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By Thomas F. Hagelien, Stein Tore Johansen, Svend Graadahl

"The dross appearing at the surface of an aluminium melt consists, in addition to aluminium, of mainly oxide films but also other non metallic inclusions. The inclusion particles are often poorly wetted by the metal and accumulate at the metal surface. However, in impeller stirred reactors for melt refining stirring may be exceedingly strong and inclusions accumulated at the metal surface may be entrained into the bulk metal. Concerning inclusion removal, such effects may deteriorate the effectiveness of melt refining.In this paper we investigate the surface entrainment of buoyant particles in a water model of an impeller stirred refining reactor. Under varying operating conditions the particle concentration in the bulk liquid is measured by laser light attenuation. The observed entrainment of particles is explained theoretically and metallurgical consequences of the findings are discussed.IntroductionIn the modern cast house continuos metal refining and casting is well established. One of the most distinct advances in metal refining has been the introduction of degassers which introduce bubbles into the metal. The bubbles act to remove dissolved elements together with nonmetallic inclusions. In the most efficient degassers stirring by different kind of rotors is applied to increase mass transfer and inclusion removal. However, it has been known from experience in the cast house that for violent stirring the concentration of some types of inclusions may increase from inlet to outlet of the reactor. This phenomenon has so far been attributed to production of dross in the reactor due to oxidation of metal. Due to removal of inclusions by bubbles the dross layer inside the reactor must be expected to increase in thickness by time. The removed inclusions and produced oxides due to strong stirring is removed at regular interval by the operators of the degasser. However, a fundamental understanding of the phenomena which take place in and below the dross layer is lacking. In the present work we add buoyant particles to the surface of a refining reactor and investigate how these particles may be entrained and dispersed into the liquid depending on the flow conditions. Similar investigations for gas stirred ladles have been performed by Taniguchi et al [1] who found that below a critical gas flow rate all particles are trapped at the surface. Above the critical gas flowrate the surface velocity are sufficiently high to entrain the particles. In this situation it looks like all particles are ready for the melt and a balance between terminal velocity and turbulent dispersion determine the concentration in the liquid."

Jan 1, 1999

[Costs may be classified according to their source and behavior: Scale of aggregation - Total costs - Unit costs Time period for which the costs are charged - Product costs - Period costs Controllability and relevance for decision-making and control - Controllable costs - Noncontrollable costs - Sunkcosts - Opportunity costs Their basic source - Production costs (also termed manufacturing costs) - Nonproduction costs How the costs change with changes in activity - Fixed costs - Variable costs - Semivariable costs Traceability to individual units of production - Direct costs - Indirect costs Use in planning (budgeting) and subsequent control - Standard costs - Normal costs ]

Jan 1, 1999

By R. Conor, O&apos

Wastewater treatment systems, both industrial and municipal, produce large quantities of sludge which require disposal. Sludge disposal poses significant environmental liabilities, logistical problems, and economic burdens. Minergy Corporation has developed and implemented several new technologies for the recycling of such high volume wastes as sludge, ash, and foundry sand. These technologies perform mineral recovery from the waste material, converting them into construction material and industrial feed stocks which are inert, marketable products. With a continuously operating processing system installed at the waste source, these technologies reduce handling, eliminate downstream liabilities, and reduce disposal costs.

Jan 1, 1999

By R. Bruce Tippin

The silicates represent the largest and most common group of minerals on earth. Yet in spite of the chemical similarities, numerous mineral processing plants worldwide are operating successfully to yield varied commercial products for numerous uses. The silicates that are commercially produced in the United States by flotation include quartz, feldspar, mica, spodumene, talc, kaolin, and wollastonite. The operation of several plants and the conditions affecting mineral separation by flotation are described. Because the process is usually dictated by the desired market, specifications for the most common products are provided. Potash is a basic fertilizer component, along with phosphate and nitrogen. Potash is typically produced from underground evaporite beds or recovered from natural brine solutions. Flotation of potash is unique in that it is processed in a saturated salt solution. The potash flotation process is outlined and several commercial operations are described.

Jan 1, 1999

By K Thorpe

Amorphous silica deposits have been identified at Tikitere and Taheke near Rotorua. Two areas at Tikitere have been surface sampled and drilled to establish a resource of amorphous silica in excess of one million tonnes. A pilot plant was established to develop a process to manufacture a high quality super pozzolanic material. This development process took two years before a commercial product was introduced to the construction industry in 1996. The amorphous silica product, marketed as Microsilica 600, is used as a pozzolanic material to produce high quality strong and durable concrete, sprayed tunnel linings, mortars and grouts. Microsilica 600 has been used locally and exported to 11 countries.

