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Contribution by G. Narsimhan It was with much pleasure that I went through D.F. Malan's excellent paper. The following explanatory and critical note has been the result of my deep study of the paper. Although by qualifications and experience I have been a chemical engineer, involved over four decades with problems in the modeling and simulation of transport-limited (heat and mass) chemical reactions in multi-phase systems, I have of and on interested myself in challenging problems in extractive metallurgy. This is the first time I have veered of to continuum mechanics, at the age of 71! Author's reply. I thank Professor Narsimhan for his extensive contribution to the paper. It provided me with the stimulus to derive an extended model. However, there are some inaccuracies in his arguments that need further discussion. Professor Narsimhan's main concern is that there is not a good enough fit between the derived viscoelastic Kelvin model and the experimental data supplied by Güler1 (see Figure l1 on page 218 of my paper). I will therefore explain the choice of a viscoelastic model in more detail and also make specific comments on the arguments given in his contribution.

Jan 1, 1996

By V. M. Torres

An empirical correlation to detennine laboratory mill grinding time has been developed. Grinding samples to 90 ± 5# below 147 micrometers was required for a flotation testwork at Companhia Vale do Rio Doce (CVRD) Research Center. The initial samples were all below 1 mm in size with different size distributions and work indices (Wi) ranging from 13 to 23 kWh/st. Grinding curves were determined for some initial samples. A correlation was developed between percent retained on 147 micrometers at a standard time and the time required to grind each sample to the required size. This correlation was then used to grind all samples, based on the preliminary grinding model. Finally, a statistical analysis with the size distribution of all samples was performed. The success of using the correlation was confirmed and an equation was determined using the data set.

Jan 1, 1996

By Animesh Jha, Chris Dometakis

"Without the use of a flux, only a poor dispersion of ceramic phase can be achieved. A molten-flux-assisted ceramic phase dispersion technique for producing aluminium alloy metalmatrix composites has been developed. In this paper, we report the physical chemistry for the dispersion of TiB2 in molten aluminium. In particular, aspects of the interfacial energy and the thermodynamics of the dispersion reactions are briefly discussed for enhancing the volume of dispersion phase in the molten metal and for controlling their morphology. This investigation also addresses the role of molten flux in the fabrication of AI-alloy mmc using a casting technique. The morphological aspects of the dispersion are explained on the basis of the classical theory· of nucleation.IntroductionMetal matrix composites (MMCs), have long been recognised as an important class of material due to their greater wear resistance, specific stiffness and temperature capability when compared to conventional monolithic alloys. Particulate reinforced composites produced by melt casting techniques have been amongst the first MMCs to achieve commercial market viability. The advent of melt mixing techniques such as the Duralcan™ process have enabled low cost, easily fabricated composites based on the AI-SiC and AIAlz0 3 systems to be produced. In this process, uncoated ceramic particles with diameters 10ltm and larger, are incorporated into conventional monolithic alloys with reinforcement levels up to 25 volume percent. The AI-7Si-SiC metal-matrix composites have good wear resistance, high strength, low density and high thermal conductivity. The combination of these physical and mechanical properties has become a major attraction for the fabrication of light-alloy composite disc rotor brakes for the automotive sector2. However, in silicon-free alloys, SiC is thermodynamically unstable above the composite melting point and is extensively attacked by the melt to form aluminium carbide3 :"

Jan 1, 1996

By S. Behl, S. Mathur

It was previously reported that dolomite samples from different locations showed varying flocculation behavior with poly(ethylene oxide) (PEO). In this study, a Florida dolomite sample was examined, and it was determined that palygorskite associated with dolomite was responsible for its flocculation with PEO. A detailed characterization of dolomite samples from different locations was made by electrokinetic, XRD and FT-IR analyses, and the relevance of these characteristics to flocculation with PEO is discussed.

Jan 1, 1996

By Mark S. Stagg, David E. Siskind, Stephen V. Crun, Willard E. Pierce

The USBM is studying the impacts of low-frequency blast vibrations on residences to assess both response and cracking potential. Complementing coal mining sites monitored in the midwest and east, vibrations were analyzed at a major construction site in southern Florida where potentially serious low-frequency blast vibrations were believed to exist.

Jan 1, 1996

By Igor Gonzales G.

