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By D Craw

Sulphur-rich minerals such as authigenic pyrite (FeS2) are commonly associated with coal mine workings. Metallic elements such as arsenic (As), copper (Cu) and zinc (Zn) are enriched in the pyrite relative to their concentrations in the surrounding environment. Exposure of pyrite and coal to air and water results in a series of oxidation and hydrolysis reactions that are commonly catalysed by species of Thiobacillus bacteria. These reactions lead to a lowering of the pH in the drainage waters (acid mine drainage, AMD) and subsequent mobilisation of trace metals in environmentally significant concentrations. This study assesses the spatial distribution of As, Zn and Cu concentration in water in relation to pH and Eh (redox potential) downstream from the tailings at the Wangaloa opencast lignite mine in southeast Otago. This mine was abandoned in the late 1980s due to a decrease in the economic viability of mining the lignite. The area is showing the characteristic symptoms of AMD, which is detrimental to the health of several Pinus radiate growing on some of the tailings. The pH of the drainage waters can get as low as 2, and in some instances, lower, but it returns to near neutral (pH 6.5) up to 200 metres down stream from the base of mine waste piles. It is well documented that the atmospheric oxidation of pyrite is catalysed microbially, causing a substantial decrease in the pH of the drainage waters. Acidification is then counteracted predominantly by natural abiotic remediation processes occurring downstream.

Jan 1, 1999

By R M. Bhatawdekar, A I. Theresraj, H S. Venkatesh

Wadi Limestone Quarry is one of the largest captive mines of Associated Cement Companies Ltd, India. The mine management wanted to extend the excavation as close to the plant as possible for maximum exploitation of the deposit. The National Institute of Rock Mechanics and the management of Wadi Limestone Quarry carried out comprehensive investigations to evolve a methodology to control vibration and flyrock within safe limits.

Jan 1, 1999

By H. Virtanen

Outokumpu copper refining operations have a long history of expansions and application of new technologies. Outokumpu is a name known around the world for technological excellence in the field of base metals, and part of the policy of operations is continuous investment and investigation in new technologies. The results of this hard work sometimes are immediate and sometimes take years. The work done during the last years at the Outokumpu Harjavalta Metals copper refinery, together with a sister technology group Outokumpu Wenmec, has started to bear fruit in terms of the following radical developments and advances that are and will be applied to assure Outokumpu's position as the technology leader and a low cost and safe producer. Some of the developments discussed include the new anode and cathode design, mechanised electrode handling, cell design incorporating features facilitating full automation, automated short circuit detection and removal, automated on line anode slime removal, and high efficiency and intensity refining.

Jan 1, 1999

By Christian Trassy, Pierre Proulx

"Inductive plasmas are now commonly used in material processing: spraying, powder synthesis, densification or spheroidization. An inductive discharge presents, in the coil region, recirculation eddies due to the Lorentz forces, resulting in an axial backflow. If the central jet is strong enough to ""pierce"" the recirculation this axial backflow disappears on the centerline, but the external layer of the injection flow is skimmed by the remaining eddy, and particulates are rejected to the discharge periphery. To avoid this disadvantage, it is common to introduce the injection pipe inside the discharge, so that its outlet is positioned after the recirculation eddy. The powders remain confined in the axial zone, to the expense of shortened residence time.In order to increase the efficiency of the particle trajectories, a double flow injector has been designed. It enables the particles to travel closer to the axis, while the outer schrouding gas is skimmed and passes through the electromagnetic eddies. This injector is made up of two concentric tubes. The powders are injected with the carrier gas in the inner tube. A schrouding gas is injected in the annular space between the inner and the outer tubes. The powder is confined to the vicinity of the axis, resulting in a more homogeneous thermal treatment.Tungsten powders have been spheroidized with and without this device. Using the double flow injection, the spheroidization yield has been increased from 70 % up to 95 %.The design of such an injection device has. been studied and improved using numerical modelling. Another useful tool, a visualisation technique described elsewhere, has been used for the experimental study, that drastically simplifies the comparison between experimental and theoretical results: injecting yttrium oxide into the discharge results in a colorful display of the 4000 K isothenn: the ""cold"" zone, below 4000, appearing as red, and the ""hot"" zone as blue. Furthermore, it is of great industrial interest since it is a very cheap and efficient way to obtain a picture of an important isotherm."

