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The removal of tritium from tritiated water (-0.5 µCiIL) was studied by metallothermic reduction using aluminum. The influence of the three variables namely the aluminum powder amount, the NaOH concentration and the reaction time has been studied on the tritium activity reduction. The experimental results and statistical analysis showed that more than 85% of tritium can be removed from the tritiated water. Further work on the tritium recovery as well as efforts to totally decontaminate water by incorporating a cryogenic concept is currently pursued.

Jan 1, 1998

By Ellicott C, Webb N

In November 1996 the NSW Minister for Mineral Resources, Hon Bob Martin MP, commissioned ACiL Economics and Policy Pty Ltd to conduct a wide ranging review of safety within the New South Wales mining industry.The review was a response to a disturbing number of fatalities which had occurred in the industry during the Minister's term of office together with a number of alarming near misses where serious failures in mining systems had occurred. Shortly after the review was commissioned, four mine workers died at Gretley Colliery near Newcastle. An inquiry is currently being conducted into the incident.

Jan 1, 1998

By D. E. Woolley

The rate of reduction of iron oxide from calcia-silica-alumina slag by carbon in liquid iron has been measured over the temperature range 1400-1600°C by monitoring the rate of carbon monoxide (CO) evolution. Slags containing ferric iron have been used in order to study the reduction of both ferric and ferrous cations. Results show that ferric iron is reduced before ferrous iron, so that the ferrous iron concentration increases initially. It is also shown that the rate constant, k, decreases at low reaction rates, or, equivalently, at low concentrations. The authors conclude that the reaction occurs in two periods. During the first period, ferric iron is reduced to ferrous iron. During the second period, ferrous iron is reduced to metallic iron, and the rate-limiting step during the second period is the mass transfer of ferrous cations in the slag phase to the slag-metal interface.

Jan 1, 1998

Political events during the past decade have caused businesses throughout the world to think globally. Countries once closed to free market enterprises are now open and seeking out foreign investment to help improve the well being of their populations. The mining industry has always been a global one. Today, though, the industry has become even more global. The driving forces behind this include the opening up of higher grade, lower cost mineral deposits in undeveloped and developing nations. In addition, permitting delays in the United States, coupled with stricter environmental guidelines and a general anti-mining attitude, have forced the mining industry to look outside US borders. The Mineral Economics and Management Society (MEMS) took as the theme of its seventh annual professional program "Economic Globalization of the Mining Industry." About 100 people attended the conference held in Arlington, VA in late March. Speakers included members of the investment community, academia, government and the mining industry.

Jan 1, 1998

By Janene Barter

Telfer Gold Mine treats both gold/copper oxide and sulfide ores in a remote location in the Great Sandy Desert, Western Australia. Currently, the oxide gold ore is treated in a conventional CIL circuit by blending the low and high grade copper ores to minimise cyanide consumption and allow smooth operation. The sulfide ore is treated through a flotation circuit to produce pyrite and copper concentrates. The pyrite concentrate is treated in the CIL. Copper concentrate is stockpiled and sold to a smelter for further processing. In recent times, as the depth of the pit has increased the copper head grade has also increased, to the point where the ore was becoming uneconomical to treat. In addition, it was desirable to reduce the amount of cyanide reporting to the tails dam both from an environmental and economical viewpoint. Newcrest Mining Limited engaged GRD Minproc Limited to evaluated a process to reduce the amount of cyanide entering the tail dam with consideration given to copper recovery. From this investigation, the Sulfidisation, Acidification, Recycle and Thickening (SART) process was selected. A detailed testwork program for SART was undertaken with the objective to design and construct a SART plant at Telfer. This paper outlines how the SART process was chosen and summarises the testwork that led to the design of the SART plant. It also touches on some of the important issues for designing this type of process.

Jan 1, 1998

By Jinsheng Chen

The major functions of longwall headgate entries are to provide access ways to the outby submains or mains for coal transportation and to the longwall face for fresh air and for transporting men and material during longwall operations. Any roof control problems such as cutter roofs or roof falls in the outby headgate entries could result in significant production delays to the longwall face and may be a threat to miners' safety Under a thinly laminated immediate roof and a high horizontal stress field, even a longwall headgate entry that has an angle of less than 45 degree to the maximum horizontal stress may experience roof deterioration in the outby headgate if the longwall panel mining sequence and retreat direction are not properly considered. This paper attempts to analyze the causes of the roof control problems experienced in the longwall gate entries at our Cumberland and Emerald mines in Pennsylvania and to determine the optimal longwall panel mining sequence and retreat direction for the future mining area at Cumberland

