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By Morris Wong

"An antimony-bearing gold ore was studied in a cyanide slurry containing 7 -20 ppm dissolved oxygen. 1 g/L NaCN at pH 9.5 and 48 hours retention time is required to extract 94 % of the gold from the 90 % minus 200 mesh ore by conventional cyanidation at a 7 ppm O2. As oxygen concentration was increased to 20 ppm, the conditions required to extract the same amount of gold were: 0.25 g/L NaCN, 16 hours retention time and 80% minus 200 mesh. Compared to conventional cyanidation, oxygen-enriched leaching was shown to reduce retention time by three times and cyanide consumption by four times. The kinetics of gold dissolution related to the dissolved oxygen concentration in slurry was expressed by following equation:XAu = 100 * (Kt + I0) / (1 + Kt + I0)where XAu is the percentage gold extraction; t is the retention time; K and Io are the slope and the intercept of the plot of XAu I (100 -XAu) vs. t respectively. The values of Kand Io depend upon the concentrations of cyanide and oxygen, the fineness of grind and the origin of ore sample etc.. A preliminary cost analysis was also performed to justify the use of oxygenating slurries.IntroductionGeneral:It was proposed almost 149 years ago (Elsner 1846) that oxygen is required for the dissolution of gold in cyanide solution. However, little attention were paid to oxygen application in the gold milling industry during the following one hundred years. Due to the constraints of gold price, reagent costs, refractory ores, and environmental issues in the past decade, the oxygen enhancement in the cyanidation process was introduced to the gold milling industry for increasing operation efficiency, reducing production costs, and meeting the requirement of environmental standard.The advantages of oxygen-enriched cyanidation have been reviewed by several investigators (Hague 1992, Jara et al 1992, Henderson 1989, Loroesch et al 1988, Elmore 1987, Cathro 1963). Common to all conclusions are the following advantages."

Jan 1, 1995

By Olli Järvinen

The precious metal refinery process is divided into the five process stages: 1 .copper/nickel leaching in autoclave 2. selenium roasting furnace 3. doré metal smelting furnace 4. silver electrolysis 5. gold recovery system. The process has been developed during the years in Outokumpu Harjavalta Metals, which treats about 600000 kg /year copper anode slime. The slime treatment process route in Outokumpu Pori plant has been developed from year 1941. During this period the process has been improved radically. The major changes has been the atmosphere leaching into the autoclave leaching, the sulfuric acid roasting furnace was changed into sulfuric dioxide / oxygen roasting. The old doré smelting furnace has changed into the TROF converter and the gold electrolysis / aqua regia process has changed into the quick hydrochloric acid leaching process. The current production in Pori plant is 30000 kg of silver, 1000 kg gold, 30000 kg of selenium and some hundred kg of platinum- palladium concentrate.

Jan 1, 1995

By R. Kanniganti

The primary problems of pillar design in seams subject to interaction are due not only to difficulties in predicting loading, but also to the often unsymmetrical nature of the stress fields. The effects of uneven stress fields on failure patterns within a pillar were studied wing a two dimensional finite element method. Lower seams, including ultra- close mining situations were evaluated considering conventional pillars. Pillar case study data for under mining were analyzed to determine if empirical trends in stable pillar sizing could be derived. Recommendations for multi-seam pillar design are made, based on anticipated loading conditions within a pressure bulb. Applications of the research results are demonstrated using case studies

Jan 1, 1995

By P. Tsang

To gain insight into the current status of pillar design practice in the underground coal mines of United States, a survey has been undertaken in the late 1993 and early 1994. A total of 552 room-and-pillar mines and 75 longwall mines have been surveyed to collect general, geological and mine plan information. The collected information are critically analyzed with special emphasis on the pillar design criteria adopted in these mines. A safety factor analysis has also been carried out for the pillars in room-and -pillar mines.

