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By J. H. Schloen

"One of the most important phases in Canada's relatively rapid development of its metal mining and refining industries was launched in 1928 when the directors of Noranda Mines Limited decided to establish an electrolytic copper refinery ""somewhere in Eastern Canada”. Noranda's president, J.Y. Murdoch, had already evolved the company's ""mine to market"" policy and was determined to prove the economic feasibility of refining Noranda copper in Canada. The time appeared to be ripe as buoyant business conditions continued into 1929. In addition, proven ore reserves at the Horne Mine in northwest Quebec had virtually tripled and the price of copper had reached a healthy 15 cents per pound. Letters Patent incorporating the company bearing the date February 6, 1929 had been granted by the Secretary of State in accordance with an application that specified a capital structure of $2 million divided into 20 000 shares with a value of $100 each. Noranda assumed 70% of the original investment in the proposed refinery, while the Nicholas Copper Company of New York (which later became Phelps Dodge Corporation) and British Metal Corporation Ltd. of London, England, each were responsible for 15%. Nicholas Copper Company agreed to supply the design and to supervise the construction of the refinery and British Metal Corporation would act as sales agent and market the refinery's products."

Jan 1, 1999

By Fathi Habashi

The year 1987 marked the centennial of the beginning of modern hydrometallurgy. On October 19, 1887 British Patent No. 14174 entitled Process of Obtaining Gold and Silver from Ores was issued*. The discovery was made by John Steward MacArthur (Fig. 1), a chemist-metallurgist, supported and assisted by Robert and William Forrest, two brothers practicing medicine in Glasgow. The discovery was made in the basement of their clinic. The process, which became known as the cyanidation process in reference to the alkali cyanide reagent used, immediately received industrial success in New Zealand in 1889 and in South Africa in 1890t. It displaced the chlorination method which had been in use. In 1903 MacArthur was awarded the first Medal of the Institution of Mining and Metallurgy in London1131 - The cyanidation process was responsible for the doubling of gold production in the world in the two decades which followed its first application (Fig. 2). To the modern metallurgist, it may be surprising to think of MacArthur coming across an obscure reagent such as an alkali cyanide as a leaching agent for gold ores. It is the purpose of this paper to discuss the background and the factors that led to this invention, the development of the understanding of the process, and the application of modern technology.

Jan 1, 1999

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999

By N. E. Ablesimov

Electron probe X-ray microanalyser of a coating deposited with "Elitron¬22A" electrospark alloying (ESA) set (anode - Cr, base-catode - chrome vanadium steel) has shown that the zone of phase forming can be divided into three parts: the coating itself, diffusion zone and a thermal affection zone in the base material. Waves of iron and chrome concentrations have been found in the diffusion zone. The authors interprete them as a phenomenon of substance self-organizing in the 30 pill deep diffusion zone, characterized by a change of compositions during the transfer of material from the coating to the base: coating - 20 µm (FeCr2), diffusion zone - 30 µm (Fe3Cr, FeCr, Fe4Cr, Fe2Cr), base - steel (Fe - 87 %, Cr - 12 %, V - I %). This ESA phenomen has been noted for the first time. It may be relative to the phenomenon of periodic formation of secondary products during the mutual diffusion of reacting substances in the case of a one-way reaction. Similar regular structures may appear in the diffusion zone during ESA of vanadium steels with vanadium, manganese steels with manganese and so on.

Jan 1, 1999

By J. Wagner, P. Eger, G. Melchert

In 1991, LTV Steel Mining Company decided to close an open pit taconite mine in northeastern Minnesota, using a passive treatment approach consisting of limiting infiltration into the stockpiles and wetland treatment to remove metals. Over 50 million metric tons of sulfide-containing waste had been stockpiled adjacent to the mine during its 30 years of operation. Drainage from the stockpiles contained elevated levels of copper, nickel, cobalt and zinc. Nickel is the major trace metal in the drainages, and prior to closure annual median concentrations ranged from 1.5-50 mg/L. Copper, cobalt and zinc are also present but are generally less than 5% of the nickel values. Median pH ranges from 5.0 to 7.5, but most of the stockpile drainages have pH greater than 6.5. Based on the chemical composition of each stockpile, a cover material was selected. The higher the potential a stockpile had to produce acid drainage, the lower the permeability of the capping material required. Covers ranged from overburden soil removed at the mine to a flexible plastic liner. Predictions of the reduction in infiltration ranged from 40% for the native soil to over 90% for the plastic liner. Five constructed wetlands have been installed since 1992, and have removed 60-90% of the nickel in the drainages. Total capital costs for all the infiltration reduction and wetlands exceeded $6.5 million, but maintenance costs are less than 1% of those for an active treatment plant. Since mine drainage problems can continue for over a hundred years, the lower annual operating costs should pay for the construction of the wetland treatment systems within seven years.

