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By J. L. Sanchez

Using a special double-zone transpiration reactor, the vapor transport chemistry of vanadium pentoxide in the presence of water vapor has been investigated. Three possible volatile hydroxides above V,O,(s) are reported in the literature: VO,(OH),, V,O,(OH),, and VO(OH),. In the present study, it was established that VO(OH), is the principal gaseous hydroxide species formed. The predominant reaction was found to be: { } The vapor pressure of VO(OH), was measured as a function of temperature, water pressure, oxygen pressure and flowrate. The results have been used to determine the Gibbs free energy of the above reaction as a function of temperature: { } The results of the present work were combined with thermodynamic data reported in the literature to obtain expressions for the AGO for the reaction above V,0,(1) and the AGO of formation (units in cal/g-mole).

Jan 1, 1993

Refractory gold ores have been the subject of intensive metallurgical study in order to achieve more efficient recovery of contained values and at the same time to minimise environmental impact. Considerable innovative gold processing technology was introduced in New Zealand last century, the most notable being the first successful commercialisation of the cyanidation process by the Crown Mines Company at Karangahake in 1889. The Karangahake gold-silver deposit was second only +to the Waihi Martha mine in total bullion production from the region with active mining from 1882 until about 1920 and sporadic production between 1930 and 1944. Reevaluation at Karangahake with associated metallurgical testing has continued since that time becoming particularly active in the last decade as a result of increasing gold prices. Gold processing technology is reviewed and results of some recent test work are presented and discussed in the context of Karangahake history and future development possibilities. This work confirms the variability and complexity of the Karangahake deposit both mineralogically and metallurgically and suggests flotation followed by new and innovative smelting is the most appropriate processing route for the recovery of gold from the high grade ore which could be produced from the Karangahake workings in moderate tonnages.

Jan 1, 1993

By J. E. Gebhardt, D. A. Rice, P. E. Richardson

An improved understanding of the significant role of electrochemical reactions in sulfide flotation has evolved in the past 20 years, This understanding has been accompanied by a corresponding increase in attempts to control the electrochemical potential of flotation pulps for monitoring and controlling sulfide flotation circuits to improve metallurgical performance. This paper discusses the basic electrochemistry of sulfide flotation and the use of electrochemical potential as a control parameter.

Jan 1, 1993

Maintaining high carbon activity is vital to the efficiency of any Carbon-In-Leach or Carbon-In-Pulp process. Reduced activity can lead to longer residence times or gold losses in the tails. Regenerated carbon from the CIL circuit at Macraes Gold Mine was analysed for kinetic activity and composition over a 15 month period. An increase in kinetic activity during the time period was recorded, which was linked to reduced Na and Ca loadings. A laboratory simulation of the loading, stripping and regeneration of gold was developed and tested. Kinetic activities were obtained for synthetically fouled carbons following three circuits of the laboratory simulation. It was shown the competitive gold adsorption ability of xanthate fouled carbon (previously reported as a serious deactivator) could be significantly recovered following effective thermal regeneration. This ability was maintained in a subsequent circuit loading.

Jan 1, 1993

In the 100 years since the formation of The Australasian Institute of Mining and Metallurgy there have been significant changes in all aspects of the mining industry.A number of the changes have been driven by technical evolution or necessity, others have been driven by developments in the application of the products produced from the mining of minerals. Other changes have been driven by shifts in community values.

