flow conditions. Operational and geological description The Casa Grande Mine is located 32 miles south of Casa Grande, AZ. The mining area is within the Casa Grande Deposit, a porphyry copper stock consisting primarily of an intensely-fractured, granodiorite cap overlying a copper sulfide base. As a result of mine dewatering activity, unsaturated conditions existed in the deposit prior to leaching (Schmidt et al., 1990; Friedel and Schmidt, 1991). No groundwater was present in any of the in-situ-leaching, test-facility wells after drilling and prior to leach solution injection. Also, no ground water seepage occurs in the test-facility drift. The Casa Grande, In-Situ-Leaching Test Facility consists of 58 injection and recovery wells collared in an underground drift. The wells were drilled at various angles into the granodiorite deposit in a series of 15 divergent fans (Fig. 1). The fans are 12.5 ft apart and lie parallel to one another between the 900- and 1100-level drifts. Each fan contains three to five wells drilled at angles ranging from 6° to 89° from the horizontal. The wells can operate in an injection or a recovery mode. Currently, 36 flow sensors and 28 pressure transducers (part of a hydrologic, data acquisition system) are used to continuously monitor injection-well flow rates and pressures.

Jan 1, 1993

By Jozef F. Zurawski

The paper discusses design and construction of a 1.8 meter (6 ft.) diameter tunnel installed under complex geology of Staten Island, New York. Contract T-13 is a section of the Oakwood Beach Water Pollution Control Project constructed for New York City Department of Environmental Protection. A knowledge of the subsurface conditions and difficulties experienced on the adjacent contracts called for an innovative approach to handle tunneling under 12 to 17 meters (40-55 ft.) of water in the variable subsurface conditions. This paper describes tunnel design and construction utilizing continuous grouting during advancement of tunnel boring machine and installation of liner plates.

Jan 1, 1993

By L. A. Melis, A. R. Marchbank, S. A. Webster

"Certain northern Saskatchewan uranium ores have a high content of nickel and cobalt which offer the potential for recovery as a by-product to uranium. A nickel/cobalt recovery process has been developed as a viable method of recovering a marketable concentrate from typical uranium raffinate solution.Impurities are first removed from the raffinate and the pure solution is then treated with sodium carbonate to recover a bulk nickel/cobalt carbonate precipitate for sale to a primary nickel producer. All contaminants of concern are removed to very low levels and the product is free of radioactive contamination with gamma emissions significantly below natural background. Cost estimates have shown that installation of a nickel/cobalt recovery circuit within a uranium process plant is economically feasible.The testwork that led up to the selected process is described along with recommendations for further investigations such as additional testing of hydroxide precipitation as a possible viable alternative to carbonate. The selected process is described and project economics are briefly reviewed.PROCESS TEST PROGRAMBackgroundExtensive metallurgical research has been performed over the years to develop a process for recovering uranium from the Midwest deposit in northern Saskatchewan. During the course of this research, a certain amount of information became available which suggested that recovery of nickel and cobalt from uranium raffinate could be economically feasible. It was decided to undertake a test program which would investigate methods of separating nickel and cobalt from radioactive and other metal contamination to permit production of a saleable product.Available technology suggested that three general approaches could be taken to recover nickel and cobalt. The first and simplest approach would be to selectively precipitate the impurities of concern, primarily arsenic, iron and radium, and then recover a bulk concentrate from the purified raffinate. The second approach would be to purify the raffinate and then remove cobalt from solution by solvent extraction producing pure nickel and cobalt solutions for further treatment. The third approach would be to precipitate all metals from solution and then selectively re-dissolve nickel and cobalt in ammoniac solution which would be further treated by solvent extraction for nickel recovery, leaving cobalt for further treatment."

Jan 1, 1993

By R. F. Hammen

Heavy metal contamination of water is a problem of immense national and international proportions. However, effective cleanup is complicated both by the toxicity and the low concentrations of metals in wastewater streams. Using high performance chelation chromatography, the solid phase extraction and purification of extremely dilute metals from water was highly effective. The process is based on selective displacement of metals from a chromatographic column containing a chelating resin. The resin is characterized by extremely efficient adsorption kinetics which allow rapid and complete removal of the metals.

