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By Andreas Rubo, Stephen Gos

Over the past couple of decades several endeavours have been made to develop lixiviants with the intention of replacing cyanide in gold leaching. In 1980s these endeavours were largely economically driven, due to cyanide shortages at that time. In more recent times, the driving force has shifted to occupational health and environmental considerations. It is often argued that the high acute toxicity of cyanide alone makes it worthwhile considering to replace it completely by less toxic alternative lixiviants. This has led to having to consider more criteria in the choice of any alternative lixiviants, which have often not been taken into account in the past. The intention of this paper is to review these alternative lixiviants and also review the criteria, which have ultimately led to most of these lixiviants never having found any large scale application, if they passed laboratory stage at all. It is also intended to show, that by handling and treating cyanide in a proper manner, the overall profile for the use of cyanide compared to these alternative lixiviants is very favourable. The question to really be answered is whether there is actually any chemical or process applicable to gold leaching that does not show the high toxicity potential of cyanide and that is still favourable with regard to looking at a broader spectrum of criteria and not only acute toxicity.

Jan 1, 2000

By S. Healey, P. Jean, G. Deschenes, M. Fulton

Three years ago, the New Britannia Mine started a project to improve productivity of its cyanidation plant. Results indicated that gold dissolution was strongly influenced by sulphide minerals and that the slower gold dissolution rate had a detrimental effect on overall gold recovery. The leaching strategy had to be modified to address this issue. Changes to the leaching circuit proved to be very successful. The first action was to introduce lead nitrate in the leaching circuit. The strategy of addition of lead nitrate was upgraded in three steps. An on-line free cyanide analyser was installed and the strategy of cyanide addition automated. The enhancement of the leaching kinetics have resulted: an 4% increase of gold recovery, from 87.8% in 1996 to 91.9% in 1999, which represents a reduction of 0.17 git Au in the leach residue; an average of 1330 additional extracted gold ounces per year from 1997 to 1999; a 21 % reduction in the cyanide consumption; the shut down of the cyanide destruction plant; and finally a contribution to the 27% reduction in the overall production cost per tonne of ore.($ 3 per ton). The significant increase of the throughput was instrumental in the reduction of the processing cost. In 1999, the improvement of gold recovery represented an additional gross revenue of $c""l.9 Million. The project is discussed in details in this paper.

Jan 1, 2000

By HJ Marais, J A. van Niekerk

An investigation was initiated by BILLITON Process Research and Gold Fields Limited for the efficient removal of thiocyanate and cyanide from leach solutions. This led to the development of the ASTERTM process, an acronym for Activated Sludge Tailings Effluent Remediation. The biological degradation of thiocyanate and cyanide in effluents provides an alternative treatment to the more traditional processes. This occurs with a large number of micro-organisms which include bacteria, actinomycetes and fungi. Cyanide and thiocyanate are degraded to ammonia and carbon dioxide. Most forms of cyanide-metal complexes are generally removed through a co.mbination of oxidation and sorption into the biofilm/biomass. Since the ASTER™ process has commercial applications, a patent has been lodged for the ASTER™ process. A culture containing thiocyanate degrading organisms has been deposited with the Australian Government Analytical Laboratories (AGAL). The identification of the bacteria is in progress. Tailings arising from a cyanidation process tend to contain cyanide and thiocyanate. The presence of these species prevents the recycling of this water upstream to a bioleach circuit due to its toxicity to the bacterial culture. Increasingly stringent legislation for the land disposal of cyanide containing solutions also necessitates the treatment of the solutions before disposal.