Jan 1, 1995

By Edgar Peek

Lixiviant regeneration is by definition a precondition for any hydrometallurgical process. In chloride hydrometallurgy either HCl or Cl2 has to be regenerated in order to establish an economically viable metallurgical process. One such regeneration process is widely used with steel pickling where HC1 is regenerated through the thermal decomposition of ferrous chloride in either spray roasters or fluid bed pyrohydrolyzers. This standard HC1 regeneration process deserves to be considered as a potential separation process, since thermodynamic calculations show that a fluid bed pyrohydrolyzer can function as a ferrous-nonferrous separator. Several nonferrous,metals such as zinc, lead and cadmium can be volatilized as a chloride under ferrous chloride pyrohydrolysis conditions. If such a nonferrous metal volatilization could be achieved in the case of slurry feeding of "contaminated" iron oxides, then this would increase the Fe/H2O ratio of the (process) feed and thus save on fuel per ton of iron, while yielding a marketable iron oxide product. Previous test work on synthetic materials revealed that the near-complete separation of zinc, lead and cadmium from iron oxide was possible in a pyrohydrolytic atmosphere, even if zinc was present as zinc ferrite (more than 99.5%). This investigation, which was carried out in a tube furnace at 1100 K has now been extended to treat synthetic zinc minerals and also franklinite ore. For the latter, it was found that 85% zinc volatilization could be achieved in 4 hours at 1300 K. It is postulated that complete zinc volatilization could not be attained due to the formation and/or presence of gahnite and hardystonite, which might be stable in HCl/H2O atmospheres at 1100 K. The effect of adding small amounts of calcium chloride to react with gahnite and hardystonite to give zinc chloride and both calcium aluminates and silicates is being discussed. Test work on slurry feeding of this complex ore in a recently constructed 4-inch diameter fluid bed pilot unit has been planned for the near future.

Jan 1, 1995

By S. Ajima

The Naoshima Smelter and Refinery is the most important copper operation of Mitsubishi Materials Corporation. There are a Mitsubishi Continuous smelter and a conventional type of copper tankhouse. The continuous smelter with 240,000 mtpy of anode production was commissioned in May 19914 replacing two existing smelters, i.e an original Mitsubishi Process line and a conventional reverberatory furnace line. In July 1992, the copper tankhouae was expanded for the purpose to close the gap of production capacity between the smelter and the tankhouse. The cathode production capacity was increased from 13,800 to 15,800 mtpm. By these plant modifications, the distribution of minor elements was significantly changed and the impurities load is getting on increase reflecting recent shortage of clean copper concentrates supply. The paper discusses the distribution of minor elements and the impurity control strategy at the smelter end the refinery.

Jan 1, 1995

By C. C. Clark, R. R. Backer, J. D. Vickery

This report presents the results of tests conducted by the U.S. Bureau of Mines to determine the transport characteristics of highly concentrated paste backfill mixes made from dewatered total mine tailings. The slurry concentrations of the mixes were all above 78 pct by weight with slumps ranging from 6.4 to 16.5 cm (2.5 to 6.5in). Laboratory material property tests and full-scale pumping tests were conducted using pipe diameters of 102,128, and 154 mm (4, 5, and 6 in) and a positive-displacement pump. The results indicated that the tested backfill mixes can be successfully transported as a stiff paste and identified the influence of and the interaction among the various mix and system variables.

Jan 1, 1995

By M. A. Giralico

Solvent Extraction (SX) technology has undergone significant refinements including outright process changes to achieve greater copper production rates with lower organic entrainment levels. LIGHTNIN has completed a detailed study aimed at improving on the conventional Holmes & Narver and Davy Power Gas type impeller designs1 by optimizing the mixing through the use of high efficiency pumper turbines instead of making system changes as others are doing. Since each individual installation requires a different design head and flow, LIGHTNIN has developed the R320 "family" of high efficiency, curved blade pumper turbines. These impellers are designed to maximize head and flow while reducing entrainment through lower power consumption, less shear generation and turbulence, elimination of air incorporation, production of the optimum droplet distribution, and lower tip speeds. These improvements also maintain the required mass transfer and copper recovery of the traditional impeller designs. The R320 impeller benefits have been quantified using Laser Doppler Velocimetry (LDV) and proven in multiple domestic and foreign installations at flow rates exceeding 15,000 GPM. Design comparisons of this improved impeller type versus traditional technology impellers in head, flow, power and entrainment are presented for review. In addition, the inherent benefits of axial flow, high efficiency impellers like the A3 1 0 and A6000 in auxiliary mix chambers will be discussed. The high flow, low shear characteristics of these patented impellers provide the necessary dispersion stability for mass transfer while speeding phase disengagement in the settlers due to low power and low shear input.