Jan 1, 1998

By W. H. (Bill) Jay

The destruction of cyanide creates a significant impost on the financial returns of gold mines. These losses increase substantially when ores containing cyanide-soluble copper are treated. Failure to remove or destroy free or WAD cyanide before it is discharged into tailings dams has, on a number of occasions, led to significant fish, bird and animal deaths. Thus, the retention of cyanide within the leach circuit and the recovery or removal of stable metal cyanide complexes needs to become standard practice for all gold mining operations. Furthermore, reducing cyanide purchases will minimise the quantity of cyanide transported to the mine site thereby reducing the opportunity for spillage of this chemical. Many different physical and chemical methods have been investigated for the removal of cyanide from process solutions. All cyanide destruction methods create a financial impost on the economic viability of the gold mine. To reduce these costs, the recycle of cyanide and the economic recovery of the metals solubilised by cyanide is of prime importance. The alternative methods currently in use, or under consideration for the treatment of copper cyanide, entail high reagent costs, produce the recovered metal in a contaminated form and require the safe handling of hydrogen cyanide. These processes will be briefly discussed within this report Environmental and financial benefits are enhanced by recent laboratory and pilot plant studies conducted by Oretek Limited. The Oretek CPC process for the recovery of copper and the recycle of cyanide from copper cyanide-containing solutions does not require pH adjustment to the alkaline cyanide leach conditions. Copper ions are coordinated to a water-soluble and/or an organic soluble polychelating agent under alkaline conditions and the cyanide ions are displaced Membrane separation, or phase separation of the polychelated copper from the cyanide ions enables the cyanide ions to be recycled and the copper to be directly electrowon from the polychelating polymer. The polychelating polymer is then recycled. Ion exchange resins and solvent extraction systems which may be incorporated into the above process will also be discussed in detail.

Jan 1, 1998

By G. Tapia, R. J. Kelley

Empresa Minera de Mantos Blancos S.A. operates two copper mines in Chile: Mantos Blancos and Mantoverde. Oxide ore is processed by acid leaching followed by SX-EW to produce copper cathodes. In order to define the leach process adequately for each ore, an extensive metallurgical testwork program was carried out during the feasibility study for each of these projects. A combination of heap and dump leaching was selected for Mantoverde, while a modification to the existing vat leach operation was selected for Mantos Blancos.

Jan 1, 1998

By Seeley D, Buckley N, Goodall J

Improving the performance and reducing the costs associated with export logistics chains is critical to the competitiveness of export coal mines. The fundamental practices associated with the use of export logistics chains made up of mine, trucking, rail and port operations are being challenged by the advent of third party operators on rail systems and the use of the Internet.Whilst individual mines can improve their processes to drive down their mining costs, they face major challenges in their endeavour to improve the performance of export logistics chains and reduce the significant logistics costs of moving coal from the mine to export ships, via the shared infrastructure of rail systems and ports. There is an increasing realisation that global competition is not only between mines but between coal export regions that are defined by their rail system and ports infrastructure.

Jan 1, 1998

By J. R. Batista, J. C. Young

Leachates from gold heap-leaching mines may contain selenium concentrations as high as 2 mg/L. Previous studies report satisfactory selenium adsorption by activated alumina from relatively "clean" drinking waters. However, the findings of these studies cannot be directly applied to the treatment of mine leachate where other ions compete for the alumina adsorption sites. This study evaluated the adsorption of selenium from a mine leachate to develop design parameters for a full-scale activated alumina process. The study revealed that 68% of the selenium in the leachate could be removed by alumina at pH levels greater than 5.0. At pH levels less than 4, silica was poorly adsorbed by alumina, and selenium adsorption was improved. Silica adversely affected the selenium adsorption capacity.

Jan 1, 1998

By Williams DJ, Battino S

The rapid crushing technique for the measurement of gas content of coal consists of accelerating the rate of gas desorption from coal by crushing. This technique allows the determination of gas content in the space of hours rather than days or weeks as required for the traditional slow desorption technique. The crushing technique is used particularly when gas content determinations are urgently required for mine safety purposes. The method is now routinely used in underground coal mines of NSW and to a lesser extent in QLD. Despite the rapidity and efficiency of this method, concerns have been raised upon the reliability of the method to deliver accurate results. Experience in Australia has shown that there is in fact some discrepancy in results between gas laboratories using the rapid crush technique. The development of rapid crushing techniques for seam gas content measurements in Australia and the main causes of variability in the gas content test results were investigated. The gas laboratories participating in the gas content testing were CSIRO Division of Coal and Energy, BHP Technical Services and GeoGas Pty. Ltd.

Jan 1, 1998

By J. K. Wolski

This paper addresses the effects of using jet fans as booster fans in mine ventilation networks. A method was developed to determine the pressure generated by jet fans using the momentum theory. The influence of a reduction cone and other ventilation parameters on the jet fan pressure was analyzed. Verification experiments conducted in the Waldo Mine are described. Examples are given to demonstrate the conditions for the effective use of jet fans.