Jan 1, 1999

This is an abstract from Environmental Service and Technology (Vol 32 No 20 1998) which will be o finterest to South African Mining and Metallurgical Scientists, involved in chromium mining and Metallurgical processing. Maybe the scourge of our dams and reservoirs?the water hyacinth can be put to good use! The novel technology of phytoremediation embraces plant accumulation processes for the cleanup of toxic heavy metals and organic chemicals. Several plant species have been identified that are excellent hyperaccumulators of a number of heavy metals, e.g., Brassica juncea (Indian mustard) and Thlaspe caerulescens (Alpine pennycress). Other speciesincluding Myriophyllum brasiliense(Parrot?s feather), Salixsp. (willow), and Popullussp. (poplar) have also demonstrated phytoremediating abilities.

Jan 1, 1999

By M. C. Ruiz

The conventional pyrometallurgical methods to treat copper sulfide concentrates include generally, one or more oxidizing steps where the formation of SO2 gas can not be prevented. From the economical point of view and the nature of some of the processes in which SO2 is produced, its complete capture is not feasible; therefore an important fraction is released to the atmosphere as fugitive emissions. In this research, the reduction of chalcocite was studied in the presence of lime as an alternative method, which overcomes the pollution problems related to SO2 emissions. The effect of temperature, time, concentration of carbon and CaO on the reduction rate were studied. Among these variables, temperature affects most the reduction rate. Conversions over 95 % can be obtained in less that 20 minutes at temperatures over 1000 ° C. The measured partial pressures of the gaseous components indicated that the chalcocite reduction proceeded through the gaseous intermediate species CO, C02, and the overall kinetics was controlled by the Boudouard reaction. The kinetic model In(1-X)= kt fits well the experimental data. Apparent activation energy of 3 14 kJ/mol was calculated for the temperature range of 900 0C-1050 °C.

Jan 1, 1999

By Chengliang Jliang, B. K. Parek, Xuxin Shao

Of the impurities present in phosphate ore, dolomite is the most difficult to remove due to the similar chemical compositions of the impurities and also adsorption of dissolved species of dolomite onto phosphate. A new amphoteric surfactant was found to be a suitable collector for separation of dolomite from phosphate. Flotation results showed that the new amphoteric collector had a high flotation selectivity for dolomite in wide pH ranges. The flotation study of francolite and dolomite in each other's supernatant demonstrated that the dissolved ions had little effect on the selectivity of the new collector, but were detrimental to the flotation separation using sodium oleate as collector. A phosphate concentrate with 35.2% P2O5 with 90% recovery was obtained using 290 g/t of the amphoteric collector from a mixture of francolite and dolomite containing 26.2% P2O5. The rejection of MgO was 81.41%.

Jan 1, 1999

By P. Barrios

Over a period of one year, an in-depth investigation was carried out in a conventional copper refinery to understand the behaviour of silver in copper electrolysis. The increase in silver content in the cathodes increases almost linearly with the duration of electrolysis, and the silver content of the electrolyte between the electrodes shows similar behaviour. The silver content of the cathode deposited daily depends directly on the silver concentration of the electrolyte and this, in turn, is strongly influenced by its internal temperature. The average temperature between the electrodes rises from the first to the second and to the third crop, because of the increase in the distance between the electrodes and the heat generated by the passage of the current. The mechanism of dissolution of silver from the anode, and its passage to the cathode, are discussed. Following the change to the Isa system, it was proved that the results and conclusions are analogous. Based on these results, a reduction of more than 20% in silver losses in the cathodes was achieved.

Jan 1, 1999

By Arthur G. Hunt

Smelting using the direct-to-blister process commenced at Olympic Dam on 31 July 1988. The unique nature of the Olympic Dam ore body led to the selection of the direct to blister smelting process. Significant improvement in the design of the furnace and the understanding of the fundamentals of the process and its operation has occurred in the 10 years of operation. The paper will discuss the operation of the #1 Smelter and the design, preparation for start up and early operating experience of the #2 Smelter.

Jan 1, 1999

More than 100,000 people from 110 countries involved in the construction aggregates and ready mix concrete industries are expected to attend Conexpo-Conlagg '99 in Las Vegas, NV March 23-27. The exhibition, the largest of its kind in the Western Hemisphere, takes place every three years. It is held at the Las Vegas Convention Center, Las Vegas Hilton Center and Pavilion. The show serves as a venue for con- tractors and others involved in aggregates construction to view the latest in equipment, technology and services. More than 1,500 exhibitors will use more than 147,200 m2 (1.6 million sq ft) of indoor and outdoor exhibit space. Attendees include presidents and company owners, sales and marketing managers, general managers and project managers. An estimated 20% of the attendees will be from outside of the United States. New for the Conexpo-Conlagg '99 show is a 3,715- m2 (40,000-sq ft) Information Technology Pavilion. This event, organized by AIEIC Systems, will showcase computer technology for the architectural, engineering and construction industries. Shown in the pavilion will be the latest developments in cost management, estimating, bidding, project management and accounting. In addition, the Information Technology Pavilion will demonstrate the latest in computer-aided design software, systems and services. Conexpo-Codagg '99 will also emphasize live demonstrations of exhibitor's products. Individual exhibitors will demonstrate their machinery so attendees can see the latest technology in action. Because the Conexpo-Codagg exposition is so large, "shows within a show" have been created to help attendees locate the products and services best suited to their interests. Seven product concentration areas will be formed. Each area houses suppliers and manufacturers of similar products or services.