Jan 1, 1999

The Gold Ridge Mine is an open-cut gold mine in the Solomon Islands. The mine is owned and operated by Gold Ridge Mining Limited, a wholly owned subsidiary of Ross Mining NL. At the invitation of the Solomon Island Government, project construction commenced in July 1997 and gold production commenced in August 1998. The mine is the countryÆs first, and represents a major milestone in the development of the Solomon Islands. At the time of project approval and construction, there was a growing awareness in the country of the potential impacts of mining in the tropics, partly due to unfavourable publicity surrounding a number of other mining operations in the Pacific region. The management of environmental impacts was therefore an important consideration in the approval of the project, and continues to receive a high level of attention from the Government and community. Ross Mining did not commit to the Gold Ridge Project until it had satisfied itself that all waste rock and tailings could be safely contained on-site, and that the standards normally expected of a mine in Australia could be met. Ross Mining approached the approval, construction, and operation of the Gold Ridge Mine with a set of operating principles that met Government and community concerns. These were:best practice environmental management; operation of the mine in accordance with standards expected of mining operations in Australia; independent peer review of key technical aspects; on-going consultation with Government and community; and equitable transfer of wealth to landowners and the local community. As a consequence, the Gold Ridge Mine has developed into a successful mining operation with a high level of support from local landowners, the general community and the Central and Provincial Governments of the Solomon Islands.

Jan 1, 1999

By G. Bonifazi

Certain deposits of incoherent materials which are near the surface and exploitable by open-pit mining may be characterized in real time before they are mined through an analysis of ground-surface imagery. If the slice to be stripped is not overly thick, in fact, surface texture and color properties may be extrapolated to its entire thickness. Image analysis techniques to process ground surface images acquired in situ (or in the laboratory shortly after their acquisition) which yield pattern vectors representative of RGB color component distributions and HSB texture parameters have been developed. The techniques were applied to a mineral sandy ore deposit containing three different lithotypes. Geostatistical analyses showed that the data used to characterize the lithotypes were reliable. The correct recognition of the lithotypes was carried out using a multi-barycenter classification algorithm. Such in situ image-analysis procedures open the way to the proper selection of the ore to be mined, or the proper way for run of mine (r.o.m). processing, or the appropriate blend to be processed before or at the same time as the mining process itself is enacted.

Jan 1, 1999

By K. C. Mills, P. N. Quested, A. P. Day, R. F. Brooks

"Methods have been developed to measure the physical properties of molten materials relevant to the fluid flow in high temperature processes. Data for the densities, viscosities and surface tensions of Al-, Ni- and Fe-based alloys are compared with (i) values for the pure metals and (ii) estimated values obtained from models making use of chemical composition of the alloy. Experimental values for metallurgical slags are also given and compared with estimated values.1 IntroductionPhysical property data has proved very useful in improving process control and product quality. For instance, in the continuous casting of steel the viscosity (TJ) of the mould flux is important since it determines (i) the optimum casting conditions, nVc = 2.5±1 dPas (m min-1) where V c is the casting speed and (ii) the level of slag entrapment (which leads to inclusions) in the metal. Thus data for properties like viscosity are exceedingly useful in understanding the process and the problems encountered and the causes of defects and problems.Another interesting development which has helped to increase our knowledge of processes and improve process control and product quality is the development of mathematical models of the fluid and heat flow in the process. These models have been developed to the stage where one of the prime requirements is for good physical property data for the industrial materials involved. Recently, Oxley [1] has shown that the use of reliable, experimental, property values for the commercial alloy in a commercial software package produced a significant improvement in the prediction of casting defects. Thus reliable property data are required for liquid metals but also for (i) liquid slags since many processes involve the use of a slag to refine and protect the metal or to lubricate the mould and (ii) refractories, sand and investment moulds."

