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By Jeffery S. Thompson

In this report, the effect of catalytic amounts of activators on gold dissolution in clear solutions with gold disks and with slur­ries of gold ores is presented. Activators are nitrogen and sulfur aromatic heterocyclic compounds, which catalyze the gold dis­solution reaction in cyanide and other lixiviant solutions. Gold dissolu!ion studies in clear solutions indicate that the catalyst must bmd to the gold surface to catalyze the dissolution reac­tion. A concentration dependence for activation is observed· the optimum catalyst concentration depends on choice of activtor lixiviant concentration, and solution agitation. Nitrogen and sul fur aromatic heterocycles catalyze gold dissolution in slurries of gold ores with cyanide and other lixiviants. The typical proce­dures of agitated leach and rolling bottles were used to evaluate gold leaching rates. Activation has been demonstrated with a variety of ore types.

Jan 1, 1996

By James L. Hendrix, Michael R. Straka, Emil B. Milosavljevic, Ljiljana Solujic, Neil P. Gallagher

Analysts that utilize the classical distillation procedures for cyanide analysis are often frustrated by the poor reproducibility and repeatability of these techniques. Capital intensive business decisions and environmental management regulations are exas­perated by the fact that the EPA/ASTM approved cyanide deter­mination methods produce data of questionable quality. Reliable cyanide values are important in monitoring the effec­tiveness of the cyanide detoxification procedures. Efficiency and cost of gold and silver cyanidation recovery can also be improved by precise cyanide monitoring in the process itself.

Jan 1, 1996

By Paul Hamilton, Brian Jones

Traditionally,relatively large gold mines in developing countries have relied on imported process plant engineering, design, pro­ject management and advisory skills. In 1995, there was a significant departure from this in Zimbabwe, when a locally based engineering company under­took and completed the construction of a one hundred and twen­ty thousand tonne per month capacity gold extraction plant for the treatment of sands/slimes residues integrated with run of mine ore. This paper describes the challenges of designing, construct­ing and commissioning a Carbon in Leach (CIL) gold extraction plant in a developing country, and discusses the various con­straints associated with it. In addition, the paper reviews the application of technology which is innovative to Zimbabwe, including the use of dewatering cyclone clusters, and two and a half tonne capacity elution/electrowinning convection units.

Jan 1, 1996

By Richard H. Johnson

The Castle Mountain Mine (CMM) is located in the eastern por­tion of San Bernardino County, Southern California, 70 miles south of Las Vegas. The CMM is a joint venture between Viceroy Gold Corp. (75% and operator) and MK Gold (25%). The CMM initially started gold production with an 8,000 tpd cyanide heap leach operation in February, 1992 when the first ore was crushed and delivered to the leach pads. Even during construction and commissioning, design work was under way to engineer and construct a 1,200 tpd Mill circuit to process the higher grade fraction of the ore through use of pulp agglomera­tion. The need for a grinding circuit became evident with the quantity of high grade material delineated during drilling and the amount of visible gold that the geologists were finding in the drill core and R.C. cuttings. Viceroy did not want to stack the higher grade ore on the heap, and it was clear that permitting a tailings pond would, at best, be a long drawn-out affair. An alternative to a tailings facility had to be found.

Jan 1, 1996

By G. A. Plakhin, A. V. Luganov, V. A. Luganov, G. V. Gorbatenko

In order to extract gold from the complex sulphur-arsenic bear­ing raw materials and to remove arsenic and sulphur from the process in an ecologically safe form we have studied oxidizing roasting of highly arsenic gold bearing concentrates with soda, leaching of cinders, processing of the obtained solution and extraction of gold from the cake. There were processed concen­trates containing from 5 to 28% of arsenic, 12-20% of sulphur in the form of pyrite and arsenopyrite. The content of gold in the concentrates was 4-75 git. The roasting temperature was changed in the range of 773-l 173K, the consumption of calcined soda was 75-200% of stoichiometric necessarily for bonding of arsenic and sulphur into the water soluble compounds, the dura­tion of the process was varied in the range of 10-120 minutes. Under roasting in optimal conditions up to 97% of arsenic and 95% of sulphur go into water soluble compounds. The out­put of cake is 65-70% of the concentrates. The extraction of gold from the cake is higher than from the raw concentrates. The technology has been tested on a pilot plant scale

Jan 1, 1996

By Brad Hewitt

Since Campbell Mine began processing ore, there has been a gravity gold recovery circuit. From 1947 to 1982, gravity gold was concentrated through the combination of jigs and mercury amalgamation. In 1982, jigs with concentrating table upgrading commenced and was utilized until the end of 1994. As of January of 1995 to the present, Knelson Concentrators in com­bination with concentrating tables have been employed to achieve a refinable product. An evaluation of the justification used for the last change is the focus of this paper.