Jan 1, 1995

By Lyman G. J

The volumetric distribution of valuable mineral, or phase, within a set of particles is called the liberation distribution. To optimise a mineral processing plant it is necessary to know the liberation distribution in most of the streams, especially those adjacent to separation devices. Possibly the most common method of analysing ore particles is to section sets of similarly-sized particles. However, the observed sections can appear liberated even if the particle is composite. This means that the 'apparent' liberation distribution can be very different to the 'actual' liberation distribution. This discrepancy is called stereological error. One must then somehow estimate the actual liberation distribution using the apparent liberation distribution. This problem is called the liberation distribution problem and its solution is the subject of this paper. The solution is based on a sorting algorithm which uses geometric probability equations. These equations are based on the assumption that sectioning is isotropic and uniform. Apart from these assumptions the equations are completely independent of particle shape or texture. The algorithm is verified by numerical simulation and experimental methods. For the numerical simulations the correspondence between the actual and estimated liberation distributions is excellent. For the experimental methods, the agreement is not as good and appears to be due to experimental errors.

Jan 1, 1995

By Robert F. Holub

The U.S. Bureau of Mines (USBM) has tested a personal dosimeter for measuring radon decay products that is manufactured by Tom Scurry Associates. The tests were made to determine the accuracy of the dosimeter system for record keeping of radiation exposures to radon decay products encountered in mining. The radioactivity-detecting head is based on a design developed by the USBM, and the associated air pump was developed by the manufacturer. The dosimeter system was tested in the USBM radon chamber. The detecting head uses CaF:Dy thermoluminescent phosphors and is mounted on a self-regulating air pump. Batteries supply power sufficient for an 8-h shift. The dosimeter system is worn on the miner's belt. Dosimeter calibration tests were performed by the USBM. In addition, the pumps were tested and evaluated under continuous flow conditions. The results of these tests indicate that the Tom Scurry Associates Model DOSI600 dosimeter is suitable for general use in mines where record keeping for natural radiation exposure is required.

Jan 1, 1995

By H. Lyn Bourne

The is the 14th consecutive year for this column and the 13th in which the royalty data have been tabulated. Some holes still exist in the list of royalties that readers hopefully will fill. Construction aggregates - either sand and gravel or crushed stone - are the most common mineral commodity. In spite of their pervasive use nationwide, royalty information for these commodities has been difficult to acquire from some states. Readers can help. Share information about these missing states and next year there will be fewer states without information. Dennis Bryan sent a copy of a report, "Regional Appraisal of Mineral Materials: Carson City District, BLM." The report was authored by real-estate appraisers. It contains more than 50 references to leases of various construction materials in Nevada and nearby states. It gives a thumbnail sketch of each lease and is a good reference. However, the authors erroneously imply that the royalty rate and the in-place value are the same. Several of this year's new entries come from the report. However, the royalties for landscaping materials vary from state to state and by rock type. Some boulders used for landscaping in Nevada have a royalty reported at $1.10/t ($1/st). At the other extreme is lava from Idaho. Used for the same purpose, it has a royalty range of $11 to $18.70/t ($10 to $17/st). Chuanming Tian of Beijing, China has shared some information about the changing mineral royalty policies in China. China first implemented an oil and gas royalty in 1984. In 1992, the government expanded that to include iron ore. In 1994, the royalty policy was extended to all mineral commodities. At the same time, the royalty rate for iron ore increased tenfold.