Jan 1, 1993

By R. Tessier, R. Grant, C. Bazin

"Brunswick Mining has investigated grinding media optimization for the purpose of improving the flotation feed and regrind product size distributions to enhance metal recoveries. The paper presents findings in the on-going testing of various sizes and shapes of grinding media. Breakage rates are used as an aid to assess the effect of grinding media. Results of empirical and phenomenological analyses demonstrate the importance of adequate selection of media sizes on the milling operation.INTRODUCTIONBrunswick Mining and Smelting operates one of the world's largest lead and zinc mine near Bathurst, New-Brunswick. The No. 12 ore body is an extremely fine grained volcanogenic massive lead, zinc, copper, silver, iron sulphide body between two metamorphosed sedimentary and felsic volcanic rock units. Pyrite content is about 60% with 20% non-sulphide minerals, mainly silica and chlorite. The operation is currently processing 10,500 tonnes of ore per day in conventional crushing, grinding, differential flotation and dewatering circuits. Details on the circuit can be found elsewhere (e.g. Hendriks and Ounpuu, 1985; Grant et al., 1991).The mill has operated for more than 25 years and despite the past milling experience, there has been much disagreement as to the required grind size. Since 1964, fineness of the flotation feed ranged from 60% to 80% passing 400 mesh (37µm) and averaged slightly over 71%in1992. Results from mineralogical analysis (Petruk and Schnarr,1981; Coleman, 1988), Brunswick metallurgical laboratory (Grant et al., 1991; Shannon et al., 1992) and Lakefield pilot plant tests (Hendriks, 1984; Hendriks and Ounpuu, 1985) clearly indicate that improved metal recoveries can be achieved by an increase in the fineness of grind, and more specifically by maximizing the amount of material in the 15-25µm range."

Jan 1, 1993

By Randall D. Peterson

Economic operation of a mine ventilation system must include some means by which operating costs can be quantified and evaluated periodically. Current practice at most mines relies upon the best judgement of foremen, engineers and managers to identify high cost or problem areas in the system and to estimate potential costs and benefits of work proposed to reduce inefficiencies. The problem with this is that significant savings can be overlooked or sub-economic projects may be undertaken when sufficient attention is not paid to the interrelationship between airflow characteristics and corporate financial criteria. In order to accurately determine costs and benefits it is necessary to view the solution of each potential ventilation problem as a separate economic opportunity.

Jan 1, 1993

By Odd G. Askilsrud, Steinar Johannessen

New powerplants, tunnels and dams are currently under construction at Meraaker to triple the annual power production of a nearly 100 year old power scheme. A total of 44 km tunnels with cross sections varying from 7 m2 to 32 m2 have been excavated in hard rock formations. Ten kilometers were excavated by a High Performance Tunnel Boring Machine (HP TBM). The remaining tunnels have been completed by the drill and blast method, using modem proven equipment and procedures. This paper gives special attention to the TBM drive and equipment selection, including, planning, site organization and performance.

Jan 1, 1993

By Albert E. Ketler

The AirBoss*200 is a unique ambient airflow sensor with important improvements in accuracy, especially in the critical low end, 0-61 m/min (0-200 fpm) where MSHA regulations apply. All solid state, its design is rugged, and there are no moving parts or delicate filaments. An on-board microprocessor calculates air velocity, linearizes and corrects for temperature, while driving voltage and current loop analog outputs to .3 meters/minute (1 ft/min) resolution. Recent developments also cover both positive and negative flow directions. A hand held computer is available to readout data and to adjust stored range selection, alarm set points, calibration data and the speed of response. Installation in hazardous areas is covered by MSHA Classes G, H and L.

Jan 1, 1993

By J. Harrison Daniel

Increasing concerns of industrial hygiene and worker health issues and resulting regulatory actions, coupled with continuing advances in mining systems, are placing new burdens on the industry and Federal Government; particularly, mine ventilation departments. More encompassing worker health programs are required to respond to Federal promulgation of regulations and to keep abreast of techno- logical advances in the mining industry. The relationship between the mining industry and Federal agencies involved in rulemaking is presented, along with the rationale of an Industrial Hygiene Management Plan. This plan or strategy focuses on developing partnerships and collaborative research groups to address the controversial health issues facing not only the mining workforce, but our society.

