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By Sam McNary

The U.S. Bureau of Mines used the East Fork Pine Creek watershed to conduct a pilot study for an inactive and abandoned mine lands inventory, during which techniques and methodologies would be developed for subsequent inventories. A total of 177 waste dump samples, 191 mill tailings samples, and 36 stream sediment samples were collected. Water samples were collected from 18 sample sites during five sampling events. Waste dump, tailings, and stream sediment samples were analyzed for antimony, arsenic, cadmium, copper, iron, lead, mercury, and zinc. Results indicate a multidisciplinary approach is necessary: disciplines should include geology, geostatistis, geochemistry, geophysics, biology, hydrology, and remote sensing; small prospects do not generally contribute to watershed contamination, major mine and mill sites may contribute metal enriched sediment of metal enriched water; speciation studies and bioavailability studies are important.

Jan 1, 1995

By D. L. Purcell, B. T. McClure, J. McDonald

The U.S. Bureau of Mines has completed a laboratory evaluation of exhaust emissions from a diesel engine using an oxygenated diesel fuel. The fuels tested were soy methyl esters in a neat (100%) form and low sulfur, petroleum number 2 diesel fuel (D2). The engine tested was a Caterpillar 3304, indirect injection, naturally aspirated, 75 kW, diesel engine that is typical of engines used in underground mining applications. The objective was to determine the extent to which oxygenated fuels, such as methyl esters, reduce diesel particulate matter (DPM), and their influence on upon gaseous emissions such as total hydrocarbons, CO, NOx, NO2, formaldehyde, and other exhaust emissions. Heavy- and light-duty transient tests were used to simulate load cycles typical of mine applications. The soy methyl ester fuel produced greater amounts of volatile DPM (organic material) but much less nonvolatile DPM (carbon soot) for overall DPM reductions. A diesel oxidation catalyst (DOC) typical of the type commonly used in metal and nonmetal mines was tested with both fuels. The DOC further reduced the volatile and total DPM when used with the soy methyl esters, but increased the total DPM for D2 due to sulfate formation. The soy methyl ester fuel reduced CO and hydrocarbon, and NOx emissions. The DOC further reduced CO and hydrocarbon emissions.

Jan 1, 1995

By Raja V. Rarnani, Robert L. Frantz

"The more than 75 research projects funded throughout the first 10 years of the Dust Center's operation have resulted in numerous cumulative findings fulfilling the goals of the Center. These project descriptions present the methodologies and project-to-project relationships leading to their various accomplishments and demonstrate the mesh between project objectives and Center goals.To develop equipment for collecting respirable dust samples.To develop experimental methods for particle-by-particle characterization of morphology, size, and chemistry.To develop experimental methods for overall respirable dust sample characterization of size distribution, chemistry, and crystallography.The project directly addresses the Center's goals to enhance the understanding of the scientific and engineering characteristics of fine and respirable mineral particles found in mining and milling atmospheres and to establish the relationship between natural and cultural factors (mine geology, mineralogy, mining and milling methods, equipment, and control measures) in the generation of fine particles. The project also aims to contribute to the development of control mechanisms for reducing ambient respirable dust concentrations and worker exposures.The work on this project is related to similar work on Coal Mine Dust Characterization (Project No. 2701/MN1) and Characterization of Dust Particles (Project No. 4203/PS3).Airborne dust sampling was performed at the following locations: 1) a sand and gravel quarry in Southern New Hampshire, 2) a welding facility, 3) a ceramic powder facility, 4) a metal powder facility, and 5) the air in Cambridge, Massachusetts. A portable sampling box incorporating two Sierra personal cascade impactors was designed and produced. At a 2-LPM flow rate, the effective cut-off diameters of the Sierra impactors were 10.0, 6.0, 3.5, 2.0, 0.9, and 0.5 mm, respectively, for each stage, and the air passed through a PVC filter after the last stage. In addition, the sampling box contained a total respirable dust filter. The substrates were weighed carefully before and after collection, and the weight increases were recorded. All films, foils, and filters were put in the balance chamber for more than 8 hours to stabilize the temperature and humidity before weighing. A Cash 21 microbalance (±0.001 mg) was used to weigh the Mylar films, SS films, and filters."

