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By Christopher Mark

Preventing pillar line squeezes, massive pillar collapses, and coal pillar bumps is critical to the safe and efficient recovery of coal during retreat mining operations. To help prevent these problems, the U.S. Bureau of Mines has developed the Analysis of Retreat Mining Pillar Stability (ARMPS) computer program. ARMPS calculates stability factors (SF) based on estimates of the loads applied to, and the load-bearing capacities of, pillars during retreat mining operations. The program can accommodate various retreat mining scenarios including angled crosscuts, varied entry spacings, barrier pillars between the active section and old (side) gobs, and slab cuts in the barriers on retreat. It also features a pillar strength formula that considers the greater strength of rectangular pillars. The program may be used to evaluate bleeder entry designs as well as active workings. A data base of 130 pillar retreat case histories has been collected across the United States to verify the program. It was found that satisfactory conditions were very rare when the ARMPS SF was less than 0.75. Conversely, very few unsatisfactory designs were found where the ARMPS SF was greater than 1.5.

Jan 1, 1995

By Rowena C. Duckworth

The Ocean Drilling Program (ODP) is the largest international geoscience project in the world, and the state-of-the-art drill ship, the JOIDES Resolution, is permanently at sea. Each year there are six scientific cruises (legs) which each last approximately two months. These legs are designed by geoscientists from the nineteen countries that subscribe to ODP. Australia and Canada presently share ODP membership under the banner of the AUSCAN Consortium. The benefits of Australia's involvement in ODP include internationalisation of Australian geoscience, advanced graduate training, and unique scientific investigations of the ocean floors in the Australasian region. In addition, visits to Australian ports by the ODP drill ship, the JOIDES Resolution, contribute up to $2 million per visit to the local economy. Amongst the many other aspects of ten years of scientific drilling, ODP has significantly contributed to our understanding of hydrothermal processes on the seafloor. To date, three hydrothermal sites have been drilled to date by the ODP, Snakepit (MAR), Middle Valley (Juan de Fuca Ridge) and TAG (MAR). Two more hydrothermal sites are scheduled for 1996.

Jan 1, 1995

By R. Buchan

A number of mineral processing techniques have been adopted for the separation of the plastics making up a typical beverage bottle, and a complete flowsheet developed. Thus, size reduction, heavy media separation and flotation were used to separate PE, PVC and PET from their mixtures with cellulose fibers and aluminum, which makes up the cap of such bottles. It is shown that while heavy media separation allows the separation of a PVC/PET mixture from the solid waste, froth flotation can be readily used to separate PVC and PET from a mixture of the two. For this purpose, the differential action of an alkaline aqueous solution (PH=II) which contains methanol and MIBC as surface tension control agents has been found to be a suitable flotation medium. This paper reports some aspects of the flotation flowsheet developed for the separation of plastics from municipal solid waste mixtures and PVC from PET.

Jan 1, 1995

By S. A. Diatchkov

There is a misconception that mineral-project economic evaluations in the former Soviet Union are either nonexistent or very limited. This is not the case. In fact, there are at least two basic methods that can be utilized to evaluate the vast mineral resources of the Commonwealth of Independent States (CIS). Evaluation procedures are based either on a comparison to known projects, which may rely on limited available data, or on potential-profit calculations, which generally uses more extensive databases. Significant philosophical differences between these systems and those utilized in the Western world include the following: •Under the centralized-government system, the economic evaluation of a mineral project was based on artificially determined mineral prices and costs. Every ten to 12 years, prices for concentrates and metals were established by the Council of Ministers and remained unchanged until the next reconsideration of prices .