Southern Peru Copper Corporation (SPCC) has recently completed the construction of copper leaching, solvent extraction, and electrowinning facilities at their Toquepala and Cuajone plants in Southern Peru. Much of the ore for these new operations is the result of the existing mining operations that have been in existence as early as 1959. At Toquepala, pre-conditioning and bacterial dump leaching of the sulfide ore that was too low in copper content to be processed through the copper concentrator began in 1987. The Cuajone heap leach operation is treating copper oxide ore that has been stockpiled since the Cuajone concentrator began operation in 1976. The pregnant leach solutions from the dump leaching at Toquepala and the permanent pad heap at Cuajone are combined into one plant feed solution. Adjacent to the large dumps at Toquepala, a solvent extraction and electrowinning facility has been constructed. The electrowinning facility has a planned annual production rate of35,000 metric tons per year Grade A cathode copper. Initial production of the cathode copper began in November 1995.

Jan 1, 1996

By J. A. Rose, A. S. Atkins

Environmental awareness has become a paramount consideration in the issue of planning and licensing arrangements for the disposal of wastes associated with mining operations. In this con- text the disposal of liquid tailings is a difficult and controversial problem with regard to environmental surface disposal. The paper outlines the use of Information Systems for decision support in the safe and environmental disposal of liquid tailings linked to conventional coarse refuse operations. This offers both an economic and an aesthetic approach to a historical perception of waste tipping in the underground coal extraction industry. The paper will demonstrate a prototype system that incorporates multimedia facilities which include data such as; voice comments, site photography, site plans and fluid flow circuits.

Jan 1, 1996

By Ernie Doell, Trung Nguyen

"In early 1995 Cluff Mining commissioned a newly constructed high density tailings thickener at its Cluff Lake uranium mill. The 85 ft diameter high density thickener is one of the first of its kind in North America, and incorporates the novel paste technology in its design to produce densified (in the range of 60 -65% solids) mill tailings suitable for stable deposition in the tailings management area. This paper discusses the impetus behind the installation of such an unconventional thickener, and the many trying experiences in making it operational.IntroductionCluff Mining, a wholly owned subsidiary of Cogema Resources Inc., is the operator of a uranium mine and mill complex at Cluff Lake which is located in northern Saskatchewan. Since 1980, the company has developed and mined out several different ore bodies within the Cluff Lake region for the production of uranium concentrates, commonly known as yellow cake. Based on the known ore reserves, the Cluff Lake operations are projected to last till the early 2000's.Tailings from the Cluff Lake mill have been discharged to a tailings management area consisting of a tailings pond and two facilities for primary and secondary treatment systems. The tailings pond has an impervious bentonite lined dam, and it is divided into a solids and a liquids holding areas. Until the beginning of 1995, the mill tailings were discharged in two separate lines to the solids pond; one line carried the slurry residue of 45-50% solids (w/w) from the CCD circuit, and the other discharged raffinate tails containing less than 1 % (w/w) gypsum precipitate. Supernatant in the solids pond is treated in the primary treatment system prior to discharging to the liquids pond. Figure 1 shows the site plan of Cluff Lake tailings management area.It has been estimated that by the end of 1995 the solids pond would be filled to about 60% of its design capacity, and probably would be full before the year 2000. Therefore, Cluff Mining had to consider a more efficient tailings disposal method that could extend the service life of the existing Cluff Lake tailings management area. A high density tailings thickener was believed to be the most practical and economical system for tailings disposal at Cluff Lake mine."

Jan 1, 1996

By Gao K, Wu C, Xia J, Burdett M

X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques have been adopted in this study, to investigate the structure of carbonaceous materials such as graphite, brown coal char as well as coke, in order to explain their dissolution performance during ironmaking. These materials have been selected for study since they are commonly used recarburizers in the metallurgical industry. It was concluded that the crystal structure in a carbonaceous material can have a significant influence on its dissolution into iron melts. The material with the highest degree of ordering, which is graphite, showed the best dissolution performance. In contrast, the material with the lowest degree of ordering, which is brown coal char, showed the worst dissolution performance.

Jan 1, 1996

By Robert Matusewicz

Ausmelt Technology has been applied to the recycling of spent pot liner (SPL) generated from primary alnminum production. The process is centered on the Ausmelt furnace, in which the SPL is converted under high temperature, oxidizing conditions to an HF containing gas stream and inert slag. fluorine is recovered from the SPL as HF gas and is concentrated and used to manufacture AIF) for recycle to the aluminum smelters. Approximately 87% of the fluorine can be recovered and converted to AIF), with the remainder being effectively tied up in the by product slag. Cost projections show that the recycling process will be competitive with other processes for SPL. The production and recycling of AIF) provides available credit that significantly offsets the operating cost of the facility. Ausmelt Technology for recycling of SPL is currently being marketed in North America by Ausmelt Technology Corporation in Denver, Colorado, and in the rest of the world by Ausmelt Limited of Dandenong, Australia.