Jan 1, 1993

By G. Sanders

The studies reported on in this paper were initiated to draw attention to the severe contamination problem in the Section 30 drilling program at Chimney Creek. The lithologic-subset sampling study reached a different conclusion from that presented in your paper, and I wish to comment on your subsequent analysis of the data and your conclusions. Request for more complete data In the section on subsampling, you mention that the subordinate lithologies were separated and sampled, yet only the dominant-lithology gold value is plotted in Fig. 4. In a contamination study, the reader is interested in the assay values for the individual subsets. Please include a table of the subsample assay data in your reply. Also, please indicate which analytical methods were used to arrive at the gold values in the subsampling study. Turning barren rock into low-grade ore Figure 5 is very revealing and typical of all of the cross sections in Section 30. Note the long strings of low-grade mineralization spread out for hundreds of feet below the ore zones. There were some very high gold values found in certain contaminated fractions during the subset sampling. The conclusion, here, was that the distinctive, strongly-mineralized dolomite layer was probably loose and crumbly and continued to disintegrate during drilling. This caused salting of the unmineralized rock samples below.

Jan 1, 1993

By Ann M. Gosier

Over the past 20 years, diesel-powered equipment has been introduced into the underground mining environment in increasing numbers. While the introduction began years earlier in the metal-nonmetal sector, the exponential growth in coal mining use during this time has been more pronounced. Reasons for the continued use and rapid growth of diesel equipment in underground mines are easily understood. The safety and operational advantages afforded by this equipment in production and support systems are demonstrable. As other mine operators witness the advantages enjoyed by their competitors, they too move to introduce an increasingly diverse array of such equipment into their underground mines. As with any industrial technology, the use of diesel-powered equipment entails potential safety and health concerns. Existing Mine Safety and Health Administration (MSHA)approval regulations (30 CFR Parts 31, 32 and 36) apply only to diesel locomotives and mobile diesel-powered equipment for noncoal mines. In the absence of specific regulations, MSHA has required the use of equipment approved under Part 36 (gassy noncoal mines) for areas of underground coal mines where permissible electrical equipment is required. However, a considerable amount of diesel-powered equipment without explosion-proof or fire prevention features is in use in areas of coal mines where permissible electrical equipment is not required. It is on the use of this latter class of equipment that MSHA is focusing much of its regulatory attention relative to coal. The agency also is focused on revising existing occupational exposure limits for gaseous emissions and instituting limits on diesel particulate emissions for both coal and metal-nonmetal mines.

Jan 1, 1993

By S. I. Nozhko, V. N. Guliy, A. A. Zolotarev, L. M. Luyshnia

The study of the apatite deposits of the Aldan Shield shows wide spread of the Precambrian apatite-carbonate ores and possibilities of using them for extraction of apatite. Dependency of flotation on ore minerals was studied according to the following scheme: preparation of the monomineralic samples of anhydrite, gypsum, chlorite, serpentine, phlogopite, apatite; mixing them in apatite ore of the average composition; followed by flotation. Another series of the experiments was conducted to ascertain a dependence of flotation activity of the different minerals on the different flotation reagents, which were used as collectors. It has been shown that apatite from silicate-carbonate ores is most extractable because it has the biggest size of grains and is the most free of inclusions. Beneficiation of the sulphate-containing apatite-carbonate rocks is possible when flotol - 7.9 is used as a collector. Meanwhile, the use of the tallaktam leads to an increase in the sulphate recovery. The estimation of individual technological features of the layered Mghydrosilicates and their influence on the process of beneficiation has been examined using samples of apatite-dolomite ore (P205-8%) with the addition of the phlogopite, serpentine and chlorite. The results show that there is little influence of the chlorite presence on the flotation while the serpentine presence leads to a decrease of the flotation, because of its high specific surface area.