Jan 1, 1995

By D. J. Brunner, S. Mathur, D. McKinney

With the advent of faster micro-processors, the use of numerical methods to simulate complex fluid dynamic phenomena in three dimensions for use in design has become prevalent in the automotive, and turbo-machinery industries. The Computational Fluid Dynamics (CFD) method divides the region of interest into small control volumes which form the mesh representing the physical characteristics of the problem, and uses the finite volume method to intergrate the equations for the conservation of mass, momentum, energy and species over each control volume. Recent developments in CFD software expedite mesh generation, and enable the use of unstructured grids, comprised of tetrahedral volumes in three dimensions and triangular areas in two. CFD more accurately represents complex geometries and allows for relative movement of meshes enabling simulation of multiple moving bodies. 'ibis paper presents two examples of how CFD simulation can be used to assess mine and tunnel ventilation problems formerly addressed by application of analytical solutions which were developed assuming ideal incompressible conditions. CFD simulation is used to evaluate the impact of varying the airflow in a descentionally ventilated airway on the layering along the roof of smoke and hot gases resulting from a vehicle fire. Control of the smoke layer is required to enable safe egress from the vehicle, particularly if the vehicle is for personnel transport, and to ensure control of the fire contaminants throughout the ventilation system. The airflow required to prevent layering against the ventilation direction, calculated from the Bakke and Leach relations (Bakke and Leach, 1962), is compared with the CFD simulation results. An evaluation of the pressures, generated as a vehicle enters a tunnel portal, using CFD simulation, is also presented for unflared and flared portal configurations. These simulation results are compared with predictions derived using an analytical method which assumes one-dimensional and incompressible flow. Results of the CFD simulation are presented in an animated video format. SIMULATION OF BACKLAYERING In designing a ventilation system for a transit tunnel, the ability of the ventilating air to control and prevent backlayering of smoke and hot gases resulting from a vehicle fire is of prime concern. The buoyant nature of hot smoke causes it to rise relative to the colder, fresh air provided by the ventilation system. If the vehicle fire occurs in a descentionally ventilated tunnel, the smoke may tend to move upgrade in a layer above the incoming ventilation airflow. The layer may become thick enough to engulf a substatntial part of the tunnel cross-section upgrade of the incident that comprises the evacuation route. This effect is termed "backlayering' and it is similar to the development of methane layers in mines for which most studies related to backlayering have been done. Prediction Techniques Analytical A number of studies have been conducted (Bakke and Leach, 1962) to define the characteristics of this phenomena and as a result have produced relations which are used both in the mine and transit ventilation fields to define the air velocities required to control layering. In the transit industry the air velocity required to prevent the backlayering phenomena from occuring during a vehicle fire is called the "critical velocity" (Associated Engineers, 1975) and is dependent upon a number of factors: tunnel height, cross-sectional area and grade; ambient air temperature and density; and the heat release rate of the fire. Common practice in transit ventilation design is to provide an airflow which meets or exceeds the critical velocity. In order to determine whether or not the critical velocity can be achieved with a particular ventilation system, a one-dimensional simulation of the tunnel network is typically performed using programs such as the Subway Environment Simulation program (SES) originally developed in the late 1970's (Associated Engineers, 1980). The results obtained from SES are compared to the critical velocity to determine the adequacy of the ventilation system. Computational Fluid Dynamics For the backlayering simulations, a commercial CFD code which has been used successfully in a wide variety of engineering applications, was used. It provides numerous options for modeling laminar and turbulent flows, multiple turbulence models, definition of multiple species and chemical reactions between them, a variety of boundary conditions (including constant pressure and constant velocity inlets) and the ability to apply user-defined FORTRAN subroutines. It includes the ability to model conductive, convective, and radiative heat transfer. FLUENT also permits the use of "body-fitted coordinates" to match the computational mesh or grid to complex real-world geometries. Computational Fluid Dynamics Model The model developed to simulate the backlayering phenomena is comprised of an airway of rectangular cross-section, 4 meters wide, 4.5 meters high, and 200 meters long. A laterally