Jan 1, 2000

By Andre R. Laplante

Gravity gold recovery can be of significant economic importance for gold copper ores that cannot be directly cyanided. Gravity is typically followed by flotation to produce a smeltable copper concentrate. Flotation tails gold values are often too low to justify a cyanidation circuit. Given this typical scenario, a very effective gravity circuit can yield higher overall gold recoveries (i.e. gravity + flotation), and also improve the NSR of gold. Typical scoping work, whilst well suited to investigate the downstream circuit, be it flotation or cyanidation, often overestimates ore variability to gravity recovery and fails to yield the data needed to predict plant gravity recovery and design the optimum gravity circuit. This presentation examines why typical scoping work fails to address gravity recovery adequately and shows how a standard test to characterize gravity recoverable gold (GRG) can provide the missing data. Case studies are presented and used to illustrate the concepts of recovery effort and aggressive gravity recovery.

Jan 1, 2000

By S. Tavani, R. E. Browner, R. Dunne

Lead is used in CIP/CIL circuit to increase the leaching rate of gold from ores. At least four mechanisms have been proposed for the action of lead in gold leaching circuits: (I) precipitation of sulphides as highly insoluble lead sulphides preventing consumption of cyanide and oxygen; (2) su,face reaction on sulphide particles forming an insoluble lead sulphide layer peventing dissolution of those sulphides; ( 3) precipitation of lead sulphide, which undergoes further oxidation to soluble lead sulphate recycling the lead to solution,· ( 4) contact reduction of lead onto the gold szaface which then acts as a secondary oxidising agent. Rotating disc studies using a pure gold disc show that small amounts (5ppm) of sulphide ions are sufficient to significantly reduce the leaching rate of gold. Lead increased the leaching rate at small concentrations but at higher levels decreased the rate of leaching. The detrimental effects of lead were only found for a pure solution when leaching the gold disc. Ores mediate the amount of lead available by ads01ption/reaction, thus, reduced leaching rates from excess lead are not serious even when 500ppm of lead ions are added to the sluny. The detrimental effects of sulphide ions could be countered by lead addition during the leaching process. A penalty, in the form of reduced leaching rate, will occur the longer lead addition is delayed. A time lag was noted between the addition of lead and the increased leaching rate when a large concentration of sulphide ions was present.

Jan 1, 2000

By Harrie van Dijk

Feeding laterite nickel slurry into high pressure acid­leach (HPAL) autoclaves in an aggressive environment with slurries heated up to 200°C requires a special pump design. For decades the GEHO piston diaphragm pumps have been used for autoclave feeding at gold ore pressure oxidation plants with slurries up to l 77°C. Lessons learned from these installations have been instrumental in designing second generation feed pumps for processing laterite nickel with operating temperatures of 200°C and a flow rate of 400 m3/h. The Australian nickel industry is using momentarily 8 GEHO positive displacement piston diaphragm pumps. For this application six GEHO ZPM 900 "dropleg" pumps have been supplied to the Murrin Murrin project and two to Bulong.

Jan 1, 2000

By Dan Mackie

Since the production prototype continuous vat leaching pilot plant was installed at Ariel Resources in Costa Rica in 1995, the test results and lessons learned have been invaluable in plotting the future of this method. Vigorous test programs in base and precious metals as well as design developments for studies have shown the advantages, economically, technically, and environmentally that favor this method over current practices in heap leaching and stirred tank leaching. Much larger individual vats have been developed with throughputs as high as 5000 t/d with larger vats envisaged, and there has been a trend towards using vats with ground ore. Five projects are slated to begin detailed engineering this year, three in precious metals and two in copper. Of particular interest to future producers is the ability to deposit d,y, detoxified tailings at a fraction of the cost of conventional methods. Proprieta,y work is ongoing which promises to eliminate the need for tailings dams when using other methods of processing such as flotation. This is of particular importance in light of dam failures around the world in recent years.