Jan 1, 1999

By Asa Weber

With continuing pressure from stockholders not only to maintain but to increase mineral revenues, producers have increased plant capacity. Depressed mineral prices have accentuated the trend toward higher production rates to maintain consistent cash flow, and these same trends have promoted the development of large-scale processing equipment. In addition to the need to handle increased throughput, larger flotation equipment can result in decreased capital-equipment and operating costs. The development of larger column and conventional flotation equipment relies, in part, on suitable scale-up procedures. To properly scale-up large flotation cells and columns, certain constraints and design parameters must be taken into consideration, including velocities in the vessel, residence time, solids suspension, and lip loading. This paper will review the design constraints and scale-up criteria for WEMCO® flotation cells. Scale-up criteria are augmented with computational-fluid- dynamics analyses and high-speed imaging techniques, as well as multiple regresesion analysis of in-plant operational data.

Jan 1, 1999

By S. Sener

In this investigation, the changes in the grindability of both ulexite and colemanite related with the different structural modifications created by the heat treatment were examined with respect to work index (Wi). The effects of the heat treatment temperature and time on grindability index were also investigated. It was observed that, heat treatment significantly affected on the grindability of ulexite. The work index of original ulexite was found 7.11 kWh/shton and decreased to 3.5 kWh/shton level within 200-480°C for 60 minutes. On the other hand, the work index of original colemanite was found as 6.48 kWh/shton and no appreciable change was observed when heated up to 320°C. Thermally assisted comminution can be used to improve the grindability characteristics of ulexite. Besides, the different behaviour of ulexite and colemanite under heat treatment can be used for their separation. The artificial mixture of ulexite and colemanite could be separated with over 90% recovery by utilizing their different grindability characteristics by thermal treatment, semi-autogeneous grinding and screening.

Jan 1, 1999

Flotation testing has been done at laboratory scale on hematite mineral and ore samples using stage additions of various hydroxamates. Chemisorption of hydroxamate species onto the hematite surface was inferred from the results, possibly involving both the undissociated hydroxamic acid and hydroxamate ion as maximum recovery occurred close to the pKa of the hydroxamic acid. Flotation testing on a specular hematite ore containing 40 per cent Fe and 42.5 per cent silica gave highest iron grades in concentrate at pH 6, in contrast to published data which suggested pH 9 as the optimum value for ore processing. Using octyl hydroxamate, a rougher concentrate assaying 67 per cent Fe at 51 per cent recovery was obtained using four stage additions of 50 g/t at pH 6. For lower grade concentrates still meeting the chemical analysis for pigment grade micaceous hematite (minimum Fe assay 60 per cent) iron recoveries of 80 per cent were possible for stage additions of 50 g/t octyl hydroxamate in the pH range 6-8.

Jan 1, 1999

By D. A. Salinas G., A. H. Castillejos E.

Pachuca tanks are commonly used in the hydrometallurgical industry to carry out leaching operations. The fluidynamic characteristics of the liquid phase, resulting from the injection of gas into the draft tube, are important to achieve the complete suspension of the mineral particles and has a decisive influence in the mass transfer processes occurring in this reactor. This study investigated the effect of different design and operating characteristics on the liquid velocity field. using a laboratory-scale Pachuca tank. The transparent model was filled with water, and air was injected through the bottom in the absence of mineral particles. The liquid velocities over the whole reactor were measured under several experimental conditions using particle image velocimetry (PIV). This technique allowed to obtain a very detailed picture of the liquid motion even in the draft tube, as long as bubbles were absent from the measured field of view. The experiments have shown that the liquid velocities increase with increasing the draft tube to tank diameters ratio, the distance from the conical bottom to the draft tube entrance, or the gas superficial velocity. On the other hand, an increase in the water level with respect to the draft tube outlet caused a decrease. A mathematical model, which used the no-slip model, to calculate the variation of axial effective density along the two-phase region, was found to predict liquid velocity fields which agree very satisfactory with the experimental results obtained under all the conditions studied.