Jan 1, 1996

By Yong Kuk Park

The horizontal cold chamber die casting process can produce a wide range of near-net shape, non-ferrous castings with small dimensional variation, excellent surface finish and very complex geometries. However, top quality die castings can be achieved only when optimal performance of the cold chamber and plunger is maintained during the molten metal injection phase of the process. Cold chambers (shot sleeves) are known to deteriorate fast and sometimes fail catastrophically because of poor design. Catastrophic fracture and wear due to deformation are leading causes to degrade quality, increase downtime and thereby decrease productivity and profitability. Therefore, a systematic approach to minimize irregular and adverse conditions which prevent an intended injection profile, is highly desirable. To eliminate them, design criteria for shot sleeves were developed using analytical tools and available experimental data. The correlation between design and mechanical failures of shot sleeves was shown by the data obtained from the die casting industry. Also, the relationship between die casting process parameters and deterioration/ failure mechanisms were carefully evaluated.

Jan 1, 1996

By Ross Gilders, Leo Cheung, C. David Desjardins

"For the past twenty years significant progress has been made in bacterial leaching. In fact, a recent article in the Northern Miner has cited that nearly all new copper production is based on bioleaching. The bacteria that play the predominant role in bioleaching is an obligate chemolithoautotroph called thiobacillus ferrooxidans. These bacteria thrive in areas rich in sulphide and prefer low acid media. In the simplest sense, they metabolize sulphide converting it to sulphate either as acid or as soluble metal sulphates. This process is well known because these bacteria generate acid mine water. Over the last five( 5) years, we have been carrying out development work on creating optimum bioleach conditions for the extraction of metals from sulphide rich ores and concentrates. Recently, a study was carried out on a byproduct sulphide concentrate produced in a tin flowsheet developed for the Mt. Pleasant Mine of ADEX Mining Corp. The objective was to determine whether a bioleach process might successfully leach this sulphide material which contains copper, zinc, iron and, what is more important, trace metals such as Indium, Gallium, and Bismuth. The current work describes the successful recovery of these metals achieving extractions of more than 80% by applying bioleaching techniques. An overview of this technical program forms the basis of this paper.IntroductionBio-Oxidation of metal sulphides has emerged to be one of the leading edge hydrometallurgical processes for the economic extraction of metals from ore and concentrates. The fundamental process involves the bacterial assisted oxidation of sulphide to sulphate yielding metal sulphates which can be subsequently leached by conventional means. The bacteria that play the predominate role is an obligate chemolithoautotroph named thiobacillus ferrooxidans (TF). These bacteria thrive in areas rich in sulphide and occur naturally worldwide. In fact, TF is responsible for generating acid in water (acid mine water) from exposed sulphide surfaces primarily through the oxidation of pyrite. TF bacteria thrive under the proper conditions of temperature and oxygen supply in the presence of sulphides and populations in excess of a million per millilitre (ml) of solution are achievable. Typically, at room temperature, the bacteria will bio-oxidize in a pH range of 1.0 to 3.0. Today, bio-oxidation has been applied commercially with great success for the extraction of uranium, copper, and gold."

Jan 1, 1996

By E. H. Cho, Q. Luo

Pittsburgh No. 8 coal, cleaned by conventional froth flotation, was oxidized in a 2-L Parr stirred bench-top autoclave. Autoclave tests were carried out for up to 5 hrs under the following conditions: 150 to 225ºC, 60 to 500 psi 02 and 15 to 60 g of coal per 600 mL of distilled water. The oxidation of coal was evaluated by measuring the total acidic group formed on the surface of the coal and by measuring the adsorption (under standard conditions) of calcium ion from a solution. The degree of oxidation of the coal increased continuously, without much leveling off, with increasing oxygen pressure. With increasing temperature, the oxidation of the coal increased sharply between 150 to 175ºC and then leveled off above 175 °C. The adsorption of calcium was >3% on coal oxidized under the most favorable conditions. The adsorption of calcium on coal increased sharply with increasing equilibrium pH. The loss in Btu was found to be sensitive to oxidation temperature. This study concluded that the optimum oxidation of coal is achieved over 3 hrs at high oxygen pressures (e.g., 500 psi) at ~170ºC. This study also concluded that, when measured in terms of calcium adsorption, Btu loss and reaction time, the oxidation achieved in an autoclave is far superior to that achieved in a fluidized bed.