Jan 1, 1993

By M. J. Virnig, Christopher A. Fleming

THE CIP PROCESS "IN THE RIGHT PLACE AT THE RIGHT TIME? After its tentative introduction to the precious metals mining industry in the earlier part of this century, the carbon in pulp (CIP) process has now come of age, and is the process of choice on all new gold mills. Well over 50 percent of all gold that is mined each year is recovered by adsorption on activated carbon, and the percentage will increase in the years ahead, when old mills using Merrill Crowe technology come to the end of their lives, and as the proportion of world gold production from low-grade resources increases. The pioneering process development work in this field, which was mainly concerned with carbon elution, was carried out by Zadra and his colleagues at the United States Bureau of Mines in the early 1950's (Zadra et al., 1950, 1952), and led to the commissioning of the first large-scale, industrial CIP plant, at the Homestake Mine in South Dakota, in 1973 (Hall et al., 1974). From there, the process spread rapidly, firstly in South Africa in the late 1970's. and then throughout the rest of the gold producing world in the 1980's. There were several factors that led to the meteoric (by gold industry standards) acceptance and successful implementation of this new technology into gold processing operations worldwide. Firstly, and perhaps most fortuitously, the development of the technology closely paralleled the 1968 release of the gold price from the rigid constraints of the $35/oz. gold standard. With the value of the metal allowed, for the first time in modern history, to fluctuate in response to free market supply and demand forces, the gold industry witnessed an unprecedented boom as the price of their commodity increased ten-fold in a remarkably short period of time. This had several important spin-offs as far as new process developments were concerned: The profits realized by established gold-mining companies increased enormously and, consequently, there was more to spend on research and development and exploration for new deposits.

Jan 1, 1993

By Wu Chao, Wang Pinglong, Meng Tingrang

This paper discusses the research results of sulphide ore properties with respects on self-heating and the assessment techniques on mine spontaneous combustion for several mines of sulphide ores in China. A group of experimental devices for testing the chemical behaviour of sulphide minerals, the geological structures, the rate of oxygen absorption, the initial self-heating temperature, and the ignition point of ore samples, etc. are also described in detail. These methods have been proved to be effective by several sulphide mines which all have the history of spontaneous combustion of sulphide ores. INTRODUCTION A fire disaster from the spontaneous combustion of sulphide ores in a mine can produce large quantities of toxic gases and heat to pollute the working environment, lead to large economic losses and loss of human life, and even compell the mine to be closed. Some mines of copper, lead, zinc, tin and iron in China are of high content of sulphur. It is of great importance to evaluate the potential of spontaneous combustion of sulphide ores before beginning to design and mine the ore deposits. At present, the mechanism of spontaneous combustion accepted commonly is that sulphide ores undergo slow oxidation on exposure to moisture air at ambient temperature, with the evolution of heat, gases and moisture. The heat generated, if not dissipated, gives rise to an increase in the temperature of the sulphide ores. As the temperature of the sulphide ores rises, the rate of oxidation increases. If this is allowed to proceed unchecked it can eventually result in the ignition of the sulphide ores. For pyrite (FeS2), it reacts with oxygen and water according to the following equations.

Jan 1, 1993

By Andrew B. Cecala, Edward D. Thimons, George W. Klinowski

The U.S. Bureau of Mines has designed and evaluated total mill ventilation systems at two different mineral processing operations. Both systems have proven very effective at reducing respirable dust levels throughout the mill in a cost-effective manner. A 25,500-cfm system installed at a clay processing mill provided approximately 10 air changes per hour. This system reduced respirable dust concentrations by approximately 40 pct throughout the mill building. The second evaluation was performed at a silica sand operation. Tests were performed with 50,000 and 100,000 cfm of ventilation to the mill building, corresponding to 17 and 34 air changes per hour. Average mill-wide respirable dust reductions were 36and 64 pct, respectively. Not only did these systems reduce respirable dust concentrations and increase visibility throughout the mills, they were also easy to install and required minimal maintenance. A total mill ventilation system provides a general purging of the mill air; the system should be viewed as a supplemental technique to assist other dust control systems in operation.

Jan 1, 1993

By D. Gu

Shaft drilling is one of the most useful methods of driving shafts. This paper describes the application and development of the technique in coal mine construction in China.