Jan 1, 1996

By Paul D. Chamberlin

There are many unit operations applicable to the processing of gold/copper ores. Deciding which are most applicable to your ore can be done using a series of tree diagrams. The diagrams show generalizations, not definitive rules. And the listing of process alternatives on the diagrams is very limited although there are dozens to choose from. Three questions help point the way to proper process selec-tion: 1. How much gold is in the ore? 2. How much copper is in the ore? 3, What is the cyanide consumption when leaching the ore?Halogens can also effectively leach gold ores and gold/cop

Jan 1, 1996

By Lawrence Devon Smith

"Within the mining industry the term “due diligence” is used to describe a detailed data review, generally in connection with the purchase or sale of a mineral property, the approval of a large capital expenditure, or the borrowing of a large sum of money.The term originates in the requirement of the board of directors of a corporation to “act honestly and in good faith and exercise the care, diligence, and skill that a reasonably prudent person would exercise in comparable circumstances” (OBCA, 1994). Furthermore, the law assumes that a corporation (or its board) will have exercised due diligence in the acquisition of an asset and, therefore, knowingly (in the absence of fraud or deceit) will have taken on the liabilities and obligations associated with the asset (Nelson, 1994). This is the familiar “Buyer Beware”.Directors are liable for their decisions except “if the director relies in good faith up on financial statements of the corporation represented by an officer of the corporation or in a written report of the auditor, or a report of a lawyer, accountant, engineer, appraiser, or other person whose profession lends credibility to a statement made by any such person.”(OBCA, 1994).Hence the importance of reports prepared by professionals. They provide confirmation that the directors have exercised due diligence in the performance of their duties. For this reason these reports are referred to as due diligence studies."

Jan 1, 1996

By Thomas Havlik

It is proposed to realise the direct leaching, during which will be generated elemental sulfur and not sulfate or sulfuric acid as end product, under conditions that sulfur will not cover the leaching surface and Hot hinder the leaching course. The following improvements have been considered: -use of organic sulfur solvents -ultra high-frequency leaching -ultrasonic leaching -use of surface detergents or surfactants in leaching processes -simultaneously crushing and leaching These proposals are under investigation and preliminary results are promising

Jan 1, 1996

By MattelmSki M

Outokumpu Harjavalta Metals Oy has been producing nickel since 1962, based on conventional flash smelting technology followed by electrowinning of nickel. In the 1980s, a research project was initiated to develop a converterless direct smelting process to produce matte for further refining in the then existing refinery. The process was tested on a pilot plant scale at Outokumpu's research centre in Pori and was found to be viable. The process was named the Direct Outokumpu Nickel Smelting Process or the DON Process. At the turn of the 1990s, Outokumpu studied various options to develop its nickel business and the Harjavalta operations. As a result of this work, the DON Process was further developed to produce two mattes: low iron matte in the flash furnace to be leached in the existing leaching circuit and high iron matte in the electric furnace to be leached in the new leaching circuit. In Harjavalta's case, it was essential and important that the process could use the existing flash furnace and electric furnace without converters.