Jan 1, 2000

By Frederick W. DeVries

The following charts were presented at the Randol Gold & Silver Forum 2000, held at the Hotel Vancouver (Vancouver, B.C.) from April 18-21, 2000. It must be borne in mind that the "facts" stated and con­clusions drawn by the author were not as the result of a rig­orous technical investigation, but rather as a member of a journalistic team seeking a rapid view for presentation as news to a TV audience. Since the author's visit, some retrenchment on the part of the operators on estimating the cyanide content of the spill seems to have occurred. This does NOT alter the conclusions that (a) the spill was an intolerable embarrassment for the world mining industry, nor (b) the potential damage to future mining investments, should prompt action not be taken: 1. to understand the reasons for the dam failure, and 2. to draw up firm concepts of how to avoid future fail­ures of dams at mining properties containing materials that are toxic, environmentally unfriendly, or with as highly dis­comfiting a profile as cyanide.

Jan 1, 2000

By Jim Smith, Jeff Hudreth, John White

Jan 1, 2000

By Carl-Henrik Knudsen, Rolf Tore Arnesen, Eigil R. Iversen

Recovery of iron and copper from acid mine drainage was studied in pilot scale at a continuous treatment plant at the mine site of the King's mine in Roeros, Norway. The average load on the plant was 1 m3/h. The process tested in this project is a three-step process consisting of: 1) Fe(OH)3 precipitation at pH 3.5, dewatering of iron sludge and transport to ferric chloride plant; 2) after filtration precipitation of residual metals at pH 9, concentration of metal sludge by flotation; 3) extraction of metals from the sludge with sulphuric acid followed by recovery of copper by electrolysis. The copper could be used for local production of different crafts, but this condition needs a further evaluation. The process economy at a full scale plant is evaluated.

Jan 1, 2000

By T Casten

Freeport IndonesiaÆs DOZ (Deep Ore Zone) mine is scheduled to commence production in the second half of 2000. The DOZ will produce 25 000 tpd using mechanised block cave mining methods and will have a number of major improvements when compared to previous block cave mines in the district. The DOZ will have an independent and improved ventilation system, a flexible and efficient truck haulage system, and a more reliable crushing and conveying system than in previous underground mines in the district. This paper will describe the mine plan, haulage, and ventilation systems, and compare them to those used in other operations in the district.

Jan 1, 2000

By C DahnTr-Lindqvist

The Kiruna mine produced about 19 Mt processed iron ore in 1999 using sublevel caving. General failure in the hangingwall has been widely studied and its mechanism is rather well understood. Failure in the footwall is more recent and not perfectly explained. Plane shear failure and Hoek and BrayÆs circular failure charts were successfully used to match the first surveyed failure surfaces. The footwall is not free yet but covered by a caved waste rock abutment whose exact behaviour is poorly known. Based on new field data and numerical models (FLAC), the following paper presents recent improvements in understanding the Kiruna mineÆs footwall failure process.

Jan 1, 2000

By NA NA

Power point slides

Jan 1, 2000

By Arthur P. Chaves, John A. Meech, Vanessa M. Torres

Process choice for a refractory gold ore can become a controversial issue, especially at the early stages of a project. This happens since at preliminary stages, a simple economic comparison among the main process options is not possible as the differences are usually smaller than the precision of estimates. This paper presents a methodology to assess the suitability of each available technologies using a heuristic approach, were technical, economic, operational and environmental aspects are taken into account using a neural network methodology. This methodology is embedded in an expert system for gold ore process design, Intelligold, which is in the final stages of development.

Jan 1, 2000

By MD Cadzow, TW Quaife, DJ Lunt, TS Giraudo

The Macraes Gold Project, operated by Gold and Resource Developments NL, engaged Minproc Limited to assist with the evaluation of a pressure oxidation circuit, this being the key component of a recovery enhancement project. The initial study gave sufficient confidence in the process to enter into project execution. The project is the first to license Newmont Mining Corporation's pressure oxidation technology, which aims to improve gold recovery from the carbonaceous sulfidic flotation concentrate. This paper outlines the fundamental chemistry of the process followed by a description of the plant that was ultimately installed. A summary of the commissioning is given together with an overview of the production results for the first three months of operation. The project ramp-up was rapid, with design temperature and throughput being achieved within days of hot commissioning. Gold recoveries have exceeded expectations and the project has increased the nominal gold output at Macraes from 110,000 oz/y to 150,000 oz/y. Ongoing plant optimisation and problem solving, mainly associated with scale formation, is discussed.