Jan 1, 1999

By Kenneth V. Luza

Underclays are associated with coals found in eastern Oklahoma. These coals are of bituminous rank and are in beds of Middle and Late Pennsylvanian age. They occur in an area of about 8,000 mi2, within the southern part of the Western Interior Coal Region. The rocks of the area consist of a thick series of sandstones, shales, underclays, coals, and limestones. There are more than 40 beds of bituminous coal in the state, but only 12 of these have been mined over large areas. The 12 are, from oldest to youngest: the lower Hartshorne, upper Hartshorne, McAlester (Stigler), upper McAlester, Cavanal, Rowe, Secor, Weir-Pittsburg, Mineral, Croweburg, Iron Post, and Dawson coals. None of the underclay associated with these coal beds is known to have been exploited commercially. Nine samples of underclay from beneath the Croweburg coal were collected over a wide area in the eastern Oklahoma coal field for evaluation. The underclays are usually shades of gray with brown or orange iron-oxide staining. Although soft and plastic in some places, they are generally hard and slickensided, and contain abundant carbonized plant fragments. Bulk chemical analyses, clay mineral identification, and ceramic tests were performed on each underclay sample. The dominant clay minerals are illite and kaolinite with some mixed-layer clays. Silica (Si02) ranges from 45.96% to 59.03% and alumina (Al2O3) varies from 14.98% to 23.60%. The U.S. Bureau of Mines Tuscaloosa Re- search Center conducted the ceramic evaluations. Samples were slow fired from 1,000°C to 1,250°C in 50°C intervals. Bulk density, color, percent linear shrinkage, and percent absorption were determined for each slow fire test. All Croweburg underclay samples are best suited for building brick.

Jan 1, 1999

By Thomas E. Newman

This paper is a case study using new laser-terrain-mapping technology by EagleScan, Inc., for creating topographic maps. Holnam, Inc., has used this technology to create maps and volumetric calculations of several mines in the United States. The information is superior to conventional methods through accuracy, manpower, time, and cost. Holnam, Inc., was the first cement manufacturer to use the Digital Airborne Topographic Imaging System (DATIS?). The technology uses the DATIS? to produce high-resolution terrain maps and volumetric assessments of any area. DATIS? is a mapping instrument that integrates (1) a Light Detection and Ranging (LIDAR) instrument to measure terrain elevation using laser light, (2) a large-format digital camera, (3) a relative position Global Positioning System (GPS) to measure aircraft position, and (4) an Inertial Measurement Unit (IMU) to measure aircraft attitude. The DATIS? can measure up to 220,000 elevation samples per mil. The system continually collects data on the aircraft's position and measures the time for each laser pulse transmission to return from the ground, giving each sample a GPS reference. The system can operate at night, in overcast sky, and during high-wind conditions and can measure terrain below vegetation cover, unlike standard aerial photography used for traditional surveying and mapping. Surveyed ground-control panels are no longer necessary with this new technology, and only one ground GPS base station located within 60 mi from the aircraft position is required. A computer elevation-point data file is created with the x, y, z coordinates of each laser elevation sample. With this file, CAD engineering programs can create topographic maps that rival products using conventional aerial mapping techniques. Volumetric measurements of stockpiles and pits are also available due to the high density of points collected from an area. This new technology radically changes the turnaround time for map users, giving a product in the format used by today's cartographers. The time line from flight to maps is measured in days instead of weeks.

Jan 1, 1999

By Robert Hivick, Frank Sames

The control of environmental effects, especially blast vibration and airblast, has become a dominating planning criterion for most surface blasting operations. Compliance with existing regulations is generally achieved through constraints in the blast design, or monitoring programs. Commonly, blast vibration and airblast signals are rated and compared by their maximum amplitude and the associated principal frequency. However, this data reduction limits the interpretation of the influence of varying blast design parameters on the vibration and airblast.

Jan 1, 1999

By David E. Siskind

"This report describes recommended vibration monitoring and assessment practices at blasting sites.Intended is regular monitoring, tracking of trends, responding to complaints of alleged damage, and the technical and data aspects of addressing lawsuits."