Jan 1, 1998

By J. M. Dean, R. L. Grayson, R. D. Begley, G. L. Winn

Evidence has accumulated indicating that cultural change toward safer workplace behaviors is beginning to occur systematically in the coal industry. Through a range of programmatic mining company successes, enforcement and litigative actions, economic responses to competition and integrated efforts by federal and state agencies, a broader participation of safety and training professionals is being achieved to address prioritized workplace problems at mines. Small steps in workplace-related improvements have been realized already, but the trends in industry safety statistics, coupled with focused programmatic initiatives, indicate that more definitive and systematic steps are occurring to improve safe behavior in the workplace routinely.

Jan 1, 1998

By Shane Andrews, Gustavo Vasquez, S. K. Varma

"The effect of solutionizing time on the corrosive wear behavior of 2014 aluminum alloy has been studied using the impact and continuous mode of scratching techniques. The transient currents (TC) evolved during the scratching of the alloy shows a linear dependence between the TC and the solutionizing time. Higher TC values at longer solutionizing time may be associated with the changes in the concentration of quenched-in vacancies, grain sizes and dislocations generated during scratching. These factors can either create (a) anodic sites or (b) pitting corrosion resulting in the generation of transient currents. The results have been compared with the similar study carried out for 6061 aluminum alloys. This 6061 aluminum alloy shows similar behavior but the rate of TC generation per unit solutionizing time is much lower than 2014 aluminum alloy. The morphological changes in the impact scratches and the TEM investigation in the scratch have been presented in this paper.IntroductionThe technique of studying corrosive wear of composites of 6061 aluminum in the monolithic and reinforced forms has been reported in the literature [1]. Two modes of scratching, consisting of impact and continuous, in a corrosive environment indicate that the composites, containing 0.10 and 0.20 volume fractions of alumina particles (VFAP), have higher corrosive wear rates than the monolith. A graph between the transient current (TC) generated during the impact scratching as a function of solutionizing time at 540°C indicates linear relationship between them. A similar slopes for the composites were observed and the TC values were less for the composite containing lesser VFAP."

Jan 1, 1998

By M. F. Almeida

"Due to the randomness of all factors influencing the sintering operation, a two-stepped procedure is proposed to find the best way of using stocked fines at a plant producing Fe-Mn alloys for the steelmaking industry. The approach is based on the following: (1) predict the result of the sintering operation by establishing the best multilinear regression model using some of the characteristics of the loaded material; and (2) find the best solution under a minimizing cost criteria by solving a linear optimization problem using the regression equation plus constraints on the feed and product. IntroductionSome tests carried out using 20% to 30% of sinter in the material loaded into a 60 000 KVA Tysland-Hole electric furnace producing Fe-Mn alloys for the steelmaking industry indicated: (1) a meaningful decrease in the off-gas temperature and, consequently, a better energy use due to the material higher porosity; (2) more uniform heat distribution as a consequence of the electrode reaction zone enlargement; (3) an improved furnace control resulting in a smoother operation; and (4) a decrease in gas production facilitating the off-gas treatment. For some years, this plant used only the coarse fraction of the Mn ores, thus stocking all the received and own-generated fine particles. In view of the mentioned results, a strategy for increasing the use of stocked fines was formulated, including a step where it was necessary to decide which components and respective quantities should be used in the blends to be sintered (Almeida, 1984).It is well known that several factors affect productivity and energy consumption in sinter production, also influencing the product quality. Raw materials characteristics, namely chemical and size composition, affect permeability to gases and may or may not allow a deeper bed. In general, finer ores decrease permeability, increasing electricity consumption by fans, but due to their higher specific surface area, react more completely with other components in the mixture. For coke granulometry, a compromise must be obtained in order not to burn it too quickly nor to widen the flame front, therefore decreasing productivity. Decreasing coke in the blend also acts in sinter bonding, decreasing its consistency and increasing crushing and return fines. Moisture addition also influences components mixing, pre-agglomeration, bed permeability and, consequently, sintering productivity. Therefore, optimum conditions must be established for both a given sintering plant and the components in the feed (Dawson, 1993)."