Jan 1, 1996

By Darrell M. Hladun, Linda M. Dufour

The benefits of computer simulation in the design of a refracto­ry gold autoclave facility is discussed. Three computer simula­tion programs used for autoclave design are briefly described in this paper. 1) METS IM® - A Process Simulation Software Package Developed by Proware: Mass and energy balances are conducted around the auto­clave and its ancillary processes. Results from the process simulation define process equipment requirements and are used for establishing operating costs. The p_rocess model integrates various unit operations including grinding, acidu­lation, pressure oxidation, counter-current-decantation, neutralization, cyanide leaching, and carbon-in-pulp or car­bon-in-leach. 2) ALGOR® - Finite Element Analysis (FEA): A computer software program is used in the design and analysis of brick lined pressure vessels, such as autoclave, heater, and flash vessels. This software creates a steady state thermal model, and accurately predicts temperature distribution throughout the entire vessel, including nozzles, which represent regions of high thermal intensity. 3) Compress©: A software package developed by Codeware used for the sizing of pressure vessel components, includ­ing shells, heads and nozzles, according to ASME Boiler and Pressure Vessel Code, Section VIII, Division 1.

Jan 1, 1996

By A. Goulsbral, D. Harrison, R. Dunne

A programme to reduce cyanide consumption at the New Celebration Gold Mine, situated 32kms South of Kalgoorlie, Western Australia, commenced in the latter part of 1990. Cyanide speciation studies at the time identified that the major loss and consequently consumption was due to the hydrolysis of cyanide, The use of artesian hypersaline waters of high magne­sium content on gold plants in Western Australian Goldfields has meant that economically viable operating pH values during cyanide leaching are around 8.9 to 9.5. The high ionic strength in these waters does to some degree retard the hydrolysis reac­tion. Notwithstanding this, the formation of hydrogen cyanide and its loss due to volatilisation is the cause of the major loss of cyanide on most gold plants in the Kalgoorlie Goldfields. This paper discusses the aspect of oxygen addition during cyanide leaching to decrease cyanide consumption and increase gold recovery.

Jan 1, 1996

By Ivan Caetano Machado

Good morning ladies and gentleman. During 1995 Prof. R. P. King (University of Utah Comminution Center) presented 2 papers on new horizons in comminution: "Comminution Research in the United States " was presented at the 1995 Meeting of the National Mining Association, while "Comminution: Meeting the Needs of Fundamental Research in the Mineral Industry" was presented at the 2nd SME Research Forum - 1995. In both papers a very interesting graph named "Energy usage for various comminution schemes" illustrated some poignant issues proposed by Prof. King. We do think that some of Prof. King's ideas might very well serve as "warm-ups" for this Comminution Panel Discussion, which are ultimately the goals to be reached by the 3-minute presentations. Thus, we shall be addressing in the sequence Prof. King's most relevant ideas (as well as introducing his graph), intending therefore show how important creative and state-of-the-art Mill Modeling is, if it is to become a Tool to Effective Cost-Saving Optimization Strategies.

Jan 1, 1996

By F. P. de Kock, P. West-Sells, B. Wassink, D .. B. Dreisingerl

During the cyanide leaching of gold ores containing copper minerals, aurocyanide (Au(CN)f) is produced and typically recovered using activated carbon. However, free cyanide, as well as cyanide associated with cuprous cyanide complexes, are generally not recovered from the barren liquor. This results in a significant economic penalty in high cyanide consumption due to the dissolution of copper. 1\vo different configurations of a novel method for the treatment of barren liquor streams for cop­per recovery and cyanide recycle are described. Recovery of copper and cyanide is affected using solvent extraction (XI 7950). Loaded organic is stripped with a high copper, high caus­tic solution which is electrowon to produce copper metal. Depleted electrolyte is treated with sulfuric acid to recover cyanide which is returned to the leaching circuit. Results of benchscale and mini-pilot plant experiments are presented.

Jan 1, 1996

By W. T. Plummer

• The SuperBowl is a fluidized bed, semi-continuous, enhanced gravity separator for gravity gold recovery. The market for this type of equipment has, until recently, been dominated by a single supplier. Many mineral processors have encouraged the SuperBowl designers to develop competitive equipment for obvious reasons. • The primary beneficiary of competition in this field will be the mineral processing community because legitimate competition fosters continuous improvement in product and price.