Jan 1, 1995

By Paul D. Tavares, John Forbes, Eric R. Drooff

As the existing major U.S. - Canada rail tunnel was too small to accommodate double-stack container cars, Canadian National Railways is constructing a new parallel tunnel with a 50% greater diameter. Starting in Sarnia, Ontario, the new shallow-cover bored tunnel runs under a large research building and several other structures in an oil refinery before travelling under the St. Clair River. Maximum predicted settlements to be caused by the 9.2 meter diameter earth pressure balance TBM in the soft St. Clair till were in excess of 100 millimeters. As such, these settlements had the potential to cause severe damage and disruption to the existing refinery. In order to reinforce the soft clays below the refinery research building and other structures, and to compensate for settlement caused by the tunnelling, the ground improvement method of Soil Fracture grouting was successfully applied for the first time in North America. This paper will describe the details of both the soil fracture grouting application and the elaborate electrolevel remote monitoring system used.

Jan 1, 1995

By G. J. Desroches, E. Ozberk, M. J. Collins, B. D. Krysa, I. M. Masters

The zinc refinery of Hudson Bay Mining and Smelting Co., Ltd. went through a major modernization in 1993, when the roaster and the calcine and fume leach circuits were replaced by a new Sherritt zinc pressure leach plant. The HBMS plant, in Flin Ron, Manitoba, represents the first commercial application of the Sherritt two-stage zinc pressure leach process, with /00% of the zinc concentrate feed processed in autoclaves. The process design of the new plant required definition of the deportments of elements such as antimony, arsenic, chlorine, cobalt, fluorine, germanium, magnesium, manganese, selenium, tellurium and thallium. This paper describes the deportment of these elements in the commercial zinc plant during the first nine months of pressure leach operation, and compares these results with operations prior to the introduction of pressure leaching, and with the results of tests carried out in the She"itt laboratory during the process development phase.

Jan 1, 1995

By Ghassan Skybey

Australian coal mines uses state of the art technology in coal rib reinforcement. This paper highlights the development over the past 15 years in coal rib support technology, along with the advantages and disadvantages of each system. It also outlines the current trend in using coal rib reinforcement in speeding up the dowels installation to improve the current low drivage rate. An innovative cuttable dowel is discussed which improves the drivage rate. This new dowel is self anchoring it uses no resin anchor it has a 5 tonnes (5.51 tons) anchor capacity and can be fully installed in approximately 10 seconds.

Jan 1, 1995

By Grobler H. P, Chitombo G. R

Production blasting of Dc Beers Consolidated Mines Limited, Koffiefontein and Finsch Mines involves both uphole trough rings of 9 to I I holes and near vertical 360 degree compound rings of 42-54 holes. The rate of production from these stages is dependent upon being able to achieve a specified fragmentation size range and this has driven the derivation of blasting practices to consistently achieve this target fragmentation. At the Dutoitspan Mine, in Kimberley, where mining of the kimberlite pipe is by block caving, 100 per cent extraction of the undercut level by ring blasting is essential. If this is not achieved, pillars are formed which not only inhibit the efficient initiation of the caving process, but also concentrates load onto the extraction level, causing damage to draw points and pillars. These two case studies demonstrate the importance of achieving optimum blasting performance for downstream mining efficiency; ie fragmentation for increased productivity at Koffiefontein Mine and 100 per cent undercut extraction for efficient initiation of the caving process at the Dutoitspan Mine. The case studies also serve to highlight the long road towards blast optimisation taken by De Beers Consolidated Mines Ltd (Koffiefontein. Finsch, Premier and Kimberley Mines) since 1989.