Jan 1, 1998

By James M. Kramer

This paper introduces an analytical approach for the determination of the vertical stress in the chain pillar system between two adjacent longwall panels. The development of this approach is based on the principles of fracture mechanics and superposition. Some empirical formulae have also been incorpomted into the development of the mathematical model. The mine entries and longwall gobs are treated as Mode I cracks in an infinite plate while the resistance of gob material and the characteristics of the pillar yield zone are considered as the distributed forces on the surface of the cracks. An user- friendly computer program has been developed to facilitate the calculation involved in this task. This approach is as accurate as the numerical analysis methods but requires much less expertise and computer hardware and software to apply

Jan 1, 1998

By A. Perry

Latin America is in the path of economic growth characterized by increased privatization, joint-venture projects, and reduced trade barriers. Privatization is changing the industrial operating mode from Government-owned/Government-operated to a privately-owned/government-regulated regime. The establishment of joint ventures, such as in construction and management of infrastructure, energy and mining projects, and deregulated industries (electricity/gas/ telecommunications), is now a common practice in the region. These changes, coupled with the growing awareness of environmental protection issues, have led to a sincere effort on the part of the countries of Latin America to establish reasonable environmental regulations and controls (RERCs) for all industries, including mining and energy, for the benefit of present and future generations. However, RERCs require further consideration of many factors with respect to environmental, geologic, economic, and social impacts in the region. The process must find a balance between the need to sustain profitable operations and the need to adequately protect the environment. While striving to find a balance between continued industrial profitability and environmental protection, the RERCs must be scientifically sound, pragmatic, flexible, and enforceable. There has been worldwide attention focused on the environment, and international symposia have been held on such issues as global warming, water pollution, air pollution, and hazardous wastes. Organizations such as the United Nations (UN) and the Organization of American States have performed rather extensive studies on the environment for various industries and activities, and have developed some broad general plans to address environmental concerns. This technical information is available for the asking, and should be considered a starting point for countries embarking on the passage and enforcement of their own RERCs.

Jan 1, 1998

By A C. Robertson

Studies by Tennent, Isokangas Pty Ltd (TIP) have indicated that underground quarrying of backfill may be a cost competitive option for providing backfill for specialised situations in underground mining. Situations where suitable bulk fill material may not be available on the surface, and where the total cost of setting up a fill distribution system are prohibitive, could favour the mining of fill material underground adjacent to the stopes being mined. Considerations include environmental impact, scheduling, surface constraints and total costs. The examples quoted in this paper, and the case studies are based on the authorsÆ personal observations and experience.

Jan 1, 1998

By Marcel Vallée

Abstract -Traditionally, samples collected for mineral deposit evaluation have been viewed without explicit reference to reliability, with the illusion that a true value is attainable from a few samples and verifications. For exploration, mineral deposit estimation and production quality control the following definition is proposed: "a sample is a small quantity of material relative to the geological mass it represents, collected according to a systematic procedure, of measurable reliability, from which the grade/quality of the mass which it represents may be estimated, based upon appropriate protocols. This paper will concentrate on the actual rock sampling process. Too often, sample size has been, and is still viewed as a matter of convenience, leaving out representivity considerations, despite the importance of samples on project estimation. Linear samples (chips, channels, drill), panel samples, broken rock or mining samples and very large samples are considered. Collection procedures and quality control protocols to improve the representivity of non-mechanical samples are proposed.

Jan 1, 1998

By N. Shi, T. C. Lowe, S. J. Zhou, M. L. Lovato, Y. T. Zhu, J. A. Valdez, W. R. Blumenthal, M. G. Stout

"A major problem of short-fiber composites is that the interfaces between the fiber and matrix become a limiting factor in improving mechanical properties such as strength. For a short fiber, a strong interface is desired to effectively transfer load from matrix to fiber, thus reducing the ineffective fiber length. However, a strong interface will make it difficult to relieve fiber stress concentration in front of an approaching crack. Stress concentrations result in fiber breakage. We report in this paper an innovative approach to overcome this problem: reinforcement morphology design. Short-fibers with enlarged ends are processed and used to reinforce a polyester matrix. The initial results show that the bone-shaped short-fibers produce a composite with significantly higher strength than can be attained with conventional short, straight fibers.IntroductionThese interfaces between the fiber and the matrix in short-fiber composites play a critical role and, in many cases, become a limiting factor in improving such mechanical properties as strength and toughness of the composites (1-4). For a short fiber, a strong interface is desired to effectively transfer load from matrix to fiber. A stronger interface can reduce the ineffective length at both ends of the fiber and, therefore, can increase the effective length that carries load (5-9). However, with a strong interface it is difficult to relieve fiber stress concentration -in front of an approaching crack; and such stress concentration can result in fiber breakage (10, 11). This effect is particularly severe for ceramic matrix composites, because of their low matrix toughness and lack of plasticity. Even for a composite with a highly ductile matrix, such as plastics, too strong an interface may still cause successive adjacent fiber breakage and subsequently reduce composite toughness (1, 11). On the other hand, a weak interface significantly decreases the fiber load-carrying length due to ineffective load transfer and complete fiber interfacial debonding and pullout during loading. A compromise in the interfacial bond strength will also compromise the load-carrying potential of short fibers."

Jan 1, 1998