Jan 1, 1999

By Kris Inwood

"In 1879, when the Dominion government initiated its controversial program of industrial promotion, iron smelting in Canada was limited to one company producing coke iron on the mainland of Nova Scotia and three small charcoal blast furnaces in Quebec. There was no steel production. By the eve of the First World War, iron and steel were being produced in very large quantities, the companies active in 1879 had disappeared and new centres of integrated iron and rolled steel production at Hamilton, Sydney and Sault Ste. Marie had come to resemble the industry as we know it today. The most dramatic change was that at Sydney, Nova Scotia, where in the early 1900s, two steelmaking companies established works. The Sydney developments have been explained as the result of resource discovery and technical change. W.J. Donald, in his authoritative account of the Canadian iron and steel industry, observes:(1) ""The most rapid growth of the Canadian iron and steel industry has occurred since 1897 ... The remarkable growth has been caused largely by the new conditions of the industry. The discovery and use of Newfoundland ores, together with the availability of Cape Breton coal, has made the Nova Scotia industry not only possible but profitable .... It is a safe conclusion that the Canadian industry would not have been an important one, had it not been for the discovery of the Michipicoten and especially the Wabana (Newfoundland) ores:' Donald also argues that metallurgical progress had been necessary to render the ores valuable. ""Newfoundland ores ... contain a considerable amount of phosphorus, and were made available for steel-making by recent inventions:' The purpose of this paper is to re-examine Donald's story. It will be argued that the origin of steel-making at Sydney is somewhat more complicated than Donald has indicated. The difficulty with Newfoundland ore extended beyond its phosphorus content and a resolution required more than the basic open hearth furnace identified by Donald. Moreover metallurgical change was only one of several developments necessary to induce industrial investment at Sydney. Surprisingly, however, the discovery of iron ore in the late nineteenth century does not appear to be part of the explanation."

Jan 1, 1999

By J. O. Marsden

The Candelaria copper-gold mine is located approximately 25 km south and east of Copiapo in Region III, Chile. The original concentrator was designed to treat 28,000 t/d (30,800 stpd) of chalcopyrite-bearing ore through a circuit consisting of a single 11.0 m (36 ft) diameter SAG mill, two ball mills, conventional rougher and scavenger flotation, column cell cleaner flotation, and ceramic disc filtration. The plant was commissioned in August 1994 and quickly reached capacity and expected levels of metallurgical performance. In May 1996, a decision was made to double the capacity of the concentrator by the addition of a second line of equipment. The expanded facilities were commissioned in October 1997, less than 18 months after the decision to proceed, and well within the budget. The original concentrator facilities were replicated or duplicated as much as possible, however, a number of important equipment changes were made to take advantage of industry developments since the original concentrator was designed. These included the use of Eimco 120 m3 (4,200 ft3) cells for rougher and scavenger flotation and the installation of a Svedala VTM -800 Vertimill for regrinding. This paper describes the rationale behind these changes and explores the reasons for the success of the project.

Jan 1, 1999

By Marco Antônio Siqueira Rodrigues

The possibilities for treating rinse waters fiom chromating bath by electrodialysis are discussed together with the possibilities of optimizing the treatment process for waste reduction and reuse of water and chemical products. An industrial effluent with 4600 ppm of Cr(VI), besides other metallic contamination, was used as work solution. This solution has been recirculated on an electrodialysis cell of three compartments, using exchange membranes Selemiom AMT and CMT. A migration of dichromate ions into the anodic compartment was obtained, so that an extraction of circa 99.9 % of Cr(VI) present on the solution was observed, resulting in water with a Cr(V[) concentration of 4 rnd. These results show that electrodialysis can be used to treat these effluents, and this water could be reused as rinse water. The solution of the anodic compartment, consisting at the beginning of the experiment of H2S04, 0.1 N, reached 7200 mg/l of Cr(VI). This concentrate could be reused on the chromating bath itself.

Jan 1, 1999

By Rauno Peippo

Horizontal Waste Heat Boiler (WHB), today's proven and dominating technology for copper smelter gas cooling, has been utilized by the industry for over half a century. During this time development has taken place in geometry, flow characteristics, cleaning technology and design details. This development has been driven by improved understanding of the specific process requirements, gained both by wide experience and by utilizing new emerging design tools, like computer flow modeling. It had to wait till mid 90's to unite effective and proven Spring Hammer cleaning technology and the process benefits gained by gas guiding vanes or baffle wall in the copper smelter WHB design. The new design has demonstrated improvement in gas cooling efficiency and the process conditions down stream in form of less dust sticking problems in the boiler and precipitators. Reduced weak acid production has also been reported as a result of the design. The theoretical aspects, computer flow modeling results and actual benefits measured in old smelting line modernization are discussed. Experience £tom modernization projects such as Phelps Dodge, Atlantic Copper, Mexicana de Cobre, and Nippon Mining, Saganoseki, are discussed. In mechanical design there has been development resulting improved gas tightness with less corrosion and better control of dust sulfation. An essential improvement is the integration of the boiler hopper and dust removing conveyor. Having no steel plate casings in the hopper and conveyor section but using of boiler tube membrane instead eliminates thermal expansion differences. The dust conveyor will be effectively cooled against hot dust lumps falling down while the acid dew point corrosion is prevented in the cooler sections of the hopper. Conceptual features are presented of a new generation Copper Flash Smelter WHB presently under construction at Boliden Mineral, Skelleftehamn, Sweden, where the latest development and innovations are adopted.

