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By Randall E. Hughes, John F. Burst

This chapter describes the nature and occurrence of the principal clay minerals that are used as ceramic raw materials, explains how these raw materials are used to produce finished goods, and summarizes positive and negative trends that will affect future demand for raw materials and products in the ceramic industry. The term ceramics was derived from the ancient Greek keramikos (a clay jar). A ceramic product is a material that has been fired to at least 468.3°C (Mitchell, 1983). In addition to being one of our earliest manufacturing and construction materials, ceramic products are among the earliest records of civilization. The enduring significance of ceramics is shown by the fact that, even today, the manufacture of whitewares, brick and related red-fired wares, refractories, and engineered ceramics continues to be a major sector of the US economy. A wide range of materials can be made into ceramic products, although relatively few earth materials make up most of the ceramics in today's markets (Table 1). Most ceramic products are made from clay or a related material. The long history of clay use in the ceramics industry stems from its variable and sometimes unique physical and chemical properties, as well as its ubiquitous occurrence and relatively low cost. Clay is important to ceramics because of its plasticity, moldability and filterability, chemical content, color. refractoriness, solubility. corrosion resistance, electrical properties, and other properties that result from the essentially two dimensional morphology of the individual clay mineral platelets. Because of their basic relationships to the chemical and physical properties of clays, the chemical and mineralogical content have been the subject of continuous studies over the past few decades. Advances in knowledge about the chemical, mineralogical, and physical properties of clays are responsible for most of the advances in processing. The need to remove off-colored contaminants, minerals with low melting points, and soluble salts has resulted in beneficiation by wet processing methods such as water washing. Water washing is restricted to kaolins, although low cost methods of water washing have been extended more recently to ball clays in Europe. High intensity magnetic filtration and flotation technologies have noticeably improved the quality of kaolins and broadly expanded their use in the ceramics industry. In addition to products for construction (e.g., brick, tile, sewer pipe, field drain pipe, cement, fiberglass, roof granules, and paint) and manufacturing (e.g., refractories, kiln furniture, sanitary ware, pottery, and dinnerware), clays are used in calcined form as ceramic fillers, carriers, extenders, and grogs. Ceramics suppliers are under economic pressure in several of these product areas. Manufacture of refractories in America has declined as steel production has decreased. Similarly, dinnerware and tile production have declined because of foreign competition. Fortunately, new uses for clays,

Jan 1, 1994

By Dennis L. Paisley, Thomas P. Turner

Laser slapper detonators are the next generation detonator under development at the Detonations Systems Group at Los Alamos National Laboratory and function very similarly to an electrical slapper. A fiber optic transmits a laser pulse to ablate a thin metal film. This film, or flyer as it is commonly called, is launched through a short barrel to km/s speeds. The flyer shock loads or slaps a high density pressing of secondary explosive, setting off a detonation therein. Laser slapper detonators afford a number of safety advantages over other conventional detonators. Most important they require very high peak laser powers to operate, orders of magnitude larger than possible sources of natural or man-made accidental stimulus. Because light is transported over fiber optics, laser slappers avoid many of the electrical hazards associated with detonators. Use of insensitive, secondary explosives makes these detonators safer to handle, manufacture, transport, and deploy.

Jan 1, 1994

Misima Mines Pty Ltd (MMPL) operates a large open cut gold mine on Misima Island in the Louisiade Archipelago in Papua New Guinea. Misima Island lies approximately 600 km east-south-east of Port Moresby. The island is 40 km long by 10 km

Jan 1, 1994

By Jerry Dolph

Hecla Mining's Lucky Friday Mine, located beneath the town of Mullan, ID, has been shaken since the 1960s by many deep underground rock bursts. The largest rock burst carried a magnitude of 3.5 on the Richter Scale. It occurred in 1969 when all of the stopes on a level approached an upper level at the same elevation. After that, a stair-step pattern was used to give the mine's levels more of an "arch." The article is an account of one of the more ferocious bursts to hit the miners of the Lucky Friday. I say "miners" instead of "mine" because I was there and it was a very personal experience for me. I had been working at the Lucky Friday for six years. During that time, I had heard and felt thousands of air blasts. In fact, in the early spring of 1986, the mine was experiencing as many as 1000 air blasts an hour, of different intensi¬ties, of course. Most of them sounded like popcorn popping. There were also a few bumps and occasionally a real boomer. That day did not seem any different

Jan 1, 1994

By D. Panda, P. K. Sahoo, A. S. Rao

The waste phosphogypsum produced by Paradeep Phosphate Limited (PPL) at Paradeep (Cuttack, Orissa, India) consists primarily of calcium sulfate with small amounts of phosphoric acid, calcium fluoride and other harmful components. Presently these are dumped as waste. In this work, laboratory trials have been made to utilize the calcium sulfate present in the phosphogypsum to prepare usable products like ammonium sulfate, calcium carbonate and magnesium sulfate.