Jan 1, 1995

By Maslov LA

We have considered the following characteristics of the crust and upper mantle of the Pacific Belt: seismic wave velocit> anomalies, mechanical stress and shear deformation rate fields, heat flow and the pattern of metallogenic provinces of the Belt. It has been noted that there exist certain regularities in distribution of the above mentioned geophysical characteristics and metallogenic zones within the Belt, displayed by prevalence of the lithophile elements in the Asia-Australian part of the Belt, and of the chalcophile ones within the American part.

Jan 1, 1995

By P Blattner

The Late Miocene gold-silver bearing epithermal system at Waihi has some close similarities in its paleo-thermal and geochemical structure with modern, volcanic-hosted geothermal systems such as Ohaaki-Broadlands. At Waihi an extensive braided quartz vein system is enveloped by hydrothermally altered andesites with minor tuff breccias and tuffs. A main stage of vein filling consists of multiple phases of chalcedonic quartz and fine to medium grained quartz, which are accompanied by pyrite, sphalerite, galena, chalcopyrite and acanthite below the base of oxidation. Platy calcite is present locally. Fluid inclusion studies indicate that the main stage quartz was deposited at temperatures of 189¦-273¦C from dilute (Tm of -0.1 to -1.0¦C) fluids that were locally boiling. Homogenisation temperature Th versus Tm data points lie within the field enveloped by dilution and boiling/gas loss paths determined for the Ohaaki geothermal field, and indicates that the parent hydrothermal fluid for the Waihi epithermal system had a similar composition to that at Ohaaki, ie 0.2 wt% equiv NaCl and 3.3 wt% equiv CO2. The hydrothermal alteration mineralogy and the isotopic composition of vein calcite indicate that the hydrothermal fluid contained relatively high concentrations of CO2 , as at Ohaaki. Oxygen isotope analyses of main stage quartz range from 6.1 to 11.6 %0 and of vein calcite from 2.29 to 9.4%0. Calculated d18Owater values for the hydrothermal fluid that deposited the main stage quartz range from 2.0 to -5.7%0, with a trend to less negative values with depth. They are similar to those in the deep chloride fluid in active geothermal systems with a substantial fluid throughput. A high fluid throughput at Waihi system is also evident from the extensive high intensity hydrothermal alteration and large volume of quartz deposited in the vein system.

Jan 1, 1995

By M. J. Brodie

"The decision to proceed with mine decommissioning, generally involves a number of complex and independent factors. These factors, including potential for re-opening, legal requirements, contingent liability, asset depreciation, due diligence, and public relations are discussed in the context of the financial implications on a net-present- value basis. It is concluded that the decision to delay mine decommissioning is commonly not in the best financial interests of the mine operator. Some measures to reduce decommissioning costs and expedite the process are presented.IntroductionThe primary audience for this paper is mining executives, although it should be of interest to all professionals involved in the planning and carrying out of mine decommissioning. Historically, mines were abandoned, not decommissioned. Then, as decommissioning became required, it was assumed that salvage revenue would pay for decommissioning. During the I980s, it became apparent that mine decommissioning costs would exceed salvage revenue for nearly all sites, and that a substantial net cost for decommissioning would be realized for some sites. Throughout this period, the approach to decommissioning has evolved through the sequential addition of measures to meet the increasing regulatory burden. This has resulted in a process in which the elements of decommissioning may not be optimized with respect to each other for the most favourable net present value to the corporation. Additional considerations which are not specific to mine decommissioning, such as environmental policy, due diligence and public relations, may now come to bear on the decision-making process.This paper addresses the issue of mine decommissioning as a three-step process. The first step involves identification and evaluation of all of the issues that relate to mine closure, the most importantof which is the potential for re-opening of a mine. Assuming that it is decided that a mine is unlikely to re-open, the second step is to determine when to carry out the decommissioning work. This aspect is examined through a net present value (NPV) approach. Finally, details regarding who does the work and how the various tasks are divided up must be resolved.Every mine is a unique concentration of minerals at some specific location, hence the development, operation and closure of a given mine must be regarded as a special case. Superimposed on the site-specific considerations are the size, history and financial status of the associated corporation."