Jan 1, 1999

By M. J. Blattman

The problem of measuring the amount of rock removed during a given time interval is faced by most milling operations. Many methods have been developed with varying degrees of success, dependent upon the mining method and the availability of usable data. The Rosebud Mine has been in production for nearly two years, employing several techniques to estimate monthly production from underground production stopes. The use of three-dimensional solids generated from survey data has greatly improved the reliability and confidence of monthly production reports. The authors will summarize the methodology currently being utilized at Rosebud.

Jan 1, 1999

By R. W. Smith, R. K. Mehta, X. P. Zheng, A. M. Raichur, M. Misra

Experimentation was per formed on the flotation of apatite and dolomite separately using anionic collectors in the presence of Mycobacterium phlei. Also, the flotation of mixtures of dolomite and apatite in the presence of anionic collectors and in the absence and presence of the bacterium were studied. It was found that M.phlei functions as a depressant for both minerals. However, it functions as a better depressant for dolomite than for apatite. Experimentation was extended to two different Florida dolomitic phosphate rocks. In this investigation a concentrate grade of less than 1.0% MgO was achieved with a 75% P2O5 recovery.

Jan 1, 1999

As mentioned in chapter 8, one of the objectives of the budget is to provide a mechanism for ongoing measurement and control of the production operation. The budget shows expected performance. Actual results are compared to this benchmark to evaluate past performance and to direct future activities. The variances between budgeted and actual results identify specific activities that did not perform as expected (whether negatively or positively). Managers who use variance analysis are essentially applying a management- by-exception philosophy. Individual organizations will determine variances that reflect their own processes and managerial interests, but these variances all follow the approach outlined here. Firms will also vary in the extent to which variances are reported. Some firms use a few variance measures for the overall production organization whereas others calculate variances for individual departments or even individual work areas. As mentioned in chapter 5, it is important to distinguish between controllable and noncontrollable costs when using budgets for control and evaluation.

Jan 1, 1999

By James P. Dorian

istorical records suggest that the gathering of geologic information in China began more than 2,000 years ago. Modern-day geological work in the nation started in the early part of this century but it progressed rather slowly. Before the founding of the People's Republic of China (PRC), there were only 800 people engaged in geological work and only 200 trained geologists among them. According to Minerals and Mining in China, many accomplishments were achieved within China's mining industry during the period of years between 1949, the founding of modern China, and 1997. These include: ? The number of types of minerals with verified reserves increased from 18 (pre-Liberation) to 162 (today). ? Mineral deposit localities grew from 5,123 (pre-Liberation) to nearly 200,000 (today). Of these 200,000 localities, more than three-quarters have verified mineral reserves. ? Minerals extraction and processing contribute to 31 % of the total industrial output value of China (today). ? Regional geological maps at a scale of 1:1,000,000 covering the entire country have been completed, while regional geological and hydrogeological maps at a scale of 1:200,000 covering two-thirds of the country have also been finished (today). ? Before 1949, China was regarded as an oil-poor country. Since the 1950s, China has developed an extensive petrochemical industry. It is largely government-owned except for a limited number of joint ventures. The central government maintains active control over China's most productive fields, including the Daqing field in the Songliao Basin of northeastern China and the Shengli and Liaohe fields in the Bohai Basin of northeastern China. ? Employment in the minerals industry engaged in geological exploration increased from 800 (pre-Liberation) to 1 million (early this decade). The new report provides an overview of the current political and economic situation in China and discusses how this affects the minerals industry. China is in transition between a socialist planned economy and a market economy. This makes it difficult for non-Chinese to keep track of developments. Minerals and Mining in China is divided into 14 chapters that contain detailed statistics, including data on the geographical location and extent of known mineral reserves, production rates, local technical personnel, imports and exports. The report reveals which companies are already active in the area by profiling 50 major investment projects in China's metals and minerals industry. According to its author, China possesses one of the world's largest mining industries, ranking among the leading producers of several metallic and nonmetallic resources. The Chinese mining industry is extraordinarily complex. It has evolved into an overwhelmingly large bureaucracy that was, until the 1980s, shrouded from and misunderstood by the international community. To date, more than 160 types of minerals have been discovered in China. But a significant portion of the minerals and energy base remains largely unidentified and evaluated. And despite China's large reserves of mineral resources, with a population of more than 1.2 billion people, the country ranks among the lowest in the world in terms of proven reserves per capita. In addition, mining recovery rates in China average about 50%, significantly