Jan 1, 1994

Laboratory tests were conducted in a full-scale continuous miner test gallery to evaluate resulting dust levels for changes in face airflow, spray water quantity and pressure, and mining height. The minimum and maximum values tested for each parameter were as follows: airflows between 1.42 and 6.14 m3/sec, water flows between 56.8 and 132.5 lpm, nozzles pressures between 413 and 1379 kPa, and mining heights between 1.52 and 2.74 m. Each of these parameters were evaluated for four common spray system designs. Respirable dust samples were collected in the operator's cab on the miner and in the immediate return. Second-order polynomial models were used to represent expected dust levels and multiple stepwise regression was used to identify significant control parameters for inclusion in the models. Separate models were developed for dust levels at the operator and return locations and for each individual spray system. Interaction between control parameters and curvature effects were found in most models. The analysis indicated that at the operator location, airflow and mining height had the most significant impact on respirable dust levels. In the return, airflow and water pressure were typically the most significant parameters. The models developed for each spray system design can be used by mine operators to guide application of control parameters for a variety of operating conditions and mining heights.

Jan 1, 1994

By K. A. Hildebrant, J. R. Norgate

"Synthetic lubricants have for many years documented extended service life and provided superior performance in temperature extremes. Increasing interest in synthetics' ability to reduce energy costs has resulted in laboratory and industry application evaluations. These tests have documented savings in functions such as worm gear drives, spur gears and in compressors. Energy savings data are presented as well as payback calculations as low as thirty days.The National Research Council of Canada has estimated that the Canadian economy loses over five billion dollars per year in friction and wear. Figures quoted were for 1986 during which it was estimated that nine hundred and forty million dollars were lost in the mining industry alone"" It has been further estimated that about 115 million dollars can be immediately recovered through improved tribology practices (Table I).The purpose of this paper is to present results and savings opportunities through the use of synthetic lubricants in various but common applications. Many other areas exist with the opportunity for energy savings such as in the use of more efficient drive equipment, reduced contact seals, spray mist lubrication systems and reduced friction coatings on rotating equipment such as pump impellers"

Jan 1, 1994

By B. L. Gibbs

Computers have been used in the minerals industry for about 30 years and, in a few cases, longer. With the explosion of microcomputing during the past 10 years, computers have changed how many minerals producers go about their work. What computer usage trends are active in the minerals industry today, and what can we expect in the future? In general, computer usage is accelerating. Engineers and geologists are becoming increasingly "application literate." Soft¬ware is increasingly oriented to how people work. User interfaces have improved, so most users need to know only a mini¬mum of system commands and structure to work with a computer. Most industry professionals know how to use word processing and spreadsheet pro¬grams. AutoCAD appears to be the drawing program of choice. One reason is availability of training and add-on programs for earthwork, mapping, contouring, etc. Another frequently cited reason for using CAD is the ability to quickly make changes to a map or design, as compared to hand methods. Management is moving toward greater acceptance of computer usage. Computers do not need workman's compensation ... even though they may get sick and take a few days off! Computer hardware used in most minerals-producing companies is strongly personal-computer based and likely to remain so. The 486 personal computers are inexpensive as compared to workstations and provide the power and speed to run most applications in minerals industry engineering offices.

Jan 1, 1994

By S. D. Prosser

The earliest record of slag in the world was the discovery of the remains of a copper blast furnace in Southern Israel, which has been carbon dated at 3500BC, nearly 6,000 years ago. Slag in Australia is a much more recent phenonenum with the first iron blast furnace commencing operations in 1848. The early days of metal smelting in Australia were marked with many company failures due to a variety of reasons. This paper traces the progress of metal and slag production from those early days up to the present times

Jan 1, 1994

Predict the spontaneous combustion potential of a mining operation using an expert system computer program.