Jan 1, 1995

The Hishikari gold deposit, discovered by the Metal Mining Agency of Japan, has become a giant class epithermal gold deposit with the highest grade of gold yet recorded in the world through detailed exploration and development by the Sumitomo Metal Mining Co., Ltd. The exploration strategy involved a regional approach combining geological and gravity surveys over a 900 km2 area which had historically produced over 120 t of gold. These surveys were carried out to grasp the common geologic features of epithermal gold deposits in the survey area. A genetic model for epithermal gold deposits in the area under regional survey was also considered based on detailed research of the Kushikino epithermal gold deposit which was in operation at that time. This model was applied to the targeted areas, and important relationships between mineralization, host lithology, intensive propylitic alteration and gravity highs became apparent. The Hishikari block was selected in this way and bonanza gold was discovered during drilling. Since the development of the Hishikari mine, information useful for further exploration for the same type of deposit has been accumulated.

Jan 1, 1995

By W. J. Dolinar

The U.S. Bureau of Mines implemented the Fe2+ /Fe3+-SO2 anode reaction in a Cu electrowinning cell with full-size electrodes. Electrowinning was conducted using industrial electrolyte at 258 A/m2 (24 A/ft2) and 40 'C. Manifold injection of electrolyte provided circulation between the electrodes. Five-day operation using an optimized manifold gave an average cell voltage of 0.94 V at 89% current efficiency, which amounted to an energy savings of 2.82 MJ/kg (0.355 kW-hr/lb) compared to conventional electrowinning. Acid misting was completely eliminated, and SO2 concentration 23 cm (9 in.) above the cell averaged 0.06 ppm.

Jan 1, 1995

By Artmont G. J, Palmer K

Alluvial gold is an ideal exploration tracer to bedrock source and indicator of bedrock mineralisation style because (i) gold occurs in a wide range of deposit types, (ii) primary composition is sensitive to style of mineralisation, and (iii) it is a heavy resistate mineral that is readily preserved and easily sampled. In regional exploration of the Central Ranges of Irian Jaya, alluvial gold mineralogy has been applied to maximise the information return from panned concentrate sampling and to focus exploration effort. Primary gold is a solid solution of Au+Ag¦Cu¦Hg, ¦ trace Pd, Te, and Sb. In general Ag¦Hg increase and Cu decreases with inferred decreasing temperature of formation, and gold from particular mineralisation styles has signature compositions that can be used as indicators of bedrock mineralisation type. Furthermore, the abundance of alluvial gold is an indicator of the economic potential of a catchment. The convergent continental-oceanic plate geology of the Central Ranges is conducive to a wide range of mineralisation styles. Mineralogy of gold in ophiolite, skarn, porphyry, mesothermal vein and possible VHMS environments is characterised from alluvial and bedrock samples, and the use of gold mineralogy in prospecting at regional scale through prospect definition to drilling is demonstrated.

Jan 1, 1995

By Isaev EN, Levin LE

New data on the geology of the Late Jurassic to Holocene sediments cover of the World and associated mineral resources (oil, gas, ferromanganese nodules, ores of massive sulphides and other metals) have been compilled in the Atlas at scale 1:25,000,000 and 1:10,000,000. The work was performed by scientists from four Institutes of Russia (VNllzarubezhgeologia, VNlloceangeologia, Vernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences and Geological Institute of the Russian Academy of Sciences). The Atlas shows variation of thickness and formational composition of the large complexes (Upper Jurassic-Early Cretaceous, Upper Cretaceous- Eocene, Oligocene-Neogene, Pliocene-Pleistocene), distribution of oil/gas and ore deposits in each complex, data of deep- sea drilling (leg 1-130), thermo-pressure condition in the sedimentary basins within Circum-Pacific Rim.