Jan 1, 1999

By Robin D. Rogers

Room temperature ionic liquids (RTIL) can replace certain traditional organic solvents in liquid/liquid extraction of metal ions from aqueous systems. The very low vapor pressure and non-flammable nature of RTIL warrant consideration of these neoteric solvents for new processing technologies which will reduce pollution, Increase safety, and lower costs. Metal ion separations in RTIL, however, will typically require the use of an extractant and research is needed to identify suitable selective extractants which have appreciable solubility in the RTIL and low solubility In the aqueous phase. Choice of extractant should also take into account the toxicity, expense, and disposal of the ligand.

Jan 1, 1999

By J. K. Mohanty, D. Panda, P. K. Sahoo, R. K. Paramguru, K. C. Nathsarma

Ferromanganese slag, a product of the manganese industry, was characterized mineralogically. The slag, which contains high Mn values, was characterized using optical microscopy, XRD analysis and electron microscopy. No separate Mn-bearing oxide mineral phase was found. The slag is amorphous, and no crystalline phase was identified in the hulk sample by XRD, However, in. fine fractions, quartz was identified. Scanning electron microscopy (SEM) revealed the presence of Mn, Si, Al and Ca in the matrix without the development of a mineral phase. Leaching experiments using H2SO4 were carried out to determine if Mn could be extracted from the slag. At room temperature, almost 100% of the manganese could be dissolved at a solid-liquid ratio o f 1:10 by leaching with dilute sulfuric acid. The impurities could be precipitated by pH adjustment to produce a manganese sulfate solution suitable for the production of MnO2 or electrolytic Mn metal. Based on the laboratory-scale experiments, a suitable process is proposed to recover manganese values from the, ferromanganese slag.

Jan 1, 1999

By K. Hanna

Early identification of adverse geologic conditions and high stress concentrations during the high-speed extraction of coal using modern mechanized long wall systems is a major challenge facing the mining industry. Often, unexpected geologic anomalies that affect rock mass quality are encountered more rapidly, leaving the mine operator with insufficient time or information to deal with the changing ground conditions. The RockVision3DTM seismic tomographic system, developed by NSA Engineering, Inc., offers substantial benefits over conventional geologic/stress-detection methods and has been used successfully in coal mines worldwide. Tomographic images, produced economically and in near-real time, are easy to interpret, allowing mine operators to deal with potential hazards on a day-to-day basis. This paper focuses on the application of RockVision3DTM technology for delineating hazards caused by stress and geologic anomalies. Case studies for two bump-prone coal mines will be discussed. For example, (1) in a German deep (>1,130 m) mine, the drilling-yield method was used to verify the effectiveness of this technology in detecting stress anomalies ahead of longwalling; (2) in a Polish mine (-500 m deep), two longwall panels 4 km apart were monitored to assess structural and stress-related factors contributing to differences in mining conditions and magnitude of structural failures.

Jan 1, 1999

By Jr. Langhans, J. S. McPartland

"The presence of zinc in cyanide solutions is generally thought to not have an adverse effect on precious metal recovery or recovery rate by heap leach processing. However, analytical interferences of zinc in solution can cause problems in accurately determining and controlling cyanide concentration in the leach solution, leading to increased cyanide consumption. Analytical methods and the chemistry of cyanide in the presence of zinc are reviewed. The effects of solution pH and zinc concentration on the free cyanide determination were evaluated in detail. Use of the standard silver nitrate titration and a modified titration method for controlling cyanide concentration during heap leaching were investigated experimentally. The practical implications of cyanide heap leaching in the presence of cyanide soluble zinc minerals are discussed.IntroductionThe presence of zinc in precious metal cyanidation circuits is not uncommon. Zinc can be introduced into cyanide leach solutions through dissolution of various zinc minerals1>, or through the use of a Merrill Crowe (zinc precipitation) circuit. Zinc minerals typically occur infrequently and in low concentration in gold ores, but are more abundant in silver ores. Merrill Crowe systems are most commonly employed for recovery of precious metals from solution for relatively high silver ores. It is desirable to control the amount of dissolved zinc in a cyanidation circuit for several reasons. Excessive zinc build-up in cyanide leach solution can, under certain circumstances, inhibit precious metal dissolution and adversely affect solution recovery systems. Additionally, high zinc concentrations can lead to excessive in-process cyanide inventories and potentially, to higher cyanide consumption"

Jan 1, 1999