Jan 1, 1995

By Christie A. B, Swain A, Brathwaite R. L

This study provides quantitative data on vein distributions within seven selected epithermal systems, four deposits hosted predominantly in rhyolitic rocks: Ohui, Wharekirauponga, Neavesville and Komata, and three major deposits mainly hosted in andesite: Martha Hill, Golden Cross and Karangahake. The technique of fractal analysis was used to help quantify vein distribution patterns. The fractal dimensions (D) obtained are related to the number of veins per metre, the degree of vein clustering, and vein thickness. An increase in any of these tends to increase the fractal dimension. It is the relative relationship of these parameters that is important for the characterisation of vein distributions, and the comparison of different deposits. Within the same systems, the rhyolites are characterised by lower vein thickness and vein density, but have a higher degree of vein clustering compared to the andesites. Sections that are deeper and more centrally located within the epithermal system and/or close to major structures, tend to have a greater degree of vein clustering, higher average vein thickness and density, and higher thickness to density ratios. This depth control is most pronounced in epithermal gold-silver systems because they have formed at shallow crustal levels where physico-chemical conditions change drastically both vertically and laterally. In addition to lithological and structural control at vein scale, deposit scale structure is of great importance in the deposition of economic mineralisation. Large open vein structures capable of sustaining high fluxes of hydrothermal fluid, favourable for the formation of large, high-grade gold deposits, are best developed in andesite sequences.

Jan 1, 1995

By Michael K. Rhodes

A 120 tonne per day BacTech bacterial oxidation plant treating refractory gold concentrates for Gold Mines of Australia's Youanmi project in Western Australia commenced operation September 1994. This was the first commercial application of the BacTech process. A pilot plant trial on concentrates produced from Youanmi ore was carried out at BacTech's laboratory in Perth. Results and measurements from this trial were used by Signet Engineering Pty Ltd to design the commercial plant. This paper cover the results obtained from the piloting, their implementation in the plant design and the initial commissioning of the full scale plant.

Jan 1, 1995

By G. M. Bernard

Cerro Colorado lies on the eastern edge of the Atacama Desert in the foothills of the Andean Cordillera of northern Chile. Compañía Minera Cerro Colorado SA (CMCC) operates Cerro Colorado. CMCC, headquartered in Santiago, Chile, is wholly owned by Rio Algom Ltd., of Toronto, Ontario. Cerro Colorado is located 120 km (75 miles)east of the port city of Iquique. Access is by 30 km (19 miles) of paved highway and 70 km (43 miles) of upgraded road. The mine site is located at an altitude of 2600 m (8531 ft) on a gentle west-sloping plateau adjacent to a deep canyon (Quebrada de Parca) to the north. Temperatures are moderate, ranging from 5° to 30° C (41° to 86° F) with an average annual rainfall of 20 mm (0.8 in.). The plateau is generally covered with 20 to 30 m (65 to 100 ft) of Quatemary sand and gravel overlaying bedrock. In the immediate vicinity of the Cerro Colorado deposit, a semicircular embayment has been eroded into a steep canyon wall that cuts through the surface gravels to expose a considerable section of the underlying bedrock.

Jan 1, 1995

This paper describes several sources of external dilution affecting the stope walls during underground sub-level and bench stoping. Factors which control ground behaviour such as the geometry of the openings, the influence of geological discontinuities, stress re-distribution and blasting practices are discussed. Crown stope instability due to stress concentrations induced by changes in the excavation geometry, is discussed and the most efficient ways to sequence blasting within a stope are analysed. Effects of undercutting by blasting, blast damage in the near field and cut-off slot blast designs are analysed. The influence of dynamic loading on the exposed walls as well as the practice of blasting fill passes within stope crowns are discussed.

Jan 1, 1995

By Golosinski T. S, Jorgenson J. D

Several methods are available for inspections of mine shafts. These involve use of inclinometers, moving beams, inertial platforms and decelerometers. Inspections which use decelerometers are of most interest since they allow assessment of conditions of shaft steelwork, conveyances and the shaft itself. This assessment is based on recording and analysing dynamic behaviour of shaft conveyances. Sample inspections of several WA shafts confirm feasibility of using this method for periodic shaft Inspections.

Jan 1, 1995