Jan 1, 1993

By Ivano Andreis, Giovanni Valent

The Yindaruqin Irrigation Project is designed to irrigate 57,000 ha of land in the central part of Gansu Province of People's Republic of China. Water for the Project will be diverted through an 87 Km long feeder canal which will convey 36 cubic meters per second from an intake on the Datong River. (Fig. 1) The feeder canal consists of approximately 10 Km of open channels, 75 Km of tunnels and 2 Km of siphons and aqueducts. This is the biggest self-flowing irrigation water control project in the Northwest of China and it is among the most interesting projects in China for the geological and environmental conditions. Nearly half of the investment in the Project is a World Bank Loan and contractors were chosen by means of international bidding. The Italian Company, CMC Ravenna, succeeded in answering the bidding for the construction of tunnels 30A and 38, perhaps the most difficult in the Project, submitting a TBM alternative to the conforming drill and blast contract recommendation.

Jan 1, 1993

By A. J. Monhemius, S. Raghavan, G. W. Warren, E. Peters, D. W. Furerstenau

A lyometallurgical process for extracting copper from an ore containing chrysocolla by leaching it with a kerosene solution containing LM 63 in the presence of small amounts of aqueous ammonia is described. The experimental results indicate that 70 to 75 percent of the copper can be extracted from the ore using an ammonia content that is about one-fourth the stoichiomeaic quantity required to leach copper in an aqueous leaching system. The rate of copper extraction was found to be a function of particle size, ammonia concentration and temperature. The large quantity of physically adsorbed water together with ammonia in the pores of chrysocolla provides a mechanism for the transport of copper to the external surface of the particles where it is complexed by the LM molecules and transferred into the organic phase. When size reduction accompanies leaching, the extraction process was found to proceed when only "trace" quantities of ammonia are present in the system. The kinetics of the extraction process appear to be controlled by a mixed (reaction and diffusion) mechanism.

Jan 1, 1993

Overview In 1992, US coal supply and demand were shaped more by weather conditions and the export market than by the economic recovery. Preliminary data compiled by the Energy Information Administration (EIA) (Table I) show that coal production declined slightly to 902 Mt (994 million st). Consumption, though, rose by about 1 % to 811 Mt (894 million st), trailing the 2.1 %growth in Gross Domestic Product. Contributing to the decrease were a sizable drop in coal exports and some coal stock withdrawals. Consumption increased largely because electric utilities turned to coal to offset a shortfall in hydroelectric generation caused by a drought in the Northwest. Apart from this, the demand for coal-fired generation was dampened by a mild winter in the northwestern and northcentral United States, and a cool summer in the central and eastern parts of the Nation. Coal use by other consumers was about the same as in 1991. The average delivered prices of coal to all consuming sectors decreased slightly in 1992, reflecting soft coal markets (Fig. 1). US coal exporters experienced a set-back in 1992 mostly because of losses in the European market. Total coal exports fell by 6% to 93 Mt (103 million st), the first decline since 1987. Coal stockpiles at the end of 1992 were about 1.8 Mt (2 million st) below 1991, despite stock buildups by some electric utilities in the East. Stocks were built up as a hedge against possible coal miners' strikes after the Feb. 1, 1993, expiration of the contract between the United Mine Workers of America and the Bituminous Coal Operators' Association.

Jan 1, 1993

Geostatistical analysis, resource estimation and three-dimensional modelling of the gold grade distribution was undertaken using exploration drillhole data taken from the Mt Leyshon gold mine. The main aims of the project were to provide an independent estimate of the primary gold resource and to improve the estimate by better understanding the statistical distribution of gold and the establishment of more robust variograms. These criteria have been achieved by the removal of low grade sub-populations, increased sample size and access to data from the most recent drilling program. The outcome of this statistical study has led to a lowering of the sill and nugget variance of the variograms used. Distinct geometric anisotropy was identified in all the resource estimation zones and was used to model gold grade distribution.Two independent resource estimates were established from the primary gold resource, one based on a geostatistical estimator (kriging) and the other on a traditional estimator (inverse distance weighting). Both methods were compared with a contemporary kriged estimate by Mt Leyshon Gold Mines Ltd.