Jan 1, 1994

The Joint' Venture Method is a procedure for assessing the value of exploration properties, particularly those for which resources have yet to be delineated. It aims to convert the terms of an actual or synthetic joint venture into the equivalence of an arms- lengths cash transaction between a willing seller and a willing buyer. This paper sets out one approach to achieving that conversion. It discusses both simple and complex cases and gives some examples from both public and private documents. It also includes some case studies in which the Joint Venture Method of valuation can be compared with values derived for the same project using other methodologies including actual cash deals. The Method has failings in both mathematics and logic. However because it does reflect or simulate an arms-length deal which takes into account past exploration effort and expenditure and an assessment of prospectivity at a particular point in time, it is felt that it can provide a reasonable approximation of trade value or asset value of a prospect, particularly if used in conjunction with other methods.

Jan 1, 1994

By R. W. Smith, J. Dubel, M. Misra

The bacterium Mycobacterium phlei is highly hydrophobic and negatively charged. It has specificity for selective adhesion to fine coal particles, mainly due to hydrophobic interaction. However, it does not attach to pyrite and ash forming minerals present in the coal matrix. Results have shown that this bacterium is an excellent flocculant for fine coal. Not only, are the coal particles visibly aggregated, but the optical micrograph has shown that the coal particles are held in the aggregate by adhesion and bacterial bridging. With Mycobacterium phlei, the flocculation characteristic of coal is markedly different from that usually observed with synthetic polymeric flocculants. In particular, the entwining characteristics of the long chain molecules of synthetic flocculants are absent in the case of Mycobacterium phlei. Since the hydrophobic interactions between the adhering particles are of greater importance in the formation of particle aggregation, the flocculation process is very selective.

Jan 1, 1994

By J. Shahabpour

"Breccias with angular and rounded clasts of a late-mineralization, ""barren"" hornblende porphyry dike set within a comminuted matrix consisting of rock fragments and quartz, cemented by quartz and K-feldspar of hydrothermal origin is observed in diamond drill cores from the Sar Cheshmeh porphyry copper deposit. Studies of age relationship between vein types, phyllic-altered clasts and the breccia groundmass suggest that the brecciation is a late event. The breccia clasts record evidence of hydrothermal reaction between the clasts and fluids responsible for the brecciation.Formation of bornite, in the breccia clasts of the originally barren hornblende porphyry dike, and in the breccia matrix, along with the scarcity of bornite in the Sar Cheshmeh deposit itself suggest involvement of fluids which are later and of different composition from the fluids responsible for the known mineralization at Sar Cheshmeh. These later fluids may be related to a later plutonic event and suggest the possibility of a later, and concealed deposit."

Jan 1, 1994

By J. G. Groppo, B. K. Parekh

Column flotation testing was conducted on the flotation feed slurry obtained from a preparation plant located in the Southern Illinois coal basin. The column flotation tests were conducted using three different bubble generating devices: a static sparger, a gas saver and a foam jet. Each of these devices was tested with three different types of frother and various column operating variables to provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. The results show that column flotation provided improved flotation performance, in terms of combustible recovery as well as ash and pyrite rejection, for each of the bubble generating devices. However, the effectiveness of each bubble generating device was dependent on the type of frother used. Alcohol frothers were most effective for use with the static sparger, somewhat less effective for the foam jet and ineffective for the gas saver. Glycol frothers were effective for all three bubble generating systems, providing high combustible recovery (>90%); low clean-coal ash (4-6% ash) and high pyrite rejection (70-80%).

Jan 1, 1994

By D Linn Coursen

Detonation propagates in the subject blasting agent at about 2.7 km/sec when it is heavily primed but explosion propagates in it at only about 0.43 km/sec when it is lightly primed. When propagating at 0.43 km/sec, it produces a borehole pressure that is slightly less than 1 kb, but no yellow fumes or other sign of incomplete reaction. It is a pumped AN/emulsion blend to which additional water is added by circumferential injection at the inlet of the hose through which it is pumped.

Jan 1, 1994

By A. Vien, A. J. Neale, B. C. Flintoff, R. P. Edwards

Froth flotation is one of the most widely used and effective processes for mineral beneficiation. First introduced in 1911, flotation technology has seen many developments over the past 80+ years. Innovations in reagent chemistry, equipment design, process analysis and process control have given design and plant engineers a powerful set of "tools" for process optimization. However, it does not follow that all flotation systems are optimized. As Klimpel observes: "The problem with the industrial flotation process is that it is relatively easy to get reasonable results, and relatively difficult to get excellent results" Klimpel (I 988). While reasonable was sufficient in the past, competitive forces will make excellent necessary in the future. Judging by the activities in many Canadian plants this transition is already underway. This paper examines the role of some of the optimization "tools" in effecting this change.