Jan 1, 1995

The Central Andes in Peru, Chile, Bolivia, and Argentina, contain two contiguous terranes which were accreted i, Gondwanaland between the end of the Devonian and the end of the Triassic. These terranes, Arequipa in the north, anni Chilenia in the south, differ from each other in the timing and style of their metallogenic development. However, they contain over 90% of the Central Andean porphyry copper resource. The copper porphyries in the Arequipa terrane are Paleocene to lower Oligocene in age, whereas the Chilenia deposits are mid-upper Cretaceous and mid-upper Miocene. Porphyry copper deposits occur outside these terranes, but are all Miocene in age. Miocene porphyry-style mineralisation also exists in the Arequipa terrane, but is copper-deficient and gold-rich. The accreted terranes may have favoured porphyry and other styles of copper mineralisation because they possessed relatively thin continental crust compared to adjacent parts of the Andes. Crustal thickening which commenced at about 30 Ma in the Arequipa terrane coincided with a major change to polymetallic, precious metal mineralisation which commonly displays high sulfidation charcteristics.

Jan 1, 1995

By David A. Collins

Red Dome Gold Mine classifies ore types within the pit by gold and copper grades. Copper grades are further distinguished by total copper and cyanide soluble copper levels. At present, Cyanide Soluble Copper samples take six hours of agitating before they can be assayed. This agitation time produces results which are a proportion of the total cyanide amenable copper. This relates to our plant's performance. Frequently the total copper result is needed before we can begin the cyanide soluble copper analysis. This caused a protracted tum around time. Mennetech Pty. Ltd has produced a catalyst proven by David Martin Menne to accelerate the cyanidation of gold. David said that the information at hand indicated that Leach WELL TM also accelerates the leaching of cyanidable copper substantially. Test work was undertaken on-site at Red Dome Gold Mine to investigate the potential of Leach WELL TM to reduce the leaching period and therefore, the overall tum around time required for cyanide soluble copper determinations.

Jan 1, 1995

By Darryl J. Butcher

The Akjoujt Project is operated by MORAK SA, a company incorporated in the Islamic Republic of Mauritania. MORAK is jointly owned by General Gold International SA (A wholly owned subsidiary of General Gold Resources NL.), SAMIN, and the International Finance Corporation. The project was devel­oped to treat approximately 2.1 million tonnes of TORCO (Treatment of Refractory Copper Ores) tailings containing an average 3.2gAu/t, and 0.75%Cu/t. The process involves the use of ammoniacal cyanidation for gold extraction, and conventional carbon adsorption, and eventual desorption, of gold values. This is believed to be only the second commercial application of this leach chemistry in the world. The other being a small vat leach operation on the Paris Mine Dumps. (This operation was described by Mr M Ruane in a paper to a previous Randol Forum.) Initial work on the process, and the Akjoujt process design assumed that the reaction involved was anaerobic. This paper describes the operating experience, plant trial, and eventual installation which has lead MORAK to the conclusion that the process is not anaerobic, but requires oxygen, or an oxidant to proceed.

Jan 1, 1995

By Robert S. MacPhail, Bret G. Cousins

Many copper-bearing ores with associated gold use Sodium Isopropyl Xanthate (SIPX) as a flotation agent. In general, SIPX will float to some extent other minerals that may not be desirable, such as pyrite. FLEX 31 is a chemically enhanced SIPX product with many of the same properties as SIPX. But FLEX 31 has the ability to reject more pyrite from concentrates and improves copper recovery when using up to 50% less FLEX 31 than is required if using SIPX. Copper activated minerals such as sphalerite and arsenopyrite show increased recoveries as well using FLEX 31. Tests have been performed on copper/zinc ores and an arsenopyrite/pyrite ore.

Jan 1, 1995

By Gary Jobson

The Mt Todd Gold Mine is owned and operated by Zapopan NL, and is located 300km south of Darwin near the town of Katherine. The crushing plant and heap leach facility, which has operated since November 1993, has recently been expanded to treat 6 Mtpa with 1995 budget gold production reaching 120,000 oz from a head grade of 1.12 git. The process flowsheet and equipment are described, with innovative key features including:

Jan 1, 1995

By Mike D. Adams

Testwork was conducted on loaded carbon samples from a small gold mine in South Africa. It was shown that a 75% saving in reagent consumption in the Zadra elution circuit could be achieved by adopting a cyanide-free elution approach, i.e. by cutting back the NaCN level from 1 % to nil, and the NaOH level from 3% to 1 %. This process change was also shown to result in a 20% improvement in the elution kinetics. Furthermore, it was also shown that a 50% enhancement in elution rate over the current situation could be achieved by use of an eluant containing 0.5% NaOH and 0.15% NaCN, corresponding to an 84% saving in reagent consumption. A further improvement in elution kinetics was found to occur by increasing the NaCN level to 3%, but this would lead to a concomitant increase in reagent consumption, due to the decomposition of cyanide at high temperatures. The presence of base metals loaded onto the carbon was also found to have a significant effect on the elution. Copper tends to adsorb as Cu(CN)2- during the adsorption stage, and acid washing converts this species to CuCN. Copper in this form is not eluted during cyanide-free elution, whereas it is eluted during a conventional cyanide elution, consuming the initial cyanide in the process. The elution data was analysed and the fit to a simple model was verified.

Jan 1, 1995

By P. M. May, J. S. Solis, G. T. Hefter

Chemical speciation plays a critical role in many areas of gold processing. These include the formation of HCN in plant liquors, interference by copper in the extraction efficiency of gold, the recovery of adsorbed gold, and the behaviour of plant effluents in the environment. Thermodynamic modelling provides a cost-efficient method of rationalizing and even predicting of chemical behaviour. Unfortunately, because thermodynamic data for cyanide complexes are of poor quality and few are known under hydrometallurgical conditions. Such models are currently of limited use. This paper describes recent work on the thermodynamics of cyanide complexes of a range of metal ions. Data will be presented on the stabilities and enthal­pies (heats) and entropies of formation of a variety of metal ion species determined by potentiometry and calorimetry. Particular emphasis will be placed on the Cu(I)/CN- system.

Jan 1, 1995

By Mark W. Johns

The design or optimization of a carbon-in-pulp (CIP) plant requires the determination and setting of a number of parameters to ensure optimum economic performance. A number of these parameters are either fixed, a function of the pulp, interdepen­dent, affect other parameters or outputs, so only a limited number of degrees of freedom exist from a metallurgical point of view. The traditional CIP contactor employs a low carbon concen­tration, a low agitation intensity and a reasonably long pulp residence time. The pump cell contactor employs a high carbon concentration, a high agitation intensity and a reasonably short pulp residence time. The two philosophies are dipolar in nature and the question arises as to which configuration is the optimum configuration for a CIP plant. The carbon particle size is shown to have a small effect on the capital cost of a CIP plant. A decrease in the pulp residence time, an increase in the pulp density, an increase in the carbon residence time, an increase in the agitation intensity and an increase in the number of stages are shown to have a positive effect on the capital cost of a CIP plant. The pulp residence time, the pulp density and carbon particle size are shown to have a small effect on the operating cost of a CIP plant. An increase in the carbon residence time, a decrease in the agitation intensity and an increase in the number of stages are shown to have a positive effect on the operating cost of a CIP plant. The optimum CIP plant, therefore, employs a short pulp residence time, the traditional pulp density, a long carbon residence time, the traditional carbon particle size, the traditional agitation intensity, and the traditional number of stages. Neither the pump cell configuration nor the traditional CIP configurations match the optimum configuration.