Jan 1, 1993

Provide the U.S. mining industry with a user friendly computer program to calculate stresses in underground coal mines in order to improve safety conditions for mine workers. Capabilities of MULSIM/NL MULSIM/NL (multiple seams, nonlinear) is a three-dimensional boundary-element method (BEM) program developed at the U.S. Bureau of Mines for stress and displacement analysis of coal mines. It can analyze one or two parallel seams that can have any orientation with respect to the Earth's surface. Three main new features distinguish MULSIM/NL from its predecessors: (1) non¬linear material models, (2) multiple mining steps, and (3) energy release and strain energy computations. MULSIM/NL has six material models for the in-seam material: (1) linear elastic for coal, (2) strain softening, (3) elastic plastic, (4) bilinear hardening, (5) strain hardening, and (6) linear elastic for gob. The multiple mining step capability enables the user to efficiently simulate a changing mine geometry. Finally, MULSIM/ NL computes energy release rate due to mining using the most recent concepts advanced by Salamon.

Jan 1, 1993

A small-charge rock excavation method based upon the Penetrating Cone Fracture (PCF) technique has been demonstrated to be capable of excavating the hardest of rocks. The PCF technique involves drilling shallow holes in the rock which are then pressurised at the bottom by a propellant charge device. A controlled fracture is initiated at the hole bottom comer and propagates in such a manner as to excavate the rock at an energy efficiency three to five times better than explosives. Due to the low flyrock velocities and airblast pressures realised with PCF breakage, the method may be used in close proximity to equipment and personnel and is thus ideally suited for integration into continuous hard rock excavation systems. Over the past 18 months full-scale testing of the PCF method has been carried out in mines in the US and Australia. This testing has utilised a 76 mm diameter gas injector for hole pressurisation and employed propellant charges ranging from 80 to 320 gm. In addition to extensive data on rock excavation performance, data on ground motion, dust, carbon monoxide and air blast have been obtained. These data indicate that none of the parameters associated with PCF breakage are detrimental to the development of PCF-based, continuous-excavation machines. Machines employing the PCF method may range from simple single-boom machines for secondary breakage and small precision-blasting jobs to integrated systems with several booms, continuous mucking capabilities and ground-support equipment for drifting and tunnelling.

Jan 1, 1993

By Peter Willbrandt

The flash smelter at NA was commissioned in March 1972 with an initial throughput of 50 tons of dry copper concentrate per hour. As a result of various measures, for example, oxygen enriched process wind, extension of the radiation part of the waste heat boiler, etc., the throughput could be increased to the present 70 tons per hour of dry concentrate. NA's plant is located on the outskirts of the city of Hamburg. The flash smelter's location and the growing awareness of the German population as regards environmental issues necessitate again and again considerable capital expenditure being spent on environmental protection. Thanks to the numerous small and large measures taken to protect the environment the emissions of dust, heavy metals such as arsenic, copper, lead, etc., and as well SO, could be drastically reduced. This paper will be giving an overview on the present state of the flash smelting process and the impact of the increasing environmental awareness at NA.