Jan 1, 1995

By Armstrong M, Kleingeld W. J

Current low prices for many metals mean that deposits have to be mined at high cut-offs (relative to their mean grade), which means that only a small percentage of mining blocks are above cut-off. Worse, at such high cut-offs, the blocks above cut-off are usually not grouped into convenient clumps for mining; they tend to be split into small isolated patches that are difficult to reach and hence expensive to extract. Companies wishing to acquire mineral properties have to be able to work out quickly what percentage of blocks are above cut-off and what can effectively be mined given the mining method envisaged. Moreover they need this information within a relatively short-time. The work presented here relates to typical South African gold mines (ie tabular orebodies) but the long-term objective is to develop tools for quantifying the impact of reserve breakup at high cut-offs for a wide range of underground mines including those that are not tabular. The mining method and the sampling procedure determine whether ore blocks can effectively be located and extracted economically. This project studied the impact of these two factors on the recoverable reserves for Witwatersrand gold mines. In order to be repeatable, the tests were done on numerical models of the deposit obtained by geostatistical simulations. To ensure realism, the orebody model and the mining scenarios were based on a specific mine. The recoverable reserves (ore tonnage above cut-off, the corresponding metal quantity and the average grade) were calculated for a wide range of cut-offs for four mining scenarios, as well as for the base case of free selection: ò Scenario 1: Blocks are taken if their true grade is above cut-off and if they are accessible from a raiseline (no information effect, no marginal blocks). ò Scenario 2: In addition to the accessible pay blocks, adjoining marginal blocks are taken (no information effect, + marginal blocks). ò Scenario 3: Blocks are taken if their estimated grade is above cut-off and if they are accessible from a raiseline. Here the estimator is the average of the face samples (information effect, no marginal blocks): ò Scenario 4: Accessible pay blocks are taken if their estimated grade is above cut-off. Adjoining marginal blocksare also taken (information effect, + marginal blocks). ò Free selection: All blocks whose true grade is above cut-off are taken irrespective of their accessibility. The results can be presented in different ways, for example by plotting ore tonnage above cut-off versus cut-off grade, or metal tonnage above cut-off versus cut-off grade etc. As expected, this shows the hierarchy between the five scenarios from the free selection base case to scenario No 2 (true accumulations, pay +

Jan 1, 1995

By J. D. Miller

Low-level radioactive contaminated soils (10-500 pci/gm) created by defense-related activities at certain superfund sites, such as Nevada Test Site (NTS), is a current environmental concern. Many of these contaminated sites may require appropriate cleanup and restoration, which could cost billions of dollars and put tremendous pressure on our limited financial resources. Therefore, the development of a selective flotation process to separate such radionuclides from contaminated soils should be considered. In this study, both a pure depleted UO2 sample and three synthetic UO2/soil mixtures were used to evaluate surface chemistry features and to examine the possibility for the flotation of fine UO2 particles from selected soils. It was intended that this model system would be a reasonable representation of contaminated soils such as those found at the Nevada Test Site which are reported to be contaminated by PuO2 fallout. The effect of reagent schedule, particle size distribution, and surface charge are discussed with respect to the flotation separation of the UO2/soil mixtures. It was found that both commercial fatty acids and reagent grade sodium oleate are effective collectors for UO2 flotation provided the pH is adjusted to the range of pH 8-9. The bench-scale flotation results successfully demonstrated that froth flotation technology can be used to remove UO2 from such model contaminated soils with appropriate flotation chemistry conditions which depend on the soil characteristics and other pretreatment procedures. In the best case, 90.2% of the UO2 was removed from a UO2/NTS soil mixture (119 ppm UO2) and the soil reduced in UO2 contamination from 119 ppm to 17 ppm in a single stage bench flotation. The impact of clay slimes present in the soil is revealed by the results which show that, for example, for a deslimed soil (28x400 mesh and 100 mg UO2/kg soil) 85¬90% UO2 recovery can be obtained with a reduction in contamination to 4.6 mg U02/kg soil.