Jan 1, 1995

By G. S. Walker, W. van Bronswijk

The accurate determination of free cyanide and metal cyanide complexes is of increasing interest to Carbon-in-Pulp (CIP) gold extraction operations as cyanide consumption is an important economic factor in the processing of complex ores. Characteristically complex ores are high cyanide consumers and these ores usually contain a range of sulfide minerals e.g. covellite (CuS), digenite (Cu1,S), chalcocite (Cu, S), Pyrrhotite (Feci-x)S), marcasite (FeS2), arsenic and antimony sulfides and zinc sulfide. These minerals can consume significant quantities of cyanide, e.g. various copper(!) cyanide complexes such as CuCN, Cu(CN)2·, Cu(CN)/ and Cu(CN)/ can form, depending on the cyanide to copper ratio in solution. Measurement of free and complexed cyanide is thus a prerequisite for efficient cyanide dosage control. Free cyanide can be determined potentiometrically or amperometrically but the methods are prone to error and are laborious [1]. Metal cyanide complexes can be determined by reverse phase HPLC, however, the species ofa single cation (e.g. Cu(CN)i-, Cu(CN);2 and Cu(CN)/) elute as one species [2]. Additionally the high amount of suspended matter in CIP leach solutions tends to introduce errors. Raman spectroscopy has the potential to be used as an in­line or on-line method of analysis. Free cyanide and the cyanides of gold, silver, copper and iron have been studied in aqueous alkaline solutions with a view to developing such a method. Spectra were obtained with a Bruker RFSl00 FT-Raman spectrometer using a 1064 nm laser delivering 800 mW of power at the sample. Depending on the solution, 250, 1000 or 4000 scans at 4 cm-1 resolution were accumulated. The cyanide stretches observed were relatively narrow (10 15 cm-1 full width at half height) and well resolved (Figure 1 ).

Jan 1, 1995

By Peter J. Stewart

My first experience with carbon reactivation in the gold industry was at Whim Creek, Meekatharra some 15 years ago. Very little was known, in fact, carbon reactivation kilns in the gold room were a complete mystery. Ten years ago at conferences such as this the mystery was more as to why field kilns would not reproduce activities achieved in the laboratory. A carbon reactivation kiln manufac­turer was thought to be brave or stupid to speak at a venue such as this. Reactivation kiln design has improved dramatically in the past 10 years and with a few exceptions, most kilns operate well. May I suggest that now, the focus is on plant practice rather than kiln design, and that the basics of plant practice as it relates to carbon activity needs revisiting. As metallurgists like to talk on engineering, accountants on the Economy and vice versa, my presentation on Carbon Reactivation will focus on plant design and operation as it effects carbon reactivation. There have been some excellent papers published over the past 15 years on the basics of carbon reactivation in relation to gold processingl,2,}. Taken that kilns operate and are effective to a greater or lesser degree, plant design and operating practise have an enormous bearing on carbon activity, solution tail, carbon loss and other cost items. This presentation will not argue the merits of equipment used for the thermal reactivation of organically fouled carbon, questions on this subject are welcome over a drink after this session.

Jan 1, 1995

By Kimberlie Staheli

A new sanitary sewer was installed in Pleasant Hill, California using microtunnelling methods. The project consisted of 693 meters of 1372 mm and 1981 mm concrete pipe. A Herrenknecht AVN 1200 was used to install the nominal 1372 mm pipe in three drives. The machine was then fitted with an oversized shield used to install the large diameter pipeline. This articulated shield allowed the excavation of a 2362 mm diameter hole with a 1524 mm machine-- a technique new to North America. This paper reviews the design considerations for the articulated shield and reports on the project challenges and solutions to overcome these challenges.

Jan 1, 1995

By D. Lelinski

Air-sparged hydrocyclone (ASH) flotation is one of the new promising technologies. Numerous applications have been successfully tested since its conception; nevertheless, research and development efforts have continued to provide for further improvements with respect to operating conditions and design considerations. Results from experimental studies on bubbles generation in the ASH system are presented in this paper. Bubble size distributions generated during ASH operation have been determined using a high-speed photographic technique. The influence of many factors including surfactant concentration, water flowrate, and porous tube pore size has been studied. Test results indicate that these process variables have a profound effect on the bubble size distribution. With an increase in surfactant concentration or water flowrate (shear field) the bubble size distributions become narrower and shift toward smaller average bubble diameters. However, the influence of pore size is more complicated. Depending on the experimental conditions the average bubble size was found to range from about 100 to 300 microns in diameter.

Jan 1, 1995