Jan 1, 2000

By Luciano Ramos, Daniel Santos

Igarape Bahia Mine, which is currently the largest gold producer in Brazil, belongs to Companhia Vale do Rio Doce - CVRD and is situated 250 miles south of Belem, state of Para, Brazil. It came into operation in 1992 with the startup of the CIP plant, fed with high grade ore, presently at 3.4gAu/t. The ore is totally oxidized, containing extremely fine particles of free gold. The ore is soft and low cyanide consumer, with a maximum work index of 12kwh/sht. In 1993 a Heap Leaching Plant was set into operation, handling low grade ore of · 1.s g Ault. The Heap Leaching Plant has undergone two major expansions. In 1994 its capacity was raised from lMtpy to 2,2Mtpy and in 1998, with a thorough remodeling of crushing operations, it was raised again to 3.5Mtpy. The CIP plant, which was originally designed with a capacity for l. lMtpy of ore, was expanded to a 2.2Mtpy capacity in 1994. Presently, the CIP plant accounts for most of Igarape Bahia's total gold output, with approximately 220,000oz per year. Igarape Bahia's annual output is around 360.000 oz. Over the last three years, work has been intensified to improve performance of both processes, aiming at maximizing productivity of the two industrial plants. Reduced costs and increased revenues have been given a special emphasis in the unified improvement program. Cost · reduction has involved developing methodologies to rationalize consumption of materials and inputs, while increased productivity has been given top priority as a means of generating increasing revenues. Thus, all of the improvement and development efforts have had a common goal: to increase operating income.

Jan 1, 2000

By Joseph Gambogi

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of futile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

Nov 26, 1999

By Mahesh C. Jha

Molybdenum, a major refractory metal, is widely used as an alloying element in steels and superalloys to improve their corrosion resistance, physical properties and mechanical strength, particularly at elevated temperatures. The current worldwide production and consumption is estimated at about 130,000 tons contained molybdenum per year. Molybdenum occurs in nature as molybdenite mineral and is recovered by a flotation process as a primary concentrate at molybdenum mines and as a byproduct concentrate at copper mines. The concentrate is roasted to a technical-grade molybdic oxide (tech oxide) in multiple-hearth roasters. About 80 percent of the tech oxide is sold, as such or after conversion to ferromolybdenum, for addition to iron and steel. The remainder is further refined to pure oxide and molybdate chemicals that are used in the manufacture of catalysts, specialty chemicals, molybdenum metal and superalloys. This paper discusses the various steps in the extractive metallurgy of molybdenum, from flotation of sulfide concentrate to reduction of pure oxide to molybdenum metal.

Nov 26, 1999

By Chris Twigge

The paper point out development and successful commercial introduction of new technologies into a metalurgicall. The discussion that follows examines the overall issues of implementation from a management perspectiva and will highlight areas where key success factors are often overlooked. The framework presented is structured around the following key themes: The prime incentive for introducing new technologies is broadly one of economics, the implementation of new technologies is, to a large degree, a process of risk management and although the implementation of new technologies revolves around technical and economic issues, in the end the decisiva factor is people. Proper recognition of the human factors is critical to success. In this sense, the above principles are discussed in the sections that follow and include a number of examples to illustrate how technology can be successfully implementad and how it can fail.

Oct 6, 1999

By Donald Gagnon

El presente trabajo señala el proceso de sostenimiento de terrenos en las minas subterráneas a través del estudio de las condiciones geológicas subterráneas del área, con el fin de establecer distintos tipos de rocas que garanticen la instalación adecuada de las fortificaciones. Asimismo se describen las características y propiedades físicas de los difentes tipos de rocas, como el uso de los distintos pernos para el sostenimiento de roca y sus técnicas de instalación.

Oct 6, 1999