Jan 1, 1995

By H. K. Olsen, B. Thomassen, H. K. Schønwandt, L. Grahl-Madsen, H. Stendal

The central part of the early Proterozoic Ketilidian orogen in South Greenland consists of an I-type granitoid batholith transected by four regional NE-SW-trending shear zones. Thebatholith was probably emplaced during subduction, from the south toward the Archaean craton in the north, in a sinistral transpressional system. A regional sediment sampling program covering5000km2shows a close connection between a gold-mineralized trend and one of the major shearzones within the epizonal facies of the batholith. The gold mineralization is not directly related to the major shear zones, but occurs in quartz-veined and silicified second-order structures. High-grade(up to 114 ppm Au over 6 m) low-tonnage mineralization is found within these second-order structures cutting both amphibolites and granitoids. The mineralization is characterized by negligible or small alteration halos. Gold is associated with various element combinations of enhanced As-Bi-W-Cu, which indicate that the mineralization is mesothermal in origin.

Jan 1, 1995

By Robert B. Parsons

"Finance Minister Paul Martin's second budget might be good for Canada's mining industry in the long run, but the budget raises a number of concerns for the industry in the near term. The budget papers suggest that the 25% resource allowance is not working as intended, and report that the Department of Finance will be reviewing this valuable allowance. The so-called ""large corporations tax"" rate will be increased. This annual tax, which is imposed on a corporation's capital even when the corporation is not in production, is particularly harmful to the mining sector.IntroductionThe Honourable Paul Martin, in his second federal budget, emphasized spending cuts and made only modest tax changes. However, two of these tax changes could have a serious impact on the Canadian mining industry: the proposed review of the 25% resource allowance; and, the increase in the large corporations tax rate.Personal Tax Measures Personal Tax Rates UnchangedThe government has been under political pressure not to increase personal tax rates. Mr. Martin's announcement that rates would not change will be popular."

Jan 1, 1995

By Tom B. Corry

INTRODUCTION Located approximately 48 km (30 miles) south of Dallas, Texas, use to be the site of the Superconducting Super Collider. For those of you unfamiliar with the project, this was a multi-billion dollar project taken on by the U.S. Government for the further advancement of technology, medicine, and science. Major components of the project consisted of a Linear Accelerator known as the LINAC; three accelerating rings known as the Low Energy Boosters (LEB), Medium Energy Booster (MEB) and the High Energy Booster (HEB); the East and West Campuses where the Inner Reactor Halls would have been located; and the 87 km (54 mile) main collider tunnel. Unfortunately, this all came to an end on December 6, 1993, with the termination of the project due to the Government's cancellation of funds. This paper will deal with the two of the underground contracts before the termination. These two contracts were the 1122 contract which ran from N25 to N40 and the 1130 contract which ran from N40 to N55. (See figure 1) The 1122 contract was awarded to us in July of 1992 and consisted of the excavation and support of six (6) shaft varying in diameter from 5.5 m (18 feet) to 8 m (26 feet) and ranging from 39.6 m (130 feet) to 61 m (200 feet) deep and the driving of approximately 13,100 m (.43,000 If.) of main collider tunnel. Our second contract, the 1130, was almost identical to our first

Jan 1, 1995

By John M. Boyle

The use of high vacuum mercury retort recovery as a safe and effective means of removing mercury from mercury hazardous waste solids rendering them non-hazardous and recovering mercury suitable for recycling.