Jan 1, 1996

By R A. Farnfield

Measurement of the environmental impact of ground vibration from blasting operations is based almost exclusively on the peak vibration level generated. This measurement is known as the Peak Particle Velocity or PPV. The recorded PPV is used to assess the impact of the vibration both in terms of structural damage and human response. Limits for vibration are almost universally quoted in terms of PPV levels and, as a consequence, blast design for vibration control is centred around techniques for the control of this peak value.

Jan 1, 1996

By J. K. Whyatt

The paper presents an approach to design a multi level room and pillar layout in a 40m thick seam overlain by a major aquifer. The design was required to maximise extraction with due consideration of the general stability of the workings, the potential water hazards, and spontaneous combustion risks due to air leakage between horizons. The approach utilised was a combination of empirical pillar sizing for water hazard control with numerical modelling to assess potential interactions between horizons. The numerical modelling allowed the size of interleaves, and the appropriate staggers to be optimised in terms of stress distribution. The stress distribution allows both the general stability of the openings and more importantly the permeability changes around the openings to be determined. The permeability of coal is sensitive to stress, and an empirical stress to permeability relationship, and theoretical permeability to flow leakage relationship has been applied to interpreting the relative spontaneous combustion risk associated with each of the proposed layouts. The final proposed design is a compromise between maximum exploitation of reserves and consideration of water hazards and of spontaneous combustion risk. Further more detailed design will be required as more comprehensive data on the geotechnical properties of the coal and overburden become available.

Jan 1, 1996

By P. Greenfield

The German steelmaking industry has come up with a novel solution to the problem of waste plastics-grind them into particles and use them in the steelmaking process. Plastics make ideal agents for removing oxygen from iron ore in blast furnaces, and save on oil and coal as well. The aim of replacing heavy oil and coal with plastics in blast furnaces is to use them as reducing agents as well as an additional energy source.

Jan 1, 1996

By M. Manrique

Various pyrometallurgical methods for treating Ilmenite and Zircon concentrates are reviewed. Laboratory experiments, using a thermal plasma reactor, have been performed to evaluate: the conversion of ilmenite to TiC or TiC-Fe and the conversion of zircon to ZrC or ZrC-SiC. Results are examined and possible processing routes are identified.

Jan 1, 1996

By Dae S. Young, Eleonora Widzyk-Capehart

A quantitative estimation of the size distribution of rock fragments is extremely important in mining, metallurgy and other geotechnical fields. This paper presents a new approach to the analysis of fragmentation. The method combines the practicality of digital image processing of the rock surface with the theoretical volume calculations based on the principles and laws of fractal geometry. The final volumetric distribution curve is compared with the results from traditional sieving indicating close agreement.

Jan 1, 1996

By L. M. Luckevich

Gypsum is a product from the neutralization of sulfuric acid by lime or limestone. This paper will discuss specifications for gypsum used in wallboard, cement and agriculture and the factors affecting its utilization potential. Process conditions during the neutralization which enhance or inhibit utilization potential will be included. In addition, this paper provides a technical and economic perspective of the gypsum industry in North America with a view to the factors affecting the utilization of synthetic gypsum in traditional applications. Current production and consumption of natural and synthetic gypsum in Nonh America are described and the impact of their differences on utilization options are discussed.

Jan 1, 1996

By D. Bruce Wilson

The reaction of oxygen and solid aluminum produces the well-known surface coating of aluminum oxide, Al2O3. Thermodynamic properties and kinetic mechanisms of this reaction are extensively documented. Less well-defined are the corresponding liquid phase reaction and reactions which would be characterized. as 'burning' of aluminum. This paper reviews the solid aluminum-oxygen reaction as a foundation for discussing the flammability of aluminum in oxygen-enriched atmospheres. Appropriate thermodYDan3ic analysis and kinetic reaction mechanisms are developed. Available models of aluminum burning are reviewed and evaluated, The appropriate information for design of engineering applications of aluminum in oxygen atmospheres? is summarized.

Jan 1, 1996