Jan 1, 1993

By Ian M. Loomis, Keith G. Wallace

The Waste Isolation Pilot Plant (WIPP) is a U.S. Department of Energy research and development facility designed to demonstrate the permanent, safe disposal of U.S. defense-generated transuranic waste. The waste storage horizon is 655 m (2150 ft) below surface in bedded salt. To date the WIPP project has not emplaced any waste. There are three intake shafts used to supply air to the underground. All air is exhausted though a single return shaft. The total design airflow during normal operations is 200 m3/s (424,000 cfm). The ventilation system is designed to provide separate air splits to construction, experimental, and storage activities. Separation is achieved by isolating the storage circuit from the construction or experimental circuits with bulkheads. Any air leakage must be towards the storage area of the facility. Field studies have shown that the pressure differential necessary to maintain the correct leakage direction is susceptible to the effects of natural ventilation; therefore, extensive studies and analyses have been conducted to quantity the natural ventilation effects on the WIPP underground airflow system. A component of this work is a monitoring system designed to measure the air properties necessary for calculation of the natural ventilation pressure (NVP). This monitoring system consists of measuring dry bulb temperature, relative humidity, and barometric pressure at strategic locations on surface and underground. The psychrometric parameters of the air are measured every fifteen minutes. From these data, trends can be determined showing the impact of NVP on the ventilation system during diurnal variations in surface climate. Both summer and winter conditions have been studied. To the author's knowledge this is the first reported instance of automatic and continuous production of time and temperature variant NVPs. This paper describes the results of the initial monitoring study. INTRODUCTION The ventilation system at the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico, is designed to perform two distinct functions. First, it supports normal mine ventilation requirements complying with all state and federal mine regulations. Second, the system is designed to prevent an uncontrolled release of radioactive contaminants from the storage and transportation areas of the facility. Although a nuclear radiation release in the facility is considered unlikely, many special features are implemented in the ventilation system to prevent the possible spread of contamination. The facility is constructed with the waste transportation and storage areas separated from the mining and non-radioactive experimental areas. The ventilation system is designed such that air leakage is from the mining and experimental areas to the storage areas. Furthermore, radiation detectors are located throughout the storage and waste transportation areas underground and an exhaust filtration building is installed on surface to prevent the possible release of radiation to the environment. For over two years the underground ventilation system has been rigorously tested and balanced. It was during this period that the adverse effects of NVP were noticed and subsequently quantified. From extensive field studies and computer models, several mitigating features were designed and constructed and special operational procedures were implemented to control the impacts of NVP. To quantify more accurately the NVP at the WIPP, a continuous monitoring system was installed. This monitoring system consists of measuring dry bulb temperature, relative humidity, and barometric pressure every fifteen minutes at strategic locations on surface and underground. From this psychrometric data, the NVP is calculated. Fan operating pressures and flows and strategic differential pressures are recorded from the site Continuous Monitoring System (CMS). The monitoring system provides a means of evaluating how the ventilation system behaves in regard to climatic conditions and to judge the efficacy of the mitigating features and operational procedures. To the author's knowledge, continuous calculation of NVP as a function of time and surface temperature has not been previously reported. Overview of the Waste Isolation Pilot Plant The U.S. Department of Energy determined that the plastic nature of bedded salt may provide the best solution to isolate transuranic (TRU) waste from the biosphere. Initial evaluations at the WIPP site began in 1974. In 1979, the United States Congress enacted Public Law 96-164 for the construction and development of the WIPP project. The mission of the WIPP is to demonstrate the safe, long-term disposal of TRU waste generated by the national defense programs of the United States. TRU waste is classified as a low to medium level waste. The waste is stored in drums and does not produce significant heat (not greater than 1 W per drum). The WIPP site is located approximately 47 km (29 miles) east of Carlsbad, New Mexico in the Chihuahuan Desert. The repository is located in the 630 m (2000 ft) thick Salado Formation. This Permian Basin salt deposit is about 225 million years old and appears to have been minimally disturbed by earthquake, faulting, and ground water activity since it was deposited. The underground facility is 660 m

Jan 1, 1993

By Steve P. Signer

A study of rock support interaction mechanics was conducted by the U.S. Bureau of Mines at the Jim Walter Resources No. 7 Mine, Brookwood, AL. Bolt loads and entry deformation were monitored at four sites in a tailgate roadway. Two sites were areas supported by fully grouted resin bolts, and two sites were supported by tensioned bolts that used resin-assisted mechanical anchors. The yield capacity of the tensioned bolts was 37 pct higher than that of the grouted bolts. To monitor loads, instruments were mounted on 16 bolts, which were installed during entry development in the standard bolt pattern. Additional instrumented bolts were installed as supplemental support just prior to the headgate pass of the first longwall. Instruments to measure roof movements included three-point roof extensometers and convergence stations. Readings were taken during section development and as each longwall panel passed the test area. The fully grouted bolts showed localized loads that were higher than loads on the tensioned bolts; however, overall loading magnitudes were similar. Many sections of the fully grouted bolts passed the yield point of the bolt steel (98 kN or 22,000 lb). However, the maximum strain measured at any loca¬tion was 50 pct of the ultimate strain, and there was adequate bolt length to transfer the high loads into the rock. Significant bending was detected at many points along the length of the bolts and seemed to be the most significant mechanism in support-rock interaction. Loads on the tensioned bolts did not exceed the yield point of 160 kN (35,000 lb). Entry deforma¬tion, supplemental bolt loading, and general entry degradation appeared to be slightly less at the tensioned bolt sites. Local geology and in situ horizontal stress were also observed to affect con¬ditions at the test sites.