Jan 1, 1993

By J. A. Meech

"The technology known as Expert Systems is being used within the minerals industry in a wide variety of problem areas. Applications include diagnosis, prediction, training, monitoring and control. Expert Systems provide a way to program computers to imitate human thinking. The construction of such systems is a straight-forward task that can be quickly learned by novices but can require a lifetime to master.To assist in the understanding and utility of this technology, a special manual bas been prepared which operates on a microcomputer under the MS-Windows environment. The manual covers all aspects of Artificial Intelligence of relevance to Expert Systems. A hypertext system allows users to probe as d•~ply as needed to achieve understanding or to simply skim the surface of the knowledge to obtain a quick overview of subjects. The manual was developed under the sponsorship of the Mineral Sciences Laboratory of CANMET and is available from the Mining and Mineral Process Engineering Department at the University of British Columbia. Annual updates are planned to keep abreast of new developments in this rapidly changing technology. RESUMELa technologie: des Systèmes Experts est utilisée par l'industrie minière pour résoudre une grande variété de problèmes. Les domaines d'application comprennent le diagnostic, la prédiction, la formation, la surveillance et le contrôle des procèdes. Les Systèmes Experts permettent d'écrire des programmes d'ordinateur qui imitent le processus de la pensée humaine. La construction de tels systèmes e:st une tâche qui peut être apprise rapidement mais qui peut prendre des années à maitriser.Pour aider à mieux comprendre et utiliser cette technologie, un manuel spécial opérant sur microordinateur dans l'environnement Windows a été développe. Le manuel couvre tous les aspects de l'intelligence artificielle qui concement les Systèmes Experts. Un système ""hypertexte"" permet à l'utilisateur d'étudier un sujet en profondeur ou de simplement couvrir une grande variété de sujet en surface. Le manuel a été développe avec l'aide financière du Laboratoire des Sciences Minérales de CANMET et est disponible au Département de Génie Minier et Minéralurgique de l'Université de la Colombie Britannique. Des mises à jour annuelles sont prévues de manière à couvrir les changements et nouveautés de cette technologie en évolution."

Jan 1, 1993

By William M. Dowall

The recently completed in-pit crushing and conveying project at Phelps Dodge's Morenci Mine is rated among the world's leading materials handling projects. The operation involves the crushing and transport of more than 109 kt/ d (120,000 stpd) of copper ore, using regenerative conveyors capable of providing more than 5.5 MW (7000 hp) of equivalent electrical energy. The Morenci Mine is located 330 km (200 miles) east of Phoenix, AZ. Phelps Dodge Corp. owns an 85% interest in the mine. The remaining 15% is owned by Sumitomo Metal Mining Co., Ltd. and Sumitomo Corp. Copper has been continuously produced from the Morenci district since the late 1800s. Until 1989, run-of-mine ore was transported from active mining faces to the Morenci and Metcalf concentrators by truck and rail haulage. In that year, a system of in-pit, semi-portable crushing plants and overland conveyors was commissioned. This substantially reduced truck haulage and effectively eliminated rail haulage in the pit. The system used two semi-portable, in-pit crushing stations equipped with 60/89 gyratory crushers. The crushed ore from both plants reported to the first of two overland belt conveyors, arranged in series, for transport from the pit to a coarse ore stockpile. The system was "backed-up" by existing locomotive rail haulage.

Jan 1, 1993

By George J. Simandl, Suzanne Paradis, Kirk D. Hancock, Jana Simandl

Traditional prospecting and boulder tracing are the two most important field techniques used in exploration for magnesite deposits hosted by sedimentary rocks. Consequently, success depends largely on the prospector's ability to identify magnesite. A density agent called sodium polytungstate (3Na2W04·9WOj'HPJ was successfully used to determine the presence of magnesite in sedimentary carbonate rocks of southeastern British Columbia. A rapid field method was developed and tested. This method permits discrimination between limy dolomites, dolomites, magnesite-bearing dolomites and magnesite-rich rocks.

Jan 1, 1993

Backfil ling of excavated Sub Level Open Stopes has been underway since March 1989 and as at December 1992 some 1 100 000 cubic metres of Cemented Aggregate Fill have been placed. During these three years significant developments in fill quantities, types and cost have taken place.Operational improvements have reduced the quantity of Cement Aggregate Fill by 40 per cent. These results have been achieved by:ò rescheduling stopes,ò designing smaller primary stope, and ò use of uncemented rockfill.Unit cost for Cement Aggregate Fill have fallen in the order of 50 per cent through:improving fill hole reli ability,simplified barricade construction procedures, reducing the cement content,ò substituting dune sand for deslimed mill tailings, ò improved maintenance at the Backfill plant, and ò renegotiated site freight agreement.This paper will review the historical developments of backfill use at Olympic Dam.

Jan 1, 1993