Jan 1, 1999

By F. Tanaka

In April 1999, a two-year campaign of the Mitsubishi furnaces was achieved at Naoshima Smelter; the present one is expected to be extended much longer. An overview of basic technology for decreasing refractory wear in the Mitsubishi Process is presented. One of the main features of the process is the use of top blowing lance technology which has a different effect on the furnace refractory than other conventional processes. The refractory wear of concern is hearth wear caused by top blown powder injection, wear of the side wall caused by splashing droplets, and wear of the bath level refractories caused by surface waves of melts in the furnace. These have been systematically investigated for many years. This paper describes the results of various model tests and their application to practical furnace design and operation.

Jan 1, 1999

By D. A. Robbins

The application of remote sensing for environmental measurements is already being utilized. Aircraft mounted imaging spectroscopy has been utilized to evaluate areas of historical mining operations as well as active mine sites. To the extent that remote sensing can provide more sensitive, cost effective, and timely monitoring potential, the technology is of interest to the industry. Questions remain about the application and validation of the data and the availability of the technology in the private sector. This presentation will discuss some of the potential uses, benefits, and concerns related to remote sensing and efforts to monitor the technology's development.

Jan 1, 1999

By J. E. Dutrizac

Mineralogical studies were carried out on nodulated copper cathodes from three primary refineries to characterize the nodular growths and to elucidate the causes of the nodulation. Nodulation is often initiated at the surface of the starter sheet or the stainless steel plating blank, although a layer of smooth copper sometimes is deposited before nodulation commences. In some instances, the "roots" of the nodules exhibit a pronounced dendritic texture that is associated with an abundance of cavities. Slimes particles are not usually associated with these growth features which lead to a globular surface deposit. The globules sometimes develop into larger nodules, and this type of nodulation is likely caused by improper addition agent concentrations. The nodules on most cathodes, however, exhibit "roots" at the contact with the substrate that are associated with microcavities and large clusters (>40 µm) of slimes particles. The slimes constituents are commonly Ag powder, PbSO4 and Cu2(Se,Te) but not AgCu(Se,Te) or Ag,(Se,Te). The size of the slimes clusters, rather than their composition, appears to be the important factor causing the copper to grow into nodules. Tiny individual slimes particles themselves do not appear to cause cathode nodulation.

Jan 1, 1999

By Eric Kelley

Having been retained as a legal expert for the fatality at the Canberra, Australia project, it made me aware of how good intended blasters profess to be implosion experts. Owners and contractors can be misled by these representations, seeing a video of Directionalized Structures constructed of reinforced concrete may be impressive to watch, but lack sound evidence of the true mechanics of an actual “implosion”; on steel structures more prevalently. If any well intended blaster comes to a determination that he can implode a structure, it should be not be construed he cannot. It should be well investigated that the specific blaster has verifiable experience. What happened in Australia reflects on all end users of explosives. I have heard a direct quote in our project in Alberta, “We don’t want to have what happened in Canberra”. Such a tragedy could have, and should have been avoided. Simple by using the “Right Tool for the Job”. We should sideline egos and economics. Would any competent blaster compromise his or her reputation, company or insurability? More importantly, have an honest conscience knowing that if the proper explosive is available, use it, don’t shortcut it. If possible expand the schedule. Better, yet, examine all avenues before the project, and last, cancel the project. A human life is our best asset and should not be compromised.

Jan 1, 1999

By R P. Langford, T A. Moore

Over the last 15 years Indonesia has experienced a surge in coalexploration, which has led to the development of a major export industry. This coal exploration has improved the understanding of the geology of the Indonesian coal deposits. The main economic coal deposits are of Eocene and Miocene to Pliocene age, which mainly occur in Kalimantan and Sumatra and were formed from peat deposits in an equatorial paleoclimate similar to that prevailing today. Some of these peats were domed peats, which grew above the normal water tables, under a climate of year-round rainfall; these peats grew above the level at which waterborne mineral matter can enter the system, resulting in low ash and sulphur, and locally very thick coal. It is believed that such peats have formed the unusually thick, low ash, and low sulphur Miocene coals of Indonesia. Coal deposits of Eocene age are typically characterised by thinner seams, with relatively higher contents of ash and sulphur. The Miocene coals and Eocene coals both appear to have formed in lacustrine, coastal plain or deltaic depositional environments, similar to the modern peat-forming environments of eastern Sumatra and parts of Kalimantan. The Eocene coals formed mainly in extensional tectonic settings. Miocene - Pliocene coal deposits formed in a range of tectonic settings.