Jan 1, 1993

The LeadtZinc Concentrator at Mount lsa treats all the lead-zinc-silver ore from the Mount Isa Mine and some of the ore from the Hilton Mine. This concentrator was commissioned in June 1966 and total lead-zinc-silver ore treatment was transferred from the Mount rsa's original No 1 Concentrator in May 1967. Plant capacity is around 5 x 106 t/y.There have been three phases of major plant modifications since commissioning:1. replacement and upgrading of the flotation section in 1979; 2. upgrading of the crushing plant and installation of a heavy medium hydrocyclone plant in 1983 for ore preconcentration, and; 3. doubling ball milling capacity and a further upgrading of the flotation section in 1992.Other developments have included the installation of flotation columns and Jameson cells.The evolution of milling practice since 1955 has been reported by Davey and Slaughter (1970), Bartrum, Dobrowolski and Schache (1977), Fiedler and Munro (1984) and Espinosa-Gomez el al (1989).Lead concentrate is smelted in Mount Isa while zinc concentrate and bulk concentrate (locally called Low Grade Middlings or LGM) are railed to Townsville and shipped to custom electrolytic zinc plants and ISP smelters.

Jan 1, 1993

In this, the centennial year of The Institute, it is appropriate that the history of the Institute in New Zealand be recorded. I am indebted to John Dew, compiler of the centenary publication æMining People A Century - Highlights of the First Hundred Years of The AusIMM 1893 - 1993Æ, for many of the early historical references in this paper. In July 1892 the Amalgamated Mining Managers' Association of Australasia held its annual conference in Ballarat, Victoria, Australia, when it was suggested by the delegate from Broken Hill that the time had arrived for the establishment of an Australasian Institute of Mining Engineers. Resulting from this meeting at Ballarat, a Provisional Committee was formed at Broken Hill with the object of forming The Australasian Institute of Mining Engineers having the following objectives. To promote the arts and sciences connected with the economic production of the useful minerals and metals, the welfare of those employed in those industries by means of meetings for social intercourse, and the reading and discussion of professional papers with the circulation by means of publications amongst its members and associates the information thus obtained.

Jan 1, 1993

By B. Mishra

Calcium and lithium gallides have been synthesized by powder metallurgy techniques in the stoichiometries that can be used as reduction alloys for the Rocky Flats Plant Salt-Scrub (SS) process. The SS process is performed to recover valuable metals from salts generated in the electrorefining and the molten salt extraction processes. Combustion synthesis has been optimized for variable heating rates up to the reaction ignition temperature and for green densities of the powder compacts in terms of the ignition temperature and the exothermic heating of the product in an effort to develop LiGa and CaGaz alloys. The problems arising from the melting point and density differences of calcium, lithium and gallium have also been studied. The SS alloy compositions were produced by mixing, pressing and sintering the metal-powders. The efficiency of the intermetallic alloy, Ca-17 wt. pct. Ga, as a reductant and the effect of gallium on salt clean- up has been discussed. Measurement of actinide recovery has been studied with cerium as the surrogate for the actinide metal. The development of an alloy for SS reduces a major contaminated waste disposal problem besides recovering the valuable reactive metal.

Jan 1, 1993

The Barra Mine was the most significant mine of Australia's earliest mining era, which took place in South Australia between 1841 and 1851, the decade prior to discovery of gold in eastern Australia. Between 1845 and 1860, Barra was the largest metalliferous mine in Australia and employed up to 1000 men and boys, most of them Cornish.""Today the site is also important in a physical and archaeological sense as it contains extensive remains of mining and processing operations of the period 1850 - 70. Most significant are three cnginchouses which housed Cornish beam engines.

Jan 1, 1993