Jan 1, 1996

By Rebecca A. Miller, Terry M. Hertel

In-pit identification of neutral waste rock at the Zortman and Landusky minesites in Montana, by visual and chemical analy­ses, will assist in proper segregation and placement of rock so that soil and water resources can be protected. The use of too few or very general segregation criteria to identify neutral waste rock can result in ineffective waste rock segregation. Conversely, the use of overly restrictive criteria can result in the unnecessary loss of valuable reclamation material that would otherwise have to be mined elsewhere and hauled to the site. Recognition of nonre­active materials can be accomplished on a site specific basis with the use of visual observation and simple chemical analyses. The choice of chemical parameters used to analyze rock samples is constrained by the length of time needed to conduct the test. These analyses must require no more than 24 hours to complete so mining can proceed without delay. Limits set for the chosen parameters must be reasonable and defensible. To achieve these objectives over one thousand samples were collected at the Zortman and Landusky minesites and clas­sified by rock type, total sulfur content, paste pH, and net neu­tralizing potential (NNP). In addition, over 22 humidity cell kinetic tests were conducted to help corroborate static results for waste rock. Another 8 humidity cells were configured in series to test waste rock blending and waste rock/limestone capping alternatives as mitigation for acid rock drainage. Leachates were analyzed for pH, conductivity, alkalinity, acidity, sulfate, Al, Cd, Cu, Fe, Mn, Zn, Mg, and Cr in some cases. Petrographic analysis, as well as total sulfur content, paste pH, and static and kinetic test results identified three geochem­ically different waste rock groups: 1) Archean amphibolite gneiss and Paleozoic carbonates and shales, 2) Tertiary syenite porphyry, and 3) other less abundant Tertiary igneous and Archean metamorphic rocks.

Jan 1, 1996

By Terry M. Hertel

The chemistry of waters processed by Acid Rock Drainage water treatment plants can affect the Total Suspended Solids quality of the plant effluents. The sulfate ions in the ARD water will combine with the calcium ions from the lime that is used to adjust pH to form calcium sulfate. When the sulfate content of the waters to be treated is greater than about 1400 parts per mil­lion, the resulting calcium sulfate concentration will be approx­imately 2100 parts per million. This concentration is above the saturation point for calcium sulfate, and the salt will drop out of solution until the concentration falls below the saturation point. This "salting" phenomenon affects the total suspended solids of the treatment plant effluents by virtue of the fact that the salts will report to the filtration apparatus used for the analy­sis. This scenario is exacerbated as an effluent sample ages. Zortman Mining's water treatment plant effluent was being affected by "salting" during the spring and summer of 1995, and it seemed as though the effluents were exceeding the TSS lim­its; for no obvious reason. A testing program was initiated to verify an observation that "salting' was taking place. Treatment plant samples were collected and allowed to age, with TSS analyses being performed every day that the samples aged. Synthetic solutions were also prepared to study the "salting" phenomenon.

Jan 1, 1996

By Kam KM, Tran B

Statistical techniques of Box and Jenkins (1976) have been used to assess the existing control schemes and determine the dynamics of flash smelting furnace at the Kalgoorlie Nickel Smelter. Pertinent process variables, such as, oxygen flow, flux flow, matte grade and iron to silica ratio in slag, were considered in the analysis using routine operating data collected over two periods of operation. Results indicate inadequate control of some of the important variables. Dynamic characteristic parameters (dead time and response time) between a set of input and output variables were identified to improve optimisation of the existing thermodynamic model used for flash furnace control.

Jan 1, 1996

By Jinhua Wang

Based on engineering examples and theoretical analysis, the mechanism of chemical consolidation for fractured roadway surrounding rock was discussed. The chemical consolidating materials and three consolidating methods, that is, capsule, forced infusion and spraying, were introduced. Finally the application effects of the chemical consolidating technique to reinforce the fractured surrounding rock of roadways were analysed.

Jan 1, 1996

By R. J. Hickson

The giant El Abra copper mine project under development in Northern Chile will come on stream in early 1997 at a production rate of 500 million pounds of cathode copper annually. Ownership is 51 % Cyprus Amax and 49% Codelco. Cyprus Amax has construction responsibility. Total project cost is $1050 million. El Abra will incorporate latest operational technology with labor efficient practices to achieve world class productivity levels and low initial cash costs of about US $0.35/lb copper. Development procedures for the almost 800 million ton oxide deposit, as well as the hydrometallurgical processes selected for recovery of the copper values are discussed. Construction costs and pertinent technical data are shown.

Jan 1, 1996