Jan 1, 1999

By D R. Swinbourne, T Lehner

Study of the distribution of minor elements between copper matte andfayalite slag is important in determining appropriate methods tomaximise the recovery of valuable metals and the rejection of harmfulelements. Boliden Mineral AB operate a large copper smelter in northern Sweden, where they had noted that the loss of silver to the slag in the settling furnace appeared to be a direct function of the tin content of the slag. This work was aimed at determining whether or not this was a cause-and-effect relationship. Copper matte containing approximately 50 wt per cent copper and small amounts of silver and tin was equilibrated with silica-saturated fayalite slag at 1250¦C, then quenched. The matte and slag were then analysed for their silver and tin contents. It was found that there was no relationship between the silver distribution and the tin distribution. The silver matte/slag distribution ratio had a value of 120 ¦ 40 while that for tin was 2.8 ¦ 0.3. It is suggested that the most likely cause of the relationship observed at the Boliden smelter was matte entrainment in the slag.

Jan 1, 1999

By P. E. Donaldson

Since 1992, Falconbridge has made available to the international copper industry, Kidd Creek's licensed refinery process technology under the name of the Kidd Process. This has resulted in the supply and installation of permanent cathodes and associated product handling equipment to refineries in Canada, the United States, South Korea, Chile and Mexico. These installations accommodate both electrorefining and electrowinning processes. The growth and industrial acceptance of the Kidd Process has generated technical advancements in the areas of product random sampling, corrugation, marking, labeling, product tracking and data acquisition. In a different area, the expanded development of custom materials processing at Kidd created a need to advance technologically. The process-related problem of high nickel concentrations in refinery electrolyte compromised an increase in current density to >300 A/m2. The need for nickel removal resulted in Kidd Creek's newly developed Nickel Recovery System. The effective and economical extraction of nickel, along with reduced antimony and bismuth levels, reduces bleed stream volumes and/or neutralization costs and simultaneously produces a marketable nickel carbonate product.

Jan 1, 1999

By R. L. Kloberdanz

Compania Minera Disputada de las Condes S.A. (Disputada) is proactively implementing closure and reclamation planning activities at its mining and beneficiation facilities (mining facilities) in Chile where regulations governing mine reclamation are not yet fully in place. These activities are being implemented to improve currently employed measures to protect human health and the environment and to enhance reclamation and facilitate future closure with regard to these areas when mining is completed. As part of this process, Disputada, with the assistance of Shepherd Miller, Inc., developed recommendations and guidelines for future closure and reclamation of the Disputada sites. These recommendations and guidance incorporate planning and operational and post-operational design considerations and practices, and standards used by the mining industry and regulatory agencies around the world. The criteria presented in the guidance are based on achieving conditions that will be suitable for the anticipated post-mining land use. This paper discusses the process and approach taken, and the results.

Jan 1, 1999

To design an apparatus that advances the state of the art in gas content testing equipment. The goal of the design is to incorporate improvements in testing sensitivity/accuracy, durability, and ease of operation over existing equipment. It is also desirable for the new design to successfully perform gas content determinations of multiple chemical species from a rock sample.

Jan 1, 1999

By D Vrkljan, Z Ester

Excavating the building pit for the World Trade Center at Rijeka, it was necessary to blast over 160000 m3 of hard mass in fused condition. The building pit is located at a densely populated residential part of the main Croatian port Rijeka, close to the railway-track and traffic routes of the town. The permanent seismic monitoring points are foreseen on endangered housing and infrastructure facilities around the pit during designing and excavation of it. The seismic monitoring has been performed on 15 permanent points by occasion of over a hundred production and continuous blasting operations. The article considers the speeds of ground oscillations depending on applied maximum quantities of explosive charge according to fire degree, total quantities of explosives at the mine-field, structure of explosive charge, applied delay of mine boring and lines initiation mode and rock mass structure