Jan 1, 1995

By I. A. Cameron, F. Ham, R. Sriram

"Planned increases in electric furnace productivity and higher matte temperatures needed for the Sudbury Smelter's S02 Abatement Plan, require an improved matte tap hole. Since startup in 1978, the matte tap holes have been incrementally improved by the addition of copper cooling blocks around the refractory tap blocks. These improvements provided a tap block life of about 100 taps per campaign.In July 1993, a prototype matte taphole was installed in Number 2 Electric Furnace to develop the technology to increase tap hole service life. The design was based on a heat transfer model of the tapping process to determine candidate refractory materials and cooler arrangements. The prototype tap hole features increased copper cooling, high conductivity refractories and extensive instrumentation. Eight trial campaigns are reviewed outlining the performance of silicon carbide and graphite refractories and typical heat loads during tapping.IntroductionFalconbridge Limited operates two 36 MYA, 6 electrode submerged arc electric furnaces in Falconbridge, Ontario. The furnaces, commissioned in 1978, smelt a partially roasted nickel-copper calcine, to produce matte for converting and slag for discard. Additional details of the smelter are available in the literature(1-4).Each furnace was equipped with two matte tap holes located in the furnace end wall. Early in the campaign, matte tap holes were identified as a weak area in the furnace which could be improved. From 1981 to 1987, incremental improvements were made to the design by the addition of water cooled copper blocks. In 1993, a prototype matte tap hole was designed and installed in Number 2 electric furnace to develop the technology to increase tap hole service life. Improved service life is required to meet planned increases in electric fWl1ace productivity and the higher matte temperature needed for the smelter's S02 Abatement Plan.This paper reviews matte tap hole development since 1978; outlines the prototype matte tap hole design, refractory selection and installation; and details the performance of the prototype tap hole during the first eight campaigns."

Jan 1, 1995

By F. W. Brackebusch

Paste backfill is a pumpable, flowable, non-Newtonian fluid consisting generally of mine tailings and cement. Paste is prepared from dilute slurries of tailings. This is done by dewatering the slurries with conventional thickening or filtering. Backfill with a paste consistency is prepared by mixing dewatered tailings with cement and water to obtain the desired consistency of medium slump concrete. The paste is pumped with concrete pumps over relatively long (1 km or 0.6 mile) horizontal distances. More commonly, though, it flows by gravity down a mine shaft and then horizontally to the void being filled. Alternatively, cement can be added near the end of the pipeline. A certain proportion of fine particles <20 µm (<625 mesh) must be present in pastes but particles of aggregate can be added without significantly affecting the flow characteristics. Detailed testwork is necessary to design a system to prepare and place paste backfill. Testwork must determine dewatering characteristics, strength of mixes and friction in pipelines. Plants must be well engineered and controlled with PLCs because high quality control is necessary to prevent plugged pipelines and excessive pressures. Relatively small amounts of cement (3% to 5%) produce stiff backfill material 1.5 to 3.5 MPa (217 to 507 psi). The advantages of paste backfill in a mining operation include reduced mine dewatering, labor and materials savings, reduced tailings impoundment requirements, good support properties and reduced spills underground. In certain cases where more than 30% of the weight of the ore is sold as a product, the entire tailings stream can be placed underground. Paste technology can he used for surface or underground placement of tailings.

Jan 1, 1995

By Nag D. K

The Dolphin Scheelite orebody is located near the old mining town of Grassy on the south-east comer of King Island in Tasmania. Surface open cut mining of the Dolphin deposit was conducted for a number of years, then the proximity of the sea and adverse stipping ratio led to underground mining. As a result of the variable orientation and dimensions of parts of the orebody a number of mining methods were practiced at the Dolphin mine until 1990 when a combination of high processing and surface site costs coupled with low tungsten prices led to the cessation of operations. In this paper the different mining methods practised are examined and critically reviewed. The more successful mining methods were developed with experience and improving equipment technology to the extent that the underground operation produced ore at the lowest unit cost during the final years of operation.