Jan 1, 1994

By C. Diaz, S. W. Marcuson, K. I. Burgess

Deep roasting in fluid bed roasters is the first unit operation in Inco&apos;s "roast-reduction smelting" process for the treatment of nickel sulphide concentrates. The roaster product, a low sulphur calcine, is reduction smelted with coke in an electric furnace to yield a sulphur-deficient matte which is then converted to low (<1%) iron matte in Peirce-Smith converters. Due to the deep roasting, a minimal amount of sulphur dioxide is evolved in the smelting and converting stages. Sulphur is eliminated from the concentrate almost exclusively in the roasters in a single, continuous, strong, gas stream suitable for treatment in an acid plant. This paper discusses the commercial scale testing of deep fluid bed roasting of nickel concentrate at Inco&apos;s Thompson Smelter as part of two commercial scale campaigns on roast reduction smelting conducted in 1981-1982. Slurry feeding, practised during the second campaign, permitted excellent control of the air/concentrate ratio in the roaster and, in turn, good control of sulphur elimination (about 80% of input). Smooth autogenous operation with high oxygen efficiencies (about 95%) was promoted by operating at bed temperatures of830°C to 850°C with calcine recycle. High throughputs and the desired metallurgy were achieved. The extensive testwork conducted during the two experimental RRS campaigns demonstrated thot deep fluid bed roasting of nickel concentrate at high oxygen efficiency is a technically viable operation.

Jan 1, 1994

By M. E. Poad

In 1986, a cooperative effort by the Homestake Mining company, the U.S. Bureau of Mines and the University of Utah was initiated to determine shaft stability while recovering high grade ore in a nearby pillar. Premining finite element simulations indicated the shaft would remain in elastic ground. Six years have elapsed and, despite some initial concern during the first lifts, it appears that the bulk of the original reserve will be safely and profitably recovered. An integrated application of rock mechanics tools from laboratory testing through numerical modelling to mine measurements and observations contributed substantially to the operational success of the project.

Jan 1, 1994

By Jan Magne Markussen

China, India and South Korea are three developing/newly industrialized countries that can show a very positive economic development in latter years. Moreover the three countries also feature amongst the countries with the highest level of activity in deep seabed mining today. India was the first country to achieve Pioneer Investor status in accordance with the UN Convention on the Law of the Sea. The country has carried out comprehensive exploitation of nodule deposits in the Central Indian Basin. India has an active programme for development of mining technology and internationally, India is probably the leading nation today as far as processing technology is concerned. China for its part has established a central coordination unit for its deep seabed involvement and its exploration and technology development is already well underway. South Korea has applied for Pioneer Investor status and much indicates that it will be allocated its own minesite in the autumn of 1994. The three countries are in mutual contact in the area of the Law of the Sea. Korea contacted both China and India when drawing up its application for pioneer investor status and allocation of minesite. However, no cooperation exists between the three regarding for example technology development, economic analysis or in studies of the environmental consequences. The main purpose of this paper is to focus on why and how the three countries would be well advised to cooperate in the above areas. Economic, technological and organizational aspects all point in that direction.

Jan 1, 1994

By Valery M. Yubko

During the last ten years seven applications for nodule-bearing areas of the World Ocean Floor International Region (IR) have been made by national companies of Russia (Yuzhmorgeologiya), France (IFREMER/AFERNOD), Japan (DORD), India (The State Department of Sea Resources Development), China (COMRA), Korea (KORDI) and the Interokeanmetal Joint Organization (IOM) of some East European countries and have been registered by the Preparatory Commission of the United Nations International Seabed Authority (ISA). Besides these groups registered within Resolution 11 of the Final Act of the III United Nations Conference on the Law of the Sea there are four international consortia registered in the USA [Kennecott (KCON), Ocean Mining Associates (DMA), Ocean Management Incorporated (OMI), and Ocean Minerals Company (OMCO)], which have interest in areas in the IR and can be considered as potential applicants. All registered areas (with the exception of the Indian Ocean) including the areas of potential applicants and also 6 areas, reserved for the ISA are located in the Clarion-Clipperton Zone of the Pacific Ocean. If within each area not less than one deposit of polymetallic nodule-bearing ores can be discovered, then, the total number of such deposits, for the present moment, is 20.

Jan 1, 1994