Jan 1, 1999

By Gabriel Voicu, Marc Bardoux, Ross Stevenson, Nuno Machado, Jean Lafrance

"Abstract - Paleoproterozoic gold is found in two different volcano-sedimentary sequences and intrusive bodies separated by 600 km within the Guiana Shield. The 2148 Ma St-Élie granite intruded volcanic-arc sequences of the Paramaca Group, whereas the 2096 Ma Omai stock penetrated backarc/ island-arc sequences of the Barama-Mazaruni Group. Positive ?Nd values suggest that both suites lack Archean crustal contaminants, which is consistent with an origin in an oceanic arc setting.The St-Élie deposit is characterized by quartz-dominant vein systems with minor metallic minerals, represented chiefly by pyrrhotite and pyrite. Biotite, calcite, and chlorite are the main gangue minerals. The alteration haloes at St-Élie feature a strong potassic zone, which is absent at Omai. The ore-controlling structures are ductile and the vein emplacement is related mainly to contemporaneous, high-angle ductile shear zones. The St-Élie deposit formed at temperatures >350°C. The stable isotopes values are compatible with a magmatic or metamorphic source.The Omai deposit is characterized by quartz-dominant vein systems with minor metallic minerals, represented mainly by pyrite. Ankerite, scheelite, albite, and chlorite are common gangue minerals. The vein emplacement is syn- to post-deformation and it is related mainly to brittle shear zones with low-angle, stockwork networks and breccia zones. The Omai deposit formed in a temperature range between 250°C and 170°C, much lower than the St-Élie deposit. The stable isotope values are compatible with mixing between deep-seated fluids of metamorphic or magmatic origin with surface- derived fluids.These differences between St-Élie and Omai are interpreted in terms of their depth of formation. Alteration patterns, structural elements, and paragenetic assemblages indicate that the gold at St-Élie was most probably emplaced at a mesozonal depth, whereas the Omai setting yields evidence for epizonal conditions."

Jan 1, 1999

By Dale S. Preece, Stephen H. Chung

"A discrete element computer program named DMC_BLAST (Distinct Motion Code) has been underdevelopment since 1987 for modeling rock blasting (Preece & Taylor, 1989). This program employsexplicit time integration and uses spherical or cylindrical elements that are represented as circles in two dimensions (2-D). DMC_BLAST calculations compare favorably with data from actual bench blasts (Preece et al, 1993b)."

Jan 1, 1999

By Gungor Tuncer, Ali Kahriman

"In bench blast design, not only the technical and economical aspects, such as block size, uniformityand cost, but also the elimination of environmental problems resulting from ground vibration and airblast should be taken into consideration."

Jan 1, 1999

By P K. Smith, R J. Ryan, W R. H Ramsay, D C. Arne, F P. Bierlein

Turbidite-hosted, mesothermal lode gold deposits in Paleozoic metasedimentary rocks of the Buller Terrane, western South Island have a similar geological history and genesis to the Paleozoic lode gold deposits ofVictoria, Australia and Nova Scotia, Canada. In all three regions the gold deposits are hosted by interbedded meta-sandstone and meta-argillite that have been folded and regionally metamorphosed to greenschist facies, and locally in Nova Scotia to amphibolite facies. The gold deposits are typically narrow, structurally controlled quartz veins associated with dilatant zones in reverse faults or fold-related fractures. The principal vein types include: bedding parallel or concordant veins, discordant veins, saddle reefs, and stockwork veins. En-echelon and "ac" type veins are sometimes also gold-bearing in Nova Scotia. The contrasting competency of the host meta-argillite and meta-sandstone beds is an important factor in vein formation, particularly for the bedding parallel veins, which are typically developed within meta-argillite beds or along the contacts between meta-argillite and meta-sandstone. Veins found within meta-sandstone units are generally discordant. The deposits in Victoria are well known for their bedding-parallel veins, saddle reefs ( Bendigo ) and leather jacket reefs (Ballarat). Bedding-parallel veins are also common in Nova Scotia , along with a few examples of saddle reefs. In contrast, vein formation probably occurred later in the deformation history of the Reefton and Lyell goldfields, with most veins being bedding discordant and more typically aligned with the axial plane cleavage of the folds rather than bedding planes. The quartz lodes in one deposit, Globe-Progress, strike approximately perpendicular to the bedding and fold axes. No saddle reefs have been recorded from the Buller Terrane. Mesothermal vein morphology reflects the amount of fmite strain, the strain rate, competency contrasts, lithotypes, and the confirming pressures to which the system was exposed. On the basis of comparable depositional depths and rheologies of the host rocks, a controlling factor influencing the development of different vein styles (and timing) might be finite strain, as exemplified by the tightness of folding in the host rocks. Folding appears to be tighter in the Victorian rocks than in either the Buller Terrane or Nova Scotian rocks.

Jan 1, 1999