Jan 1, 1999

By Jose Hector Figueroa P.

Mexicana de Cananea, S.A de C.V. is a major copper producer mining a large deposit of the disseminated porphyry type considered one of the largest copper resources of the world with 2.7 billion tons of 0.60% copper for the mill plus 4.1 billion tons of averaging 0.26% copper for leaching. Mining of low grade sulfide leach ore, has been an important part of the overall production of the open pit mine which started in 1944. Before this time all the mining in Cananea was by underground methods. The leaching process in Cananea began on the 1920's with in situ operations in the underground mine and small dumps up to the 1950's. Large scale leaching operations began in 1960 and the copper solutions produced were treated in precipitation plants until 1,980 when the first SX/EW Plant was put in operation in Cananea. Leaching action is essentially ferric-bacterial, with no fiesh acid added to the leaching solutions. Traditionally, 5540% copper extraction is recovered fiom ROM, 70- 120 meter high leach dumps in 80 months of leaching. Cananea has successfully improved copper recoveries by implementing several actions that include: 1. Stripping of old dumps. 2. Leaching of old dumps through slotted casing. 3. Crushing conveying leach ore to minus 8 inch and stacking it in 30 meter lifts. As result of these actions, copper recovery has been increased' to about 70% of total copper with actions 1 and 2 and up to 85% in half the time by crushing-conveying the leach ore, based on the same solubility index of the run-of-mine ore. This paper describes the above actions that were implemented to enhance the leaching recoveries from. sulfide leach dumps and the economics of such actions.

Jan 1, 1999

By C. Camurri

Results from the Metallurgical Department of Universidad de Conception showed that fire-refined copper could be rolled without previous remelting for deoxidation. The goal of this work is to determine the rheology of fire-refined copper from tensile tests at different temperatures and strain rates, and Ford plane compression tests. All that in order to simulate and calculate rolling process variables. For rheology hardness coefficients, n variables between 0.28 at 600°C and 0.46 at ambient temperature are obtained. The sensibility coefficient for strain rate m varies between 0.056 at 600°C and 0.006 at ambient temperature. The activation energy for plastic flow Q in the considered temperature range is 1436 cal/mol.

Jan 1, 1999

By William H. Langer

U.S. Geological Survey (USGS) recently initiated the Front Range Infrastructure Resources Project. This is a multidisciplinary study along the Rocky Mountain Front Range from Pueblo, Colorado, to Cheyenne, Wyoming, and is designed to collect, compile, and analyze new and existing data on natural aggregate (stone, sand, and gravel), as well as water, and energy resources. To identify aggregate resources in the Front Range, a 1:500,000-scale reconnaissance map showing locations and quality of both bedrock and surficial sources of natural aggregate in the Front Range urban corridor was prepared by processing the digital geologic maps of Colorado and Wyoming. The first step of the process was to identify map units as either bedrock or unconsolidated material. Bedrock was classified according to type (i.e., limestone, granite, gneiss, etc.), which in turn was classified based on the suitability of the bedrock for use as crushed stone. Unconsolidated materials were classified according to relative age, with the older, more weathered materials being defined as less suitable for use as aggregate than younger materials. As a spin-off from the Front Range Project, the techniques developed for analyzing the Front Range geology have been modified and expanded to include all of Colorado and New Mexico. More detailed digital aggregate maps (1:24,000 scale) are being prepared in collaboration with the Colorado Geological Survey (CGS). Maps from the CGS "Atlas of Sand, Gravel and Quarry Aggregate Resources, Colorado Front Range Counties" show the distribution of potential resources of sand and gravel and provide general information about the physical properties of the resources. These maps are being digitized and merged into a single Geographic Information System (GIS) data base. In addition, the project is adding more specific information to the maps about deposit thickness, volume, and quality. This additional information is being obtained through field-characterization studies and modeling activities. The GIs data base can be displayed and queried using off-the-shelf software such as ArcInfo?, ArcView?, and Map Professional?. In addition, the USGS is developing a decision-support system to assist users in analyzing various land-use options on resource availability.

Jan 1, 1999