Jan 1, 1995

By J. Partyka, Trevor R. J. Kelly

This paper presents the results on noise testing of a fan only, as well as the results of a steel silencer and of flexible silencers that were connected directly to a fan. On-site facilities and free-field method set by the British Standards Institution were used to measure and then compare the fan only and different practical silencer configuration setups. In order to determine the fan-silencer combination that would give the maximum noise attenuation, total noise intensity, noise contributed to by the fan motor only, as well as aerodynamical noise created through air interacting with the fan parts were considered to obtain decibel readings for the octave bands. Subsequently, the optimal configuration found was the setup with flexible silencers on the fan inlet and the fan outlet. If only one silencer is used, it should be installed on the fan inlet. The aerodynamic noise affects the low frequencies. The flow noise is then overtaken at 1 kHz by the mechanical noise.

Jan 1, 1995

By Luis M. Chia

The direct dissolution of zinc in an organic solution of di-(2-ethylhexyl) phosphoric acid (D2EHPA) and kerosene was studied. The objective was to gain a better understanding of the fundamentals involved in the anodic step of the galvanic stripping process. Results showed that metallic zinc does dissolve spontaneously at ambient temperature by an electrochemical mechanism and the presence of additional oxygen activated the process. When oxygen was removed by prior nitrogen sparging, dissolution did not occur indicating a depolarizing cathodic reaction is necessary. The concentration of water in the organic also affected the rate of dissolution. A factorially designed experiment was made using four variables at two levels selected by evaluating results from previous screening tests. D2EHPA concentration, surface area and agitation were all found to be significant for the values chosen. Temperature was less significant and it was found that zinc dissolution is probably a diffusion or mixed controlled process, as indicated by the calculated activation energy of 6 kcal/mole.

Jan 1, 1995

By M. G. Bakker, D. D. Murphy, D. R. Spears

The US Bureau of Mines studied the mechanism of shear flocculation of silica with stearic acid. At pH 6 and 12, shear flocculation of silica was not observed with the addition of up to 4.5 x 10-4 M (5 lb/st) stearic acid. However, in the presence of 0.1 M NaCl at pH 6, shear-flocculation was observed at stearic acid concentrations = 10-4 M (22.5 lb/st). Adsorption of stearic acid on silica was studied using stearic acids spin-labeled with a doxyl group. The presence of the spin-labeling group did not greatly affect the shear flocculation properties of stearic acid. Adsorption of labeled stearic acid on silica was measured as a function of surfactant concentration with electron paramagnetic resonance (EPR) spectroscopy and gas chromatography (GC). The GC results indicated that the stearic acid was predominately adsorbed on the surface at concentrations above 10-4 M. From the EPR spectra, the formation of aggregates of stearic acid was apparent at concentrations of approximately 10-5 M (22.5 lb/st). The results are discussed in terms of a possible mechanism for shear flocculation.

Jan 1, 1995

By Ivo André

Sorption of copper ions from aqueous solutions by dried biomass of the aquatic plant Potamogeton luscens was studied at laboratory scale. The aquatic plant was collected in water resources in Brazil, washed, dried at 60°C and ground in a bladed mixer. Sorption experiments were conducted in agitated flasks and in a packed bed column. Maximum copper removal was obtained between pH 5.0 and 6.6 when copper was present in the ionic form Cu&apos;. Sorption followed the Langmuir isotherm with saturation attained at 35 mg/g. Free energy of sorption was found, to be of the order of -25 kJ/mol. Sorption kinetics data were better described by a second order reaction and rate constants were calculated in 0.030 1/(min.mg) for - 4.0 mm particles and 0.081 1/(min.mg) for - 0.59 mm particles. Removal of metal ions in a packed bed column showed that Potamogeton luscens biomass can be used in several sorption/dessorption cycles. After sorbent saturation, copper ions can be recovered from the loaded biomass by elution-with H2SO4, solution. Main mechanism responsible for heavy metal uptake was found to be ion exchange. Results are discussed in terms of the surface properties of the biomaterial, solution chemistry of copper ions and thermodynamics parameters.

Jan 1, 1995